Articles | Volume 21, issue 11
https://doi.org/10.5194/acp-21-8999-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-21-8999-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
14 Jun 2021
Research article |
| 14 Jun 2021
| 14 Jun 2021
Towards a chemical mechanism of the oxidation of aqueous sulfur dioxide via isoprene hydroxyl hydroperoxides (ISOPOOH)
John A. Paulson School of Engineering and Applied Sciences, Harvard University, Cambridge, MA 02138, USA
now at: Multiphase Chemistry Department, Max Planck Institute for Chemistry, 55128 Mainz, Germany
Kelvin H. Bates
Harvard University Center for the Environment, Cambridge, MA 02138, USA
Jean C. Rivera-Rios
Department of Chemistry and Chemical Biology, Harvard University, Cambridge, MA 02138, USA
now at: School of Chemical & Biomolecular Engineering, Georgia Institute of Technology, Atlanta, GA 30332, USA
Joshua L. Cox
Department of Chemistry and Chemical Biology, Harvard University, Cambridge, MA 02138, USA
Joshua D. Shutter
Department of Chemistry and Chemical Biology, Harvard University, Cambridge, MA 02138, USA
Frank N. Keutsch
John A. Paulson School of Engineering and Applied Sciences, Harvard University, Cambridge, MA 02138, USA
Department of Chemistry and Chemical Biology, Harvard University, Cambridge, MA 02138, USA
Department of Earth and Planetary Sciences, Harvard University, Cambridge, MA 02138, USA
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Cited
13 citations as recorded by crossref.
- Mechanistic Study of the Aqueous Reaction of Organic Peroxides with HSO3− on the Surface of a Water Droplet H. Li et al. 10.1002/anie.202105416
- The fate of organic peroxides indoors: quantifying humidity-dependent uptake on naturally soiled indoor window glass M. Webb et al. 10.1039/D3EM00041A
- Formaldehyde and hydroperoxide distribution around the Arabian Peninsula – evaluation of EMAC model results with ship-based measurements D. Dienhart et al. 10.5194/acp-23-119-2023
- Hydrolysis reactivity reveals significant seasonal variation in the composition of organic peroxides in ambient PM2.5 Y. Dai et al. 10.1016/j.scitotenv.2024.172143
- Mechanistic Study of the Aqueous Reaction of Organic Peroxides with HSO3− on the Surface of a Water Droplet H. Li et al. 10.1002/ange.202105416
- Hydroxymethanesulfonate formation as a significant pathway of transformation of SO2 H. Zhang et al. 10.1016/j.atmosenv.2022.119474
- Emerging investigator series: aqueous oxidation of isoprene-derived organic aerosol species as a source of atmospheric formic and acetic acids K. Bates et al. 10.1039/D3EA00076A
- Severe atmospheric pollution in the Middle East is attributable to anthropogenic sources S. Osipov et al. 10.1038/s43247-022-00514-6
- Kinetic study of isoprene hydroxy hydroperoxide radicals reacting with sulphur dioxide and their global-scale impact on sulphate formation H. Hata & K. Tonokura 10.1039/D4EM00232F
- Organic Peroxides in Aerosol: Key Reactive Intermediates for Multiphase Processes in the Atmosphere S. Wang et al. 10.1021/acs.chemrev.2c00430
- A possible unaccounted source of nitrogen-containing compound formation in aerosols: amines reacting with secondary ozonides J. Qiu et al. 10.5194/acp-24-155-2024
- Synthesis and Characterization of Atmospherically Relevant Hydroxy Hydroperoxides P. Mettke et al. 10.3390/atmos13040507
- Gas-Phase Oxidation Rates and Products of 1,2-Dihydroxy Isoprene K. Bates et al. 10.1021/acs.est.1c04177
13 citations as recorded by crossref.
- Mechanistic Study of the Aqueous Reaction of Organic Peroxides with HSO3− on the Surface of a Water Droplet H. Li et al. 10.1002/anie.202105416
- The fate of organic peroxides indoors: quantifying humidity-dependent uptake on naturally soiled indoor window glass M. Webb et al. 10.1039/D3EM00041A
- Formaldehyde and hydroperoxide distribution around the Arabian Peninsula – evaluation of EMAC model results with ship-based measurements D. Dienhart et al. 10.5194/acp-23-119-2023
- Hydrolysis reactivity reveals significant seasonal variation in the composition of organic peroxides in ambient PM2.5 Y. Dai et al. 10.1016/j.scitotenv.2024.172143
- Mechanistic Study of the Aqueous Reaction of Organic Peroxides with HSO3− on the Surface of a Water Droplet H. Li et al. 10.1002/ange.202105416
- Hydroxymethanesulfonate formation as a significant pathway of transformation of SO2 H. Zhang et al. 10.1016/j.atmosenv.2022.119474
- Emerging investigator series: aqueous oxidation of isoprene-derived organic aerosol species as a source of atmospheric formic and acetic acids K. Bates et al. 10.1039/D3EA00076A
- Severe atmospheric pollution in the Middle East is attributable to anthropogenic sources S. Osipov et al. 10.1038/s43247-022-00514-6
- Kinetic study of isoprene hydroxy hydroperoxide radicals reacting with sulphur dioxide and their global-scale impact on sulphate formation H. Hata & K. Tonokura 10.1039/D4EM00232F
- Organic Peroxides in Aerosol: Key Reactive Intermediates for Multiphase Processes in the Atmosphere S. Wang et al. 10.1021/acs.chemrev.2c00430
- A possible unaccounted source of nitrogen-containing compound formation in aerosols: amines reacting with secondary ozonides J. Qiu et al. 10.5194/acp-24-155-2024
- Synthesis and Characterization of Atmospherically Relevant Hydroxy Hydroperoxides P. Mettke et al. 10.3390/atmos13040507
- Gas-Phase Oxidation Rates and Products of 1,2-Dihydroxy Isoprene K. Bates et al. 10.1021/acs.est.1c04177
Latest update: 21 Nov 2024
Short summary
We examined the mechanism and products of oxidation of dissolved sulfur dioxide with the main isomers of isoprene hydroxyl hydroperoxides, via laboratory and model analysis. Two chemical mechanism pathways are proposed and the results provide an improved understanding of the broader atmospheric chemistry and role of multifunctional organic hydroperoxides, which should be the dominant VOC oxidation products under low-NO conditions, highlighting their significant contribution to sulfate formation.
We examined the mechanism and products of oxidation of dissolved sulfur dioxide with the main...
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