Articles | Volume 20, issue 23
https://doi.org/10.5194/acp-20-14769-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-20-14769-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Measurement report: Important contributions of oxygenated compounds to emissions and chemistry of volatile organic compounds in urban air
Caihong Wu
Institute for Environmental and Climate Research, Jinan University,
Guangzhou 511443, China
Guangdong–Hong Kong–Macau Joint Laboratory of Collaborative
Innovation for Environmental Quality, Guangzhou 511443, China
Chaomin Wang
Institute for Environmental and Climate Research, Jinan University,
Guangzhou 511443, China
Guangdong–Hong Kong–Macau Joint Laboratory of Collaborative
Innovation for Environmental Quality, Guangzhou 511443, China
Sihang Wang
Institute for Environmental and Climate Research, Jinan University,
Guangzhou 511443, China
Guangdong–Hong Kong–Macau Joint Laboratory of Collaborative
Innovation for Environmental Quality, Guangzhou 511443, China
Wenjie Wang
State Joint Key Laboratory of Environmental Simulation and
Pollution Control, College of Environmental Sciences and Engineering, Peking
University, Beijing 100871, China
Institute for Environmental and Climate Research, Jinan University,
Guangzhou 511443, China
Guangdong–Hong Kong–Macau Joint Laboratory of Collaborative
Innovation for Environmental Quality, Guangzhou 511443, China
Jipeng Qi
Institute for Environmental and Climate Research, Jinan University,
Guangzhou 511443, China
Guangdong–Hong Kong–Macau Joint Laboratory of Collaborative
Innovation for Environmental Quality, Guangzhou 511443, China
Baolin Wang
School of Environmental Science and Engineering, Qilu University of
Technology, Jinan 250353, China
Hongli Wang
State Environmental Protection Key Laboratory of Formation and
Prevention of Urban Air Pollution Complex, Shanghai Academy of Environmental
Sciences, Shanghai 200233, China
Chen Wang
School of Environmental Science and Engineering, Qilu University of
Technology, Jinan 250353, China
Wei Song
State Key Laboratory of Organic Geochemistry, Guangzhou Institute
of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China
Xinming Wang
State Key Laboratory of Organic Geochemistry, Guangzhou Institute
of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China
Weiwei Hu
State Key Laboratory of Organic Geochemistry, Guangzhou Institute
of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China
Shengrong Lou
State Environmental Protection Key Laboratory of Formation and
Prevention of Urban Air Pollution Complex, Shanghai Academy of Environmental
Sciences, Shanghai 200233, China
Chenshuo Ye
State Joint Key Laboratory of Environmental Simulation and
Pollution Control, College of Environmental Sciences and Engineering, Peking
University, Beijing 100871, China
Yuwen Peng
Institute for Environmental and Climate Research, Jinan University,
Guangzhou 511443, China
Guangdong–Hong Kong–Macau Joint Laboratory of Collaborative
Innovation for Environmental Quality, Guangzhou 511443, China
Zelong Wang
Institute for Environmental and Climate Research, Jinan University,
Guangzhou 511443, China
Guangdong–Hong Kong–Macau Joint Laboratory of Collaborative
Innovation for Environmental Quality, Guangzhou 511443, China
Yibo Huangfu
Institute for Environmental and Climate Research, Jinan University,
Guangzhou 511443, China
Guangdong–Hong Kong–Macau Joint Laboratory of Collaborative
Innovation for Environmental Quality, Guangzhou 511443, China
Yan Xie
College of Environment and Energy, South China University of
Technology, Guangzhou 510006, China
Manni Zhu
College of Environment and Energy, South China University of
Technology, Guangzhou 510006, China
Junyu Zheng
Institute for Environmental and Climate Research, Jinan University,
Guangzhou 511443, China
Guangdong–Hong Kong–Macau Joint Laboratory of Collaborative
Innovation for Environmental Quality, Guangzhou 511443, China
Xuemei Wang
Institute for Environmental and Climate Research, Jinan University,
Guangzhou 511443, China
Guangdong–Hong Kong–Macau Joint Laboratory of Collaborative
Innovation for Environmental Quality, Guangzhou 511443, China
Bin Jiang
Institute for Environmental and Climate Research, Jinan University,
Guangzhou 511443, China
Guangdong–Hong Kong–Macau Joint Laboratory of Collaborative
Innovation for Environmental Quality, Guangzhou 511443, China
Zhanyi Zhang
Institute for Environmental and Climate Research, Jinan University,
Guangzhou 511443, China
Guangdong–Hong Kong–Macau Joint Laboratory of Collaborative
Innovation for Environmental Quality, Guangzhou 511443, China
Min Shao
CORRESPONDING AUTHOR
Institute for Environmental and Climate Research, Jinan University,
Guangzhou 511443, China
Guangdong–Hong Kong–Macau Joint Laboratory of Collaborative
Innovation for Environmental Quality, Guangzhou 511443, China
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Cited
99 citations as recorded by crossref.
- A new parameterization of photolysis rates for oxygenated volatile organic compounds (OVOCs) Y. Peng et al.
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- Variations and sources of volatile organic compounds (VOCs) in urban region: insights from measurements on a tall tower X. Li et al.
- Comprehensive observations of carbonyls of Mt. Hua in Central China: Vertical distribution and effects on ozone formation Y. Zhang et al.
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- Volatile organic compounds in wintertime North China Plain: Insights from measurements of proton transfer reaction time-of-flight mass spectrometer (PTR-ToF-MS) X. He et al.
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- Online measurements of cycloalkanes based on NO+ chemical ionization in proton transfer reaction time-of-flight mass spectrometry (PTR-ToF-MS) Y. Chen et al.
- Pioneering observation of atmospheric volatile organic compounds in Hangzhou in eastern China and implications for upcoming 2022 Asian Games B. Li et al.
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- Comparative Analysis of Secondary Organic Aerosol Formation during PM2.5 Pollution and Complex Pollution of PM2.5 and O3 in Chengdu, China T. Song et al.
- Photochemical Initial Concentrations of Vocs: New Insights on Nmhcs and Pilot Study on Carbonyls B. Li et al.
- Differences in the key volatile organic compound species between their emitted and ambient concentrations in ozone formation X. Zheng & S. Xie
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- Measurement report: Vertical and temporal variability in the near-surface ozone production rate and sensitivity in an urban area in the Pearl River Delta region, China J. Zhou et al.
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- Vehicular VOC speciation dynamics under China's progressive emission standards: Mechanistic drivers from real-time monitoring A. Wang et al.
- Light oxygenated volatile organic compound concentrations in an Eastern Mediterranean urban atmosphere rivalling those in megacities A. Borbon et al.
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- Assessment of long tubing in measuring atmospheric trace gases: applications on tall towers X. Li et al.
- Impact of improved representation of volatile organic compound emissions and production of NOx reservoirs on modeled urban ozone production K. Travis et al.
- Characteristics of VOC Composition at Urban and Suburban Sites of New Delhi, India in Winter N. Tripathi et al.
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- Investigation of Summertime Ozone Formation and Sources of Volatile Organic Compounds in the Suburb Area of Hefei: A Case Study of 2020 H. Yu et al.
- The important contribution of secondary formation and biomass burning to oxidized organic nitrogen (OON) in a polluted urban area: insights from in situ measurements of a chemical ionization mass spectrometer (CIMS) Y. Cai et al.
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99 citations as recorded by crossref.
- A new parameterization of photolysis rates for oxygenated volatile organic compounds (OVOCs) Y. Peng et al.
- A comprehensive review on anthropogenic volatile organic compounds (VOCs) emission estimates in China: Comparison and outlook B. Li et al.
- Characteristics and formation mechanisms of atmospheric carbonyls in an oilfield region of northern China T. Chen et al.
- Thin organic films unexpectedly enhance alcohol uptake on soot analogs: critical implications for aerosol aging X. Kong et al.
- Ozone dry deposition and chemical removal in the urban environment of Beijing: I. Chemical and meteorological controlling parameters D. Choi et al.
- Tracing the Formation of Secondary Aerosols Influenced by Solar Radiation and Relative Humidity in Suburban Environment Y. Wu et al.
- Impact of formaldehyde on ozone formation in Central China: Important role of biogenic emission in forest region W. Dai et al.
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- Photochemical impacts of atmospheric carbonyl compounds on ozone formation and radical chemistry in urban Shanghai Y. Chen et al.
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- Aircraft-based observation of volatile organic compounds (VOCs) over the North China Plain Y. Huangfu et al.
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- Variations and sources of volatile organic compounds (VOCs) in urban region: insights from measurements on a tall tower X. Li et al.
- Comprehensive observations of carbonyls of Mt. Hua in Central China: Vertical distribution and effects on ozone formation Y. Zhang et al.
- Tower-based measurements of NMHCs and OVOCs in the Pearl River Delta: Vertical distribution, source analysis and chemical reactivity Z. Mo et al.
- Volatile organic compounds in wintertime North China Plain: Insights from measurements of proton transfer reaction time-of-flight mass spectrometer (PTR-ToF-MS) X. He et al.
- Characteristics of Volatile Organic Compounds in Megacity Shenzhen, China: Seasonal Variation, Temperature Dependence, and Source Apportionment Y. Song et al.
- Online measurements of cycloalkanes based on NO+ chemical ionization in proton transfer reaction time-of-flight mass spectrometry (PTR-ToF-MS) Y. Chen et al.
- Pioneering observation of atmospheric volatile organic compounds in Hangzhou in eastern China and implications for upcoming 2022 Asian Games B. Li et al.
- Photochemical Initial Concentrations of Vocs: New Insights on Nmhcs and Pilot Study on Carbonyls B. Li et al.
- Comparative Analysis of Secondary Organic Aerosol Formation during PM2.5 Pollution and Complex Pollution of PM2.5 and O3 in Chengdu, China T. Song et al.
- Photochemical Initial Concentrations of Vocs: New Insights on Nmhcs and Pilot Study on Carbonyls B. Li et al.
- Differences in the key volatile organic compound species between their emitted and ambient concentrations in ozone formation X. Zheng & S. Xie
- Molecular and seasonal characteristics of organic vapors in urban Beijing: insights from Vocus-PTR measurements Z. An et al.
- Sources, concentrations, and seasonal variations of VOC and aerosol particles in downtown Munich in 2023/2024 Y. Li et al.
- Real-world VOCs from ethanol gasoline vehicles: Speciation, ozone formation potential, and inter-city differences Z. Zhang et al.
- Pollution characteristics, source appointment and environmental effect of oxygenated volatile organic compounds in Guangdong-Hong Kong-Macao Greater Bay Area: Implication for air quality management G. Liu et al.
- A large role of missing volatile organic compound reactivity from anthropogenic emissions in ozone pollution regulation W. Wang et al.
- Sources of atmospheric oxygenated volatile organic compounds in different air masses in Shenzhen, China Z. Li et al.
- Unexpected High Contribution of Residential Biomass Burning to Non‐Methane Organic Gases (NMOGs) in the Yangtze River Delta Region of China Y. Gao et al.
- Ozone pollution in the plate and logistics capital of China: Insight into the formation, source apportionment, and regional transport G. Wang et al.
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- Measurements of higher alkanes using NO+ chemical ionization in PTR-ToF-MS: important contributions of higher alkanes to secondary organic aerosols in China C. Wang et al.
- Vertical changes in volatile organic compounds (VOCs) and impacts on photochemical ozone formation X. Li et al.
- Emission characteristic of OVOCs, I/SVOCs, OC and EC from wood combustion at different moisture contents Y. Peng et al.
- Measurement report: Vertical and temporal variability in the near-surface ozone production rate and sensitivity in an urban area in the Pearl River Delta region, China J. Zhou et al.
- Observation-based analysis of ozone production sensitivity for two persistent ozone episodes in Guangdong, China K. Song et al.
- Vehicular VOC speciation dynamics under China's progressive emission standards: Mechanistic drivers from real-time monitoring A. Wang et al.
- Light oxygenated volatile organic compound concentrations in an Eastern Mediterranean urban atmosphere rivalling those in megacities A. Borbon et al.
- Crucial VOCs influences on ozone formation in North China: A spatial perspective D. Liu et al.
- Environmental Benefits of Substituting Coatings from Solvent-Borne to Water-Borne Coatings Revealed by Total OH Reactivity Measurements J. Qi et al.
- OVOCs drive radical cycling and ozone formation in background air E. Xiong et al.
- Multisize particulate matter and volatile organic compounds in arid and semiarid areas of Northwest China X. Zhou et al.
- Assessment of long tubing in measuring atmospheric trace gases: applications on tall towers X. Li et al.
- Impact of improved representation of volatile organic compound emissions and production of NOx reservoirs on modeled urban ozone production K. Travis et al.
- Characteristics of VOC Composition at Urban and Suburban Sites of New Delhi, India in Winter N. Tripathi et al.
- The role of atmospheric volatile organic compounds (VOCs) in ozone formation around China's largest plywood manufacturer N. Li et al.
- Composition and Evolution of Reactive Organic Carbon in Urban Air C. Ye et al.
- Inter-comparisons of VOC oxidation mechanisms based on box model: A focus on OH reactivity X. Yang et al.
- Integrated evaluation of VOCs pollution from a refuse transfer station: From source emissions to ambient exposure H. Gong et al.
- Recent Progress in Atmospheric Chemistry Research in China: Establishing a Theoretical Framework for the “Air Pollution Complex” T. Zhu et al.
- Emission Characteristics and Formation Mechanism of Carbonyl Compounds from Residential Solid Fuel Combustion Based on Real-World Measurements and Tube-Furnace Experiments Z. Liu et al.
- Composition and reactivity of volatile organic compounds in the South Coast Air Basin and San Joaquin Valley of California S. Liu et al.
- Characterization, sources and reactivity of carbonyl volatile organic compounds in North China: Based on long-term observations Z. Chen et al.
- Investigation of Summertime Ozone Formation and Sources of Volatile Organic Compounds in the Suburb Area of Hefei: A Case Study of 2020 H. Yu et al.
- The important contribution of secondary formation and biomass burning to oxidized organic nitrogen (OON) in a polluted urban area: insights from in situ measurements of a chemical ionization mass spectrometer (CIMS) Y. Cai et al.
- Chemical characterization of oxygenated organic compounds in the gas phase and particle phase using iodide CIMS with FIGAERO in urban air C. Ye et al.
- Real‐Time Characterization of Aerosol Compositions, Sources, and Aging Processes in Guangzhou During PRIDE‐GBA 2018 Campaign W. Chen et al.
- NOx regime-dependent effects of biogenic emissions on toluene degradation and product formation S. Han et al.
- Spatial heterogeneity and sources of atmospheric carbonyls during ozone episodes in the Pearl River Delta L. Wei et al.
- Formation and impacts of nitryl chloride in Pearl River Delta H. Wang et al.
- Characterization of organic vapors by a Vocus proton-transfer-reaction mass spectrometry at a mountain site in southeastern China Y. Zhang et al.
- Elucidating key factors in regulating budgets of ozone and its precursors in atmospheric boundary layer X. Song et al.
- Volatile organic compounds at a highland forest site in the southeast of the Tibetan Plateau: Source apportionment and reactivity contributions S. Guo et al.
- Uncovering the degradation kinetics and mechanisms of difluoroacetone in the atmosphere and at the air–water interface by the OH radical and Cl atom: a theoretical investigation X. Song et al.
- Ground-based formaldehyde across the Pearl River Delta: A snapshot and meta-analysis study X. Mo et al.
- Comparison of three source apportionment methods based on observed and initial HCHO in Taiyuan, China Y. Cui et al.
- Unraveling the chemical complexity and secondary VOCs formation in indoor combustion: candles, incense, and cooking Q. Deng et al.
- Measuring and modeling investigation of the net photochemical ozone production rate via an improved dual-channel reaction chamber technique Y. Hao et al.
- On-Site Detection of Volatile Organic Compounds (VOCs) R. Epping & M. Koch
- Photolysis frequency of nitrophenols derived from ambient measurements Y. Peng et al.
- Low-NO-like Oxidation Pathway Makes a Significant Contribution to Secondary Organic Aerosol in Polluted Urban Air C. Ye et al.
- Environmental Applications of Mass Spectrometry for Emerging Contaminants A. Meher & A. Zarouri
- Impact of primary oxygenated volatile organic compounds on ozone formation in the Yangtze River Delta region X. Li et al.
- Fate of Oxygenated Volatile Organic Compounds in the Yangtze River Delta Region: Source Contributions and Impacts on the Atmospheric Oxidation Capacity J. Li et al.
- Emissions of carboxylic acids, hydrogen cyanide (HCN) and isocyanic acid (HNCO) from vehicle exhaust T. Li et al.
- Wintertime fine aerosol particles composition and its evolution in two megacities of southern and northern China Y. Cheng et al.
- Oxygenated volatile organic compounds (VOCs) as significant but varied contributors to VOC emissions from vehicles S. Wang et al.
- Catalytic ozonation of VOCs at low temperature: A comprehensive review B. Liu et al.
- Elucidating the mechanisms of rapid O3 increase in North China Plain during COVID-19 lockdown period R. Li et al.
- Oxygenated volatile organic compounds in Beijing: Characteristics, chemical reactivity, and source identification G. Zhang et al.
- Significant contribution of carbonyls to atmospheric oxidation capacity (AOC) during the winter haze pollution over North China Plain X. Yang et al.
- Study the effect of photochemical processes on VOC source apportionment at a site in the Pearl River Estuary of southern China G. Fang et al.
- Comprehensive Evaluation of Simulation Performance of Nonmethane Hydrocarbons (NMHCs) and Oxygenated VOCs in China Using a Three-Dimensional Numerical Model Y. Zhang et al.
- Towards a high-quality in situ observation network for oxygenated volatile organic compounds (OVOCs) in Europe: transferring metrological traceability to the field M. Iturrate-Garcia et al.
- Measurement report: Enhanced photochemical formation of formic and isocyanic acids in urban regions aloft – insights from tower-based online gradient measurements Q. Yang et al.
- The critical role of oxygenated volatile organic compounds (OVOCs) in shaping photochemical O3 chemistry and control strategy in a subtropical coastal environment L. Hui et al.
- Total OH Reactivity Measurements in a Suburban Site of Shanghai G. Yang et al.
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Saved (final revised paper)
Latest update: 16 May 2026
Short summary
Based on measurements from an online mass spectrometer, we quantify volatile organic compound (VOC) concentrations from numerous ions of the mass spectrometer, using information from laboratory-obtained calibration results. We find that most VOC concentrations are from oxygenated VOCs (OVOCs). We further show that these OVOCs also contribute significantly to OH reactivity. Our results suggest the important role of OVOCs in VOC emissions and chemistry in urban air.
Based on measurements from an online mass spectrometer, we quantify volatile organic compound...
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