Articles | Volume 20, issue 22
https://doi.org/10.5194/acp-20-14393-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-20-14393-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Direct contribution of ammonia to α-pinene secondary organic aerosol formation
Liqing Hao
CORRESPONDING AUTHOR
Department of Applied Physics, University of Eastern Finland, Kuopio,
Finland
Eetu Kari
Department of Applied Physics, University of Eastern Finland, Kuopio,
Finland
now at: Neste Oyj, Porvoo, Finland
Ari Leskinen
Department of Applied Physics, University of Eastern Finland, Kuopio,
Finland
Finnish Meteorological Institute, Kuopio, Finland
Douglas R. Worsnop
Department of Applied Physics, University of Eastern Finland, Kuopio,
Finland
Aerodyne Research Inc., Billerica, MA 08121-3976, USA
Annele Virtanen
CORRESPONDING AUTHOR
Department of Applied Physics, University of Eastern Finland, Kuopio,
Finland
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Cited
25 citations as recorded by crossref.
- Insights into national distribution of NH3 concentrations in Republic of Korea: findings from passive sampler observations and implications for sources and management G. Yu et al.
- High-resolution inventories for Reactive Nitrogen Emissions from China’s livestock during 2005–2022 Y. Chen et al.
- Enhancement of Secondary Organic Aerosol formation from isoprene photooxidation by ammonia X. Xu et al.
- Ammonia emission from real-world in-use vehicle fleets in a megacity in China - based on tunnel measurement J. Guo et al.
- Anthropogenic–Biogenic Interactions at Night: Enhanced Formation of Secondary Aerosols and Particulate Nitrogen- and Sulfur-Containing Organics from β-Pinene Oxidation L. Xu et al.
- Secondary organic aerosol formation from cis-3-hexen-1-ol/NOx photo-oxidation: The roles of cis-3-hexen-1-ol concentration, illumination intensity, NOx and NH3 D. Shi et al.
- Nanocluster aerosol formation via ozone chemistry on worn clothing: Influence of environmental parameters S. Yang & D. Licina
- Contrasting molecular characteristics and formation mechanisms of biogenic and anthropogenic secondary organic aerosols at the summit and foot of Mt. Huang, East China Y. Wang et al.
- Nanocluster Aerosols from Ozone–Human Chemistry Are Dominated by Squalene–Ozone Reactions S. Yang & D. Licina
- Significant secondary formation of nitrogenous organic aerosols in an urban atmosphere revealed by bihourly measurements of bulk organic nitrogen and comprehensive molecular markers X. Yu et al.
- Measurement report: Effects of anthropogenic emissions and environmental factors on the formation of biogenic secondary organic aerosol (BSOA) in a coastal city of southeastern China Y. Hong et al.
- Enhanced organic aerosol formation induced by inorganic aerosol formed in laboratory photochemical experiments A. Ali et al.
- Poly(aniline)-based ammonia sensors: Understanding the role of polyurethane on structural/morphological properties and sensing performances E. da Silva et al.
- A novel reaction between ammonia and Criegee intermediates can form amines and suppress oligomers from isoprene X. Li et al.
- Investigating the role of ammonia in enhancing secondary organic aerosol formation from the co-photooxidation of anthropogenic and biogenic VOCs Y. Yan et al.
- The First Global Map of Atmospheric Ammonia (NH3) as Observed by the HIRAS/FY-3D Satellite M. Zhou et al.
- Online characterization of primary and secondary emissions of particulate matter and acidic molecules from a modern fleet of city buses L. Zhou et al.
- Influence of Ammonia and Relative Humidity on the Formation and Composition of Secondary Brown Carbon from Oxidation of 1-Methylnaphthalene and Longifolene Y. Cui et al.
- Characterization of secondary organic aerosol (SOA) formation and toxicity from α-pinene photo-oxidation under effects of nitrogen oxides (NOx) and ammonia (NH3) K. Lui et al.
- Source variability and atmospheric processing of NHx using δ15N: Linkages with WSOC fluorescence indices C. Shaw et al.
- Effects of NH3 on secondary aerosol formation from toluene/NOx photo-oxidation in different O3 formation regimes Z. Bao et al.
- SO2 and NH3 emissions enhance organosulfur compounds and fine particle formation from the photooxidation of a typical aromatic hydrocarbon Z. Yang et al.
- Investigation of Summertime Ozone Formation and Sources of Volatile Organic Compounds in the Suburb Area of Hefei: A Case Study of 2020 H. Yu et al.
- Ozone Initiates Human-Derived Emission of Nanocluster Aerosols S. Yang et al.
- Effects of NOx and NH3 on the secondary organic aerosol formation from α-pinene photooxidation Y. Zhao et al.
25 citations as recorded by crossref.
- Insights into national distribution of NH3 concentrations in Republic of Korea: findings from passive sampler observations and implications for sources and management G. Yu et al.
- High-resolution inventories for Reactive Nitrogen Emissions from China’s livestock during 2005–2022 Y. Chen et al.
- Enhancement of Secondary Organic Aerosol formation from isoprene photooxidation by ammonia X. Xu et al.
- Ammonia emission from real-world in-use vehicle fleets in a megacity in China - based on tunnel measurement J. Guo et al.
- Anthropogenic–Biogenic Interactions at Night: Enhanced Formation of Secondary Aerosols and Particulate Nitrogen- and Sulfur-Containing Organics from β-Pinene Oxidation L. Xu et al.
- Secondary organic aerosol formation from cis-3-hexen-1-ol/NOx photo-oxidation: The roles of cis-3-hexen-1-ol concentration, illumination intensity, NOx and NH3 D. Shi et al.
- Nanocluster aerosol formation via ozone chemistry on worn clothing: Influence of environmental parameters S. Yang & D. Licina
- Contrasting molecular characteristics and formation mechanisms of biogenic and anthropogenic secondary organic aerosols at the summit and foot of Mt. Huang, East China Y. Wang et al.
- Nanocluster Aerosols from Ozone–Human Chemistry Are Dominated by Squalene–Ozone Reactions S. Yang & D. Licina
- Significant secondary formation of nitrogenous organic aerosols in an urban atmosphere revealed by bihourly measurements of bulk organic nitrogen and comprehensive molecular markers X. Yu et al.
- Measurement report: Effects of anthropogenic emissions and environmental factors on the formation of biogenic secondary organic aerosol (BSOA) in a coastal city of southeastern China Y. Hong et al.
- Enhanced organic aerosol formation induced by inorganic aerosol formed in laboratory photochemical experiments A. Ali et al.
- Poly(aniline)-based ammonia sensors: Understanding the role of polyurethane on structural/morphological properties and sensing performances E. da Silva et al.
- A novel reaction between ammonia and Criegee intermediates can form amines and suppress oligomers from isoprene X. Li et al.
- Investigating the role of ammonia in enhancing secondary organic aerosol formation from the co-photooxidation of anthropogenic and biogenic VOCs Y. Yan et al.
- The First Global Map of Atmospheric Ammonia (NH3) as Observed by the HIRAS/FY-3D Satellite M. Zhou et al.
- Online characterization of primary and secondary emissions of particulate matter and acidic molecules from a modern fleet of city buses L. Zhou et al.
- Influence of Ammonia and Relative Humidity on the Formation and Composition of Secondary Brown Carbon from Oxidation of 1-Methylnaphthalene and Longifolene Y. Cui et al.
- Characterization of secondary organic aerosol (SOA) formation and toxicity from α-pinene photo-oxidation under effects of nitrogen oxides (NOx) and ammonia (NH3) K. Lui et al.
- Source variability and atmospheric processing of NHx using δ15N: Linkages with WSOC fluorescence indices C. Shaw et al.
- Effects of NH3 on secondary aerosol formation from toluene/NOx photo-oxidation in different O3 formation regimes Z. Bao et al.
- SO2 and NH3 emissions enhance organosulfur compounds and fine particle formation from the photooxidation of a typical aromatic hydrocarbon Z. Yang et al.
- Investigation of Summertime Ozone Formation and Sources of Volatile Organic Compounds in the Suburb Area of Hefei: A Case Study of 2020 H. Yu et al.
- Ozone Initiates Human-Derived Emission of Nanocluster Aerosols S. Yang et al.
- Effects of NOx and NH3 on the secondary organic aerosol formation from α-pinene photooxidation Y. Zhao et al.
Saved (final revised paper)
Latest update: 18 May 2026
Short summary
Our work presents the observational results of secondary organic aerosol (SOA) formation in the presence of ammonia. The particle-phase ammonium was continuously produced even after SOA formation had ceased. The gas-phase organic acids were observed to contribute to the formed particle-phase ammonium salts. This study suggests that the presence of ammonia may change the mass and chemical composition of large-size SOA particles and can potentially alter the aerosol impact on climate change.
Our work presents the observational results of secondary organic aerosol (SOA) formation in the...
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