Articles | Volume 21, issue 13
https://doi.org/10.5194/acp-21-10799-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-21-10799-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
16 Jul 2021
Research article |
| 16 Jul 2021
| 16 Jul 2021
Molecular composition and volatility of multi-generation products formed from isoprene oxidation by nitrate radical
Rongrong Wu
Institute of Energy and Climate Research, Troposphere (IEK-8),
Forschungszentrum Jülich GmbH, 52428 Jülich, Germany
College of Environmental Sciences and Engineering, State Key Joint
Laboratory of Environmental Simulation and Pollution Control, Peking
University, 100871, Beijing, China
Luc Vereecken
Institute of Energy and Climate Research, Troposphere (IEK-8),
Forschungszentrum Jülich GmbH, 52428 Jülich, Germany
Epameinondas Tsiligiannis
Department of Chemistry and Molecular Biology, University of
Gothenburg, 41296, Gothenburg, Sweden
Sungah Kang
Institute of Energy and Climate Research, Troposphere (IEK-8),
Forschungszentrum Jülich GmbH, 52428 Jülich, Germany
Sascha R. Albrecht
Institute of Energy and Climate Research, Troposphere (IEK-8),
Forschungszentrum Jülich GmbH, 52428 Jülich, Germany
present address: SOLIDpower GmbH, 52525 Heinsberg, Germany
Luisa Hantschke
Institute of Energy and Climate Research, Troposphere (IEK-8),
Forschungszentrum Jülich GmbH, 52428 Jülich, Germany
Defeng Zhao
Department of Atmospheric and Oceanic Sciences & Institute of
Atmospheric Sciences, Fudan University, 200438, Shanghai, China
Anna Novelli
Institute of Energy and Climate Research, Troposphere (IEK-8),
Forschungszentrum Jülich GmbH, 52428 Jülich, Germany
Hendrik Fuchs
Institute of Energy and Climate Research, Troposphere (IEK-8),
Forschungszentrum Jülich GmbH, 52428 Jülich, Germany
Ralf Tillmann
Institute of Energy and Climate Research, Troposphere (IEK-8),
Forschungszentrum Jülich GmbH, 52428 Jülich, Germany
Thorsten Hohaus
Institute of Energy and Climate Research, Troposphere (IEK-8),
Forschungszentrum Jülich GmbH, 52428 Jülich, Germany
Philip T. M. Carlsson
Institute of Energy and Climate Research, Troposphere (IEK-8),
Forschungszentrum Jülich GmbH, 52428 Jülich, Germany
Justin Shenolikar
Atmospheric Chemistry Department, Max Planck Institut für Chemie,
55128 Mainz, Germany
François Bernard
Institut de Combustion, Aérothermique, Réactivité et
Environnement (ICARE), UPR CNRS, 45071 Orléans, France
John N. Crowley
Atmospheric Chemistry Department, Max Planck Institut für Chemie,
55128 Mainz, Germany
Juliane L. Fry
Department of Chemistry, Reed College, Portland, OR 97202, USA
Bellamy Brownwood
Department of Chemistry, Reed College, Portland, OR 97202, USA
Joel A. Thornton
Department of Atmospheric Sciences, University of Washington, Seattle,
WA 98195, USA
Steven S. Brown
NOAA Chemical Sciences Laboratory, Boulder, CO 80305, USA
Department of Chemistry, University of Colorado, Boulder, CO 80309,
USA
Astrid Kiendler-Scharr
Institute of Energy and Climate Research, Troposphere (IEK-8),
Forschungszentrum Jülich GmbH, 52428 Jülich, Germany
Andreas Wahner
Institute of Energy and Climate Research, Troposphere (IEK-8),
Forschungszentrum Jülich GmbH, 52428 Jülich, Germany
Mattias Hallquist
Department of Chemistry and Molecular Biology, University of
Gothenburg, 41296, Gothenburg, Sweden
Institute of Energy and Climate Research, Troposphere (IEK-8),
Forschungszentrum Jülich GmbH, 52428 Jülich, Germany
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Cited
21 citations as recorded by crossref.
- Volatility of aerosol particles from NO3 oxidation of various biogenic organic precursors E. Graham et al. 10.5194/acp-23-7347-2023
- A Four Carbon Organonitrate as a Significant Product of Secondary Isoprene Chemistry E. Tsiligiannis et al. 10.1029/2021GL097366
- Volatility Measurements of Oxygenated Volatile Organics from Fresh and Aged Residential Wood Burning Emissions M. Priestley et al. 10.1021/acsearthspacechem.3c00066
- Nighttime reactions of a series of unsaturated alcohols with NO3•: Kinetics, products and mechanisms study Y. Xu et al. 10.1016/j.jes.2024.03.043
- Volatility of Cl-Initiated C12–C14 n-Alkylcyclohexane Secondary Organic Aerosol: Effects of NOx and Photoaging K. Wang et al. 10.1021/acsearthspacechem.2c00035
- Impact of ozone and inlet design on the quantification of isoprene-derived organic nitrates by thermal dissociation cavity ring-down spectroscopy (TD-CRDS) P. Dewald et al. 10.5194/amt-14-5501-2021
- Comparison of isoprene chemical mechanisms under atmospheric night-time conditions in chamber experiments: evidence of hydroperoxy aldehydes and epoxy products from NO3 oxidation P. Carlsson et al. 10.5194/acp-23-3147-2023
- Molecular Characteristics of Atmospheric Organosulfates During Summer and Winter Seasons in Two Cities of Southern and Northern China Y. Lin et al. 10.1029/2022JD036672
- Photolytically induced changes in composition and volatility of biogenic secondary organic aerosol from nitrate radical oxidation during night-to-day transition C. Wu et al. 10.5194/acp-21-14907-2021
- Identification of highly oxygenated organic molecules and their role in aerosol formation in the reaction of limonene with nitrate radical Y. Guo et al. 10.5194/acp-22-11323-2022
- Hydrolysis reactivity reveals significant seasonal variation in the composition of organic peroxides in ambient PM2.5 Y. Dai et al. 10.1016/j.scitotenv.2024.172143
- Application of fuzzy c-means clustering for analysis of chemical ionization mass spectra: insights into the gas phase chemistry of NO3-initiated oxidation of isoprene R. Wu et al. 10.5194/amt-17-1811-2024
- Effect of NO2 on nocturnal chemistry of isoprene: Gaseous oxygenated products and secondary organic aerosol formation Y. Chen et al. 10.1016/j.scitotenv.2022.156908
- Particulate-bound alkyl nitrate pollution and formation mechanisms in Beijing, China J. Yang et al. 10.5194/acp-24-123-2024
- Diel variation of seawater volatile organic compounds, DMSP-related compounds, and microbial plankton inside and outside a tropical coral reef ecosystem M. Masdeu-Navarro et al. 10.3389/fmars.2024.1341619
- Recent advances in mass spectrometry techniques for atmospheric chemistry research on molecular‐level W. Zhang et al. 10.1002/mas.21857
- Field Detection of Highly Oxygenated Organic Molecules in Shanghai by Chemical Ionization–Orbitrap Y. Zhang et al. 10.1021/acs.est.1c08346
- Fate of the nitrate radical at the summit of a semi-rural mountain site in Germany assessed with direct reactivity measurements P. Dewald et al. 10.5194/acp-22-7051-2022
- Seasonal variation in oxygenated organic molecules in urban Beijing and their contribution to secondary organic aerosol Y. Guo et al. 10.5194/acp-22-10077-2022
- Evaluation of isoprene nitrate chemistry in detailed chemical mechanisms A. Mayhew et al. 10.5194/acp-22-14783-2022
- Highly oxygenated organic molecule (HOM) formation in the isoprene oxidation by NO<sub>3</sub> radical D. Zhao et al. 10.5194/acp-21-9681-2021
20 citations as recorded by crossref.
- Volatility of aerosol particles from NO3 oxidation of various biogenic organic precursors E. Graham et al. 10.5194/acp-23-7347-2023
- A Four Carbon Organonitrate as a Significant Product of Secondary Isoprene Chemistry E. Tsiligiannis et al. 10.1029/2021GL097366
- Volatility Measurements of Oxygenated Volatile Organics from Fresh and Aged Residential Wood Burning Emissions M. Priestley et al. 10.1021/acsearthspacechem.3c00066
- Nighttime reactions of a series of unsaturated alcohols with NO3•: Kinetics, products and mechanisms study Y. Xu et al. 10.1016/j.jes.2024.03.043
- Volatility of Cl-Initiated C12–C14 n-Alkylcyclohexane Secondary Organic Aerosol: Effects of NOx and Photoaging K. Wang et al. 10.1021/acsearthspacechem.2c00035
- Impact of ozone and inlet design on the quantification of isoprene-derived organic nitrates by thermal dissociation cavity ring-down spectroscopy (TD-CRDS) P. Dewald et al. 10.5194/amt-14-5501-2021
- Comparison of isoprene chemical mechanisms under atmospheric night-time conditions in chamber experiments: evidence of hydroperoxy aldehydes and epoxy products from NO3 oxidation P. Carlsson et al. 10.5194/acp-23-3147-2023
- Molecular Characteristics of Atmospheric Organosulfates During Summer and Winter Seasons in Two Cities of Southern and Northern China Y. Lin et al. 10.1029/2022JD036672
- Photolytically induced changes in composition and volatility of biogenic secondary organic aerosol from nitrate radical oxidation during night-to-day transition C. Wu et al. 10.5194/acp-21-14907-2021
- Identification of highly oxygenated organic molecules and their role in aerosol formation in the reaction of limonene with nitrate radical Y. Guo et al. 10.5194/acp-22-11323-2022
- Hydrolysis reactivity reveals significant seasonal variation in the composition of organic peroxides in ambient PM2.5 Y. Dai et al. 10.1016/j.scitotenv.2024.172143
- Application of fuzzy c-means clustering for analysis of chemical ionization mass spectra: insights into the gas phase chemistry of NO3-initiated oxidation of isoprene R. Wu et al. 10.5194/amt-17-1811-2024
- Effect of NO2 on nocturnal chemistry of isoprene: Gaseous oxygenated products and secondary organic aerosol formation Y. Chen et al. 10.1016/j.scitotenv.2022.156908
- Particulate-bound alkyl nitrate pollution and formation mechanisms in Beijing, China J. Yang et al. 10.5194/acp-24-123-2024
- Diel variation of seawater volatile organic compounds, DMSP-related compounds, and microbial plankton inside and outside a tropical coral reef ecosystem M. Masdeu-Navarro et al. 10.3389/fmars.2024.1341619
- Recent advances in mass spectrometry techniques for atmospheric chemistry research on molecular‐level W. Zhang et al. 10.1002/mas.21857
- Field Detection of Highly Oxygenated Organic Molecules in Shanghai by Chemical Ionization–Orbitrap Y. Zhang et al. 10.1021/acs.est.1c08346
- Fate of the nitrate radical at the summit of a semi-rural mountain site in Germany assessed with direct reactivity measurements P. Dewald et al. 10.5194/acp-22-7051-2022
- Seasonal variation in oxygenated organic molecules in urban Beijing and their contribution to secondary organic aerosol Y. Guo et al. 10.5194/acp-22-10077-2022
- Evaluation of isoprene nitrate chemistry in detailed chemical mechanisms A. Mayhew et al. 10.5194/acp-22-14783-2022
Latest update: 24 Apr 2024
Short summary
Isoprene is the biogenic volatile organic compound with the largest emissions rates. The nighttime reaction of isoprene with the NO3 radical has a large potential to contribute to SOA. We classified isoprene nitrates into generations and proposed formation pathways. Considering the potential functionalization of the isoprene nitrates we propose that mainly isoprene dimers contribute to SOA formation from the isoprene NO3 reactions with at least a 5 % mass yield.
Isoprene is the biogenic volatile organic compound with the largest emissions rates. The...
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