Measured solid state and subcooled liquid vapour pressures of nitroaromatics using Knudsen effusion mass spectrometry

Shelley, Petroc D.; Bannan, Thomas J.; Worrall, Stephen D.; Alfarra, M. Rami; Krieger, Ulrich K.; Percival, Carl J.; Garforth, Arthur; Topping, David

doi:https://doi.org/10.5194/acp-20-8293-2020

Articles | Volume 20, issue 14

https://doi.org/10.5194/acp-20-8293-2020

© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.

https://doi.org/10.5194/acp-20-8293-2020

© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.

Articles | Volume 20, issue 14

Research article

|

17 Jul 2020

Research article |

| 17 Jul 2020

Measured solid state and subcooled liquid vapour pressures of nitroaromatics using Knudsen effusion mass spectrometry

Petroc D. Shelley, Thomas J. Bannan, Stephen D. Worrall, M. Rami Alfarra, Ulrich K. Krieger, Carl J. Percival, Arthur Garforth, and David Topping

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Final revised paper (published on 17 Jul 2020)
Supplement to the final revised paper
Preprint (discussion started on 31 Jan 2020)
Supplement to the preprint

Interactive discussion

Status: closed

AC: Author comment | RC: Referee comment | SC: Short comment | EC: Editor comment

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- Supplement

RC1: 'Review 1', Anonymous Referee #1, 04 Mar 2020
- AC1: 'Author Comments', Petroc Shelley, 26 May 2020
RC2: 'Review Comments', Anonymous Referee #2, 14 Apr 2020
- AC1: 'Author Comments', Petroc Shelley, 26 May 2020
AC1: 'Author Comments', Petroc Shelley, 26 May 2020

Peer-review completion

AR: Author's response | RR: Referee report | ED: Editor decision

AR by Petroc Shelley on behalf of the Authors (26 May 2020) Author's response Manuscript

ED: Referee Nomination & Report Request started (09 Jun 2020) by Alexander Laskin

RR by Anonymous Referee #1 (21 Jun 2020)

RR by Anonymous Referee #2 (23 Jun 2020)

ED: Publish as is (23 Jun 2020) by Alexander Laskin

AR by Petroc Shelley on behalf of the Authors (26 Jun 2020)

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Short summary

The methods used to estimate the vapour pressures of compounds in the atmosphere typically perform poorly when applied to organic compounds found in the atmosphere. New measurements have been made and compared to previous experimental data and estimated values so that the limitations within the estimation methods can be identified and in the future be rectified.