Articles | Volume 20, issue 7
https://doi.org/10.5194/acp-20-4367-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-20-4367-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Heterogeneous N2O5 reactions on atmospheric aerosols at four Chinese sites: improving model representation of uptake parameters
Chuan Yu
Environment Research Institute, Shandong University, Ji'nan, Shandong, China
Department of Civil and Environmental Engineering, The Hong Kong
Polytechnic University, Hong Kong, China
Division of Environment and Sustainability, The Hong Kong University of Science and Technology, Hong Kong, China
Department of Civil and Environmental Engineering, The Hong Kong
Polytechnic University, Hong Kong, China
Department of Civil and Environmental Engineering, The Hong Kong
Polytechnic University, Hong Kong, China
Weihao Wang
Department of Civil and Environmental Engineering, The Hong Kong
Polytechnic University, Hong Kong, China
Yee Jun Tham
Department of Civil and Environmental Engineering, The Hong Kong
Polytechnic University, Hong Kong, China
Institute for Atmospheric and Earth System Research/Physics,
University of Helsinki, 00014, Helsinki, Finland
Tianshu Chen
Environment Research Institute, Shandong University, Ji'nan, Shandong, China
Penggang Zheng
Environment Research Institute, Shandong University, Ji'nan, Shandong, China
Hongyong Li
Environment Research Institute, Shandong University, Ji'nan, Shandong, China
Environment Research Institute, Shandong University, Ji'nan, Shandong, China
Xinfeng Wang
Environment Research Institute, Shandong University, Ji'nan, Shandong, China
Likun Xue
Environment Research Institute, Shandong University, Ji'nan, Shandong, China
Yan Zhou
Guangdong Environmental Monitoring Center, State Environmental
Protection Key Laboratory of Regional Air Quality Monitoring, Guangzhou,
China
Dingli Yue
Guangdong Environmental Monitoring Center, State Environmental
Protection Key Laboratory of Regional Air Quality Monitoring, Guangzhou,
China
Yubo Ou
Guangdong Environmental Monitoring Center, State Environmental
Protection Key Laboratory of Regional Air Quality Monitoring, Guangzhou,
China
Jian Gao
Chinese Research Academy of Environmental Sciences, Beijing, China
Keding Lu
State Key Joint Laboratory of Environmental Simulation and Pollution
Control, College of Environmental Sciences and Engineering, Peking
University, Beijing, China
Steven S. Brown
Chemical Sciences Division, Earth System Research Laboratory, NOAA,
Boulder, CO, USA
Department of Chemistry, University of Colorado Boulder, Boulder, CO, USA
Yuanhang Zhang
State Key Joint Laboratory of Environmental Simulation and Pollution
Control, College of Environmental Sciences and Engineering, Peking
University, Beijing, China
Department of Civil and Environmental Engineering, The Hong Kong
Polytechnic University, Hong Kong, China
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Cited
51 citations as recorded by crossref.
- Fast Nocturnal Heterogeneous Chemistry in a Coastal Background Atmosphere and Its Implications for Daytime Photochemistry Y. Niu et al.
- The significant contribution of nitrate to a severe haze event in the winter of Guangzhou, China C. Cheng et al.
- The determination of ClNO2 via thermal dissociation–tunable infrared laser direct absorption spectroscopy J. Halfacre et al.
- Formation and impacts of nitryl chloride in Pearl River Delta H. Wang et al.
- Real-time measurements of PM2.5 water-soluble inorganic ions at a high-altitude mountain site in the western North Pacific: Impact of upslope wind and long-range transported biomass-burning smoke W. Chen et al.
- High atmospheric oxidation capacity drives wintertime nitrate pollution in the eastern Yangtze River Delta of China H. Zang et al.
- Resolving the amine-promoted hydrolysis mechanism of N 2 O 5 under tropospheric conditions C. Zhou et al.
- Vertical Gradient of Nitryl Chloride and Implications for Atmospheric Photochemistry in Pearl River Delta, China, during Wintertime H. Wang et al.
- Nitrate pollution deterioration in winter driven by surface ozone increase Z. Zhang et al.
- The application and uncertainty of the observation-based model in ozone and secondary aerosols simulation: A review J. Wei et al.
- Secondary Formation and Impacts of Gaseous Nitro-Phenolic Compounds in the Continental Outflow Observed at a Background Site in South China Y. Chen et al.
- Different Response Mechanisms of N‐Bearing Components to Emission Reduction Across China During COVID‐19 Lockdown Period R. Li et al.
- Modeling particulate nitrate in China: Current findings and future directions X. Xie et al.
- Gas-phase reactions accelerate nitrate formation in spring and early summer in a megacity of the Sichuan Basin, China Y. Li et al.
- The atmospheric oxidizing capacity in China – Part 1: Roles of different photochemical processes J. Dai et al.
- Measurement report: High contribution of N2O5 uptake to particulate nitrate formation in NO2-limited urban areas Z. Lin et al.
- N2O5 uptake onto saline mineral dust: a potential missing source of tropospheric ClNO2 in inland China H. Wang et al.
- Incorporation of multi-phase halogen chemistry into the Community Multiscale Air Quality (CMAQ) model K. Kim et al.
- Significant contributions of sea spray aerosol to vertical ClNO2 formation over coastal South China Y. Zhu et al.
- Ground-level ozone pollution in China: a synthesis of recent findings on influencing factors and impacts T. Wang et al.
- Identifying Driving Factors of Atmospheric N2O5 with Machine Learning X. Chen et al.
- Direct measurement of N2O5 heterogeneous uptake coefficients on ambient aerosols via an aerosol flow tube system: design, characterization and performance X. Chen et al.
- Secondary aerosol formation drives atmospheric particulate matter pollution over megacities (Beijing and Seoul) in East Asia Y. Qiu et al.
- Budget of atmospheric nitrous acid (HONO) during the haze and clean periods in Shanghai: Importance of heterogeneous reactions J. Feng et al.
- Nocturnal atmospheric chemistry of NO3 and N2O5 over Changzhou in the Yangtze River Delta in China C. Lin et al.
- Characterizing nitrate radical budget trends in Beijing during 2013–2019 H. Wang et al.
- Intercomparison of measured and modelled photochemical ozone production rates: Suggestion of chemistry hypothesis regarding unmeasured VOCs J. Zhou et al.
- Heterogeneous Nitrate Production Mechanisms in Intense Haze Events in the North China Plain Y. Chan et al.
- Elucidate the formation mechanism of particulate nitrate based on direct radical observations in the Yangtze River Delta summer 2019 T. Zhai et al.
- Atmospheric nitrate formation pathways in urban and rural atmosphere of Northeast China: Implications for complicated anthropogenic effects Z. Li et al.
- Box Model Applications for Secondary Inorganic Aerosol: A Review Focused on Nitrate Formation S. Park
- The impact of chlorine chemistry combined with heterogeneous N2O5 reactions on air quality in China X. Yang et al.
- Potential deterioration of ozone pollution in coastal areas caused by marine-emitted halogens: A case study in the Guangdong-Hong Kong-Macao Greater Bay Area S. Fan & Y. Li
- A Novel Apportionment Method Utilizing Particle Mass Size Distribution across Multiple Particle Size Ranges P. Wang et al.
- High-level HONO exacerbates double high pollution of O3 and PM2.5 in China C. Liu et al.
- Interpretation of NO3–N2O5 observation via steady state in high-aerosol air mass: the impact of equilibrium coefficient in ambient conditions X. Chen et al.
- The impacts of marine-emitted halogens on OH radicals in East Asia during summer S. Fan & Y. Li
- Reactive halogens in polluted atmospheres: Sources, processes, and impacts on secondary pollutants T. Wang et al.
- The impact of sea-salt chloride on ozone through heterogeneous reaction with N2O5 in a coastal region of south China J. Dai et al.
- Widespread surface ozone reduction triggered by dust storm disturbance on ozone production and destruction chemistry Y. Zhang et al.
- Measurement report: Atmospheric nitrate radical chemistry in the South China Sea influenced by the urban outflow of the Pearl River Delta J. Wang et al.
- A systematic review of reactive nitrogen simulations with chemical transport models in China H. Zhang et al.
- Measurement report: Variations and environmental impacts of atmospheric N2O5 concentrations in urban Beijing during the 2022 Winter Olympics T. Zhang et al.
- Secondary inorganic aerosol chemistry and its impact on atmospheric visibility over an ammonia-rich urban area in Central Taiwan L. Young et al.
- Particle hygroscopicity inhomogeneity and its impact on reactive uptake T. Zong et al.
- Nocturnal N2O5 and NO3 chemistry and its impact on wintertime HNO3 in Seoul during ASIA-AQ campaign J. Kim et al.
- Direct measurement of N2O5 heterogeneous uptake coefficients on atmospheric aerosols in southwestern China and evaluation of current parameterizations J. Li et al.
- Insights into the direct effects of declining aerosol concentrations on O3 and secondary organic aerosols during a PM2.5–O3 co-pollution episode F. Wang et al.
- The formation and mitigation of nitrate pollution: comparison between urban and suburban environments S. Yang et al.
- Nocturnal Atmospheric Oxidative Processes in the Indo‐Gangetic Plain and Their Variation During the COVID‐19 Lockdowns D. Meidan et al.
- Formation mechanism and control strategy for particulate nitrate in China H. Wang et al.
51 citations as recorded by crossref.
- Fast Nocturnal Heterogeneous Chemistry in a Coastal Background Atmosphere and Its Implications for Daytime Photochemistry Y. Niu et al.
- The significant contribution of nitrate to a severe haze event in the winter of Guangzhou, China C. Cheng et al.
- The determination of ClNO2 via thermal dissociation–tunable infrared laser direct absorption spectroscopy J. Halfacre et al.
- Formation and impacts of nitryl chloride in Pearl River Delta H. Wang et al.
- Real-time measurements of PM2.5 water-soluble inorganic ions at a high-altitude mountain site in the western North Pacific: Impact of upslope wind and long-range transported biomass-burning smoke W. Chen et al.
- High atmospheric oxidation capacity drives wintertime nitrate pollution in the eastern Yangtze River Delta of China H. Zang et al.
- Resolving the amine-promoted hydrolysis mechanism of N 2 O 5 under tropospheric conditions C. Zhou et al.
- Vertical Gradient of Nitryl Chloride and Implications for Atmospheric Photochemistry in Pearl River Delta, China, during Wintertime H. Wang et al.
- Nitrate pollution deterioration in winter driven by surface ozone increase Z. Zhang et al.
- The application and uncertainty of the observation-based model in ozone and secondary aerosols simulation: A review J. Wei et al.
- Secondary Formation and Impacts of Gaseous Nitro-Phenolic Compounds in the Continental Outflow Observed at a Background Site in South China Y. Chen et al.
- Different Response Mechanisms of N‐Bearing Components to Emission Reduction Across China During COVID‐19 Lockdown Period R. Li et al.
- Modeling particulate nitrate in China: Current findings and future directions X. Xie et al.
- Gas-phase reactions accelerate nitrate formation in spring and early summer in a megacity of the Sichuan Basin, China Y. Li et al.
- The atmospheric oxidizing capacity in China – Part 1: Roles of different photochemical processes J. Dai et al.
- Measurement report: High contribution of N2O5 uptake to particulate nitrate formation in NO2-limited urban areas Z. Lin et al.
- N2O5 uptake onto saline mineral dust: a potential missing source of tropospheric ClNO2 in inland China H. Wang et al.
- Incorporation of multi-phase halogen chemistry into the Community Multiscale Air Quality (CMAQ) model K. Kim et al.
- Significant contributions of sea spray aerosol to vertical ClNO2 formation over coastal South China Y. Zhu et al.
- Ground-level ozone pollution in China: a synthesis of recent findings on influencing factors and impacts T. Wang et al.
- Identifying Driving Factors of Atmospheric N2O5 with Machine Learning X. Chen et al.
- Direct measurement of N2O5 heterogeneous uptake coefficients on ambient aerosols via an aerosol flow tube system: design, characterization and performance X. Chen et al.
- Secondary aerosol formation drives atmospheric particulate matter pollution over megacities (Beijing and Seoul) in East Asia Y. Qiu et al.
- Budget of atmospheric nitrous acid (HONO) during the haze and clean periods in Shanghai: Importance of heterogeneous reactions J. Feng et al.
- Nocturnal atmospheric chemistry of NO3 and N2O5 over Changzhou in the Yangtze River Delta in China C. Lin et al.
- Characterizing nitrate radical budget trends in Beijing during 2013–2019 H. Wang et al.
- Intercomparison of measured and modelled photochemical ozone production rates: Suggestion of chemistry hypothesis regarding unmeasured VOCs J. Zhou et al.
- Heterogeneous Nitrate Production Mechanisms in Intense Haze Events in the North China Plain Y. Chan et al.
- Elucidate the formation mechanism of particulate nitrate based on direct radical observations in the Yangtze River Delta summer 2019 T. Zhai et al.
- Atmospheric nitrate formation pathways in urban and rural atmosphere of Northeast China: Implications for complicated anthropogenic effects Z. Li et al.
- Box Model Applications for Secondary Inorganic Aerosol: A Review Focused on Nitrate Formation S. Park
- The impact of chlorine chemistry combined with heterogeneous N2O5 reactions on air quality in China X. Yang et al.
- Potential deterioration of ozone pollution in coastal areas caused by marine-emitted halogens: A case study in the Guangdong-Hong Kong-Macao Greater Bay Area S. Fan & Y. Li
- A Novel Apportionment Method Utilizing Particle Mass Size Distribution across Multiple Particle Size Ranges P. Wang et al.
- High-level HONO exacerbates double high pollution of O3 and PM2.5 in China C. Liu et al.
- Interpretation of NO3–N2O5 observation via steady state in high-aerosol air mass: the impact of equilibrium coefficient in ambient conditions X. Chen et al.
- The impacts of marine-emitted halogens on OH radicals in East Asia during summer S. Fan & Y. Li
- Reactive halogens in polluted atmospheres: Sources, processes, and impacts on secondary pollutants T. Wang et al.
- The impact of sea-salt chloride on ozone through heterogeneous reaction with N2O5 in a coastal region of south China J. Dai et al.
- Widespread surface ozone reduction triggered by dust storm disturbance on ozone production and destruction chemistry Y. Zhang et al.
- Measurement report: Atmospheric nitrate radical chemistry in the South China Sea influenced by the urban outflow of the Pearl River Delta J. Wang et al.
- A systematic review of reactive nitrogen simulations with chemical transport models in China H. Zhang et al.
- Measurement report: Variations and environmental impacts of atmospheric N2O5 concentrations in urban Beijing during the 2022 Winter Olympics T. Zhang et al.
- Secondary inorganic aerosol chemistry and its impact on atmospheric visibility over an ammonia-rich urban area in Central Taiwan L. Young et al.
- Particle hygroscopicity inhomogeneity and its impact on reactive uptake T. Zong et al.
- Nocturnal N2O5 and NO3 chemistry and its impact on wintertime HNO3 in Seoul during ASIA-AQ campaign J. Kim et al.
- Direct measurement of N2O5 heterogeneous uptake coefficients on atmospheric aerosols in southwestern China and evaluation of current parameterizations J. Li et al.
- Insights into the direct effects of declining aerosol concentrations on O3 and secondary organic aerosols during a PM2.5–O3 co-pollution episode F. Wang et al.
- The formation and mitigation of nitrate pollution: comparison between urban and suburban environments S. Yang et al.
- Nocturnal Atmospheric Oxidative Processes in the Indo‐Gangetic Plain and Their Variation During the COVID‐19 Lockdowns D. Meidan et al.
- Formation mechanism and control strategy for particulate nitrate in China H. Wang et al.
Saved (final revised paper)
Latest update: 11 May 2026
Short summary
This study provides a holistic picture of N2O5 heterogeneous uptake on ambient aerosols and the influencing factors under various climatic and chemical conditions in China, and it proposes an observation-based empirical parameterization. The empirical parameterization can be used in air quality models to improve the prediction of PM2.5 and photochemical pollution in China and similar polluted regions of the world.
This study provides a holistic picture of N2O5 heterogeneous uptake on ambient aerosols and the...
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