Articles | Volume 21, issue 13
https://doi.org/10.5194/acp-21-10159-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-21-10159-2021
© Author(s) 2021. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Measurement report
| 
07 Jul 2021
Measurement report |
| 07 Jul 2021
| 07 Jul 2021
Measurement report: Spatial variability of northern Iberian rainfall stable isotope values – investigating atmospheric controls on daily and monthly timescales
Ana Moreno
Department of Geoenvironmental Processes and Global Change, Pyrenean Institute of Ecology – CSIC, Avda. Montañana 1005, 50059 Zaragoza,
Spain
Miguel Iglesias
Department of Geology, University of Oviedo, C/Arias de Velasco,
s/no 33005 Oviedo, Spain
Centro de Investigaciones sobre Desertificación, Consejo Superior
de Investigaciones Científicas (CIDE-CSIC), 46113 Moncada, Valencia,
Spain
Carlos Pérez-Mejías
Institute of Global Environmental Change, Xi'an Jiaotong University, Xi'an, 710049, China
Department of Geoenvironmental Processes and Global Change, Pyrenean Institute of Ecology – CSIC, Avda. Montañana 1005, 50059 Zaragoza,
Spain
Miguel Bartolomé
Earth Sciences Department, University of Zaragoza, C/Pedro Cerbuna 12, 50009 Zaragoza, Spain
Departamento de Geología. Museo Nacional de Ciencias Naturales – CSIC, C/José Gutiérrez Abascal 2, 28006 Madrid, Spain
Carlos Sancho
Earth Sciences Department, University of Zaragoza, C/Pedro Cerbuna 12, 50009 Zaragoza, Spain
deceased, February 2019
Heather Stoll
Geological Institute, NO G59, Department of Earth Sciences,
Sonneggstrasse 5, ETH, 8092 Zurich, Switzerland
Isabel Cacho
CRG Marine Geosciences, Department de Dinàmica de la Terra i
de l'Oceà, Facultat de Ciències de la Terra, Universitat de Barcelona,
C/Martí i Franquès, s/no, 08028 Barcelona, Spain
Jaime Frigola
CRG Marine Geosciences, Department de Dinàmica de la Terra i
de l'Oceà, Facultat de Ciències de la Terra, Universitat de Barcelona,
C/Martí i Franquès, s/no, 08028 Barcelona, Spain
Cinta Osácar
Earth Sciences Department, University of Zaragoza, C/Pedro Cerbuna 12, 50009 Zaragoza, Spain
Arsenio Muñoz
Earth Sciences Department, University of Zaragoza, C/Pedro Cerbuna 12, 50009 Zaragoza, Spain
Antonio Delgado-Huertas
Stable Isotope Biogeochemistry Laboratory, IACT-CSIC, Avda. de Las
Palmeras no 4, 18100 Armilla (Granada), Spain
Ileana Bladé
Group of Meteorology, Department of Applied Physics, Faculty of
Physics, University of Barcelona, Martí i Franqués, 1, 08028
Barcelona, Spain
Françoise Vimeux
HydroSciences Montpellier (HSM), UMR 5569 (UM, CNRS, IRD), 34095
Montpellier, France
Institut Pierre Simon Laplace (IPSL), Laboratoire des Sciences de
Climat et du l'Environnement (LSCE), UMR 8212 (CEA, CNRS, UVSQ), 91191
Gif-sur-Yvette, France
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In this work we study the microclimate and the geomorphological features of Devaux ice cave in the Central Pyrenees. The research is based on cave monitoring, geomorphology, and geochemical analyses. We infer two different thermal regimes. The cave is impacted by flooding in late winter/early spring when the main outlets freeze, damming the water inside. Rock temperatures below 0°C and the absence of drip water indicate frozen rock, while relict ice formations record past damming events.
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The Cryosphere, 17, 3177–3192, https://doi.org/10.5194/tc-17-3177-2023, https://doi.org/10.5194/tc-17-3177-2023, 2023
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The Aneto glacier, the largest glacier in the Pyrenees, has shown continuous surface and ice thickness losses in the last decades. In this study, we examine changes in its surface and ice thickness for 1981–2022 and the remaining ice thickness in 2020. During these 41 years, the glacier has shrunk by 64.7 %, and the ice thickness has decreased by 30.5 m on average. The mean ice thickness in 2022 was 11.9 m, compared to 32.9 m in 1981. The results highlight the critical situation of the glacier.
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Cave monitoring studies including cave drip water are unique opportunities to sample water which has percolated through the soil and rock. The change in drip water chemistry is resolved over the course of 16 months, inferring seasonal and hydrological variations in soil and karst processes at the water–air and water–rock interface. Such data sets improve the understanding of hydrological and hydrochemical processes and ultimately advance the interpretation of geochemical stalagmite records.
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Based on the analysis of the response of coccolithophores’ morphological attributes in a laboratory dissolution experiment and surface sediment samples from the South China Sea, we proposed that the thickness shape (ks) factor of fossil coccoliths together with the normalized ks variation, which is the ratio of the standard deviation of ks (σ) over the mean ks (σ/ks), is a robust and novel proxy to reconstruct past changes in deep ocean carbon chemistry.
Thibauld M. Béjard, Andrés S. Rigual-Hernández, José A. Flores, Javier P. Tarruella, Xavier Durrieu de Madron, Isabel Cacho, Neghar Haghipour, Aidan Hunter, and Francisco J. Sierro
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The Mediterranean Sea is undergoing a rapid and unprecedented environmental change. Planktic foraminifera calcification is affected on different timescales. On seasonal and interannual scales, calcification trends differ according to the species and are linked mainly to sea surface temperatures and carbonate system parameters, while comparison with pre/post-industrial assemblages shows that all three species have reduced their calcification between 10 % to 35 % according to the species.
Miguel Bartolomé, Gérard Cazenave, Marc Luetscher, Christoph Spötl, Fernando Gázquez, Ánchel Belmonte, Alexandra V. Turchyn, Juan Ignacio López-Moreno, and Ana Moreno
The Cryosphere, 17, 477–497, https://doi.org/10.5194/tc-17-477-2023, https://doi.org/10.5194/tc-17-477-2023, 2023
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In this work we study the microclimate and the geomorphological features of Devaux ice cave in the Central Pyrenees. The research is based on cave monitoring, geomorphology, and geochemical analyses. We infer two different thermal regimes. The cave is impacted by flooding in late winter/early spring when the main outlets freeze, damming the water inside. Rock temperatures below 0°C and the absence of drip water indicate frozen rock, while relict ice formations record past damming events.
Jessica G. M. Crumpton-Banks, Thomas Tanner, Ivan Hernández Almeida, James W. B. Rae, and Heather Stoll
Biogeosciences, 19, 5633–5644, https://doi.org/10.5194/bg-19-5633-2022, https://doi.org/10.5194/bg-19-5633-2022, 2022
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Past ocean carbon is reconstructed using proxies, but it is unknown whether preparing ocean sediment for one proxy might damage the data given by another. We have tested whether the extraction of an organic proxy archive from sediment samples impacts the geochemistry of tiny shells also within the sediment. We find no difference in shell geochemistry between samples which come from treated and untreated sediment. This will help us to maximize scientific return from valuable sediment samples.
José Guitián, Miguel Ángel Fuertes, José-Abel Flores, Iván Hernández-Almeida, and Heather Stoll
Biogeosciences, 19, 5007–5019, https://doi.org/10.5194/bg-19-5007-2022, https://doi.org/10.5194/bg-19-5007-2022, 2022
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The effect of environmental conditions on the degree of calcification of marine phytoplankton remains unclear. This study implements a new microscopic approach to quantify the calcification of ancient coccolithophores, using North Atlantic sediments. Results show significant differences in the thickness and shape factor of coccoliths for samples with minimum dissolution, providing the first evaluation of phytoplankton physiology adaptation to million-year-scale variable environmental conditions.
Franziska A. Lechleitner, Christopher C. Day, Oliver Kost, Micah Wilhelm, Negar Haghipour, Gideon M. Henderson, and Heather M. Stoll
Clim. Past, 17, 1903–1918, https://doi.org/10.5194/cp-17-1903-2021, https://doi.org/10.5194/cp-17-1903-2021, 2021
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Soil respiration is a critical but poorly constrained component of the global carbon cycle. We analyse the effect of changing soil respiration rates on the stable carbon isotope ratio of speleothems from northern Spain covering the last deglaciation. Using geochemical analysis and forward modelling we quantify the processes affecting speleothem stable carbon isotope ratios and extract a signature of increasing soil respiration synchronous with deglacial warming.
Hongrui Zhang, Chuanlian Liu, Luz María Mejía, and Heather Stoll
Biogeosciences, 18, 1909–1916, https://doi.org/10.5194/bg-18-1909-2021, https://doi.org/10.5194/bg-18-1909-2021, 2021
Ana Moreno, Miguel Bartolomé, Juan Ignacio López-Moreno, Jorge Pey, Juan Pablo Corella, Jordi García-Orellana, Carlos Sancho, María Leunda, Graciela Gil-Romera, Penélope González-Sampériz, Carlos Pérez-Mejías, Francisco Navarro, Jaime Otero-García, Javier Lapazaran, Esteban Alonso-González, Cristina Cid, Jerónimo López-Martínez, Belén Oliva-Urcia, Sérgio Henrique Faria, María José Sierra, Rocío Millán, Xavier Querol, Andrés Alastuey, and José M. García-Ruíz
The Cryosphere, 15, 1157–1172, https://doi.org/10.5194/tc-15-1157-2021, https://doi.org/10.5194/tc-15-1157-2021, 2021
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Our study of the chronological sequence of Monte Perdido Glacier in the Central Pyrenees (Spain) reveals that, although the intense warming associated with the Roman period or Medieval Climate Anomaly produced important ice mass losses, it was insufficient to make this glacier disappear. By contrast, recent global warming has melted away almost 600 years of ice accumulated since the Little Ice Age, jeopardising the survival of this and other southern European glaciers over the next few decades.
Catarina Cavaleiro, Antje H. L. Voelker, Heather Stoll, Karl-Heinz Baumann, and Michal Kucera
Clim. Past, 16, 2017–2037, https://doi.org/10.5194/cp-16-2017-2020, https://doi.org/10.5194/cp-16-2017-2020, 2020
Laia Comas-Bru, Kira Rehfeld, Carla Roesch, Sahar Amirnezhad-Mozhdehi, Sandy P. Harrison, Kamolphat Atsawawaranunt, Syed Masood Ahmad, Yassine Ait Brahim, Andy Baker, Matthew Bosomworth, Sebastian F. M. Breitenbach, Yuval Burstyn, Andrea Columbu, Michael Deininger, Attila Demény, Bronwyn Dixon, Jens Fohlmeister, István Gábor Hatvani, Jun Hu, Nikita Kaushal, Zoltán Kern, Inga Labuhn, Franziska A. Lechleitner, Andrew Lorrey, Belen Martrat, Valdir Felipe Novello, Jessica Oster, Carlos Pérez-Mejías, Denis Scholz, Nick Scroxton, Nitesh Sinha, Brittany Marie Ward, Sophie Warken, Haiwei Zhang, and SISAL Working Group members
Earth Syst. Sci. Data, 12, 2579–2606, https://doi.org/10.5194/essd-12-2579-2020, https://doi.org/10.5194/essd-12-2579-2020, 2020
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This paper presents an updated version of the SISAL (Speleothem Isotope Synthesis and Analysis) database. This new version contains isotopic data from 691 speleothem records from 294 cave sites and new age–depth models, including their uncertainties, for 512 speleothems.
Matías Frugone-Álvarez, Claudio Latorre, Fernando Barreiro-Lostres, Santiago Giralt, Ana Moreno, Josué Polanco-Martínez, Antonio Maldonado, María Laura Carrevedo, Patricia Bernárdez, Ricardo Prego, Antonio Delgado Huertas, Magdalena Fuentealba, and Blas Valero-Garcés
Clim. Past, 16, 1097–1125, https://doi.org/10.5194/cp-16-1097-2020, https://doi.org/10.5194/cp-16-1097-2020, 2020
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The manuscript identifies the main volcanic phases in the Laguna del Maule volcanic field and their impact in the lake basin through the late glacial and Holocene. We show that the bio-productivity and geochemical variabilities in the lake are related with climatic dynamics type ENSO, SPA and SWW and that the main phases are synchronous with the major regional climate changes on millennial timescales.
Sergio M. Vicente-Serrano, Cesar Azorin-Molina, Marina Peña-Gallardo, Miquel Tomas-Burguera, Fernando Domínguez-Castro, Natalia Martín-Hernández, Santiago Beguería, Ahmed El Kenawy, Iván Noguera, and Mónica García
Nat. Hazards Earth Syst. Sci., 19, 1189–1213, https://doi.org/10.5194/nhess-19-1189-2019, https://doi.org/10.5194/nhess-19-1189-2019, 2019
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Drought is a major driver of vegetation activity in Spain. Here we used a high-resolution remote-sensing dataset spanning the period from 1981 to 2015 to assess the sensitivity of 23 vegetation types to drought across Spain. Results demonstrate that vegetation activity is controlled largely by the interannual variability of drought. Nevertheless, there are some considerable spatio-temporal variations, which can be linked to differences in land cover and aridity conditions.
Albert Català, Isabel Cacho, Jaime Frigola, Leopoldo D. Pena, and Fabrizio Lirer
Clim. Past, 15, 927–942, https://doi.org/10.5194/cp-15-927-2019, https://doi.org/10.5194/cp-15-927-2019, 2019
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We present a new high-resolution sea surface temperature (SST) reconstruction for the Holocene (last 11 700 years) in the westernmost Mediterranean Sea. We identify three sub-periods: the Early Holocene with warmest SST; the Middle Holocene with a cooling trend ending at 4200 years, which is identified as a double peak cooling event that marks the transition between the Middle and Late Holocene; and the Late Holocene with very different behaviour in both long- and short-term SST variability.
Monica Bini, Giovanni Zanchetta, Aurel Perşoiu, Rosine Cartier, Albert Català, Isabel Cacho, Jonathan R. Dean, Federico Di Rita, Russell N. Drysdale, Martin Finnè, Ilaria Isola, Bassem Jalali, Fabrizio Lirer, Donatella Magri, Alessia Masi, Leszek Marks, Anna Maria Mercuri, Odile Peyron, Laura Sadori, Marie-Alexandrine Sicre, Fabian Welc, Christoph Zielhofer, and Elodie Brisset
Clim. Past, 15, 555–577, https://doi.org/10.5194/cp-15-555-2019, https://doi.org/10.5194/cp-15-555-2019, 2019
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The Mediterranean region has returned some of the clearest evidence of a climatically dry period occurring approximately 4200 years ago. We reviewed selected proxies to infer regional climate patterns between 4.3 and 3.8 ka. Temperature data suggest a cooling anomaly, even if this is not uniform, whereas winter was drier, along with dry summers. However, some exceptions to this prevail, where wetter condition seems to have persisted, suggesting regional heterogeneity.
Hongrui Zhang, Heather Stoll, Clara Bolton, Xiaobo Jin, and Chuanlian Liu
Biogeosciences, 15, 4759–4775, https://doi.org/10.5194/bg-15-4759-2018, https://doi.org/10.5194/bg-15-4759-2018, 2018
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The sinking speeds of coccoliths are relevant for laboratory methods to separate coccoliths for geochemical analysis. However, in the absence of estimates of coccolith settling velocity, previous implementations have depended mainly on time-consuming method development by trial and error. In this study, the sinking velocities of cocooliths were carefully measured for the first time. We also provide an estimation of coccolith sinking velocity by shape, which will make coccolith separation easier.
Sergio M. Vicente-Serrano, Raquel Nieto, Luis Gimeno, Cesar Azorin-Molina, Anita Drumond, Ahmed El Kenawy, Fernando Dominguez-Castro, Miquel Tomas-Burguera, and Marina Peña-Gallardo
Earth Syst. Dynam., 9, 915–937, https://doi.org/10.5194/esd-9-915-2018, https://doi.org/10.5194/esd-9-915-2018, 2018
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We analyzed changes in surface relative humidity (RH) at the global scale from 1979 to 2014 and compared the variability and trends in RH with those in land evapotranspiration and ocean evaporation in moisture source areas across a range of selected regions worldwide. Our results stress that the different hypotheses that may explain the decrease in RH under a global warming scenario could act together to explain recent RH trends.
Saúl González-Lemos, José Guitián, Miguel-Ángel Fuertes, José-Abel Flores, and Heather M. Stoll
Biogeosciences, 15, 1079–1091, https://doi.org/10.5194/bg-15-1079-2018, https://doi.org/10.5194/bg-15-1079-2018, 2018
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Changes in atmospheric carbon dioxide affect ocean chemistry and the ability of marine organisms to manufacture shells from calcium carbonate. We describe a technique to obtain more reproducible measurements of the thickness of calcium carbonate shells made by microscopic marine algae called coccolithophores, which will allow researchers to compare how the shell thickness responds to variations in ocean chemistry in the past and present.
Jesús Revuelto, Cesar Azorin-Molina, Esteban Alonso-González, Alba Sanmiguel-Vallelado, Francisco Navarro-Serrano, Ibai Rico, and Juan Ignacio López-Moreno
Earth Syst. Sci. Data, 9, 993–1005, https://doi.org/10.5194/essd-9-993-2017, https://doi.org/10.5194/essd-9-993-2017, 2017
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This work describes the snow and meteorological data set available for the Izas Experimental Catchment in the Central Spanish Pyrenees, from the 2011 to 2017 snow seasons. The climatic data set consists of (i) continuous meteorological variables acquired from an automatic weather station (AWS), (ii) detailed information on snow depth distribution collected with a terrestrial laser scanner for certain dates and (iii) time-lapse images showing the evolution of the snow-covered area.
Timothé Bolliet, Patrick Brockmann, Valérie Masson-Delmotte, Franck Bassinot, Valérie Daux, Dominique Genty, Amaelle Landais, Marlène Lavrieux, Elisabeth Michel, Pablo Ortega, Camille Risi, Didier M. Roche, Françoise Vimeux, and Claire Waelbroeck
Clim. Past, 12, 1693–1719, https://doi.org/10.5194/cp-12-1693-2016, https://doi.org/10.5194/cp-12-1693-2016, 2016
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This paper presents a new database of past climate proxies which aims to facilitate the distribution of data by using a user-friendly interface. Available data from the last 40 years are often fragmented, with lots of different formats, and online libraries are sometimes nonintuitive. We thus built a new dynamic web portal for data browsing, visualizing, and batch downloading of hundreds of datasets presenting a homogeneous format.
Mercè Cisneros, Isabel Cacho, Jaime Frigola, Miquel Canals, Pere Masqué, Belen Martrat, Marta Casado, Joan O. Grimalt, Leopoldo D. Pena, Giulia Margaritelli, and Fabrizio Lirer
Clim. Past, 12, 849–869, https://doi.org/10.5194/cp-12-849-2016, https://doi.org/10.5194/cp-12-849-2016, 2016
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We present a high-resolution multi-proxy study about the evolution of sea surface conditions along the last 2700 yr in the north-western Mediterranean Sea based on five sediment records from two different sites north of Minorca. The novelty of the results and the followed approach, constructing stack records from the studied proxies to preserve the most robust patterns, provides a special value to the study. This complex period appears to have significant regional changes in the climatic signal.
Juan Ignacio López-Moreno, Jesús Revuelto, Ibai Rico, Javier Chueca-Cía, Asunción Julián, Alfredo Serreta, Enrique Serrano, Sergio Martín Vicente-Serrano, Cesar Azorin-Molina, Esteban Alonso-González, and José María García-Ruiz
The Cryosphere, 10, 681–694, https://doi.org/10.5194/tc-10-681-2016, https://doi.org/10.5194/tc-10-681-2016, 2016
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This paper analyzes the evolution of the Monte Perdido Glacier, Spanish Pyrenees, since 1981. Changes in ice volume were estimated by geodetic methods and terrestrial laser scanning. An acceleration in ice thinning is detected during the 21st century. Local climatic changes observed during the study period do not seem sufficient to explain the acceleration. The strong disequilibrium between the glacier and the current climate and feedback mechanisms seems to be the most plausible explanation.
P. Pereira, A. Gimeìnez-Morera, A. Novara, S. Keesstra, A. Jordán, R. E. Masto, E. Brevik, C. Azorin-Molina, and A. Cerdà
Hydrol. Earth Syst. Sci. Discuss., https://doi.org/10.5194/hessd-12-12947-2015, https://doi.org/10.5194/hessd-12-12947-2015, 2015
Revised manuscript has not been submitted
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Road and railway embankments contribute importantly to soil and water losses in South-Eastern Spain. Comparing with other land uses as scrubland and citrus plantations, road and railway embankments increased exponentially the amount of sediment transport and runoff. Restoration programs are needed to decrease soil and water losses in these man-made infrastructures.
I. Hernández-Almeida, F.-J. Sierro, I. Cacho, and J.-A. Flores
Clim. Past, 11, 687–696, https://doi.org/10.5194/cp-11-687-2015, https://doi.org/10.5194/cp-11-687-2015, 2015
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This manuscript presents new Mg/Ca and previously published δ18O measurements of Neogloboquadrina pachyderma sinistral for MIS 31-19, from a sediment core from the subpolar North Atlantic. The mechanism proposed here involves northward subsurface transport of warm and salty subtropical waters during periods of weaker AMOC, leading to ice-sheet instability and IRD discharge. This is the first time that these rapid climate oscillations are described for the early Pleistocene.
O. Margalef, I. Cacho, S. Pla-Rabes, N. Cañellas-Boltà, J. J. Pueyo, A. Sáez, L. D. Pena, B. L. Valero-Garcés, V. Rull, and S. Giralt
Clim. Past Discuss., https://doi.org/10.5194/cpd-11-1407-2015, https://doi.org/10.5194/cpd-11-1407-2015, 2015
Manuscript not accepted for further review
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The Rano Aroi peat record (Easter Island, 27ºS) is characterized by six major events of enhanced precipitation between 38 and 65 kyr BP coinciding with Heinrich and Dansgaard-Oeschger (DO) Stadials. These events draw a coherent regional picture involving atmospheric and oceanic reorganization. The singular location of Easter Island, filling a gap in an area where marine records are not available, contributes to understand the mechanisms behind these global rapid climatic excursions.
A. Okazaki, Y. Satoh, G. Tremoy, F. Vimeux, R. Scheepmaker, and K. Yoshimura
Atmos. Chem. Phys., 15, 3193–3204, https://doi.org/10.5194/acp-15-3193-2015, https://doi.org/10.5194/acp-15-3193-2015, 2015
J. Revuelto, J. I. López-Moreno, C. Azorin-Molina, and S. M. Vicente-Serrano
The Cryosphere, 8, 1989–2006, https://doi.org/10.5194/tc-8-1989-2014, https://doi.org/10.5194/tc-8-1989-2014, 2014
M. N. Müller, M. Lebrato, U. Riebesell, J. Barcelos e Ramos, K. G. Schulz, S. Blanco-Ameijeiras, S. Sett, A. Eisenhauer, and H. M. Stoll
Biogeosciences, 11, 1065–1075, https://doi.org/10.5194/bg-11-1065-2014, https://doi.org/10.5194/bg-11-1065-2014, 2014
C. Risi, A. Landais, R. Winkler, and F. Vimeux
Clim. Past, 9, 2173–2193, https://doi.org/10.5194/cp-9-2173-2013, https://doi.org/10.5194/cp-9-2173-2013, 2013
Related subject area
Subject: Isotopes | Research Activity: Field Measurements | Altitude Range: Troposphere | Science Focus: Chemistry (chemical composition and reactions)
A seasonal analysis of aerosol NO3− sources and NOx oxidation pathways in the Southern Ocean marine boundary layer
Nitrate chemistry in the northeast US – Part 1: Nitrogen isotope seasonality tracks nitrate formation chemistry
Nitrate chemistry in the northeast US – Part 2: Oxygen isotopes reveal differences in particulate and gas-phase formation
Photolytic modification of seasonal nitrate isotope cycles in East Antarctica
Atmospheric methane isotopes identify inventory knowledge gaps in the Surat Basin, Australia, coal seam gas and agricultural regions
Methane (CH4) sources in Krakow, Poland: insights from isotope analysis
Isotopic signatures of major methane sources in the coal seam gas fields and adjacent agricultural districts, Queensland, Australia
Measurement report: Nitrogen isotopes (δ15N) and first quantification of oxygen isotope anomalies (Δ17O, δ18O) in atmospheric nitrogen dioxide
Isotopic constraints on atmospheric sulfate formation pathways in the Mt. Everest region, southern Tibetan Plateau
Baffin Bay sea ice extent and synoptic moisture transport drive water vapor isotope (δ18O, δ2H, and deuterium excess) variability in coastal northwest Greenland
New evidence for atmospheric mercury transformations in the marine boundary layer from stable mercury isotopes
The isotopic composition of atmospheric nitrous oxide observed at the high-altitude research station Jungfraujoch, Switzerland
Deposition, recycling, and archival of nitrate stable isotopes between the air–snow interface: comparison between Dronning Maud Land and Dome C, Antarctica
Oxygen and sulfur mass-independent isotopic signatures in black crusts: the complementary negative Δ33S reservoir of sulfate aerosols?
Atmospheric radiocarbon measurements to quantify CO2 emissions in the UK from 2014 to 2015
An improved estimate for the δ13C and δ18O signatures of carbon monoxide produced from atmospheric oxidation of volatile organic compounds
Seasonality in the Δ33S measured in urban aerosols highlights an additional oxidation pathway for atmospheric SO2
The Δ17O and δ18O values of atmospheric nitrates simultaneously collected downwind of anthropogenic sources – implications for polluted air masses
A very limited role of tropospheric chlorine as a sink of the greenhouse gas methane
Detection and variability of combustion-derived vapor in an urban basin
Stable sulfur isotope measurements to trace the fate of SO2 in the Athabasca oil sands region
Triple oxygen isotopes indicate urbanization affects sources of nitrate in wet and dry atmospheric deposition
Isotopic constraints on heterogeneous sulfate production in Beijing haze
Estimation of the fossil fuel component in atmospheric CO2 based on radiocarbon measurements at the Beromünster tall tower, Switzerland
Constraining N2O emissions since 1940 using firn air isotope measurements in both hemispheres
Seasonal variations of triple oxygen isotopic compositions of atmospheric sulfate, nitrate, and ozone at Dumont d'Urville, coastal Antarctica
Carbon isotopic signature of coal-derived methane emissions to the atmosphere: from coalification to alteration
Isotopic composition for source identification of mercury in atmospheric fine particles
Isotopic constraints on the role of hypohalous acids in sulfate aerosol formation in the remote marine boundary layer
In situ observations of the isotopic composition of methane at the Cabauw tall tower site
Oxygen isotope mass balance of atmospheric nitrate at Dome C, East Antarctica, during the OPALE campaign
Isotopic effects of nitrate photochemistry in snow: a field study at Dome C, Antarctica
Stable carbon isotope ratios of ambient secondary organic aerosols in Toronto
WAIS Divide ice core suggests sustained changes in the atmospheric formation pathways of sulfate and nitrate since the 19th century in the extratropical Southern Hemisphere
Stable carbon isotope ratios of toluene in the boundary layer and the lower free troposphere
Emission ratio and isotopic signatures of molecular hydrogen emissions from tropical biomass burning
Can the carbon isotopic composition of methane be reconstructed from multi-site firn air measurements?
Air–snow transfer of nitrate on the East Antarctic Plateau – Part 1: Isotopic evidence for a photolytically driven dynamic equilibrium in summer
Chemical characterization and stable carbon isotopic composition of particulate Polycyclic Aromatic Hydrocarbons issued from combustion of 10 Mediterranean woods
Quantification of the carbonaceous matter origin in submicron marine aerosol by 13C and 14C isotope analysis
Temporal and spatial variability of the stable isotopic composition of atmospheric molecular hydrogen: observations at six EUROHYDROS stations
Continuous isotopic composition measurements of tropospheric CO2 at Jungfraujoch (3580 m a.s.l.), Switzerland: real-time observation of regional pollution events
Anthropogenic imprints on nitrogen and oxygen isotopic composition of precipitation nitrate in a nitrogen-polluted city in southern China
Analysis of 13C and 18O isotope data of CO2 in CARIBIC aircraft samples as tracers of upper troposphere/lower stratosphere mixing and the global carbon cycle
Tracing the fate of atmospheric nitrate deposited onto a forest ecosystem in Eastern Asia using Δ17O
Photolysis imprint in the nitrate stable isotope signal in snow and atmosphere of East Antarctica and implications for reactive nitrogen cycling
Sources and transport of Δ14C in CO2 within the Mexico City Basin and vicinity
Jessica M. Burger, Emily Joyce, Meredith G. Hastings, Kurt A. M. Spence, and Katye E. Altieri
Atmos. Chem. Phys., 23, 5605–5622, https://doi.org/10.5194/acp-23-5605-2023, https://doi.org/10.5194/acp-23-5605-2023, 2023
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A seasonal analysis of the nitrogen isotopes of atmospheric nitrate over the remote Southern Ocean reveals that similar natural NOx sources dominate in spring and summer, while winter is representative of background-level conditions. The oxygen isotopes suggest that similar oxidation pathways involving more ozone occur in spring and winter, while the hydroxyl radical is the main oxidant in summer. This work helps to constrain NOx cycling and oxidant budgets in a data-sparse remote marine region.
Claire Bekker, Wendell W. Walters, Lee T. Murray, and Meredith G. Hastings
Atmos. Chem. Phys., 23, 4185–4201, https://doi.org/10.5194/acp-23-4185-2023, https://doi.org/10.5194/acp-23-4185-2023, 2023
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Nitrate is a critical component of the atmosphere that degrades air quality and ecosystem health. We have investigated the nitrogen isotope compositions of nitrate from deposition samples collected across the northeastern United States. Spatiotemporal variability in the nitrogen isotope compositions was found to track with nitrate formation chemistry. Our results highlight that nitrogen isotope compositions may be a robust tool for improving model representation of nitrate chemistry.
Heejeong Kim, Wendell W. Walters, Claire Bekker, Lee T. Murray, and Meredith G. Hastings
Atmos. Chem. Phys., 23, 4203–4219, https://doi.org/10.5194/acp-23-4203-2023, https://doi.org/10.5194/acp-23-4203-2023, 2023
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Atmospheric nitrate has an important impact on human and ecosystem health. We evaluated atmospheric nitrate formation pathways in the northeastern US utilizing oxygen isotope compositions, which indicated a significant difference between the phases of nitrate (i.e., gas vs. particle). Comparing the observations with model simulations indicated that N2O5 hydrolysis chemistry was overpredicted. Our study has important implications for improving atmospheric chemistry model representation.
Pete D. Akers, Joël Savarino, Nicolas Caillon, Olivier Magand, and Emmanuel Le Meur
Atmos. Chem. Phys., 22, 15637–15657, https://doi.org/10.5194/acp-22-15637-2022, https://doi.org/10.5194/acp-22-15637-2022, 2022
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Nitrate isotopes in Antarctic ice do not preserve the seasonal isotopic cycles of the atmosphere, which limits their use to study the past. We studied nitrate along an 850 km Antarctic transect to learn how these cycles are changed by sunlight-driven chemistry in the snow. Our findings suggest that the snow accumulation rate and other environmental signals can be extracted from nitrate with the right sampling and analytical approaches.
Bryce F. J. Kelly, Xinyi Lu, Stephen J. Harris, Bruno G. Neininger, Jorg M. Hacker, Stefan Schwietzke, Rebecca E. Fisher, James L. France, Euan G. Nisbet, David Lowry, Carina van der Veen, Malika Menoud, and Thomas Röckmann
Atmos. Chem. Phys., 22, 15527–15558, https://doi.org/10.5194/acp-22-15527-2022, https://doi.org/10.5194/acp-22-15527-2022, 2022
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This study explores using the composition of methane of in-flight atmospheric air samples for greenhouse gas inventory verification. The air samples were collected above one of the largest coal seam gas production regions in the world. Adjacent to these gas fields are coal mines, Australia's largest cattle feedlot, and over 1 million grazing cattle. The results are also used to identify methane mitigation opportunities.
Malika Menoud, Carina van der Veen, Jaroslaw Necki, Jakub Bartyzel, Barbara Szénási, Mila Stanisavljević, Isabelle Pison, Philippe Bousquet, and Thomas Röckmann
Atmos. Chem. Phys., 21, 13167–13185, https://doi.org/10.5194/acp-21-13167-2021, https://doi.org/10.5194/acp-21-13167-2021, 2021
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Using measurements of methane isotopes in ambient air and a 3D atmospheric transport model, in Krakow, Poland, we mainly detected fossil-fuel-related sources, coming from coal mining in Silesia and from the use of natural gas in the city. Emission inventories report large emissions from coal mine activity in Silesia, which is in agreement with our measurements. However, methane sources in the urban area of Krakow related to the use of fossil fuels might be underestimated in the inventories.
Xinyi Lu, Stephen J. Harris, Rebecca E. Fisher, James L. France, Euan G. Nisbet, David Lowry, Thomas Röckmann, Carina van der Veen, Malika Menoud, Stefan Schwietzke, and Bryce F. J. Kelly
Atmos. Chem. Phys., 21, 10527–10555, https://doi.org/10.5194/acp-21-10527-2021, https://doi.org/10.5194/acp-21-10527-2021, 2021
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Many coal seam gas (CSG) facilities in the Surat Basin, Australia, are adjacent to other sources of methane, including agricultural, urban, and natural seeps. This makes it challenging to estimate the amount of methane being emitted into the atmosphere from CSG facilities. This research demonstrates that measurements of the carbon and hydrogen stable isotopic composition of methane can distinguish between and apportion methane emissions from CSG facilities, cattle, and many other sources.
Sarah Albertin, Joël Savarino, Slimane Bekki, Albane Barbero, and Nicolas Caillon
Atmos. Chem. Phys., 21, 10477–10497, https://doi.org/10.5194/acp-21-10477-2021, https://doi.org/10.5194/acp-21-10477-2021, 2021
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We report an efficient method to collect atmospheric NO2 adapted for multi-isotopic analysis and present the first NO2 triple oxygen and double nitrogen isotope measurements. Atmospheric samplings carried out in Grenoble, France, highlight the NO2 isotopic signature sensitivity to the local NOx emissions and chemical regimes. These preliminary results are very promising for using the combination of Δ17O and δ15N of NO2 as a probe of the atmospheric NOx emissions and chemistry.
Kun Wang, Shohei Hattori, Mang Lin, Sakiko Ishino, Becky Alexander, Kazuki Kamezaki, Naohiro Yoshida, and Shichang Kang
Atmos. Chem. Phys., 21, 8357–8376, https://doi.org/10.5194/acp-21-8357-2021, https://doi.org/10.5194/acp-21-8357-2021, 2021
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Sulfate aerosols play an important climatic role and exert adverse effects on the ecological environment and human health. In this study, we present the triple oxygen isotopic composition of sulfate from the Mt. Everest region, southern Tibetan Plateau, and decipher the formation mechanisms of atmospheric sulfate in this pristine environment. The results indicate the important role of the S(IV) + O3 pathway in atmospheric sulfate formation promoted by conditions of high cloud water pH.
Pete D. Akers, Ben G. Kopec, Kyle S. Mattingly, Eric S. Klein, Douglas Causey, and Jeffrey M. Welker
Atmos. Chem. Phys., 20, 13929–13955, https://doi.org/10.5194/acp-20-13929-2020, https://doi.org/10.5194/acp-20-13929-2020, 2020
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Water vapor isotopes recorded for 2 years in coastal northern Greenland largely reflect changes in sea ice cover, with distinct values when Baffin Bay is ice covered in winter vs. open in summer. Resulting changes in moisture transport, surface winds, and air temperature also modify the isotopes. Local glacial ice may thus preserve past changes in the Baffin Bay sea ice extent, and this will help us better understand how the Arctic environment and water cycle responds to global climate change.
Ben Yu, Lin Yang, Linlin Wang, Hongwei Liu, Cailing Xiao, Yong Liang, Qian Liu, Yongguang Yin, Ligang Hu, Jianbo Shi, and Guibin Jiang
Atmos. Chem. Phys., 20, 9713–9723, https://doi.org/10.5194/acp-20-9713-2020, https://doi.org/10.5194/acp-20-9713-2020, 2020
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We found that Br atoms in the marine boundary layer are the most probable oxidizer that transform gaseous elemental mercury into gaseous oxidized mercury, according to the mercury isotopes in the total gaseous mercury. On the other hand, Br or Cl atoms are not the primary oxidizers that produced oxidized mercury on particles. This study showed that mercury isotopes can provide new evidence that help us to fully understand the transformations of atmospheric mercury.
Longfei Yu, Eliza Harris, Stephan Henne, Sarah Eggleston, Martin Steinbacher, Lukas Emmenegger, Christoph Zellweger, and Joachim Mohn
Atmos. Chem. Phys., 20, 6495–6519, https://doi.org/10.5194/acp-20-6495-2020, https://doi.org/10.5194/acp-20-6495-2020, 2020
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We observed the isotopic composition of nitrous oxide in the unpolluted air at Jungfraujoch for 5 years. Our results indicate a clear seasonal pattern in the isotopic composition, corresponding with that in atmospheric nitrous oxide levels. This is most likely due to temporal variations in both emission processes and air mass sources for Jungfraujoch. Our findings are of importance to global nitrous oxide modelling and to better understanding of long-term trends in atmospheric nitrous oxide.
V. Holly L. Winton, Alison Ming, Nicolas Caillon, Lisa Hauge, Anna E. Jones, Joel Savarino, Xin Yang, and Markus M. Frey
Atmos. Chem. Phys., 20, 5861–5885, https://doi.org/10.5194/acp-20-5861-2020, https://doi.org/10.5194/acp-20-5861-2020, 2020
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The transfer of the nitrogen stable isotopic composition in nitrate between the air and snow at low accumulation sites in Antarctica leaves an UV imprint in the snow. Quantifying how nitrate isotope values change allows us to interpret longer ice core records. Based on nitrate observations and modelling at Kohnen, East Antarctica, the dominant factors controlling the nitrate isotope signature in deep snow layers are the depth of light penetration into the snowpack and the snow accumulation rate.
Isabelle Genot, David Au Yang, Erwan Martin, Pierre Cartigny, Erwann Legendre, and Marc De Rafelis
Atmos. Chem. Phys., 20, 4255–4273, https://doi.org/10.5194/acp-20-4255-2020, https://doi.org/10.5194/acp-20-4255-2020, 2020
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Given their critical impact on radiative forcing, sulfate aerosols have been extensively studied using their isotope signatures (δ34S, ∆33S, ∆36S, δ18O, and ∆17O). A striking observation is that ∆33S > 0 ‰, implying a missing reservoir in the sulfur cycle. Here, we measured ∆33S < 0 ‰ in black crust sulfates (i.e., formed on carbonate walls) that must therefore result from distinct chemical pathway(s) compared to sulfate aerosols, and they may well represent this complementary reservoir.
Angelina Wenger, Katherine Pugsley, Simon O'Doherty, Matt Rigby, Alistair J. Manning, Mark F. Lunt, and Emily D. White
Atmos. Chem. Phys., 19, 14057–14070, https://doi.org/10.5194/acp-19-14057-2019, https://doi.org/10.5194/acp-19-14057-2019, 2019
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We present 14CO2 observations at a background site in Ireland and a tall tower site in the UK. These data have been used to calculate the contribution of fossil fuel sources to atmospheric CO2 mole fractions from the UK and Ireland. 14CO2 emissions from nuclear industry sites in the UK cause a higher uncertainty in the results compared to observations in other locations. The observed ffCO2 at the site was not significantly different from simulated values based on the bottom-up inventory.
Isaac J. Vimont, Jocelyn C. Turnbull, Vasilii V. Petrenko, Philip F. Place, Colm Sweeney, Natasha Miles, Scott Richardson, Bruce H. Vaughn, and James W. C. White
Atmos. Chem. Phys., 19, 8547–8562, https://doi.org/10.5194/acp-19-8547-2019, https://doi.org/10.5194/acp-19-8547-2019, 2019
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Stable isotopes of Carbon Monoxide (CO) and radiocarbon carbon dioxide were measured over three summers at Indianapolis, Indiana, US, and for 1 year at a site thought to be strongly influenced by CO from oxidized volatile organic compounds (VOCs) in South Carolina, US. The Indianapolis results were used to provide an estimate of the carbon and oxygen isotopic signatures of CO produced from oxidized VOCs. This updated estimate agrees well with the data from South Carolina during the summer.
David Au Yang, Pierre Cartigny, Karine Desboeufs, and David Widory
Atmos. Chem. Phys., 19, 3779–3796, https://doi.org/10.5194/acp-19-3779-2019, https://doi.org/10.5194/acp-19-3779-2019, 2019
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Sulfates present in urban aerosols collected worldwide usually exhibit 33S-anomalies whose origin remains unclear. Besides, the sulfate concentration is not very well modelled nowadays, which, coupled with the isotopic composition anomaly on the 33S, would highlight the presence of at least an additional oxidation pathway, different from O2+TMI, O3, OH, H2O2 and NO2. We suggest here the implication of two other possible oxidation pathways.
Martine M. Savard, Amanda S. Cole, Robert Vet, and Anna Smirnoff
Atmos. Chem. Phys., 18, 10373–10389, https://doi.org/10.5194/acp-18-10373-2018, https://doi.org/10.5194/acp-18-10373-2018, 2018
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Improving air quality requires understanding of the atmospheric processes transforming nitrous oxides emitted by human activities into nitrates, an N form that may degrade natural ecosystems. Isotopes (∆17O, δ18O) are characterized in separate wet, particulate and gaseous nitrates for the first time. The gas ranges are distinct from those of the other nitrates, and the plume dynamics emerge as crucial in interpreting the results, which unravel key processes behind the distribution of nitrates.
Sergey Gromov, Carl A. M. Brenninkmeijer, and Patrick Jöckel
Atmos. Chem. Phys., 18, 9831–9843, https://doi.org/10.5194/acp-18-9831-2018, https://doi.org/10.5194/acp-18-9831-2018, 2018
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Using the observational data on 13C (CO) and 13C (CH4) from the extra-tropical Southern Hemisphere (ETSH) and EMAC model we (1) provide an independent, observation-based evaluation of Cl atom concentration variations in the ETSH throughout 1994–2000, (2) show that the role of tropospheric Cl as a sink of CH4 is seriously overestimated in the literature, (3) demonstrate that the 13C/12C ratio of CO is a sensitive indicator for the isotopic composition of reacted CH4 and therefore for its sources.
Richard P. Fiorella, Ryan Bares, John C. Lin, James R. Ehleringer, and Gabriel J. Bowen
Atmos. Chem. Phys., 18, 8529–8547, https://doi.org/10.5194/acp-18-8529-2018, https://doi.org/10.5194/acp-18-8529-2018, 2018
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Fossil fuel combustion produces water; where fossil fuel combustion is concentrated in urban areas, this humidity source may represent ~ 10 % of total humidity. In turn, this water vapor addition may alter urban meteorology, though the contribution of combustion vapor is difficult to measure. Using stable water isotopes, we estimate that up to 16 % of urban humidity may arise from combustion when the atmosphere is stable during winter, and develop recommendations for application in other cities.
Neda Amiri, Roya Ghahreman, Ofelia Rempillo, Travis W. Tokarek, Charles A. Odame-Ankrah, Hans D. Osthoff, and Ann-Lise Norman
Atmos. Chem. Phys., 18, 7757–7780, https://doi.org/10.5194/acp-18-7757-2018, https://doi.org/10.5194/acp-18-7757-2018, 2018
David M. Nelson, Urumu Tsunogai, Dong Ding, Takuya Ohyama, Daisuke D. Komatsu, Fumiko Nakagawa, Izumi Noguchi, and Takashi Yamaguchi
Atmos. Chem. Phys., 18, 6381–6392, https://doi.org/10.5194/acp-18-6381-2018, https://doi.org/10.5194/acp-18-6381-2018, 2018
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Atmospheric nitrate may be produced locally and/or come from upwind regions. To address this issue we measured oxygen and nitrogen isotopes of wet and dry nitrate deposition at nearby urban and rural sites. Our results suggest that, relative to nitrate in wet deposition in urban environments and wet and dry deposition in rural environments, nitrate in dry deposition in urban environments results from local NOx emissions more so than wet deposition, which is transported longer distances.
Pengzhen He, Becky Alexander, Lei Geng, Xiyuan Chi, Shidong Fan, Haicong Zhan, Hui Kang, Guangjie Zheng, Yafang Cheng, Hang Su, Cheng Liu, and Zhouqing Xie
Atmos. Chem. Phys., 18, 5515–5528, https://doi.org/10.5194/acp-18-5515-2018, https://doi.org/10.5194/acp-18-5515-2018, 2018
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We use observations of the oxygen isotopic composition of sulfate aerosol as a fingerprint to quantify various sulfate formation mechanisms during pollution events in Beijing, China. We found that heterogeneous reactions on aerosols dominated sulfate production in general; however, in-cloud reactions would dominate haze sulfate production when cloud liquid water content was high. The findings also suggest the heterogeneity of aerosol acidity should be parameterized in models.
Tesfaye A. Berhanu, Sönke Szidat, Dominik Brunner, Ece Satar, Rüdiger Schanda, Peter Nyfeler, Michael Battaglia, Martin Steinbacher, Samuel Hammer, and Markus Leuenberger
Atmos. Chem. Phys., 17, 10753–10766, https://doi.org/10.5194/acp-17-10753-2017, https://doi.org/10.5194/acp-17-10753-2017, 2017
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Fossil fuel CO2 is the major contributor of anthropogenic CO2 in the atmosphere, and accurate quantification is essential to better understand the carbon cycle. Such accurate quantification can be conducted based on radiocarbon measurements. In this study, we present radiocarbon measurements from a tall tower site in Switzerland. From these measurements, we have observed seasonally varying fossil fuel CO2 contributions and a biospheric CO2 component that varies diurnally and seasonally.
Markella Prokopiou, Patricia Martinerie, Célia J. Sapart, Emmanuel Witrant, Guillaume Monteil, Kentaro Ishijima, Sophie Bernard, Jan Kaiser, Ingeborg Levin, Thomas Blunier, David Etheridge, Ed Dlugokencky, Roderik S. W. van de Wal, and Thomas Röckmann
Atmos. Chem. Phys., 17, 4539–4564, https://doi.org/10.5194/acp-17-4539-2017, https://doi.org/10.5194/acp-17-4539-2017, 2017
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Nitrous oxide is the third most important anthropogenic greenhouse gas with an increasing mole fraction. To understand its natural and anthropogenic sources
we employ isotope measurements. Results show that while the N2O mole fraction increases, its heavy isotope content decreases. The isotopic changes observed underline the dominance of agricultural emissions especially at the early part of the record, whereas in the later decades the contribution from other anthropogenic sources increases.
Sakiko Ishino, Shohei Hattori, Joel Savarino, Bruno Jourdain, Susanne Preunkert, Michel Legrand, Nicolas Caillon, Albane Barbero, Kota Kuribayashi, and Naohiro Yoshida
Atmos. Chem. Phys., 17, 3713–3727, https://doi.org/10.5194/acp-17-3713-2017, https://doi.org/10.5194/acp-17-3713-2017, 2017
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We show the first simultaneous observations of triple oxygen isotopic compositions of atmospheric sulfate, nitrate, and ozone at Dumont d'Urville, coastal Antarctica. The contrasting seasonal trends between oxygen isotopes of ozone and those of sulfate and nitrate indicate that these signatures in sulfate and nitrate are mainly controlled by changes in oxidation chemistry. We also discuss the specific oxidation chemistry induced by the unique phenomena at the site.
Giulia Zazzeri, Dave Lowry, Rebecca E. Fisher, James L. France, Mathias Lanoisellé, Bryce F. J. Kelly, Jaroslaw M. Necki, Charlotte P. Iverach, Elisa Ginty, Miroslaw Zimnoch, Alina Jasek, and Euan G. Nisbet
Atmos. Chem. Phys., 16, 13669–13680, https://doi.org/10.5194/acp-16-13669-2016, https://doi.org/10.5194/acp-16-13669-2016, 2016
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Methane emissions estimates from the coal sector are highly uncertain. Precise δ13C isotopic signatures of methane sources can be used in atmospheric models for a methane budget assessment. Emissions from both underground and opencast coal mines in the UK, Australia and Poland were sampled and isotopically characterised using high-precision measurements of δ13C values. Representative isotopic signatures were provided, taking into account specific ranks of coal and mine type.
Qiang Huang, Jiubin Chen, Weilin Huang, Pingqing Fu, Benjamin Guinot, Xinbin Feng, Lihai Shang, Zhuhong Wang, Zhongwei Wang, Shengliu Yuan, Hongming Cai, Lianfang Wei, and Ben Yu
Atmos. Chem. Phys., 16, 11773–11786, https://doi.org/10.5194/acp-16-11773-2016, https://doi.org/10.5194/acp-16-11773-2016, 2016
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Atmospheric airborne mercury is of particular concern because, once inhaled, both Hg and its vectors might have adverse effects on human beings. In this study, we attempted to identify the sources of PM2.5-Hg in Beijing, China, using Hg isotopic composition. Large range and seasonal variations in both mass-dependent and mass-independent fractionations of Hg isotopes in haze particles demonstrate the usefulness of Hg isotopes for directly tracing the sources and its vectors in the atmosphere.
Qianjie Chen, Lei Geng, Johan A. Schmidt, Zhouqing Xie, Hui Kang, Jordi Dachs, Jihong Cole-Dai, Andrew J. Schauer, Madeline G. Camp, and Becky Alexander
Atmos. Chem. Phys., 16, 11433–11450, https://doi.org/10.5194/acp-16-11433-2016, https://doi.org/10.5194/acp-16-11433-2016, 2016
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The formation mechanisms of sulfate in the marine boundary layer are not well understood, which could result in large uncertainties in aerosol radiative forcing. We measure the oxygen isotopic composition (Δ17O) of sulfate collected in the MBL and analyze with a global transport model. Our results suggest that 33–50 % of MBL sulfate is formed via oxidation of S(IV) by hypohalous acids HOBr / HOCl in the aqueous phase, and the daily-mean HOBr/HOCl concentrations are on the order of 0.01–0.1 ppt.
Thomas Röckmann, Simon Eyer, Carina van der Veen, Maria E. Popa, Béla Tuzson, Guillaume Monteil, Sander Houweling, Eliza Harris, Dominik Brunner, Hubertus Fischer, Giulia Zazzeri, David Lowry, Euan G. Nisbet, Willi A. Brand, Jaroslav M. Necki, Lukas Emmenegger, and Joachim Mohn
Atmos. Chem. Phys., 16, 10469–10487, https://doi.org/10.5194/acp-16-10469-2016, https://doi.org/10.5194/acp-16-10469-2016, 2016
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A dual isotope ratio mass spectrometric system (IRMS) and a quantum cascade laser absorption spectroscopy (QCLAS)-based technique were deployed at the Cabauw experimental site for atmospheric research (CESAR) in the Netherlands and performed in situ, high-frequency (approx. hourly) measurements for a period of more than 5 months, yielding a combined dataset with more than 2500 measurements of both δ13C and δD.
Joël Savarino, William C. Vicars, Michel Legrand, Suzanne Preunkert, Bruno Jourdain, Markus M. Frey, Alexandre Kukui, Nicolas Caillon, and Jaime Gil Roca
Atmos. Chem. Phys., 16, 2659–2673, https://doi.org/10.5194/acp-16-2659-2016, https://doi.org/10.5194/acp-16-2659-2016, 2016
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Atmospheric nitrate is collected on the East Antarctic ice sheet. Nitrogen and oxygen stable isotopes and concentrations of nitrate are measured. Using a box model, we show that there is s systematic discrepancy between observations and model results. We suggest that this discrepancy probably results from unknown NOx chemistry above the Antarctic ice sheet. However, possible misconception in the stable isotope mass balance is not completely excluded.
T. A. Berhanu, J. Savarino, J. Erbland, W. C. Vicars, S. Preunkert, J. F. Martins, and M. S. Johnson
Atmos. Chem. Phys., 15, 11243–11256, https://doi.org/10.5194/acp-15-11243-2015, https://doi.org/10.5194/acp-15-11243-2015, 2015
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In this field study at Dome C, Antarctica, we investigated the effect of solar UV photolysis on the stable isotopes of nitrate in snow via comparison of two identical snow pits while exposing only one to solar UV. From the difference between the average isotopic fractionations calculated for each pit, we determined a purely photolytic nitrogen isotopic fractionation of -55.8‰, in good agreement with what has been recently determined in a laboratory study.
M. Saccon, A. Kornilova, L. Huang, S. Moukhtar, and J. Rudolph
Atmos. Chem. Phys., 15, 10825–10838, https://doi.org/10.5194/acp-15-10825-2015, https://doi.org/10.5194/acp-15-10825-2015, 2015
E. D. Sofen, B. Alexander, E. J. Steig, M. H. Thiemens, S. A. Kunasek, H. M. Amos, A. J. Schauer, M. G. Hastings, J. Bautista, T. L. Jackson, L. E. Vogel, J. R. McConnell, D. R. Pasteris, and E. S. Saltzman
Atmos. Chem. Phys., 14, 5749–5769, https://doi.org/10.5194/acp-14-5749-2014, https://doi.org/10.5194/acp-14-5749-2014, 2014
J. Wintel, E. Hösen, R. Koppmann, M. Krebsbach, A. Hofzumahaus, and F. Rohrer
Atmos. Chem. Phys., 13, 11059–11071, https://doi.org/10.5194/acp-13-11059-2013, https://doi.org/10.5194/acp-13-11059-2013, 2013
F. A. Haumann, A. M. Batenburg, G. Pieterse, C. Gerbig, M. C. Krol, and T. Röckmann
Atmos. Chem. Phys., 13, 9401–9413, https://doi.org/10.5194/acp-13-9401-2013, https://doi.org/10.5194/acp-13-9401-2013, 2013
C. J. Sapart, P. Martinerie, E. Witrant, J. Chappellaz, R. S. W. van de Wal, P. Sperlich, C. van der Veen, S. Bernard, W. T. Sturges, T. Blunier, J. Schwander, D. Etheridge, and T. Röckmann
Atmos. Chem. Phys., 13, 6993–7005, https://doi.org/10.5194/acp-13-6993-2013, https://doi.org/10.5194/acp-13-6993-2013, 2013
J. Erbland, W. C. Vicars, J. Savarino, S. Morin, M. M. Frey, D. Frosini, E. Vince, and J. M. F. Martins
Atmos. Chem. Phys., 13, 6403–6419, https://doi.org/10.5194/acp-13-6403-2013, https://doi.org/10.5194/acp-13-6403-2013, 2013
A. Guillon, K. Le Ménach, P.-M. Flaud, N. Marchand, H. Budzinski, and E. Villenave
Atmos. Chem. Phys., 13, 2703–2719, https://doi.org/10.5194/acp-13-2703-2013, https://doi.org/10.5194/acp-13-2703-2013, 2013
D. Ceburnis, A. Garbaras, S. Szidat, M. Rinaldi, S. Fahrni, N. Perron, L. Wacker, S. Leinert, V. Remeikis, M. C. Facchini, A. S. H. Prevot, S. G. Jennings, M. Ramonet, and C. D. O'Dowd
Atmos. Chem. Phys., 11, 8593–8606, https://doi.org/10.5194/acp-11-8593-2011, https://doi.org/10.5194/acp-11-8593-2011, 2011
A. M. Batenburg, S. Walter, G. Pieterse, I. Levin, M. Schmidt, A. Jordan, S. Hammer, C. Yver, and T. Röckmann
Atmos. Chem. Phys., 11, 6985–6999, https://doi.org/10.5194/acp-11-6985-2011, https://doi.org/10.5194/acp-11-6985-2011, 2011
B. Tuzson, S. Henne, D. Brunner, M. Steinbacher, J. Mohn, B. Buchmann, and L. Emmenegger
Atmos. Chem. Phys., 11, 1685–1696, https://doi.org/10.5194/acp-11-1685-2011, https://doi.org/10.5194/acp-11-1685-2011, 2011
Y. T. Fang, K. Koba, X. M. Wang, D. Z. Wen, J. Li, Y. Takebayashi, X. Y. Liu, and M. Yoh
Atmos. Chem. Phys., 11, 1313–1325, https://doi.org/10.5194/acp-11-1313-2011, https://doi.org/10.5194/acp-11-1313-2011, 2011
S. S. Assonov, C. A. M. Brenninkmeijer, T. J. Schuck, and P. Taylor
Atmos. Chem. Phys., 10, 8575–8599, https://doi.org/10.5194/acp-10-8575-2010, https://doi.org/10.5194/acp-10-8575-2010, 2010
U. Tsunogai, D. D. Komatsu, S. Daita, G. A. Kazemi, F. Nakagawa, I. Noguchi, and J. Zhang
Atmos. Chem. Phys., 10, 1809–1820, https://doi.org/10.5194/acp-10-1809-2010, https://doi.org/10.5194/acp-10-1809-2010, 2010
M. M. Frey, J. Savarino, S. Morin, J. Erbland, and J. M. F. Martins
Atmos. Chem. Phys., 9, 8681–8696, https://doi.org/10.5194/acp-9-8681-2009, https://doi.org/10.5194/acp-9-8681-2009, 2009
S. A. Vay, S. C. Tyler, Y. Choi, D. R. Blake, N. J. Blake, G. W. Sachse, G. S. Diskin, and H. B. Singh
Atmos. Chem. Phys., 9, 4973–4985, https://doi.org/10.5194/acp-9-4973-2009, https://doi.org/10.5194/acp-9-4973-2009, 2009
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Short summary
We present a large and unique dataset of the rainfall isotopic composition at seven sites from northern Iberia to characterize their variability at daily and monthly timescales and to assess the role of climate and geographic factors in the modulation of δ18O values. We found that the origin, moisture uptake along the trajectory and type of precipitation play a key role. These results will help to improve the interpretation of δ18O paleorecords from lacustrine carbonates or speleothems.
We present a large and unique dataset of the rainfall isotopic composition at seven sites from...
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