Articles | Volume 21, issue 5
https://doi.org/10.5194/acp-21-4123-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-21-4123-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
18 Mar 2021
Research article |
| 18 Mar 2021
| 18 Mar 2021
Atmospheric organic vapors in two European pine forests measured by a Vocus PTR-TOF: insights into monoterpene and sesquiterpene oxidation processes
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, Helsinki, 00014, Finland
Manjula R. Canagaratna
Aerodyne Research Inc., Billerica, Massachusetts 01821, USA
Matthieu Riva
Univ. Lyon, Université Claude Bernard Lyon 1, CNRS, IRCELYON,
69626 Villeurbanne, France
Pekka Rantala
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, Helsinki, 00014, Finland
Yanjun Zhang
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, Helsinki, 00014, Finland
Steven Thomas
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, Helsinki, 00014, Finland
Liine Heikkinen
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, Helsinki, 00014, Finland
Pierre-Marie Flaud
University of Bordeaux, EPOC, UMR 5805 CNRS, 33405 Talence CEDEX,
France
CNRS, EPOC, UMR 5805 CNRS, 33405 Talence CEDEX, France
Eric Villenave
University of Bordeaux, EPOC, UMR 5805 CNRS, 33405 Talence CEDEX,
France
CNRS, EPOC, UMR 5805 CNRS, 33405 Talence CEDEX, France
Emilie Perraudin
University of Bordeaux, EPOC, UMR 5805 CNRS, 33405 Talence CEDEX,
France
CNRS, EPOC, UMR 5805 CNRS, 33405 Talence CEDEX, France
Douglas Worsnop
Aerodyne Research Inc., Billerica, Massachusetts 01821, USA
Markku Kulmala
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, Helsinki, 00014, Finland
Mikael Ehn
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, Helsinki, 00014, Finland
Federico Bianchi
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, Helsinki, 00014, Finland
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Cited
28 citations as recorded by crossref.
- Characterization of organic vapors by a Vocus proton-transfer-reaction mass spectrometry at a mountain site in southeastern China Y. Zhang et al. 10.1016/j.scitotenv.2024.170633
- Correlation between the Concentrations of Atmospheric Ions and Radon as Judged from Measurements at the Fonovaya Observatory M. Arshinov et al. 10.1134/S1024856022010158
- Marine gas-phase sulfur emissions during an induced phytoplankton bloom D. Kilgour et al. 10.5194/acp-22-1601-2022
- Simulation of organic aerosol, its precursors, and related oxidants in the Landes pine forest in southwestern France: accounting for domain-specific land use and physical conditions A. Cholakian et al. 10.5194/acp-23-3679-2023
- Oxidation product characterization from ozonolysis of the diterpene <i>ent</i>-kaurene Y. Luo et al. 10.5194/acp-22-5619-2022
- Exploring condensable organic vapors and their co-occurrence with PM2.5and O3in winter in Eastern China Y. Liu et al. 10.1039/D2EA00143H
- Volatility of Secondary Organic Aerosol from β-Caryophyllene Ozonolysis over a Wide Tropospheric Temperature Range L. Gao et al. 10.1021/acs.est.3c01151
- Measurement report: Molecular composition and volatility of gaseous organic compounds in a boreal forest – from volatile organic compounds to highly oxygenated organic molecules W. Huang et al. 10.5194/acp-21-8961-2021
- Tracing the Formation of Secondary Aerosols Influenced by Solar Radiation and Relative Humidity in Suburban Environment Y. Wu et al. 10.1029/2022JD036913
- Comprehensive observations of carbonyls of Mt. Hua in Central China: Vertical distribution and effects on ozone formation Y. Zhang et al. 10.1016/j.scitotenv.2023.167983
- Resolving emission factors and formation pathways of organic gaseous compounds from residential combustion of European brown coal A. Hartikainen et al. 10.1016/j.combustflame.2024.113485
- The synergistic role of sulfuric acid, ammonia and organics in particle formation over an agricultural land L. Dada et al. 10.1039/D3EA00065F
- Abundant oxygenated volatile organic compounds and their contribution to photochemical pollution in subtropical Hong Kong L. Hui et al. 10.1016/j.envpol.2023.122287
- Enhanced Aerosol Source Identification by Utilizing High Molecular Weight Signals in Aerosol Mass Spectra Y. Zhang et al. 10.1021/acsestair.3c00102
- Multivariate model-based investigation of the temperature dependence of ozone concentration in Finnish boreal forest S. Isokääntä et al. 10.1016/j.atmosenv.2022.119315
- Urban and Remote cheMistry modELLing with the new chemical mechanism URMELL: part I gas-phase mechanism development M. Luttkus et al. 10.1039/D3EA00094J
- Observations of biogenic volatile organic compounds over a mixed temperate forest during the summer to autumn transition M. Vermeuel et al. 10.5194/acp-23-4123-2023
- Recent advances in mass spectrometry techniques for atmospheric chemistry research on molecular‐level W. Zhang et al. 10.1002/mas.21857
- Fragmentation inside proton-transfer-reaction-based mass spectrometers limits the detection of ROOR and ROOH peroxides H. Li et al. 10.5194/amt-15-1811-2022
- Measurements of atmospheric C10–C15 biogenic volatile organic compounds (BVOCs) with sorbent tubes H. Hellén et al. 10.5194/amt-17-315-2024
- Atmospheric Nitrous Acid Measurement in the French Landes Forest X. Wang et al. 10.1021/acsearthspacechem.1c00231
- Sources of Wintertime Atmospheric Organic Pollutants in a Large Canadian City: Insights from Particle and Gas Phase Measurements L. Rivellini et al. 10.1021/acsestair.4c00039
- Detailed Speciation of Non-Methane Volatile Organic Compounds in Exhaust Emissions from Diesel and Gasoline Euro 5 Vehicles Using Online and Offline Measurements B. Marques et al. 10.3390/toxics10040184
- Sources of organic gases and aerosol particles and their roles in nighttime particle growth at a rural forested site in southwest Germany J. Song et al. 10.5194/acp-24-6699-2024
- Development of a Refrigerant-Free Cryotrap Unit for Pre-Concentration of Biogenic Volatile Organic Compounds in Air X. Ding et al. 10.3390/atmos15050587
- Early stem growth mutation alters metabolic flux changes enhance sesquiterpenoids biosynthesis in Atractylodes lancea (Thunb.) DC. D. Wang et al. 10.1007/s11240-022-02240-5
- Application of fuzzy c-means clustering for analysis of chemical ionization mass spectra: insights into the gas phase chemistry of NO3-initiated oxidation of isoprene R. Wu et al. 10.5194/amt-17-1811-2024
- Spatially Resolved Source Apportionment of Industrial VOCs Using a Mobile Monitoring Platform R. Healy et al. 10.3390/atmos13101722
28 citations as recorded by crossref.
- Characterization of organic vapors by a Vocus proton-transfer-reaction mass spectrometry at a mountain site in southeastern China Y. Zhang et al. 10.1016/j.scitotenv.2024.170633
- Correlation between the Concentrations of Atmospheric Ions and Radon as Judged from Measurements at the Fonovaya Observatory M. Arshinov et al. 10.1134/S1024856022010158
- Marine gas-phase sulfur emissions during an induced phytoplankton bloom D. Kilgour et al. 10.5194/acp-22-1601-2022
- Simulation of organic aerosol, its precursors, and related oxidants in the Landes pine forest in southwestern France: accounting for domain-specific land use and physical conditions A. Cholakian et al. 10.5194/acp-23-3679-2023
- Oxidation product characterization from ozonolysis of the diterpene <i>ent</i>-kaurene Y. Luo et al. 10.5194/acp-22-5619-2022
- Exploring condensable organic vapors and their co-occurrence with PM2.5and O3in winter in Eastern China Y. Liu et al. 10.1039/D2EA00143H
- Volatility of Secondary Organic Aerosol from β-Caryophyllene Ozonolysis over a Wide Tropospheric Temperature Range L. Gao et al. 10.1021/acs.est.3c01151
- Measurement report: Molecular composition and volatility of gaseous organic compounds in a boreal forest – from volatile organic compounds to highly oxygenated organic molecules W. Huang et al. 10.5194/acp-21-8961-2021
- Tracing the Formation of Secondary Aerosols Influenced by Solar Radiation and Relative Humidity in Suburban Environment Y. Wu et al. 10.1029/2022JD036913
- Comprehensive observations of carbonyls of Mt. Hua in Central China: Vertical distribution and effects on ozone formation Y. Zhang et al. 10.1016/j.scitotenv.2023.167983
- Resolving emission factors and formation pathways of organic gaseous compounds from residential combustion of European brown coal A. Hartikainen et al. 10.1016/j.combustflame.2024.113485
- The synergistic role of sulfuric acid, ammonia and organics in particle formation over an agricultural land L. Dada et al. 10.1039/D3EA00065F
- Abundant oxygenated volatile organic compounds and their contribution to photochemical pollution in subtropical Hong Kong L. Hui et al. 10.1016/j.envpol.2023.122287
- Enhanced Aerosol Source Identification by Utilizing High Molecular Weight Signals in Aerosol Mass Spectra Y. Zhang et al. 10.1021/acsestair.3c00102
- Multivariate model-based investigation of the temperature dependence of ozone concentration in Finnish boreal forest S. Isokääntä et al. 10.1016/j.atmosenv.2022.119315
- Urban and Remote cheMistry modELLing with the new chemical mechanism URMELL: part I gas-phase mechanism development M. Luttkus et al. 10.1039/D3EA00094J
- Observations of biogenic volatile organic compounds over a mixed temperate forest during the summer to autumn transition M. Vermeuel et al. 10.5194/acp-23-4123-2023
- Recent advances in mass spectrometry techniques for atmospheric chemistry research on molecular‐level W. Zhang et al. 10.1002/mas.21857
- Fragmentation inside proton-transfer-reaction-based mass spectrometers limits the detection of ROOR and ROOH peroxides H. Li et al. 10.5194/amt-15-1811-2022
- Measurements of atmospheric C10–C15 biogenic volatile organic compounds (BVOCs) with sorbent tubes H. Hellén et al. 10.5194/amt-17-315-2024
- Atmospheric Nitrous Acid Measurement in the French Landes Forest X. Wang et al. 10.1021/acsearthspacechem.1c00231
- Sources of Wintertime Atmospheric Organic Pollutants in a Large Canadian City: Insights from Particle and Gas Phase Measurements L. Rivellini et al. 10.1021/acsestair.4c00039
- Detailed Speciation of Non-Methane Volatile Organic Compounds in Exhaust Emissions from Diesel and Gasoline Euro 5 Vehicles Using Online and Offline Measurements B. Marques et al. 10.3390/toxics10040184
- Sources of organic gases and aerosol particles and their roles in nighttime particle growth at a rural forested site in southwest Germany J. Song et al. 10.5194/acp-24-6699-2024
- Development of a Refrigerant-Free Cryotrap Unit for Pre-Concentration of Biogenic Volatile Organic Compounds in Air X. Ding et al. 10.3390/atmos15050587
- Early stem growth mutation alters metabolic flux changes enhance sesquiterpenoids biosynthesis in Atractylodes lancea (Thunb.) DC. D. Wang et al. 10.1007/s11240-022-02240-5
- Application of fuzzy c-means clustering for analysis of chemical ionization mass spectra: insights into the gas phase chemistry of NO3-initiated oxidation of isoprene R. Wu et al. 10.5194/amt-17-1811-2024
- Spatially Resolved Source Apportionment of Industrial VOCs Using a Mobile Monitoring Platform R. Healy et al. 10.3390/atmos13101722
Latest update: 01 Jul 2024
Short summary
For the first time, we performed binPMF analysis on the complex mass spectra acquired with the Vocus PTR-TOF in two European pine forests and identified various primary emission sources and secondary oxidation processes of atmospheric organic vapors, i.e., terpenes and their oxidation products, with varying oxidation degrees. Further insights were gained regarding monoterpene and sesquiterpene reactions based on the interpretation results.
For the first time, we performed binPMF analysis on the complex mass spectra acquired with the...
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