Articles | Volume 20, issue 13
https://doi.org/10.5194/acp-20-8103-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-20-8103-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Predictions of the glass transition temperature and viscosity of organic aerosols from volatility distributions
Department of Chemistry, University of California, Irvine, CA
92697-2025, USA
Douglas A. Day
Cooperative Institute for Research in Environmental Sciences (CIRES),
University of Colorado, Boulder, CO 80309, USA
Department of Chemistry, University of Colorado, Boulder, CO 80309, USA
Harald Stark
Cooperative Institute for Research in Environmental Sciences (CIRES),
University of Colorado, Boulder, CO 80309, USA
Department of Chemistry, University of Colorado, Boulder, CO 80309, USA
Aerodyne Research Inc., Billerica, MA 01821, USA
Jose L. Jimenez
Cooperative Institute for Research in Environmental Sciences (CIRES),
University of Colorado, Boulder, CO 80309, USA
Department of Chemistry, University of Colorado, Boulder, CO 80309, USA
Department of Chemistry, University of California, Irvine, CA
92697-2025, USA
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- Structure – Glass transition temperature relationship for non-polymeric molecules: The concept of internal plasticizing effect A. Nowok et al. 10.1016/j.molliq.2024.124222
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61 citations as recorded by crossref.
- Model Framework for Predicting Semivolatile Organic Material Emissions Indoors from Organic Aerosol Measurements: Applications to HOMEChem Stir-Frying B. Cummings et al. 10.1021/acs.est.3c04183
- Modeling the molecular composition of secondary organic aerosol under highly polluted conditions: A case study in the Yangtze River Delta Region in China Q. Huang et al. 10.1016/j.scitotenv.2024.173327
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- Predicting glass transition temperature and melting point of organic compounds via machine learning and molecular embeddings T. Galeazzo & M. Shiraiwa 10.1039/D1EA00090J
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- Machine-Learning-Based Prediction of the Glass Transition Temperature of Organic Compounds Using Experimental Data G. Armeli et al. 10.1021/acsomega.2c08146
- Glyoxal as a Potential Source of Highly Viscous Aerosol Particles J. Peters et al. 10.1021/acsearthspacechem.1c00245
- A comprehensive evaluation of enhanced temperature influence on gas and aerosol chemistry in the lamp-enclosed oxidation flow reactor (OFR) system T. Pan et al. 10.5194/amt-17-4915-2024
- Diurnal and Seasonal Variations in the Phase State of Secondary Organic Aerosol Material over the Contiguous US Simulated in CMAQ Y. Li et al. 10.1021/acsearthspacechem.1c00094
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- Evidence for Anthropogenic Organic Aerosols Contributing to Ice Nucleation P. Tian et al. 10.1029/2022GL099990
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- Emerging investigator series: chemical and physical properties of organic mixtures on indoor surfaces during HOMEChem R. O'Brien et al. 10.1039/D1EM00060H
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- Sunlight can convert atmospheric aerosols into a glassy solid state and modify their environmental impacts V. Baboomian et al. 10.1073/pnas.2208121119
- Global Distribution of the Phase State and Mixing Times within Secondary Organic Aerosol Particles in the Troposphere Based on Room-Temperature Viscosity Measurements A. Maclean et al. 10.1021/acsearthspacechem.1c00296
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- Modeling Volatility-Based Aerosol Phase State Predictions in the Amazon Rainforest Q. Rasool et al. 10.1021/acsearthspacechem.1c00255
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- Secondary Organic Aerosol Formation from Cyanobacterial-Derived Volatile Organic Compounds H. Plaas et al. 10.1021/acsearthspacechem.3c00177
- Organic aerosol volatility and viscosity in the North China Plain: contrast between summer and winter W. Xu et al. 10.5194/acp-21-5463-2021
- Structure – Glass transition temperature relationship for non-polymeric molecules: The concept of internal plasticizing effect A. Nowok et al. 10.1016/j.molliq.2024.124222
- Toward closure between predicted and observed particle viscosity over a wide range of temperatures and relative humidity S. Kasparoglu et al. 10.5194/acp-21-1127-2021
- Case study evaluation of size-resolved molecular composition and phase state of carbonaceous particles in wildfire influenced smoke from the Pacific Northwest G. Vandergrift et al. 10.1039/D3EA00058C
- Estimation of secondary organic aerosol viscosity from explicit modeling of gas-phase oxidation of isoprene and <i>α</i>-pinene T. Galeazzo et al. 10.5194/acp-21-10199-2021
2 citations as recorded by crossref.
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- Modeling the Impact of the Organic Aerosol Phase State on Multiphase OH Reactive Uptake Kinetics and the Resultant Heterogeneous Oxidation Timescale of Organic Aerosol in the Amazon Rainforest Q. Rasool et al. 10.1021/acsearthspacechem.2c00366
Latest update: 26 Dec 2024
Short summary
Viscosity is an important property of organic aerosols, but viscosity measurements of ambient organic aerosols are scarce. We developed a method to predict glass transition temperatures using volatility and the atomic oxygen-to-carbon ratio. The method was applied to field observations of volatility distributions to predict viscosity of ambient organic aerosols, yielding consistent results with ambient particle phase-state measurements and global simulations.
Viscosity is an important property of organic aerosols, but viscosity measurements of ambient...
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