Articles | Volume 20, issue 9
https://doi.org/10.5194/acp-20-5513-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-20-5513-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
12 May 2020
Research article |
| 12 May 2020
| 12 May 2020
Partitioning of hydrogen peroxide in gas-liquid and gas-aerosol phases
Xiaoning Xuan
State Key Laboratory of Environmental Simulation and Pollution Control, College of Environmental Sciences and Engineering, Peking University, Beijing, 100871, China
Zhongming Chen
CORRESPONDING AUTHOR
State Key Laboratory of Environmental Simulation and Pollution Control, College of Environmental Sciences and Engineering, Peking University, Beijing, 100871, China
Yiwei Gong
State Key Laboratory of Environmental Simulation and Pollution Control, College of Environmental Sciences and Engineering, Peking University, Beijing, 100871, China
Hengqing Shen
State Key Laboratory of Environmental Simulation and Pollution Control, College of Environmental Sciences and Engineering, Peking University, Beijing, 100871, China
Shiyi Chen
State Key Laboratory of Environmental Simulation and Pollution Control, College of Environmental Sciences and Engineering, Peking University, Beijing, 100871, China
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Cited
32 citations as recorded by crossref.
- Hydrogen peroxide serves as pivotal fountainhead for aerosol aqueous sulfate formation from a global perspective J. Gao et al.
- Fates of Organic Hydroperoxides in Atmospheric Condensed Phases S. Enami
- Dependence of aerosol formation on OH radical sources under humid conditions from m-xylene Q. Zhang et al.
- Distinct photochemistry in glycine particles mixed with different atmospheric nitrate salts Z. Liang et al.
- Decomposition mechanism of α-alkoxyalkyl-hydroperoxides in the liquid phase: temperature dependent kinetics and theoretical calculations M. Hu et al.
- Effects of Acidity on Reactive Oxygen Species Formation from Secondary Organic Aerosols J. Wei et al.
- Proton-Catalyzed Decomposition of Multifunctionalized Organic Hydroperoxides Derived from the Reactions of Criegee Intermediates with Ethylene Glycol in Aqueous Organic Media S. Enami
- Hydrogen peroxide photoformation in particulate matter and its contribution to S(IV) oxidation during winter in Fairbanks, Alaska M. Sunday et al.
- Impact of aerosol in-situ peroxide formations induced by metal complexes on atmospheric H2O2 budgets H. Song et al.
- Distribution of hydrogen peroxide over Europe during the BLUESKY aircraft campaign Z. Hamryszczak et al.
- Iodine Activation from Iodate Reduction in Aqueous Films via Photocatalyzed and Dark Reactions M. Reza et al.
- Compilation of reaction kinetics parameters determined in the Key Development Project for Air Pollution Formation Mechanism and Control Technologies in China Y. Liu et al.
- Effects of Metal Ions on Aqueous-Phase Decomposition of α-Hydroxyalkyl-Hydroperoxides Derived from Terpene Alcohols M. Hu et al.
- The number fraction of iron-containing particles affects OH, HO2 and H2O2 budgets in the atmospheric aqueous phase A. Khaled et al.
- Atmospheric Multiphase Chemistry of Organic Polyoxides S. ENAMI
- Aqueous-phase fates of α-alkoxyalkyl-hydroperoxides derived from the reactions of Criegee intermediates with alcohols M. Hu et al.
- Key Factors Determining the Formation of Sulfate Aerosols Through Multiphase Chemistry—A Kinetic Modeling Study Based on Beijing Conditions T. Wang et al.
- Enhanced chemiluminescence resonance energy transfer using surfactant‐modified AIE carbon dots J. Zhong et al.
- Multiphase Oxidation of Sulfur Dioxide in Aerosol Particles: Implications for Sulfate Formation in Polluted Environments T. Liu et al.
- Recent advancements in observations, sources, and environmental effects of atmospheric hydrogen peroxide (H2O2) L. Duan et al.
- Atmospheric Nitrated Phenolic Compounds in Particle, Gaseous, and Aqueous Phases During Cloud Events at a Mountain Site in North China: Distribution Characteristics and Aqueous‐Phase Formation M. Li et al.
- Photochemical Aging of Atmospheric Fine Particles as a Potential Source for Gas-Phase Hydrogen Peroxide P. Liu et al.
- Persistent Uptake of H2O2 onto Ambient PM2.5 via Dark-Fenton Chemistry X. Qin et al.
- Machine Learning Approach for the Estimation of Henry’s Law Constant Based on Molecular Descriptors A. Ullah et al.
- Influence of Meteorological Factors and Chemical Processes on the Explosive Growth of PM2.5 in Shanghai, China W. Sun et al.
- Aerosol Promotes Peroxyacetyl Nitrate Formation During Winter in the North China Plain W. Xu et al.
- Decomposition of multifunctionalized α-alkoxyalkyl-hydroperoxides derived from the reactions of Criegee intermediates with diols in liquid phases Y. Endo et al.
- Temperature Dependence of Aqueous-Phase Decomposition of α-Hydroxyalkyl-Hydroperoxides M. Hu et al.
- Hydrolysis reactivity reveals significant seasonal variation in the composition of organic peroxides in ambient PM2.5 Y. Dai et al.
- Proton-Catalyzed Decomposition of α-Hydroxyalkyl-Hydroperoxides in Water J. Qiu et al.
- Kinetics of Heterogeneous Reaction of H2O2 and SO2 on Coal Fly Ash: Temperature Effect and Their Synergistic Effects L. Zhou et al.
- Organic Peroxides in Aerosol: Key Reactive Intermediates for Multiphase Processes in the Atmosphere S. Wang et al.
32 citations as recorded by crossref.
- Hydrogen peroxide serves as pivotal fountainhead for aerosol aqueous sulfate formation from a global perspective J. Gao et al.
- Fates of Organic Hydroperoxides in Atmospheric Condensed Phases S. Enami
- Dependence of aerosol formation on OH radical sources under humid conditions from m-xylene Q. Zhang et al.
- Distinct photochemistry in glycine particles mixed with different atmospheric nitrate salts Z. Liang et al.
- Decomposition mechanism of α-alkoxyalkyl-hydroperoxides in the liquid phase: temperature dependent kinetics and theoretical calculations M. Hu et al.
- Effects of Acidity on Reactive Oxygen Species Formation from Secondary Organic Aerosols J. Wei et al.
- Proton-Catalyzed Decomposition of Multifunctionalized Organic Hydroperoxides Derived from the Reactions of Criegee Intermediates with Ethylene Glycol in Aqueous Organic Media S. Enami
- Hydrogen peroxide photoformation in particulate matter and its contribution to S(IV) oxidation during winter in Fairbanks, Alaska M. Sunday et al.
- Impact of aerosol in-situ peroxide formations induced by metal complexes on atmospheric H2O2 budgets H. Song et al.
- Distribution of hydrogen peroxide over Europe during the BLUESKY aircraft campaign Z. Hamryszczak et al.
- Iodine Activation from Iodate Reduction in Aqueous Films via Photocatalyzed and Dark Reactions M. Reza et al.
- Compilation of reaction kinetics parameters determined in the Key Development Project for Air Pollution Formation Mechanism and Control Technologies in China Y. Liu et al.
- Effects of Metal Ions on Aqueous-Phase Decomposition of α-Hydroxyalkyl-Hydroperoxides Derived from Terpene Alcohols M. Hu et al.
- The number fraction of iron-containing particles affects OH, HO2 and H2O2 budgets in the atmospheric aqueous phase A. Khaled et al.
- Atmospheric Multiphase Chemistry of Organic Polyoxides S. ENAMI
- Aqueous-phase fates of α-alkoxyalkyl-hydroperoxides derived from the reactions of Criegee intermediates with alcohols M. Hu et al.
- Key Factors Determining the Formation of Sulfate Aerosols Through Multiphase Chemistry—A Kinetic Modeling Study Based on Beijing Conditions T. Wang et al.
- Enhanced chemiluminescence resonance energy transfer using surfactant‐modified AIE carbon dots J. Zhong et al.
- Multiphase Oxidation of Sulfur Dioxide in Aerosol Particles: Implications for Sulfate Formation in Polluted Environments T. Liu et al.
- Recent advancements in observations, sources, and environmental effects of atmospheric hydrogen peroxide (H2O2) L. Duan et al.
- Atmospheric Nitrated Phenolic Compounds in Particle, Gaseous, and Aqueous Phases During Cloud Events at a Mountain Site in North China: Distribution Characteristics and Aqueous‐Phase Formation M. Li et al.
- Photochemical Aging of Atmospheric Fine Particles as a Potential Source for Gas-Phase Hydrogen Peroxide P. Liu et al.
- Persistent Uptake of H2O2 onto Ambient PM2.5 via Dark-Fenton Chemistry X. Qin et al.
- Machine Learning Approach for the Estimation of Henry’s Law Constant Based on Molecular Descriptors A. Ullah et al.
- Influence of Meteorological Factors and Chemical Processes on the Explosive Growth of PM2.5 in Shanghai, China W. Sun et al.
- Aerosol Promotes Peroxyacetyl Nitrate Formation During Winter in the North China Plain W. Xu et al.
- Decomposition of multifunctionalized α-alkoxyalkyl-hydroperoxides derived from the reactions of Criegee intermediates with diols in liquid phases Y. Endo et al.
- Temperature Dependence of Aqueous-Phase Decomposition of α-Hydroxyalkyl-Hydroperoxides M. Hu et al.
- Hydrolysis reactivity reveals significant seasonal variation in the composition of organic peroxides in ambient PM2.5 Y. Dai et al.
- Proton-Catalyzed Decomposition of α-Hydroxyalkyl-Hydroperoxides in Water J. Qiu et al.
- Kinetics of Heterogeneous Reaction of H2O2 and SO2 on Coal Fly Ash: Temperature Effect and Their Synergistic Effects L. Zhou et al.
- Organic Peroxides in Aerosol: Key Reactive Intermediates for Multiphase Processes in the Atmosphere S. Wang et al.
Saved (final revised paper)
Latest update: 23 May 2026
Short summary
In this study, we found that the effective field-derived Henry's law constant for the ground rainwater and the gas-phase H2O2 was about 2.5 times that of the theoretical value, and the effective gas–particle partitioning coefficient for the aerosol particle and the gas-phase H2O2 was 4 orders of magnitude higher than the theoretical one. We suggested the missing source of H2O2 in the particulate phase, e.g. the contribution from the decomposition/hydrolysis of organic peroxides.
In this study, we found that the effective field-derived Henry's law constant for the ground...
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