Articles | Volume 20, issue 7
https://doi.org/10.5194/acp-20-4255-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-20-4255-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Oxygen and sulfur mass-independent isotopic signatures in black crusts: the complementary negative Δ33S reservoir of sulfate aerosols?
Isabelle Genot
CORRESPONDING AUTHOR
Institut de physique du globe de Paris, Université de Paris, CNRS,
75005 Paris, France
Sorbonne Université, CNRS-INSU, Institut des Sciences de la Terre
de Paris, IsteP UMR7193 Paris, France
David Au Yang
Institut de physique du globe de Paris, Université de Paris, CNRS,
75005 Paris, France
GEOTOP/Université du Québec à Montréal, Montréal H3C 3P8,
Canada
Department of Earth and Planetary Sciences, McGill University,
Montréal, Canada
Erwan Martin
Sorbonne Université, CNRS-INSU, Institut des Sciences de la Terre
de Paris, IsteP UMR7193 Paris, France
Pierre Cartigny
Institut de physique du globe de Paris, Université de Paris, CNRS,
75005 Paris, France
Erwann Legendre
Sorbonne Université, CNRS-INSU, Institut des Sciences de la Terre
de Paris, IsteP UMR7193 Paris, France
LATMOS, UVSQ, Université Paris Saclay, Sorbonne Université,
CNRS, INSU, IPSL, 11 Boulevard d'Alembert, 78280, Guyancourt, France
Marc De Rafelis
Géosciences Environnement Toulouse (GET), Université Toulouse III – Paul Sabatier, CNRS UMR 5563, IRD, 14 avenue Edouard Belin, 31400
Toulouse, France
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Cited
11 citations as recorded by crossref.
- A multi-analytical approach for the identification of pollutant sources on black crust samples: Stable isotope ratio of carbon, sulphur, and oxygen M. Ricciardi et al. 10.1016/j.scitotenv.2024.175557
- Toward the Origins of Quadruple Sulfur Isotope Anomalies in Modern Sulfate: A Multitracer Approach and Implications for Paleo- and Planetary Atmospheres B. Yin et al. 10.1021/acsearthspacechem.2c00360
- Tracing the origin of elevated springtime atmospheric sulfate on the southern Himalayan-Tibetan plateau S. Dasari et al. 10.1039/D3VA00085K
- High-Resolution Monitoring and Redox-Potential-Based Solute Transport Modeling to Partition Denitrification Pathways at an Agricultural Site J. Richard-Cerda et al. 10.1021/acsestwater.4c00540
- South-hemispheric marine aerosol Hg and S isotope compositions reveal different oxidation pathways D. AuYang et al. 10.1360/nso/20220014
- Sulfur isotope anomalies in coal combustion: Applications to the present and early Earth environments Y. Shen et al. 10.1073/pnas.2408199121
- The mass-independent oxygen isotopic composition in sulfate aerosol-a useful tool to identify sulfate formation: a review Y. Zhao et al. 10.1016/j.atmosres.2020.105447
- Multiple Sulfur Isotopic Evidence for Sulfate Formation in Haze Pollution X. Han et al. 10.1021/acs.est.3c05072
- Continuous-Flow Stable Sulfur Isotope Analysis of Organic and Inorganic Compounds by EA-MC-ICPMS A. Horst et al. 10.1021/acs.analchem.4c00439
- Record of pre-industrial atmospheric sulfate in continental interiors Y. Peng et al. 10.1038/s41561-023-01211-5
- Study on the mechanism of the black crust formation on the ancient marble sculptures and the effect of pollution in Beijing area F. Wang et al. 10.1016/j.heliyon.2022.e10442
11 citations as recorded by crossref.
- A multi-analytical approach for the identification of pollutant sources on black crust samples: Stable isotope ratio of carbon, sulphur, and oxygen M. Ricciardi et al. 10.1016/j.scitotenv.2024.175557
- Toward the Origins of Quadruple Sulfur Isotope Anomalies in Modern Sulfate: A Multitracer Approach and Implications for Paleo- and Planetary Atmospheres B. Yin et al. 10.1021/acsearthspacechem.2c00360
- Tracing the origin of elevated springtime atmospheric sulfate on the southern Himalayan-Tibetan plateau S. Dasari et al. 10.1039/D3VA00085K
- High-Resolution Monitoring and Redox-Potential-Based Solute Transport Modeling to Partition Denitrification Pathways at an Agricultural Site J. Richard-Cerda et al. 10.1021/acsestwater.4c00540
- South-hemispheric marine aerosol Hg and S isotope compositions reveal different oxidation pathways D. AuYang et al. 10.1360/nso/20220014
- Sulfur isotope anomalies in coal combustion: Applications to the present and early Earth environments Y. Shen et al. 10.1073/pnas.2408199121
- The mass-independent oxygen isotopic composition in sulfate aerosol-a useful tool to identify sulfate formation: a review Y. Zhao et al. 10.1016/j.atmosres.2020.105447
- Multiple Sulfur Isotopic Evidence for Sulfate Formation in Haze Pollution X. Han et al. 10.1021/acs.est.3c05072
- Continuous-Flow Stable Sulfur Isotope Analysis of Organic and Inorganic Compounds by EA-MC-ICPMS A. Horst et al. 10.1021/acs.analchem.4c00439
- Record of pre-industrial atmospheric sulfate in continental interiors Y. Peng et al. 10.1038/s41561-023-01211-5
- Study on the mechanism of the black crust formation on the ancient marble sculptures and the effect of pollution in Beijing area F. Wang et al. 10.1016/j.heliyon.2022.e10442
Latest update: 06 Apr 2025
Short summary
Given their critical impact on radiative forcing, sulfate aerosols have been extensively studied using their isotope signatures (δ34S, ∆33S, ∆36S, δ18O, and ∆17O). A striking observation is that ∆33S > 0 ‰, implying a missing reservoir in the sulfur cycle. Here, we measured ∆33S < 0 ‰ in black crust sulfates (i.e., formed on carbonate walls) that must therefore result from distinct chemical pathway(s) compared to sulfate aerosols, and they may well represent this complementary reservoir.
Given their critical impact on radiative forcing, sulfate aerosols have been extensively studied...
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