Articles | Volume 20, issue 6
https://doi.org/10.5194/acp-20-3859-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-20-3859-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Global inorganic nitrate production mechanisms: comparison of a global model with nitrate isotope observations
Department of Atmospheric Sciences, University of Washington, Seattle,
WA 98195, USA
Tomás Sherwen
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry,
University of York, York YO10 5DD, UK
National Center for Atmospheric Science, University of York, York YO10
5DD, UK
Christopher D. Holmes
Department of Earth, Ocean and Atmospheric Science, Florida State
University, Tallahassee, FL 32306, USA
Jenny A. Fisher
Centre for Atmospheric Chemistry, University of Wollongong,
Wollongong, New South Wales 2522, Australia
Qianjie Chen
Department of Atmospheric Sciences, University of Washington, Seattle,
WA 98195, USA
now at: Department of Chemistry, University of Michigan, Ann Arbor, MI
48109, USA
Mat J. Evans
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry,
University of York, York YO10 5DD, UK
National Center for Atmospheric Science, University of York, York YO10
5DD, UK
Prasad Kasibhatla
Nicholas School of the Environment, Duke University, Durham, NC 27708,
USA
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- Diurnal variations in oxygen and nitrogen isotopes of atmospheric nitrogen dioxide and nitrate: implications for tracing NOx oxidation pathways and emission sources S. Albertin et al. 10.5194/acp-24-1361-2024
- Long-term study of chemical characteristics of aerosol compositions in the rural environment of Rūgšteliškis (Lithuania) T. Gill et al. 10.1016/j.apr.2024.102048
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- Formation pathways and source apportionments of inorganic nitrogen-containing aerosols in urban environment: Insights from nitrogen and oxygen isotopic compositions in Guangzhou, China D. Xi et al. 10.1016/j.atmosenv.2023.119888
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- Impacts of post-depositional processing on nitrate isotopes in the snow and the overlying atmosphere at Summit, Greenland Z. Jiang et al. 10.5194/tc-16-2709-2022
- Isotopic components and source analysis of inorganic nitrogen in coastal aerosols of the Yellow Sea K. Zhang et al. 10.3389/fmars.2022.993160
- Isotopic constraints confirm the significant role of microbial nitrogen oxides emissions from the land and ocean environment W. Song et al. 10.1093/nsr/nwac106
- Measurement report: Nitrogen isotopes (<i>δ</i><sup>15</sup>N) and first quantification of oxygen isotope anomalies (<i>Δ</i><sup>17</sup>O, <i>δ</i><sup>18</sup>O) in atmospheric nitrogen dioxide S. Albertin et al. 10.5194/acp-21-10477-2021
- Diesel vehicle emission accounts for the dominate NO source to atmospheric particulate nitrate in a coastal city: Insights from nitrate dual isotopes of PM2.5 W. Zhang et al. 10.1016/j.atmosres.2022.106328
- Persistent Nitrate in Alpine Waters with Changing Atmospheric Deposition and Warming Trends S. Clark et al. 10.1021/acs.est.1c02515
- An inverse model to correct for the effects of post-depositional processing on ice-core nitrate and its isotopes: model framework and applications at Summit, Greenland, and Dome C, Antarctica Z. Jiang et al. 10.5194/acp-24-4895-2024
- Determination of the triple oxygen isotopic composition of tropospheric ozone in terminal positions using a multistep nitrite‐coated filter‐pack system H. Xu et al. 10.1002/rcm.9124
- Atmospheric nitrate formation pathways in urban and rural atmosphere of Northeast China: Implications for complicated anthropogenic effects Z. Li et al. 10.1016/j.envpol.2021.118752
- A systematic review of reactive nitrogen simulations with chemical transport models in China H. Zhang et al. 10.1016/j.atmosres.2024.107586
- Mass-Independent Fractionation of Oxygen Isotopes in the Atmosphere M. Brinjikji & J. Lyons 10.2138/rmg.2021.86.06
- Formation Mechanisms and Source Apportionments of Nitrate Aerosols in a Megacity of Eastern China Based On Multiple Isotope Observations M. Fan et al. 10.1029/2022JD038129
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Short summary
Nitrogen oxides are important for the formation of tropospheric oxidants and are removed from the atmosphere mainly through the formation of nitrate. We compare observations of the oxygen isotopes of nitrate with a global model to test our understanding of the chemistry nitrate formation. We use the model to quantify nitrate formation pathways in the atmosphere and identify key uncertainties and their relevance for the oxidation capacity of the atmosphere.
Nitrogen oxides are important for the formation of tropospheric oxidants and are removed from...
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