Articles | Volume 20, issue 12
Atmos. Chem. Phys., 20, 7429–7458, 2020
https://doi.org/10.5194/acp-20-7429-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Atmos. Chem. Phys., 20, 7429–7458, 2020
https://doi.org/10.5194/acp-20-7429-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
26 Jun 2020
Research article
| 26 Jun 2020
H migration in peroxy radicals under atmospheric conditions
Luc Vereecken and Barbara Nozière
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Cited
33 citations as recorded by crossref.
- Unimolecular Reactions Following Indoor and Outdoor Limonene Ozonolysis J. Chen et al. 10.1021/acs.jpca.0c09882
- Efficient alkane oxidation under combustion engine and atmospheric conditions Z. Wang et al. 10.1038/s42004-020-00445-3
- Screening for New Pathways in Atmospheric Oxidation Chemistry with Automated Mechanism Generation V. Barber et al. 10.1021/acs.jpca.1c04297
- Peroxy Radical Processes and Product Formation in the OH Radical-Initiated Oxidation of α-Pinene for Near-Atmospheric Conditions T. Berndt 10.1021/acs.jpca.1c05576
- Efficient Production of Carbonyl Sulfide in the Low‐NO x Oxidation of Dimethyl Sulfide C. Jernigan et al. 10.1029/2021GL096838
- On the similarities and differences between the products of oxidation of hydrocarbons under simulated atmospheric conditions and cool flames R. Benoit et al. 10.5194/acp-21-7845-2021
- Highly oxygenated organic molecule (HOM) formation in the isoprene oxidation by NO<sub>3</sub> radical D. Zhao et al. 10.5194/acp-21-9681-2021
- A structure activity relationship for ring closure reactions in unsaturated alkylperoxy radicals L. Vereecken et al. 10.1039/D1CP02758A
- Autoxidation mechanism for atmospheric oxidation of tertiary amines: Implications for secondary organic aerosol formation F. Ma et al. 10.1016/j.chemosphere.2020.129207
- Atmospheric Chemistry of Allylic Radicals from Isoprene: A Successive Cyclization-Driven Autoxidation Mechanism F. Ma et al. 10.1021/acs.est.0c07925
- Atmospheric photo-oxidation of myrcene: OH reaction rate constant, gas-phase oxidation products and radical budgets Z. Tan et al. 10.5194/acp-21-16067-2021
- Simplified Protocol for the Calculation of Multiconformer Transition State Theory Rate Constants Applied to Tropospheric OH-Initiated Oxidation Reactions L. Viegas 10.1021/acs.jpca.1c00683
- Atmospheric Autoxidation of Amines K. Møller et al. 10.1021/acs.est.0c03937
- Particle Formation from Photooxidation of αpinene, Limonene, and Myrcene D. Hanson et al. 10.1021/acs.jpca.1c08427
- Using GECKO-A to derive mechanistic understanding of secondary organic aerosol formation from the ubiquitous but understudied camphene I. Afreh et al. 10.5194/acp-21-11467-2021
- Reactions of organic peroxy radicals, RO2, with substituted and biogenic alkenes at room temperature: unsuspected sinks for some RO2 in the atmosphere? B. Nozière & F. Fache 10.1039/D1SC02263F
- Gas-Phase Chlorine Radical Oxidation of Alkanes: Effects of Structural Branching, NOx, and Relative Humidity Observed during Environmental Chamber Experiments L. Jahn et al. 10.1021/acs.jpca.1c03516
- Atmospheric Autoxidation of Organophosphate Esters Z. Fu et al. 10.1021/acs.est.1c04817
- Rates and Yields of Unimolecular Reactions Producing Highly Oxidized Peroxy Radicals in the OH-Induced Autoxidation of α-Pinene, β-Pinene, and Limonene I. Piletic & T. Kleindienst 10.1021/acs.jpca.1c07961
- Anthropogenic Volatile Organic Compound (AVOC) Autoxidation as a Source of Highly Oxygenated Organic Molecules (HOM) M. Rissanen 10.1021/acs.jpca.1c06465
- Unimolecular and water reactions of oxygenated and unsaturated Criegee intermediates under atmospheric conditions L. Vereecken et al. 10.1039/D1CP05877K
- Photooxidation of pinonaldehyde at ambient conditions investigated in the atmospheric simulation chamber SAPHIR M. Rolletter et al. 10.5194/acp-20-13701-2020
- Chemistry of Simple Organic Peroxy Radicals under Atmospheric through Combustion Conditions: Role of Temperature, Pressure, and NOx Level M. Goldman et al. 10.1021/acs.jpca.1c07203
- Formation of Substituted Alkyls as Precursors of Peroxy Radicals with a Rapid H-Shift in the Atmosphere X. Wu et al. 10.1021/acs.jpclett.1c02503
- Molecular composition and volatility of multi-generation products formed from isoprene oxidation by nitrate radical R. Wu et al. 10.5194/acp-21-10799-2021
- Structures and reactivity of peroxy radicals and dimeric products revealed by online tandem mass spectrometry S. Tomaz et al. 10.1038/s41467-020-20532-2
- Biomass burning plume chemistry: OH-radical-initiated oxidation of 3-penten-2-one and its main oxidation product 2-hydroxypropanal N. Illmann et al. 10.5194/acp-21-18557-2021
- Molecular mechanism for rapid autoxidation in α-pinene ozonolysis S. Iyer et al. 10.1038/s41467-021-21172-w
- Theoretical and experimental study of peroxy and alkoxy radicals in the NO3-initiated oxidation of isoprene L. Vereecken et al. 10.1039/D0CP06267G
- High-pressure limit rate rules for intramolecular H-migration reactions of α,β-hydroxyalkylperoxy radicals J. Pu et al. 10.1007/s00214-021-02849-3
- Chlorine-Initiated Oxidation of α-Pinene: Formation of Secondary Organic Aerosol and Highly Oxygenated Organic Molecules C. Masoud & L. Ruiz 10.1021/acsearthspacechem.1c00150
- Highly Oxygenated Organic Nitrates Formed from NO3 Radical-Initiated Oxidation of β-Pinene H. Shen et al. 10.1021/acs.est.1c03978
- Atmospheric photooxidation and ozonolysis of Δ<sup>3</sup>-carene and 3-caronaldehyde: rate constants and product yields L. Hantschke et al. 10.5194/acp-21-12665-2021
33 citations as recorded by crossref.
- Unimolecular Reactions Following Indoor and Outdoor Limonene Ozonolysis J. Chen et al. 10.1021/acs.jpca.0c09882
- Efficient alkane oxidation under combustion engine and atmospheric conditions Z. Wang et al. 10.1038/s42004-020-00445-3
- Screening for New Pathways in Atmospheric Oxidation Chemistry with Automated Mechanism Generation V. Barber et al. 10.1021/acs.jpca.1c04297
- Peroxy Radical Processes and Product Formation in the OH Radical-Initiated Oxidation of α-Pinene for Near-Atmospheric Conditions T. Berndt 10.1021/acs.jpca.1c05576
- Efficient Production of Carbonyl Sulfide in the Low‐NO x Oxidation of Dimethyl Sulfide C. Jernigan et al. 10.1029/2021GL096838
- On the similarities and differences between the products of oxidation of hydrocarbons under simulated atmospheric conditions and cool flames R. Benoit et al. 10.5194/acp-21-7845-2021
- Highly oxygenated organic molecule (HOM) formation in the isoprene oxidation by NO<sub>3</sub> radical D. Zhao et al. 10.5194/acp-21-9681-2021
- A structure activity relationship for ring closure reactions in unsaturated alkylperoxy radicals L. Vereecken et al. 10.1039/D1CP02758A
- Autoxidation mechanism for atmospheric oxidation of tertiary amines: Implications for secondary organic aerosol formation F. Ma et al. 10.1016/j.chemosphere.2020.129207
- Atmospheric Chemistry of Allylic Radicals from Isoprene: A Successive Cyclization-Driven Autoxidation Mechanism F. Ma et al. 10.1021/acs.est.0c07925
- Atmospheric photo-oxidation of myrcene: OH reaction rate constant, gas-phase oxidation products and radical budgets Z. Tan et al. 10.5194/acp-21-16067-2021
- Simplified Protocol for the Calculation of Multiconformer Transition State Theory Rate Constants Applied to Tropospheric OH-Initiated Oxidation Reactions L. Viegas 10.1021/acs.jpca.1c00683
- Atmospheric Autoxidation of Amines K. Møller et al. 10.1021/acs.est.0c03937
- Particle Formation from Photooxidation of αpinene, Limonene, and Myrcene D. Hanson et al. 10.1021/acs.jpca.1c08427
- Using GECKO-A to derive mechanistic understanding of secondary organic aerosol formation from the ubiquitous but understudied camphene I. Afreh et al. 10.5194/acp-21-11467-2021
- Reactions of organic peroxy radicals, RO2, with substituted and biogenic alkenes at room temperature: unsuspected sinks for some RO2 in the atmosphere? B. Nozière & F. Fache 10.1039/D1SC02263F
- Gas-Phase Chlorine Radical Oxidation of Alkanes: Effects of Structural Branching, NOx, and Relative Humidity Observed during Environmental Chamber Experiments L. Jahn et al. 10.1021/acs.jpca.1c03516
- Atmospheric Autoxidation of Organophosphate Esters Z. Fu et al. 10.1021/acs.est.1c04817
- Rates and Yields of Unimolecular Reactions Producing Highly Oxidized Peroxy Radicals in the OH-Induced Autoxidation of α-Pinene, β-Pinene, and Limonene I. Piletic & T. Kleindienst 10.1021/acs.jpca.1c07961
- Anthropogenic Volatile Organic Compound (AVOC) Autoxidation as a Source of Highly Oxygenated Organic Molecules (HOM) M. Rissanen 10.1021/acs.jpca.1c06465
- Unimolecular and water reactions of oxygenated and unsaturated Criegee intermediates under atmospheric conditions L. Vereecken et al. 10.1039/D1CP05877K
- Photooxidation of pinonaldehyde at ambient conditions investigated in the atmospheric simulation chamber SAPHIR M. Rolletter et al. 10.5194/acp-20-13701-2020
- Chemistry of Simple Organic Peroxy Radicals under Atmospheric through Combustion Conditions: Role of Temperature, Pressure, and NOx Level M. Goldman et al. 10.1021/acs.jpca.1c07203
- Formation of Substituted Alkyls as Precursors of Peroxy Radicals with a Rapid H-Shift in the Atmosphere X. Wu et al. 10.1021/acs.jpclett.1c02503
- Molecular composition and volatility of multi-generation products formed from isoprene oxidation by nitrate radical R. Wu et al. 10.5194/acp-21-10799-2021
- Structures and reactivity of peroxy radicals and dimeric products revealed by online tandem mass spectrometry S. Tomaz et al. 10.1038/s41467-020-20532-2
- Biomass burning plume chemistry: OH-radical-initiated oxidation of 3-penten-2-one and its main oxidation product 2-hydroxypropanal N. Illmann et al. 10.5194/acp-21-18557-2021
- Molecular mechanism for rapid autoxidation in α-pinene ozonolysis S. Iyer et al. 10.1038/s41467-021-21172-w
- Theoretical and experimental study of peroxy and alkoxy radicals in the NO3-initiated oxidation of isoprene L. Vereecken et al. 10.1039/D0CP06267G
- High-pressure limit rate rules for intramolecular H-migration reactions of α,β-hydroxyalkylperoxy radicals J. Pu et al. 10.1007/s00214-021-02849-3
- Chlorine-Initiated Oxidation of α-Pinene: Formation of Secondary Organic Aerosol and Highly Oxygenated Organic Molecules C. Masoud & L. Ruiz 10.1021/acsearthspacechem.1c00150
- Highly Oxygenated Organic Nitrates Formed from NO3 Radical-Initiated Oxidation of β-Pinene H. Shen et al. 10.1021/acs.est.1c03978
- Atmospheric photooxidation and ozonolysis of Δ<sup>3</sup>-carene and 3-caronaldehyde: rate constants and product yields L. Hantschke et al. 10.5194/acp-21-12665-2021
Latest update: 03 Feb 2023
Short summary
Alkyl peroxy radicals, RO2, are important intermediates in the oxidation of organic material in the atmosphere. It was shown earlier that hydrogen atom migration within RO2 can be important and results in the formation of additional oxidants and large highly oxygenated molecules that lead to more and larger aerosols. In this work we propose a method for predicting the chemical rate for these H migrations in RO2, helping atmospheric models to correctly include these reactions.
Alkyl peroxy radicals, RO2, are important intermediates in the oxidation of organic material in...
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