Articles | Volume 20, issue 13
https://doi.org/10.5194/acp-20-8103-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-20-8103-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Predictions of the glass transition temperature and viscosity of organic aerosols from volatility distributions
Department of Chemistry, University of California, Irvine, CA
92697-2025, USA
Douglas A. Day
Cooperative Institute for Research in Environmental Sciences (CIRES),
University of Colorado, Boulder, CO 80309, USA
Department of Chemistry, University of Colorado, Boulder, CO 80309, USA
Harald Stark
Cooperative Institute for Research in Environmental Sciences (CIRES),
University of Colorado, Boulder, CO 80309, USA
Department of Chemistry, University of Colorado, Boulder, CO 80309, USA
Aerodyne Research Inc., Billerica, MA 01821, USA
Jose L. Jimenez
Cooperative Institute for Research in Environmental Sciences (CIRES),
University of Colorado, Boulder, CO 80309, USA
Department of Chemistry, University of Colorado, Boulder, CO 80309, USA
Department of Chemistry, University of California, Irvine, CA
92697-2025, USA
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- Representation of Multiphase OH Oxidation of Amorphous Organic Aerosol for Tropospheric Conditions J. Li & D. Knopf 10.1021/acs.est.0c07668
- Viscosity and liquid–liquid phase separation in healthy and stressed plant SOA N. Smith et al. 10.1039/D0EA00020E
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- Enhanced Nitrate Fraction: Enabling Urban Aerosol Particles to Remain in a Liquid State at Reduced Relative Humidity Y. Liu et al. 10.1029/2023GL105505
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- Humidity-Dependent Viscosity of Secondary Organic Aerosol from Ozonolysis of β-Caryophyllene: Measurements, Predictions, and Implications A. Maclean et al. 10.1021/acsearthspacechem.0c00296
- Nonequilibrium Behavior in Isoprene Secondary Organic Aerosol Y. Chen et al. 10.1021/acs.est.3c03532
- Predicting the influence of particle size on the glass transition temperature and viscosity of secondary organic material M. Petters & S. Kasparoglu 10.1038/s41598-020-71490-0
- Modeling the Impact of the Organic Aerosol Phase State on Multiphase OH Reactive Uptake Kinetics and the Resultant Heterogeneous Oxidation Timescale of Organic Aerosol in the Amazon Rainforest Q. Rasool et al. 10.1021/acsearthspacechem.2c00366
46 citations as recorded by crossref.
- Model Framework for Predicting Semivolatile Organic Material Emissions Indoors from Organic Aerosol Measurements: Applications to HOMEChem Stir-Frying B. Cummings et al. 10.1021/acs.est.3c04183
- Peroxides on the Surface of Organic Aerosol Particles Using Matrix-Assisted Ionization in Vacuum (MAIV) Mass Spectrometry Y. Qin et al. 10.1021/acs.est.3c02895
- Impact of Aerosols on Precipitation over Western Ghats K. Kumar & B. Manjunatha 10.1007/s41810-021-00111-8
- Direct observation and assessment of phase states of ambient and lab-generated sub-micron particles upon humidification Z. Cheng et al. 10.1039/D1RA02530A
- Evidence for Anthropogenic Organic Aerosols Contributing to Ice Nucleation P. Tian et al. 10.1029/2022GL099990
- Morphology and Viscosity Changes after Reactive Uptake of Isoprene Epoxydiols in Submicrometer Phase Separated Particles with Secondary Organic Aerosol Formed from Different Volatile Organic Compounds Z. Lei et al. 10.1021/acsearthspacechem.1c00156
- Emerging investigator series: chemical and physical properties of organic mixtures on indoor surfaces during HOMEChem R. O'Brien et al. 10.1039/D1EM00060H
- Long-term observational constraints of organic aerosol dependence on inorganic species in the southeast US Y. Zheng et al. 10.5194/acp-20-13091-2020
- Evolution of Sea Spray Aerosol Particle Phase State Across a Phytoplankton Bloom P. Tumminello et al. 10.1021/acsearthspacechem.1c00186
- Estimating mean molecular weight, carbon number, and OM∕OC with mid-infrared spectroscopy in organic particulate matter samples from a monitoring network A. Yazdani et al. 10.5194/amt-14-4805-2021
- Predicting glass transition temperature and melting point of organic compounds via machine learning and molecular embeddings T. Galeazzo & M. Shiraiwa 10.1039/D1EA00090J
- Phase state of organic aerosols may limit temperature-driven thermodynamic repartitioning following outdoor-to-indoor transport B. Cummings et al. 10.1039/D2EM00093H
- Molecular Understanding of the Enhancement in Organic Aerosol Mass at High Relative Humidity M. Surdu et al. 10.1021/acs.est.2c04587
- Molecular Dynamics and Near-Tg Phenomena of Cyclic Thioethers H. Hellwig et al. 10.3390/ijms242417166
- The effects of morphology, mobility size, and secondary organic aerosol (SOA) material coating on the ice nucleation activity of black carbon in the cirrus regime C. Zhang et al. 10.5194/acp-20-13957-2020
- Machine-Learning-Based Prediction of the Glass Transition Temperature of Organic Compounds Using Experimental Data G. Armeli et al. 10.1021/acsomega.2c08146
- Sunlight can convert atmospheric aerosols into a glassy solid state and modify their environmental impacts V. Baboomian et al. 10.1073/pnas.2208121119
- Glyoxal as a Potential Source of Highly Viscous Aerosol Particles J. Peters et al. 10.1021/acsearthspacechem.1c00245
- Global Distribution of the Phase State and Mixing Times within Secondary Organic Aerosol Particles in the Troposphere Based on Room-Temperature Viscosity Measurements A. Maclean et al. 10.1021/acsearthspacechem.1c00296
- Diurnal and Seasonal Variations in the Phase State of Secondary Organic Aerosol Material over the Contiguous US Simulated in CMAQ Y. Li et al. 10.1021/acsearthspacechem.1c00094
- Molecular Characterization of Organosulfate-Dominated Aerosols over Agricultural Fields from the Southern Great Plains by High-Resolution Mass Spectrometry G. Vandergrift et al. 10.1021/acsearthspacechem.2c00043
- Impact of aging on the sources, volatility, and viscosity of organic aerosols in Chinese outflows T. Feng et al. 10.5194/acp-23-611-2023
- Indoor aerosol water content and phase state in U.S. residences: impacts of relative humidity, aerosol mass and composition, and mechanical system operation B. Cummings et al. 10.1039/D0EM00122H
- Experimental Determination of the Relationship Between Organic Aerosol Viscosity and Ice Nucleation at Upper Free Tropospheric Conditions S. Kasparoglu et al. 10.1029/2021JD036296
- Modeling Volatility-Based Aerosol Phase State Predictions in the Amazon Rainforest Q. Rasool et al. 10.1021/acsearthspacechem.1c00255
- Chemical characterization of biomass pyrolysis oil facilitated by aerosolization and size separation E. Halpern et al. 10.1080/02786826.2023.2254355
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- The Significant Role of New Particle Composition and Morphology on the HNO3-Driven Growth of Particles down to Sub-10 nm Y. Li et al. 10.1021/acs.est.3c09454
- Formation of secondary organic aerosol from wildfire emissions enhanced by long-time ageing Y. He et al. 10.1038/s41561-023-01355-4
- Molecular and physical composition of tar balls in wildfire smoke: an investigation with complementary ionisation methods and 15-Tesla FT-ICR mass spectrometry A. Ijaz et al. 10.1039/D3EA00085K
- Predicting Atmospheric Particle Phase State Using an Explainable Machine Learning Approach Based on Particle Rebound Measurements Y. Qiu et al. 10.1021/acs.est.3c05284
- Utilizing an electrical low-pressure impactor to indirectly probe water uptake via particle bounce measurements K. Fischer & G. Petrucci 10.5194/amt-14-7565-2021
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- Gas–particle partitioning of semivolatile organic compounds when wildfire smoke comes to town Y. Liang et al. 10.5194/acp-23-12441-2023
- Representation of Multiphase OH Oxidation of Amorphous Organic Aerosol for Tropospheric Conditions J. Li & D. Knopf 10.1021/acs.est.0c07668
- Viscosity and liquid–liquid phase separation in healthy and stressed plant SOA N. Smith et al. 10.1039/D0EA00020E
- Secondary Organic Aerosol Formation from Cyanobacterial-Derived Volatile Organic Compounds H. Plaas et al. 10.1021/acsearthspacechem.3c00177
- Organic aerosol volatility and viscosity in the North China Plain: contrast between summer and winter W. Xu et al. 10.5194/acp-21-5463-2021
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- Gas-Particle Uptake and Hygroscopic Growth by Organosulfate Particles P. Ohno et al. 10.1021/acsearthspacechem.2c00195
- Case study evaluation of size-resolved molecular composition and phase state of carbonaceous particles in wildfire influenced smoke from the Pacific Northwest G. Vandergrift et al. 10.1039/D3EA00058C
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- Humidity-Dependent Viscosity of Secondary Organic Aerosol from Ozonolysis of β-Caryophyllene: Measurements, Predictions, and Implications A. Maclean et al. 10.1021/acsearthspacechem.0c00296
- Nonequilibrium Behavior in Isoprene Secondary Organic Aerosol Y. Chen et al. 10.1021/acs.est.3c03532
2 citations as recorded by crossref.
- Predicting the influence of particle size on the glass transition temperature and viscosity of secondary organic material M. Petters & S. Kasparoglu 10.1038/s41598-020-71490-0
- Modeling the Impact of the Organic Aerosol Phase State on Multiphase OH Reactive Uptake Kinetics and the Resultant Heterogeneous Oxidation Timescale of Organic Aerosol in the Amazon Rainforest Q. Rasool et al. 10.1021/acsearthspacechem.2c00366
Latest update: 19 Apr 2024
Short summary
Viscosity is an important property of organic aerosols, but viscosity measurements of ambient organic aerosols are scarce. We developed a method to predict glass transition temperatures using volatility and the atomic oxygen-to-carbon ratio. The method was applied to field observations of volatility distributions to predict viscosity of ambient organic aerosols, yielding consistent results with ambient particle phase-state measurements and global simulations.
Viscosity is an important property of organic aerosols, but viscosity measurements of ambient...
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