Articles | Volume 21, issue 1
https://doi.org/10.5194/acp-21-129-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-21-129-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
08 Jan 2021
Research article |
| 08 Jan 2021
| 08 Jan 2021
The production and hydrolysis of organic nitrates from OH radical oxidation of β-ocimene
Ana C. Morales
Department of Chemistry, Purdue University, West Lafayette, IN 47906, USA
Thilina Jayarathne
Department of Chemistry, Purdue University, West Lafayette, IN 47906, USA
now at: Bristol Myers Squibb, 1 Squibb Drive, New Brunswick, NJ 08901, USA
Jonathan H. Slade
Department of Chemistry & Biochemistry, University of California
San Diego, La Jolla, CA 92093, USA
Alexander Laskin
Department of Chemistry, Purdue University, West Lafayette, IN 47906, USA
Department of Earth, Atmospheric, and Planetary Sciences, Purdue
University, West Lafayette, IN 47906, USA
Paul B. Shepson
CORRESPONDING AUTHOR
Department of Chemistry, Purdue University, West Lafayette, IN 47906, USA
Department of Earth, Atmospheric, and Planetary Sciences, Purdue
University, West Lafayette, IN 47906, USA
School of Marine and Atmospheric Sciences, Stony Brook University,
Stony Brook, NY 11794, USA
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Cited
15 citations as recorded by crossref.
- Condensed Phase Kinetic Studies of Hydroxynitrates Derived from the Photooxidation of Carene, Limonene, trans-Carveol, and Perillic Alcohol J. Vesto et al. 10.3390/atmos13040592
- Synthesis and Hydrolysis of Atmospherically Relevant Monoterpene-Derived Organic Nitrates Y. Wang et al. 10.1021/acs.est.1c05310
- Long-term study of chemical characteristics of aerosol compositions in the rural environment of Rūgšteliškis (Lithuania) T. Gill et al. 10.1016/j.apr.2024.102048
- Reactivity of a Carene-Derived Hydroxynitrate in Mixed Organic/Aqueous Matrices: Applying Synthetic Chemistry to Product Identification and Mechanistic Implications A. McAlister et al. 10.3390/atmos12121617
- Additional HONO and OH Generation from Photoexcited Phenyl Organic Nitrates in the Photoreaction of Aromatics and NOx T. Chen et al. 10.1021/acs.est.3c10193
- The First Seasonal Snowfall Impacts Plant Photosynthesis and Monoterpene Emissions M. Riches et al. 10.1029/2022GL100368
- Biogenic and anthropogenic sources of isoprene and monoterpenes and their secondary organic aerosol in Delhi, India D. Bryant et al. 10.5194/acp-23-61-2023
- Time‐Resolved Measurements of PM2.5 Chemical Composition and Brown Carbon Absorption in Nanjing, East China: Diurnal Variations and Organic Tracer‐Based PMF Analysis W. Feng et al. 10.1029/2023JD039092
- Mechanism-based structure-activity relationship investigation on hydrolysis kinetics of atmospheric organic nitrates Q. Zhao et al. 10.1038/s41612-023-00517-w
- Secondary organic aerosol formation from cis-3-hexen-1-ol/NOx photo-oxidation: The roles of cis-3-hexen-1-ol concentration, illumination intensity, NOx and NH3 D. Shi et al. 10.1016/j.atmosenv.2022.119090
- Size Distribution and Secondary Formation of Particulate Organic Nitrates in Winter in a Coastal Area A. Shakoor et al. 10.3390/su152416776
- Molecular and Structural Characterization of Isomeric Compounds in Atmospheric Organic Aerosol Using Ion Mobility-Mass Spectrometry C. West et al. 10.1021/acs.jpca.2c06459
- OH, HO2, and RO2 radical chemistry in a rural forest environment: measurements, model comparisons, and evidence of a missing radical sink B. Bottorff et al. 10.5194/acp-23-10287-2023
- Atmospheric degradation mechanisms and kinetics for OH-initiated oxidation of trans-β-ocimene B. Du & W. Zhang 10.1080/00268976.2022.2152747
- Measurement of Henry's law constants of ethyl nitrate in deionized water, synthetic sea salt solutions, and n-octanol K. Easterbrook et al. 10.1016/j.chemosphere.2023.140482
15 citations as recorded by crossref.
- Condensed Phase Kinetic Studies of Hydroxynitrates Derived from the Photooxidation of Carene, Limonene, trans-Carveol, and Perillic Alcohol J. Vesto et al. 10.3390/atmos13040592
- Synthesis and Hydrolysis of Atmospherically Relevant Monoterpene-Derived Organic Nitrates Y. Wang et al. 10.1021/acs.est.1c05310
- Long-term study of chemical characteristics of aerosol compositions in the rural environment of Rūgšteliškis (Lithuania) T. Gill et al. 10.1016/j.apr.2024.102048
- Reactivity of a Carene-Derived Hydroxynitrate in Mixed Organic/Aqueous Matrices: Applying Synthetic Chemistry to Product Identification and Mechanistic Implications A. McAlister et al. 10.3390/atmos12121617
- Additional HONO and OH Generation from Photoexcited Phenyl Organic Nitrates in the Photoreaction of Aromatics and NOx T. Chen et al. 10.1021/acs.est.3c10193
- The First Seasonal Snowfall Impacts Plant Photosynthesis and Monoterpene Emissions M. Riches et al. 10.1029/2022GL100368
- Biogenic and anthropogenic sources of isoprene and monoterpenes and their secondary organic aerosol in Delhi, India D. Bryant et al. 10.5194/acp-23-61-2023
- Time‐Resolved Measurements of PM2.5 Chemical Composition and Brown Carbon Absorption in Nanjing, East China: Diurnal Variations and Organic Tracer‐Based PMF Analysis W. Feng et al. 10.1029/2023JD039092
- Mechanism-based structure-activity relationship investigation on hydrolysis kinetics of atmospheric organic nitrates Q. Zhao et al. 10.1038/s41612-023-00517-w
- Secondary organic aerosol formation from cis-3-hexen-1-ol/NOx photo-oxidation: The roles of cis-3-hexen-1-ol concentration, illumination intensity, NOx and NH3 D. Shi et al. 10.1016/j.atmosenv.2022.119090
- Size Distribution and Secondary Formation of Particulate Organic Nitrates in Winter in a Coastal Area A. Shakoor et al. 10.3390/su152416776
- Molecular and Structural Characterization of Isomeric Compounds in Atmospheric Organic Aerosol Using Ion Mobility-Mass Spectrometry C. West et al. 10.1021/acs.jpca.2c06459
- OH, HO2, and RO2 radical chemistry in a rural forest environment: measurements, model comparisons, and evidence of a missing radical sink B. Bottorff et al. 10.5194/acp-23-10287-2023
- Atmospheric degradation mechanisms and kinetics for OH-initiated oxidation of trans-β-ocimene B. Du & W. Zhang 10.1080/00268976.2022.2152747
- Measurement of Henry's law constants of ethyl nitrate in deionized water, synthetic sea salt solutions, and n-octanol K. Easterbrook et al. 10.1016/j.chemosphere.2023.140482
Latest update: 15 Apr 2024
Short summary
Organic nitrates formed from the oxidation of biogenic volatile organic compounds impact both ozone and particulate matter as they remove nitrogen oxides, but they represent important aerosol precursors. We conducted a series of reaction chamber experiments that quantified the total organic nitrate and secondary organic aerosol yield from the OH-radical-initiated oxidation of ocimene, and also measured their hydrolysis lifetimes in the aqueous phase, as a function of pH.
Organic nitrates formed from the oxidation of biogenic volatile organic compounds impact both...
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