Articles | Volume 21, issue 10
https://doi.org/10.5194/acp-21-7567-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-21-7567-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
18 May 2021
Research article |
| 18 May 2021
| 18 May 2021
Formation kinetics and mechanisms of ozone and secondary organic aerosols from photochemical oxidation of different aromatic hydrocarbons: dependence on NOx and organic substituents
Hao Luo
Guangdong Key Laboratory of Environmental Catalysis and Health Risk
Control, Guangdong-Hong Kong-Macao Joint Laboratory for Contaminants
Exposure and Health, Institute of Environmental Health and Pollution
control, Guangdong University of Technology, Guangzhou 510006, China
Guangzhou Key Laboratory of Environmental Catalysis and Pollution
Control, Key Laboratory of City Cluster Environmental Safety and Green
Development, School of Environmental Science and Engineering, Guangdong
University of Technology, Guangzhou 510006, China
Jiangyao Chen
Guangdong Key Laboratory of Environmental Catalysis and Health Risk
Control, Guangdong-Hong Kong-Macao Joint Laboratory for Contaminants
Exposure and Health, Institute of Environmental Health and Pollution
control, Guangdong University of Technology, Guangzhou 510006, China
Guangzhou Key Laboratory of Environmental Catalysis and Pollution
Control, Key Laboratory of City Cluster Environmental Safety and Green
Development, School of Environmental Science and Engineering, Guangdong
University of Technology, Guangzhou 510006, China
Guiying Li
Guangdong Key Laboratory of Environmental Catalysis and Health Risk
Control, Guangdong-Hong Kong-Macao Joint Laboratory for Contaminants
Exposure and Health, Institute of Environmental Health and Pollution
control, Guangdong University of Technology, Guangzhou 510006, China
Guangzhou Key Laboratory of Environmental Catalysis and Pollution
Control, Key Laboratory of City Cluster Environmental Safety and Green
Development, School of Environmental Science and Engineering, Guangdong
University of Technology, Guangzhou 510006, China
Taicheng An
CORRESPONDING AUTHOR
Guangdong Key Laboratory of Environmental Catalysis and Health Risk
Control, Guangdong-Hong Kong-Macao Joint Laboratory for Contaminants
Exposure and Health, Institute of Environmental Health and Pollution
control, Guangdong University of Technology, Guangzhou 510006, China
Guangzhou Key Laboratory of Environmental Catalysis and Pollution
Control, Key Laboratory of City Cluster Environmental Safety and Green
Development, School of Environmental Science and Engineering, Guangdong
University of Technology, Guangzhou 510006, China
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Cited
14 citations as recorded by crossref.
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- Unraveling the Unique Role of Methyl Position on the Ring-Opening Barrier in Photocatalytic Decomposition of Xylene Isomers R. Chen et al. 10.1021/acscatal.2c01418
- Odorous organic gas emission characteristics from cooked food wastes during aerobic decomposition Z. Wang et al. 10.1016/j.jclepro.2023.139961
- Non-target analysis of crude oil photooxidation products at high latitudes and their biological effects Z. Redman et al. 10.1016/j.chemosphere.2024.141794
- A New Type of Quartz Smog Chamber: Design and Characterization W. Ma et al. 10.1021/acs.est.1c06341
- Removal efficiencies of emissions of volatile organic compounds by adsorption systems installed in small-scale auto-repair painting operations H. Chun & M. Song 10.1007/s11869-023-01451-9
- A possible unaccounted source of nitrogen-containing compound formation in aerosols: amines reacting with secondary ozonides J. Qiu et al. 10.5194/acp-24-155-2024
- PM2.5 pollution modulates the response of ozone formation to VOC emitted from various sources: Insights from machine learning C. Tao et al. 10.1016/j.scitotenv.2024.170009
- The underappreciated role of monocarbonyl-dicarbonyl interconversion in secondary organic aerosol formation during photochemical oxidation of m-xylene J. Chen et al. 10.1016/j.scitotenv.2021.152575
- Synergistic generation mechanisms of SOA and ozone from the photochemical oxidation of 1,3,5-trimethylbenzene: Influence of precursors ratio, temperature and radiation intensity H. Zhang et al. 10.1016/j.atmosres.2023.106924
- In situ DRIFTS FT-IR and DFT study on Fe-V-W/Ti removal of NOx and VOCs Z. Chen et al. 10.1007/s11356-022-21244-4
- Heterogeneous reaction of toluene/NO2/O3 on α-Fe2O3 nanoparticles: the impacts of O3, light illumination, and relative humidity on the formation of N-containing organic compounds (NOC) X. He et al. 10.1039/D2EN00426G
14 citations as recorded by crossref.
- Photooxidation potential of fine particles from desulfurization flue gas aerosol X. Gao et al. 10.1016/j.cej.2023.143096
- Measurement report: Source apportionment and environmental impacts of volatile organic compounds (VOCs) in Lhasa, a highland city in China C. Ye et al. 10.5194/acp-23-10383-2023
- Bridged-ozonolysis of mixed aromatic hydrocarbons and organic amines: Inter-inhibited decay rate, altered product yield and synergistic-effect-enhanced secondary organic aerosol formation W. Li et al. 10.1016/j.scitotenv.2022.156872
- Unraveling the Unique Role of Methyl Position on the Ring-Opening Barrier in Photocatalytic Decomposition of Xylene Isomers R. Chen et al. 10.1021/acscatal.2c01418
- Odorous organic gas emission characteristics from cooked food wastes during aerobic decomposition Z. Wang et al. 10.1016/j.jclepro.2023.139961
- Non-target analysis of crude oil photooxidation products at high latitudes and their biological effects Z. Redman et al. 10.1016/j.chemosphere.2024.141794
- A New Type of Quartz Smog Chamber: Design and Characterization W. Ma et al. 10.1021/acs.est.1c06341
- Removal efficiencies of emissions of volatile organic compounds by adsorption systems installed in small-scale auto-repair painting operations H. Chun & M. Song 10.1007/s11869-023-01451-9
- A possible unaccounted source of nitrogen-containing compound formation in aerosols: amines reacting with secondary ozonides J. Qiu et al. 10.5194/acp-24-155-2024
- PM2.5 pollution modulates the response of ozone formation to VOC emitted from various sources: Insights from machine learning C. Tao et al. 10.1016/j.scitotenv.2024.170009
- The underappreciated role of monocarbonyl-dicarbonyl interconversion in secondary organic aerosol formation during photochemical oxidation of m-xylene J. Chen et al. 10.1016/j.scitotenv.2021.152575
- Synergistic generation mechanisms of SOA and ozone from the photochemical oxidation of 1,3,5-trimethylbenzene: Influence of precursors ratio, temperature and radiation intensity H. Zhang et al. 10.1016/j.atmosres.2023.106924
- In situ DRIFTS FT-IR and DFT study on Fe-V-W/Ti removal of NOx and VOCs Z. Chen et al. 10.1007/s11356-022-21244-4
- Heterogeneous reaction of toluene/NO2/O3 on α-Fe2O3 nanoparticles: the impacts of O3, light illumination, and relative humidity on the formation of N-containing organic compounds (NOC) X. He et al. 10.1039/D2EN00426G
Latest update: 19 Apr 2024
Short summary
The formation kinetics and mechanism of O3 and SOA from different AHs are still unclear. Thus the photochemical oxidation mechanism of nine AHs with NO2 is studied. Increased formation rate and yield of O3 and SOA are observed via promoting AH content. Raising the number of AH substituents enhances O3 formation but decreases SOA yield, which is promoted by increasing the methyl group number of AHs. Results help show conversion of AHs to secondary pollutants in the real atmospheric environment.
The formation kinetics and mechanism of O3 and SOA from different AHs are still unclear. Thus...
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