Articles | Volume 21, issue 3
https://doi.org/10.5194/acp-21-2125-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-21-2125-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Evaluating the sensitivity of radical chemistry and ozone formation to ambient VOCs and NOx in Beijing
Lisa K. Whalley
CORRESPONDING AUTHOR
School of Chemistry, University of Leeds, Leeds, LS2 9JT, UK
National Centre for Atmospheric Science, University of Leeds, Leeds, LS2 9JT, UK
Eloise J. Slater
School of Chemistry, University of Leeds, Leeds, LS2 9JT, UK
Robert Woodward-Massey
School of Chemistry, University of Leeds, Leeds, LS2 9JT, UK
now at: College of Environmental Sciences and Engineering, Peking University, Beijing 100871, China
Chunxiang Ye
School of Chemistry, University of Leeds, Leeds, LS2 9JT, UK
now at: College of Environmental Sciences and Engineering, Peking University, Beijing 100871, China
James D. Lee
National Centre for Atmospheric Science, University of York, Heslington, York, YO10 5DD, UK
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry, University of York, Heslington, York, YO10 5DD, UK
Freya Squires
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry, University of York, Heslington, York, YO10 5DD, UK
James R. Hopkins
National Centre for Atmospheric Science, University of York, Heslington, York, YO10 5DD, UK
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry, University of York, Heslington, York, YO10 5DD, UK
Rachel E. Dunmore
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry, University of York, Heslington, York, YO10 5DD, UK
Marvin Shaw
National Centre for Atmospheric Science, University of York, Heslington, York, YO10 5DD, UK
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry, University of York, Heslington, York, YO10 5DD, UK
Jacqueline F. Hamilton
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry, University of York, Heslington, York, YO10 5DD, UK
Alastair C. Lewis
National Centre for Atmospheric Science, University of York, Heslington, York, YO10 5DD, UK
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry, University of York, Heslington, York, YO10 5DD, UK
Archit Mehra
Centre for Atmospheric Science, School of Earth and Environmental Sciences, The University of Manchester, Manchester, M13 9PL, UK
now at: Faculty of Science and Engineering, University of Chester, Chester, CH2 4NU, UK
Stephen D. Worrall
Centre for Atmospheric Science, School of Earth and Environmental Sciences, The University of Manchester, Manchester, M13 9PL, UK
now at: Aston Institute of Materials Research, School of Engineering and Applied Science, Aston University, Birmingham, B4 7ET, UK
Asan Bacak
Centre for Atmospheric Science, School of Earth and Environmental Sciences, The University of Manchester, Manchester, M13 9PL, UK
now at: Turkish Accelerator & Radiation Laboratory, Ankara University Institute of Accelerator Technologies, Atmospheric and Environmental Chemistry Laboratory, Gölbaşı Campus, Ankara, Turkey
Thomas J. Bannan
Centre for Atmospheric Science, School of Earth and Environmental Sciences, The University of Manchester, Manchester, M13 9PL, UK
Centre for Atmospheric Science, School of Earth and Environmental Sciences, The University of Manchester, Manchester, M13 9PL, UK
National Centre for Atmospheric Science, University of Manchester, Manchester, M13 9PL, UK
Carl J. Percival
Jet Propulsion Laboratory, California Institute of Technology, Pasadena, CA, USA
Bin Ouyang
Department of Chemistry, University of Cambridge, Cambridge, UK
now at: Lancaster Environment Centre, Lancaster University, Lancaster, LA1 4YW, UK
Roderic L. Jones
Department of Chemistry, University of Cambridge, Cambridge, UK
Leigh R. Crilley
School of Geography, Earth and Environmental Sciences, University of Birmingham, Birmingham, B15 2TT, UK
now at: Department of Chemistry, York University, Toronto, ON, M3J 1P3, Canada
Louisa J. Kramer
School of Geography, Earth and Environmental Sciences, University of Birmingham, Birmingham, B15 2TT, UK
William J. Bloss
School of Geography, Earth and Environmental Sciences, University of Birmingham, Birmingham, B15 2TT, UK
School of Geography, Earth and Environmental Sciences, University of Birmingham, Birmingham, B15 2TT, UK
Simone Kotthaus
Department of Meteorology, University of Reading, Reading, UK
Institut Pierre Simon Laplace, École Polytechnique, Palaiseau, France
Sue Grimmond
Department of Meteorology, University of Reading, Reading, UK
State Key Laboratory of Atmospheric Boundary Layer Physics and Atmospheric Chemistry, Institute for Atmospheric Physics, Chinese Academy of Sciences, 40 Huayanli, Chaoyang District, Beijing 100029, China
Weiqi Xu
State Key Laboratory of Atmospheric Boundary Layer Physics and Atmospheric Chemistry, Institute for Atmospheric Physics, Chinese Academy of Sciences, 40 Huayanli, Chaoyang District, Beijing 100029, China
Siyao Yue
State Key Laboratory of Atmospheric Boundary Layer Physics and Atmospheric Chemistry, Institute for Atmospheric Physics, Chinese Academy of Sciences, 40 Huayanli, Chaoyang District, Beijing 100029, China
Lujie Ren
State Key Laboratory of Atmospheric Boundary Layer Physics and Atmospheric Chemistry, Institute for Atmospheric Physics, Chinese Academy of Sciences, 40 Huayanli, Chaoyang District, Beijing 100029, China
W. Joe F. Acton
Lancaster Environment Centre, Lancaster University, Lancaster, LA1 4YW, UK
C. Nicholas Hewitt
Lancaster Environment Centre, Lancaster University, Lancaster, LA1 4YW, UK
Xinming Wang
State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, 511 Kehua Street, Wushan, Tianhe District, Guangzhou, GD 510640, China
Pingqing Fu
Institute of Surface-Earth System Science, Tianjin University, Tianjin 300072, China
Dwayne E. Heard
School of Chemistry, University of Leeds, Leeds, LS2 9JT, UK
Viewed
Total article views: 6,037 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 03 Sep 2020)
HTML | XML | Total | Supplement | BibTeX | EndNote | |
---|---|---|---|---|---|---|
4,224 | 1,754 | 59 | 6,037 | 274 | 52 | 135 |
- HTML: 4,224
- PDF: 1,754
- XML: 59
- Total: 6,037
- Supplement: 274
- BibTeX: 52
- EndNote: 135
Total article views: 4,876 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 12 Feb 2021)
HTML | XML | Total | Supplement | BibTeX | EndNote | |
---|---|---|---|---|---|---|
3,541 | 1,282 | 53 | 4,876 | 274 | 45 | 115 |
- HTML: 3,541
- PDF: 1,282
- XML: 53
- Total: 4,876
- Supplement: 274
- BibTeX: 45
- EndNote: 115
Total article views: 1,161 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 03 Sep 2020)
HTML | XML | Total | BibTeX | EndNote | |
---|---|---|---|---|---|
683 | 472 | 6 | 1,161 | 7 | 20 |
- HTML: 683
- PDF: 472
- XML: 6
- Total: 1,161
- BibTeX: 7
- EndNote: 20
Viewed (geographical distribution)
Total article views: 6,037 (including HTML, PDF, and XML)
Thereof 5,984 with geography defined
and 53 with unknown origin.
Total article views: 4,876 (including HTML, PDF, and XML)
Thereof 4,832 with geography defined
and 44 with unknown origin.
Total article views: 1,161 (including HTML, PDF, and XML)
Thereof 1,152 with geography defined
and 9 with unknown origin.
Country | # | Views | % |
---|
Country | # | Views | % |
---|
Country | # | Views | % |
---|
Total: | 0 |
HTML: | 0 |
PDF: | 0 |
XML: | 0 |
- 1
1
Total: | 0 |
HTML: | 0 |
PDF: | 0 |
XML: | 0 |
- 1
1
Total: | 0 |
HTML: | 0 |
PDF: | 0 |
XML: | 0 |
- 1
1
Cited
78 citations as recorded by crossref.
- PM2.5-bound silicon-containing secondary organic aerosols (Si-SOA) in Beijing ambient air J. Xu et al. 10.1016/j.chemosphere.2021.132377
- Unraveling the O3-NOX-VOCs relationships induced by anomalous ozone in industrial regions during COVID-19 in Shanghai B. Lu et al. 10.1016/j.atmosenv.2023.119864
- Effect of the air flows ratio on energy behavior and NOx emissions from a top-lit updraft biomass cookstove D. Muñoz et al. 10.1007/s40430-023-04473-7
- Effect of support structure of Pt/silicaite-1 catalyst on non-thermal plasma (NTP) assisted chlorobenzene degradation and PCDD/Fs formation Y. Mu et al. 10.1016/j.chemosphere.2024.142294
- Fractal analysis of impact of PM2.5 on surface O3 sensitivity regime based on field observations C. Liu et al. 10.1016/j.scitotenv.2022.160136
- Unclassical Radical Generation Mechanisms in the Troposphere: A Review X. Yang et al. 10.1021/acs.est.4c00742
- Tropospheric ozone changes and ozone sensitivity from the present day to the future under shared socio-economic pathways Z. Liu et al. 10.5194/acp-22-1209-2022
- Reducing Soil-Emitted Nitrous Acid as a Feasible Strategy for Tackling Ozone Pollution C. Xue et al. 10.1021/acs.est.4c01070
- The impacts of VOCs on PM2.5 increasing via their chemical losses estimates: A case study in a typical industrial city of China W. Wei et al. 10.1016/j.atmosenv.2022.118978
- Suppression of surface ozone by an aerosol-inhibited photochemical ozone regime P. Ivatt et al. 10.1038/s41561-022-00972-9
- Investigation of OH-reactivity budget in the isoprene, α-pinene and m-xylene oxidation with OH under high NOx conditions Y. Sakamoto et al. 10.1016/j.atmosenv.2021.118916
- Volatile organic compounds at a roadside site in Hong Kong: Characteristics, chemical reactivity, and health risk assessment S. Han et al. 10.1016/j.scitotenv.2022.161370
- The effect of nitrous acid (HONO) on ozone formation during pollution episodes in southeastern China: Results from model improvement and mechanism insights B. Hu et al. 10.1016/j.scitotenv.2023.164477
- Radical chemistry in the Pearl River Delta: observations and modeling of OH and HO2 radicals in Shenzhen in 2018 X. Yang et al. 10.5194/acp-22-12525-2022
- A review on methodology in O3-NOx-VOC sensitivity study C. Liu & K. Shi 10.1016/j.envpol.2021.118249
- Impacts of missing OH reactivity and aerosol uptake of HO2 radicals on tropospheric O3 production during the AQUAS-Kyoto summer campaign in 2018 N. Kohno et al. 10.1016/j.atmosenv.2022.119130
- Evaluation of isoprene nitrate chemistry in detailed chemical mechanisms A. Mayhew et al. 10.5194/acp-22-14783-2022
- Plasma‐Modified Coal Fly Ash Zeolites with Enhanced Catalytic Efficiency toward the Total Oxidation of Volatile Organic Compounds as Low‐Cost Substitutes for Platinum Group Metals Catalysts S. Boycheva et al. 10.1002/pssa.202100632
- Experimental chemical budgets of OH, HO2, and RO2 radicals in rural air in western Germany during the JULIAC campaign 2019 C. Cho et al. 10.5194/acp-23-2003-2023
- Photooxidation Chemistry of Hydrofluoroolefins: Assessing the Impact of Substituents on the Greenhouse Gas Replacements J. Wang et al. 10.1021/acsearthspacechem.3c00013
- Characteristics of summertime ambient volatile organic compounds in Beijing: Composition, source apportionment, and chemical reactivity S. Yao et al. 10.1016/j.apr.2023.101725
- Observations and Explicit Modeling of Summer and Autumn Ozone Formation in Urban Beijing: Identification of Key Precursor Species and Sources J. Han et al. 10.2139/ssrn.4146251
- Observations and explicit modeling of summer and autumn ozone formation in urban Beijing: Identification of key precursor species and sources J. Han et al. 10.1016/j.atmosenv.2023.119932
- Potential deterioration of ozone pollution in coastal areas caused by marine-emitted halogens: A case study in the Guangdong-Hong Kong-Macao Greater Bay Area S. Fan & Y. Li 10.1016/j.scitotenv.2022.160456
- Production of HONO from NO<sub>2</sub> uptake on illuminated TiO<sub>2</sub> aerosol particles and following the illumination of mixed TiO<sub>2</sub>∕ammonium nitrate particles J. Dyson et al. 10.5194/acp-21-5755-2021
- The Lack of HONO Measurement May Affect the Accurate Diagnosis of Ozone Production Sensitivity P. Liu et al. 10.1021/acsenvironau.2c00048
- Ozone production sensitivity in the highland city of Lhasa: a comparative analysis with Beijing Y. Chen et al. 10.1007/s11869-024-01604-4
- The atmospheric oxidizing capacity in China – Part 1: Roles of different photochemical processes J. Dai et al. 10.5194/acp-23-14127-2023
- OH, HO2, and RO2 radical chemistry in a rural forest environment: measurements, model comparisons, and evidence of a missing radical sink B. Bottorff et al. 10.5194/acp-23-10287-2023
- Reactive Chlorine Species Advancing the Atmospheric Oxidation Capacities of Inland Urban Environments W. Ma et al. 10.1021/acs.est.3c05169
- A quantitative understanding of total OH reactivity and ozone production in a coastal industrial area during the Yokohama air quality study (AQUAS) campaign of summer 2019 J. Li et al. 10.1016/j.atmosenv.2021.118754
- Ground-level ozone pollution in China: a synthesis of recent findings on influencing factors and impacts T. Wang et al. 10.1088/1748-9326/ac69fe
- In situ ozone production is highly sensitive to volatile organic compounds in Delhi, India B. Nelson et al. 10.5194/acp-21-13609-2021
- Chlorobenzene Mineralization Using Plasma/Photocatalysis Hybrid Reactor: Exploiting the Synergistic Effect N. KONE et al. 10.3390/catal13020431
- A review of gas-phase chemical mechanisms commonly used in atmospheric chemistry modelling Y. Liu et al. 10.1016/j.jes.2022.10.031
- OH and HO<sub>2</sub> radical chemistry at a suburban site during the EXPLORE-YRD campaign in 2018 X. Ma et al. 10.5194/acp-22-7005-2022
- Secondary reactions of aromatics-derived oxygenated organic molecules lead to plentiful highly oxygenated organic molecules within an intraday OH exposure Y. Wang et al. 10.5194/acp-24-7961-2024
- Exploration of radical chemistry, precursor sensitivity and O3 control strategies in a provincial capital city, northwestern China J. Liu et al. 10.1016/j.atmosenv.2024.120792
- Local radical chemistry driven ozone pollution in a megacity: A case study J. Guo et al. 10.1016/j.atmosenv.2023.120227
- Measurement report: Vertical and temporal variability in the near-surface ozone production rate and sensitivity in an urban area in the Pearl River Delta region, China J. Zhou et al. 10.5194/acp-24-9805-2024
- Observationally Constrained Modeling of Peroxy Radical During an Ozone Episode in the Pearl River Delta Region, China J. Wang et al. 10.1029/2022JD038279
- Airborne observations of peroxy radicals during the EMeRGe campaign in Europe M. George et al. 10.5194/acp-23-7799-2023
- Effect of the Alkoxy Radical Chemistry on the Ozone Formation from Anthropogenic Organic Compounds Investigated in Chamber Experiments M. Färber et al. 10.1021/acsestair.4c00064
- Intercomparison of measured and modelled photochemical ozone production rates: Suggestion of chemistry hypothesis regarding unmeasured VOCs J. Zhou et al. 10.1016/j.scitotenv.2024.175290
- Using observed urban NOx sinks to constrain VOC reactivity and the ozone and radical budget in the Seoul Metropolitan Area B. Nault et al. 10.5194/acp-24-9573-2024
- Observational Evidence of Unknown NOx Source and Its Perturbation of Oxidative Capacity in Bermuda's Marine Boundary Layer Y. Wang et al. 10.1029/2023JD039582
- Atmospheric conditions and composition that influence PM<sub>2.5</sub> oxidative potential in Beijing, China S. Campbell et al. 10.5194/acp-21-5549-2021
- Recent advances in the abatement of volatile organic compounds (VOCs) and chlorinated-VOCs by non-thermal plasma technology: A review Y. Mu & P. Williams 10.1016/j.chemosphere.2022.136481
- Optimizing a twin-chamber system for direct ozone production rate measurement Y. Wang et al. 10.1016/j.envpol.2024.123837
- A systematic review of reactive nitrogen simulations with chemical transport models in China H. Zhang et al. 10.1016/j.atmosres.2024.107586
- Observations of speciated isoprene nitrates in Beijing: implications for isoprene chemistry C. Reeves et al. 10.5194/acp-21-6315-2021
- Radical chemistry and ozone production at a UK coastal receptor site R. Woodward-Massey et al. 10.5194/acp-23-14393-2023
- Improved laser-induced fluorescent instrument for online peroxy radical measurement: Consistency in high-sensitivity for detection G. Zhang et al. 10.1016/j.snb.2024.136774
- Direct evidence of local photochemical production driven ozone episode in Beijing: A case study Z. Tan et al. 10.1016/j.scitotenv.2021.148868
- The impacts of marine-emitted halogens on OH radicals in East Asia during summer S. Fan & Y. Li 10.5194/acp-22-7331-2022
- O3–precursor relationship over multiple patterns of timescale: a case study in Zibo, Shandong Province, China Z. Zheng et al. 10.5194/acp-23-2649-2023
- Insight into the reactions of n-, iso-, sec- and tert-Butylperoxy radicals with hydroperoxyl radical in the Atmosphere: Reaction Mechanism, thermodynamic analysis and kinetics Z. Yang et al. 10.1016/j.comptc.2023.114436
- Titanium Dioxide Promotes New Particle Formation: A Smog Chamber Study H. Zhang et al. 10.1021/acs.est.2c06946
- Increased ozone pollution alongside reduced nitrogen dioxide concentrations during Vienna’s first COVID-19 lockdown: Significance for air quality management M. Brancher 10.1016/j.envpol.2021.117153
- Peroxy radical chemistry during ozone photochemical pollution season at a suburban site in the boundary of Jiangsu–Anhui–Shandong–Henan region, China N. Wei et al. 10.1016/j.scitotenv.2023.166355
- Ambient volatile organic compounds in the Seoul metropolitan area of South Korea: Chemical reactivity, risks and source apportionment D. Eun et al. 10.1016/j.envres.2024.118749
- The effect of different climate and air quality policies in China on in situ ozone production in Beijing B. Nelson et al. 10.5194/acp-24-9031-2024
- The reaction of organic peroxy radicals with unsaturated compounds controlled by a non-epoxide pathway under atmospheric conditions B. Nozière et al. 10.1039/D2CP05166D
- Ozone formation potential related to the release of volatile organic compounds (VOCs) and nitrogen oxide (NOX) from a typical industrial park in the Pearl River Delta T. An et al. 10.1039/D4EA00091A
- Daytime isoprene nitrates under changing NOx and O3 A. Mayhew et al. 10.5194/acp-23-8473-2023
- Impact of temperature-dependent non-PAN peroxynitrate formation, RO2NO2, on nighttime atmospheric chemistry M. Färber et al. 10.1039/D3CP04163H
- Atmospheric measurements at Mt. Tai – Part II: HONO budget and radical (ROx + NO3) chemistry in the lower boundary layer C. Xue et al. 10.5194/acp-22-1035-2022
- Atmospheric oxidizing capacity in autumn Beijing: Analysis of the O3 and PM2.5 episodes based on observation-based model C. Jia et al. 10.1016/j.jes.2021.11.020
- Experimental and theoretical study on the impact of a nitrate group on the chemistry of alkoxy radicals A. Novelli et al. 10.1039/D0CP05555G
- Process-based and observation-constrained SOA simulations in China: the role of semivolatile and intermediate-volatility organic compounds and OH levels R. Miao et al. 10.5194/acp-21-16183-2021
- Overview: On the transport and transformation of pollutants in the outflow of major population centres – observational data from the EMeRGe European intensive operational period in summer 2017 M. Andrés Hernández et al. 10.5194/acp-22-5877-2022
- Impact of HO2 aerosol uptake on radical levels and O3 production during summertime in Beijing J. Dyson et al. 10.5194/acp-23-5679-2023
- VOCs sources and roles in O3 formation in the central Yangtze River Delta region of China Z. Liu et al. 10.1016/j.atmosenv.2023.119755
- Source apportionment of gaseous Nitrophenols and their contribution to HONO formation in an urban area M. Ahmed et al. 10.1016/j.chemosphere.2023.139499
- Analysis of VOCs Emitted from Small Laundry Facilities: Contributions to Ozone and Secondary Aerosol Formation and Human Risk Assessment D. Eun et al. 10.3390/ijerph192215130
- Elevated levels of OH observed in haze events during wintertime in central Beijing E. Slater et al. 10.5194/acp-20-14847-2020
- Surface–atmosphere fluxes of volatile organic compounds in Beijing W. Acton et al. 10.5194/acp-20-15101-2020
- Low-NO atmospheric oxidation pathways in a polluted megacity M. Newland et al. 10.5194/acp-21-1613-2021
75 citations as recorded by crossref.
- PM2.5-bound silicon-containing secondary organic aerosols (Si-SOA) in Beijing ambient air J. Xu et al. 10.1016/j.chemosphere.2021.132377
- Unraveling the O3-NOX-VOCs relationships induced by anomalous ozone in industrial regions during COVID-19 in Shanghai B. Lu et al. 10.1016/j.atmosenv.2023.119864
- Effect of the air flows ratio on energy behavior and NOx emissions from a top-lit updraft biomass cookstove D. Muñoz et al. 10.1007/s40430-023-04473-7
- Effect of support structure of Pt/silicaite-1 catalyst on non-thermal plasma (NTP) assisted chlorobenzene degradation and PCDD/Fs formation Y. Mu et al. 10.1016/j.chemosphere.2024.142294
- Fractal analysis of impact of PM2.5 on surface O3 sensitivity regime based on field observations C. Liu et al. 10.1016/j.scitotenv.2022.160136
- Unclassical Radical Generation Mechanisms in the Troposphere: A Review X. Yang et al. 10.1021/acs.est.4c00742
- Tropospheric ozone changes and ozone sensitivity from the present day to the future under shared socio-economic pathways Z. Liu et al. 10.5194/acp-22-1209-2022
- Reducing Soil-Emitted Nitrous Acid as a Feasible Strategy for Tackling Ozone Pollution C. Xue et al. 10.1021/acs.est.4c01070
- The impacts of VOCs on PM2.5 increasing via their chemical losses estimates: A case study in a typical industrial city of China W. Wei et al. 10.1016/j.atmosenv.2022.118978
- Suppression of surface ozone by an aerosol-inhibited photochemical ozone regime P. Ivatt et al. 10.1038/s41561-022-00972-9
- Investigation of OH-reactivity budget in the isoprene, α-pinene and m-xylene oxidation with OH under high NOx conditions Y. Sakamoto et al. 10.1016/j.atmosenv.2021.118916
- Volatile organic compounds at a roadside site in Hong Kong: Characteristics, chemical reactivity, and health risk assessment S. Han et al. 10.1016/j.scitotenv.2022.161370
- The effect of nitrous acid (HONO) on ozone formation during pollution episodes in southeastern China: Results from model improvement and mechanism insights B. Hu et al. 10.1016/j.scitotenv.2023.164477
- Radical chemistry in the Pearl River Delta: observations and modeling of OH and HO2 radicals in Shenzhen in 2018 X. Yang et al. 10.5194/acp-22-12525-2022
- A review on methodology in O3-NOx-VOC sensitivity study C. Liu & K. Shi 10.1016/j.envpol.2021.118249
- Impacts of missing OH reactivity and aerosol uptake of HO2 radicals on tropospheric O3 production during the AQUAS-Kyoto summer campaign in 2018 N. Kohno et al. 10.1016/j.atmosenv.2022.119130
- Evaluation of isoprene nitrate chemistry in detailed chemical mechanisms A. Mayhew et al. 10.5194/acp-22-14783-2022
- Plasma‐Modified Coal Fly Ash Zeolites with Enhanced Catalytic Efficiency toward the Total Oxidation of Volatile Organic Compounds as Low‐Cost Substitutes for Platinum Group Metals Catalysts S. Boycheva et al. 10.1002/pssa.202100632
- Experimental chemical budgets of OH, HO2, and RO2 radicals in rural air in western Germany during the JULIAC campaign 2019 C. Cho et al. 10.5194/acp-23-2003-2023
- Photooxidation Chemistry of Hydrofluoroolefins: Assessing the Impact of Substituents on the Greenhouse Gas Replacements J. Wang et al. 10.1021/acsearthspacechem.3c00013
- Characteristics of summertime ambient volatile organic compounds in Beijing: Composition, source apportionment, and chemical reactivity S. Yao et al. 10.1016/j.apr.2023.101725
- Observations and Explicit Modeling of Summer and Autumn Ozone Formation in Urban Beijing: Identification of Key Precursor Species and Sources J. Han et al. 10.2139/ssrn.4146251
- Observations and explicit modeling of summer and autumn ozone formation in urban Beijing: Identification of key precursor species and sources J. Han et al. 10.1016/j.atmosenv.2023.119932
- Potential deterioration of ozone pollution in coastal areas caused by marine-emitted halogens: A case study in the Guangdong-Hong Kong-Macao Greater Bay Area S. Fan & Y. Li 10.1016/j.scitotenv.2022.160456
- Production of HONO from NO<sub>2</sub> uptake on illuminated TiO<sub>2</sub> aerosol particles and following the illumination of mixed TiO<sub>2</sub>∕ammonium nitrate particles J. Dyson et al. 10.5194/acp-21-5755-2021
- The Lack of HONO Measurement May Affect the Accurate Diagnosis of Ozone Production Sensitivity P. Liu et al. 10.1021/acsenvironau.2c00048
- Ozone production sensitivity in the highland city of Lhasa: a comparative analysis with Beijing Y. Chen et al. 10.1007/s11869-024-01604-4
- The atmospheric oxidizing capacity in China – Part 1: Roles of different photochemical processes J. Dai et al. 10.5194/acp-23-14127-2023
- OH, HO2, and RO2 radical chemistry in a rural forest environment: measurements, model comparisons, and evidence of a missing radical sink B. Bottorff et al. 10.5194/acp-23-10287-2023
- Reactive Chlorine Species Advancing the Atmospheric Oxidation Capacities of Inland Urban Environments W. Ma et al. 10.1021/acs.est.3c05169
- A quantitative understanding of total OH reactivity and ozone production in a coastal industrial area during the Yokohama air quality study (AQUAS) campaign of summer 2019 J. Li et al. 10.1016/j.atmosenv.2021.118754
- Ground-level ozone pollution in China: a synthesis of recent findings on influencing factors and impacts T. Wang et al. 10.1088/1748-9326/ac69fe
- In situ ozone production is highly sensitive to volatile organic compounds in Delhi, India B. Nelson et al. 10.5194/acp-21-13609-2021
- Chlorobenzene Mineralization Using Plasma/Photocatalysis Hybrid Reactor: Exploiting the Synergistic Effect N. KONE et al. 10.3390/catal13020431
- A review of gas-phase chemical mechanisms commonly used in atmospheric chemistry modelling Y. Liu et al. 10.1016/j.jes.2022.10.031
- OH and HO<sub>2</sub> radical chemistry at a suburban site during the EXPLORE-YRD campaign in 2018 X. Ma et al. 10.5194/acp-22-7005-2022
- Secondary reactions of aromatics-derived oxygenated organic molecules lead to plentiful highly oxygenated organic molecules within an intraday OH exposure Y. Wang et al. 10.5194/acp-24-7961-2024
- Exploration of radical chemistry, precursor sensitivity and O3 control strategies in a provincial capital city, northwestern China J. Liu et al. 10.1016/j.atmosenv.2024.120792
- Local radical chemistry driven ozone pollution in a megacity: A case study J. Guo et al. 10.1016/j.atmosenv.2023.120227
- Measurement report: Vertical and temporal variability in the near-surface ozone production rate and sensitivity in an urban area in the Pearl River Delta region, China J. Zhou et al. 10.5194/acp-24-9805-2024
- Observationally Constrained Modeling of Peroxy Radical During an Ozone Episode in the Pearl River Delta Region, China J. Wang et al. 10.1029/2022JD038279
- Airborne observations of peroxy radicals during the EMeRGe campaign in Europe M. George et al. 10.5194/acp-23-7799-2023
- Effect of the Alkoxy Radical Chemistry on the Ozone Formation from Anthropogenic Organic Compounds Investigated in Chamber Experiments M. Färber et al. 10.1021/acsestair.4c00064
- Intercomparison of measured and modelled photochemical ozone production rates: Suggestion of chemistry hypothesis regarding unmeasured VOCs J. Zhou et al. 10.1016/j.scitotenv.2024.175290
- Using observed urban NOx sinks to constrain VOC reactivity and the ozone and radical budget in the Seoul Metropolitan Area B. Nault et al. 10.5194/acp-24-9573-2024
- Observational Evidence of Unknown NOx Source and Its Perturbation of Oxidative Capacity in Bermuda's Marine Boundary Layer Y. Wang et al. 10.1029/2023JD039582
- Atmospheric conditions and composition that influence PM<sub>2.5</sub> oxidative potential in Beijing, China S. Campbell et al. 10.5194/acp-21-5549-2021
- Recent advances in the abatement of volatile organic compounds (VOCs) and chlorinated-VOCs by non-thermal plasma technology: A review Y. Mu & P. Williams 10.1016/j.chemosphere.2022.136481
- Optimizing a twin-chamber system for direct ozone production rate measurement Y. Wang et al. 10.1016/j.envpol.2024.123837
- A systematic review of reactive nitrogen simulations with chemical transport models in China H. Zhang et al. 10.1016/j.atmosres.2024.107586
- Observations of speciated isoprene nitrates in Beijing: implications for isoprene chemistry C. Reeves et al. 10.5194/acp-21-6315-2021
- Radical chemistry and ozone production at a UK coastal receptor site R. Woodward-Massey et al. 10.5194/acp-23-14393-2023
- Improved laser-induced fluorescent instrument for online peroxy radical measurement: Consistency in high-sensitivity for detection G. Zhang et al. 10.1016/j.snb.2024.136774
- Direct evidence of local photochemical production driven ozone episode in Beijing: A case study Z. Tan et al. 10.1016/j.scitotenv.2021.148868
- The impacts of marine-emitted halogens on OH radicals in East Asia during summer S. Fan & Y. Li 10.5194/acp-22-7331-2022
- O3–precursor relationship over multiple patterns of timescale: a case study in Zibo, Shandong Province, China Z. Zheng et al. 10.5194/acp-23-2649-2023
- Insight into the reactions of n-, iso-, sec- and tert-Butylperoxy radicals with hydroperoxyl radical in the Atmosphere: Reaction Mechanism, thermodynamic analysis and kinetics Z. Yang et al. 10.1016/j.comptc.2023.114436
- Titanium Dioxide Promotes New Particle Formation: A Smog Chamber Study H. Zhang et al. 10.1021/acs.est.2c06946
- Increased ozone pollution alongside reduced nitrogen dioxide concentrations during Vienna’s first COVID-19 lockdown: Significance for air quality management M. Brancher 10.1016/j.envpol.2021.117153
- Peroxy radical chemistry during ozone photochemical pollution season at a suburban site in the boundary of Jiangsu–Anhui–Shandong–Henan region, China N. Wei et al. 10.1016/j.scitotenv.2023.166355
- Ambient volatile organic compounds in the Seoul metropolitan area of South Korea: Chemical reactivity, risks and source apportionment D. Eun et al. 10.1016/j.envres.2024.118749
- The effect of different climate and air quality policies in China on in situ ozone production in Beijing B. Nelson et al. 10.5194/acp-24-9031-2024
- The reaction of organic peroxy radicals with unsaturated compounds controlled by a non-epoxide pathway under atmospheric conditions B. Nozière et al. 10.1039/D2CP05166D
- Ozone formation potential related to the release of volatile organic compounds (VOCs) and nitrogen oxide (NOX) from a typical industrial park in the Pearl River Delta T. An et al. 10.1039/D4EA00091A
- Daytime isoprene nitrates under changing NOx and O3 A. Mayhew et al. 10.5194/acp-23-8473-2023
- Impact of temperature-dependent non-PAN peroxynitrate formation, RO2NO2, on nighttime atmospheric chemistry M. Färber et al. 10.1039/D3CP04163H
- Atmospheric measurements at Mt. Tai – Part II: HONO budget and radical (ROx + NO3) chemistry in the lower boundary layer C. Xue et al. 10.5194/acp-22-1035-2022
- Atmospheric oxidizing capacity in autumn Beijing: Analysis of the O3 and PM2.5 episodes based on observation-based model C. Jia et al. 10.1016/j.jes.2021.11.020
- Experimental and theoretical study on the impact of a nitrate group on the chemistry of alkoxy radicals A. Novelli et al. 10.1039/D0CP05555G
- Process-based and observation-constrained SOA simulations in China: the role of semivolatile and intermediate-volatility organic compounds and OH levels R. Miao et al. 10.5194/acp-21-16183-2021
- Overview: On the transport and transformation of pollutants in the outflow of major population centres – observational data from the EMeRGe European intensive operational period in summer 2017 M. Andrés Hernández et al. 10.5194/acp-22-5877-2022
- Impact of HO2 aerosol uptake on radical levels and O3 production during summertime in Beijing J. Dyson et al. 10.5194/acp-23-5679-2023
- VOCs sources and roles in O3 formation in the central Yangtze River Delta region of China Z. Liu et al. 10.1016/j.atmosenv.2023.119755
- Source apportionment of gaseous Nitrophenols and their contribution to HONO formation in an urban area M. Ahmed et al. 10.1016/j.chemosphere.2023.139499
- Analysis of VOCs Emitted from Small Laundry Facilities: Contributions to Ozone and Secondary Aerosol Formation and Human Risk Assessment D. Eun et al. 10.3390/ijerph192215130
3 citations as recorded by crossref.
- Elevated levels of OH observed in haze events during wintertime in central Beijing E. Slater et al. 10.5194/acp-20-14847-2020
- Surface–atmosphere fluxes of volatile organic compounds in Beijing W. Acton et al. 10.5194/acp-20-15101-2020
- Low-NO atmospheric oxidation pathways in a polluted megacity M. Newland et al. 10.5194/acp-21-1613-2021
Latest update: 20 Nov 2024
Short summary
To understand how emission controls will impact ozone, an understanding of the sources and sinks of OH and the chemical cycling between peroxy radicals is needed. This paper presents measurements of OH, HO2 and total RO2 taken in central Beijing. The radical observations are compared to a detailed chemistry model, which shows that under low NO conditions, there is a missing OH source. Under high NOx conditions, the model under-predicts RO2 and impacts our ability to model ozone.
To understand how emission controls will impact ozone, an understanding of the sources and sinks...
Altmetrics
Final-revised paper
Preprint