Articles | Volume 20, issue 16
https://doi.org/10.5194/acp-20-9581-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-20-9581-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
17 Aug 2020
Research article |
| 17 Aug 2020
| 17 Aug 2020
Glyoxal's impact on dry ammonium salts: fast and reversible surface aerosol browning
Department of Chemistry and Biochemistry, University of San Diego,
5998 Alcala Park, San Diego, CA 92110, USA
Lelia N. Hawkins
Department of Chemistry, Harvey Mudd College, 301 Platt Blvd,
Claremont, CA 91711, USA
Kevin Jansen
Department of Chemistry/Cooperative Institute for Research in
Environmental Sciences, University of Colorado, Boulder, CO 80309, USA
Hannah G. Welsh
Department of Chemistry, Harvey Mudd College, 301 Platt Blvd,
Claremont, CA 91711, USA
Raunak Pednekar
Department of Chemistry, Harvey Mudd College, 301 Platt Blvd,
Claremont, CA 91711, USA
deceased
Alexia de Loera
Department of Chemistry and Biochemistry, University of San Diego,
5998 Alcala Park, San Diego, CA 92110, USA
Natalie G. Jimenez
Department of Chemistry and Biochemistry, University of San Diego,
5998 Alcala Park, San Diego, CA 92110, USA
Margaret A. Tolbert
Department of Chemistry/Cooperative Institute for Research in
Environmental Sciences, University of Colorado, Boulder, CO 80309, USA
Mathieu Cazaunau
Laboratoire Interuniversitaire des Systèmes Atmosphériques
(LISA), UMR7583, CNRS, Université Paris-Est Créteil (UPEC) et
Université de Paris, Institut Pierre Simon Laplace (IPSL), Créteil,
France
Aline Gratien
Laboratoire Interuniversitaire des Systèmes Atmosphériques
(LISA), UMR7583, CNRS, Université Paris-Est Créteil (UPEC) et
Université de Paris, Institut Pierre Simon Laplace (IPSL), Créteil,
France
Antonin Bergé
Laboratoire Interuniversitaire des Systèmes Atmosphériques
(LISA), UMR7583, CNRS, Université Paris-Est Créteil (UPEC) et
Université de Paris, Institut Pierre Simon Laplace (IPSL), Créteil,
France
Edouard Pangui
Laboratoire Interuniversitaire des Systèmes Atmosphériques
(LISA), UMR7583, CNRS, Université Paris-Est Créteil (UPEC) et
Université de Paris, Institut Pierre Simon Laplace (IPSL), Créteil,
France
Paola Formenti
Laboratoire Interuniversitaire des Systèmes Atmosphériques
(LISA), UMR7583, CNRS, Université Paris-Est Créteil (UPEC) et
Université de Paris, Institut Pierre Simon Laplace (IPSL), Créteil,
France
Jean-François Doussin
Laboratoire Interuniversitaire des Systèmes Atmosphériques
(LISA), UMR7583, CNRS, Université Paris-Est Créteil (UPEC) et
Université de Paris, Institut Pierre Simon Laplace (IPSL), Créteil,
France
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Cited
14 citations as recorded by crossref.
- Glyoxal as a Potential Source of Highly Viscous Aerosol Particles J. Peters et al. 10.1021/acsearthspacechem.1c00245
- Elucidating the critical oligomeric steps in secondary organic aerosol and brown carbon formation Y. Ji et al. 10.5194/acp-22-7259-2022
- Secondary Brown Carbon Formation From Photooxidation of Furans From Biomass Burning T. Joo et al. 10.1029/2023GL104900
- Surface Formation Pathway of Nitrogen- and Sulfur-Containing Organic Compounds on Ammonium Sulfate J. Chen et al. 10.1021/acs.jpca.5c00332
- Ammonolysis of Glyoxal at the Air‐Water Nanodroplet Interface Z. Dong et al. 10.1002/anie.202316060
- Ammonolysis of Glyoxal at the Air‐Water Nanodroplet Interface Z. Dong et al. 10.1002/ange.202316060
- Research progress on secondary formation, photosensitive reaction mechanism and human health effects of chromophoric brown carbon B. Chen et al. 10.1016/j.jes.2024.04.003
- Surfactant Effects in Irradiated, Hanging-Droplet, Aqueous-Phase Glyoxal/Ammonium Sulfate Aerosol Mimic Systems D. Fertil et al. 10.1021/acsearthspacechem.4c00288
- pH-Dependent Kinetics of Imidazole Production in Aqueous Glyoxal/Ammonium Sulfate Microdroplets M. Marracci & C. Murray 10.1021/acsearthspacechem.5c00023
- Effects of Organic Matrices on Nucleophilic Aqueous Aerosol Chemistry: Yields and Mechanistic Insight for Brown Carbon Formation from Glyoxal and Ammonia G. Drozd et al. 10.1021/acsearthspacechem.2c00068
- The semi-solid phase of atmospheric particles facilitates the formation of secondary brown carbon: Possible contribution of ionic strength to Maillard-like reactions J. Xie et al. 10.1016/j.atmosenv.2024.120991
- Field observational constraints on the controllers in glyoxal (CHOCHO) reactive uptake to aerosol D. Kim et al. 10.5194/acp-22-805-2022
- Aqueous-phase chemistry of glyoxal with multifunctional reduced nitrogen compounds: a potential missing route for secondary brown carbon Y. Ji et al. 10.5194/acp-24-3079-2024
- Increased UV–Visible Particle Absorption via Evaporation and Drying of Aqueous Droplets Containing Catechol/HONO Solutions Y. Wang et al. 10.1021/acs.estlett.5c00364
14 citations as recorded by crossref.
- Glyoxal as a Potential Source of Highly Viscous Aerosol Particles J. Peters et al. 10.1021/acsearthspacechem.1c00245
- Elucidating the critical oligomeric steps in secondary organic aerosol and brown carbon formation Y. Ji et al. 10.5194/acp-22-7259-2022
- Secondary Brown Carbon Formation From Photooxidation of Furans From Biomass Burning T. Joo et al. 10.1029/2023GL104900
- Surface Formation Pathway of Nitrogen- and Sulfur-Containing Organic Compounds on Ammonium Sulfate J. Chen et al. 10.1021/acs.jpca.5c00332
- Ammonolysis of Glyoxal at the Air‐Water Nanodroplet Interface Z. Dong et al. 10.1002/anie.202316060
- Ammonolysis of Glyoxal at the Air‐Water Nanodroplet Interface Z. Dong et al. 10.1002/ange.202316060
- Research progress on secondary formation, photosensitive reaction mechanism and human health effects of chromophoric brown carbon B. Chen et al. 10.1016/j.jes.2024.04.003
- Surfactant Effects in Irradiated, Hanging-Droplet, Aqueous-Phase Glyoxal/Ammonium Sulfate Aerosol Mimic Systems D. Fertil et al. 10.1021/acsearthspacechem.4c00288
- pH-Dependent Kinetics of Imidazole Production in Aqueous Glyoxal/Ammonium Sulfate Microdroplets M. Marracci & C. Murray 10.1021/acsearthspacechem.5c00023
- Effects of Organic Matrices on Nucleophilic Aqueous Aerosol Chemistry: Yields and Mechanistic Insight for Brown Carbon Formation from Glyoxal and Ammonia G. Drozd et al. 10.1021/acsearthspacechem.2c00068
- The semi-solid phase of atmospheric particles facilitates the formation of secondary brown carbon: Possible contribution of ionic strength to Maillard-like reactions J. Xie et al. 10.1016/j.atmosenv.2024.120991
- Field observational constraints on the controllers in glyoxal (CHOCHO) reactive uptake to aerosol D. Kim et al. 10.5194/acp-22-805-2022
- Aqueous-phase chemistry of glyoxal with multifunctional reduced nitrogen compounds: a potential missing route for secondary brown carbon Y. Ji et al. 10.5194/acp-24-3079-2024
- Increased UV–Visible Particle Absorption via Evaporation and Drying of Aqueous Droplets Containing Catechol/HONO Solutions Y. Wang et al. 10.1021/acs.estlett.5c00364
Latest update: 14 May 2025
Short summary
When exposed to glyoxal in chamber experiments, dry ammonium or methylammonium sulfate particles turn brown immediately and reversibly without increasing in size. Much less browning was observed on wet aerosol particles, and no browning was observed with sodium sulfate aerosol. While estimated dry aerosol light absorption caused by background glyoxal (70 ppt) is insignificant compared to that of secondary brown carbon overall, in polluted regions this process could be a source of brown carbon.
When exposed to glyoxal in chamber experiments, dry ammonium or methylammonium sulfate particles...
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