Articles | Volume 20, issue 2
https://doi.org/10.5194/acp-20-1183-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-20-1183-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Peroxy radical chemistry and the volatility basis set
Meredith Schervish
Center for Atmospheric Particle Studies, Carnegie Mellon University, 5000 Forbes Avenue, Pittsburgh, PA 15213, USA
Center for Atmospheric Particle Studies, Carnegie Mellon University, 5000 Forbes Avenue, Pittsburgh, PA 15213, USA
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Cited
81 citations as recorded by crossref.
- Modeling Volatility-Based Aerosol Phase State Predictions in the Amazon Rainforest Q. Rasool et al. 10.1021/acsearthspacechem.1c00255
- Production of Peroxy Radicals from the Photochemical Reaction of Fatty Acids at the Air–Water Interface N. Hayeck et al. 10.1021/acsearthspacechem.0c00048
- Probing key organic substances driving new particle growth initiated by iodine nucleation in coastal atmosphere Y. Wan et al. 10.5194/acp-20-9821-2020
- Seasonal variation in oxygenated organic molecules in urban Beijing and their contribution to secondary organic aerosol Y. Guo et al. 10.5194/acp-22-10077-2022
- Suppression of anthropogenic secondary organic aerosol formation by isoprene K. Li et al. 10.1038/s41612-022-00233-x
- Direct Measurements of Isoprene Autoxidation: Pinpointing Atmospheric Oxidation in Tropical Forests D. J. Medeiros et al. 10.1021/jacsau.1c00525
- Photo-oxidation of Aromatic Hydrocarbons Produces Low-Volatility Organic Compounds M. Wang et al. 10.1021/acs.est.0c02100
- Shelf-Life Prediction of Peanut Oil (Arachis hypogaea L.) Using an Accelerated Shelf-Life Testing (ASLT) Method in the Polypropylene Packaging S. Nurhasanah et al. 10.1088/1755-1315/1024/1/012056
- Oxygenated organic molecules produced by low-NOx photooxidation of aromatic compounds: contributions to secondary organic aerosol and steric hindrance X. Cheng et al. 10.5194/acp-24-2099-2024
- Formation Process of Particles and Cloud Condensation Nuclei Over the Amazon Rainforest: The Role of Local and Remote New‐Particle Formation B. Zhao et al. 10.1029/2022GL100940
- Molecular Composition of Anthropogenic Oxygenated Organic Molecules and Their Contribution to Organic Aerosol in a Coastal City C. Yang et al. 10.1021/acs.est.3c03244
- The INNpinJeR: a new wall-free reactor for studying gas-phase reactions W. Scholz et al. 10.1039/D1EA00072A
- Massive Assessment of the Geometries of Atmospheric Molecular Clusters A. Jensen & J. Elm 10.1021/acs.jctc.4c01046
- Molecular insights into new particle formation in Barcelona, Spain J. Brean et al. 10.5194/acp-20-10029-2020
- Dimeric product formation in the self-reaction of small peroxy radicals using synchrotron radiation vacuum ultraviolet photoionization mass spectrometry L. Liu et al. 10.1016/j.chemosphere.2024.142846
- Dynamic Oxidative Potential of Organic Aerosol from Heated Cooking Oil S. Wang et al. 10.1021/acsearthspacechem.1c00038
- Chamber investigation of the formation and transformation of secondary organic aerosol in mixtures of biogenic and anthropogenic volatile organic compounds A. Voliotis et al. 10.5194/acp-22-14147-2022
- Quantum chemical modeling of organic enhanced atmospheric nucleation: A critical review J. Elm et al. 10.1002/wcms.1662
- Isoprene nitrates drive new particle formation in Amazon’s upper troposphere J. Curtius et al. 10.1038/s41586-024-08192-4
- Exploring the composition and volatility of secondary organic aerosols in mixed anthropogenic and biogenic precursor systems A. Voliotis et al. 10.5194/acp-21-14251-2021
- The Synergistic Role of Sulfuric Acid, Bases, and Oxidized Organics Governing New‐Particle Formation in Beijing C. Yan et al. 10.1029/2020GL091944
- Volatility of Secondary Organic Aerosol from β-Caryophyllene Ozonolysis over a Wide Tropospheric Temperature Range L. Gao et al. 10.1021/acs.est.3c01151
- Atmospheric new particle formation from the CERN CLOUD experiment J. Kirkby et al. 10.1038/s41561-023-01305-0
- The importance of sesquiterpene oxidation products for secondary organic aerosol formation in a springtime hemiboreal forest L. Barreira et al. 10.5194/acp-21-11781-2021
- Nocturnal atmospheric synergistic oxidation reduces the formation of low-volatility organic compounds from biogenic emissions H. Zang et al. 10.5194/acp-24-11701-2024
- Effects of Nitrogen Oxides on the Production of Reactive Oxygen Species and Environmentally Persistent Free Radicals from α-Pinene and Naphthalene Secondary Organic Aerosols K. Edwards et al. 10.1021/acs.jpca.2c05532
- Interactions of peroxy radicals from monoterpene and isoprene oxidation simulated in the radical volatility basis set M. Schervish et al. 10.1039/D4EA00056K
- Measurement report: Molecular composition and volatility of gaseous organic compounds in a boreal forest – from volatile organic compounds to highly oxygenated organic molecules W. Huang et al. 10.5194/acp-21-8961-2021
- Nontrivial Impact of Relative Humidity on Organic New Particle Formation from Ozonolysis of cis-3-Hexenyl Acetate A. Flueckiger et al. 10.3390/air1040017
- Organic aerosol volatility and viscosity in the North China Plain: contrast between summer and winter W. Xu et al. 10.5194/acp-21-5463-2021
- HO2 + NO2: Kinetics, Thermochemistry, and Evidence for a Bimolecular Product Channel K. McKee et al. 10.1021/acs.jpca.2c04601
- Unraveling the atmospheric oxidation mechanism and kinetics of naphthalene: Insights from theoretical exploration X. Wu et al. 10.1016/j.chemosphere.2024.141356
- CRI-HOM: A novel chemical mechanism for simulating highly oxygenated organic molecules (HOMs) in global chemistry–aerosol–climate models J. Weber et al. 10.5194/acp-20-10889-2020
- Impact of Urban Pollution on Organic-Mediated New-Particle Formation and Particle Number Concentration in the Amazon Rainforest B. Zhao et al. 10.1021/acs.est.0c07465
- Nitrate Radicals Suppress Biogenic New Particle Formation from Monoterpene Oxidation D. Li et al. 10.1021/acs.est.3c07958
- Rapid Nucleation and Growth of Indoor Atmospheric Nanocluster Aerosol during the Use of Scented Volatile Chemical Products in Residential Buildings S. Patra et al. 10.1021/acsestair.4c00118
- The influence of the addition of isoprene on the volatility of particles formed from the photo-oxidation of anthropogenic–biogenic mixtures A. Voliotis et al. 10.5194/acp-22-13677-2022
- Linking gas, particulate, and toxic endpoints to air emissions in the Community Regional Atmospheric Chemistry Multiphase Mechanism (CRACMM) H. Pye et al. 10.5194/acp-23-5043-2023
- Mass spectrometry-based Aerosolomics: a new approach to resolve sources, composition, and partitioning of secondary organic aerosol M. Thoma et al. 10.5194/amt-15-7137-2022
- New Particle Formation Promoted by OH Reactions during α-Pinene Ozonolysis S. Inomata 10.1021/acsearthspacechem.1c00142
- Variability in Aromatic Aerosol Yields under Very Low NOxConditions at Different HO2/RO2Regimes W. Peng et al. 10.1021/acs.est.1c04392
- Identification of highly oxygenated organic molecules and their role in aerosol formation in the reaction of limonene with nitrate radical Y. Guo et al. 10.5194/acp-22-11323-2022
- Role of sesquiterpenes in biogenic new particle formation L. Dada et al. 10.1126/sciadv.adi5297
- Fragmentation inside proton-transfer-reaction-based mass spectrometers limits the detection of ROOR and ROOH peroxides H. Li et al. 10.5194/amt-15-1811-2022
- Secondary organic aerosol formation from camphene oxidation: measurements and modeling Q. Li et al. 10.5194/acp-22-3131-2022
- Unambiguous identification of N-containing oxygenated organic molecules using a chemical-ionization Orbitrap (CI-Orbitrap) in an eastern Chinese megacity Y. Lu et al. 10.5194/acp-23-3233-2023
- The search for sparse data in molecular datasets: Application of active learning to identify extremely low volatile organic compounds V. Besel et al. 10.1016/j.jaerosci.2024.106375
- Hygroscopic growth and CCN activity of secondary organic aerosol produced from dark ozonolysis of γ-terpinene H. Bouzidi et al. 10.1016/j.scitotenv.2022.153010
- Potential pre-industrial–like new particle formation induced by pure biogenic organic vapors in Finnish peatland W. Huang et al. 10.1126/sciadv.adm9191
- Chemical composition of nanoparticles from <i>α</i>-pinene nucleation and the influence of isoprene and relative humidity at low temperature L. Caudillo et al. 10.5194/acp-21-17099-2021
- Formation of secondary organic aerosol from wildfire emissions enhanced by long-time ageing Y. He et al. 10.1038/s41561-023-01355-4
- Particle Formation from Photooxidation of αpinene, Limonene, and Myrcene D. Hanson et al. 10.1021/acs.jpca.1c08427
- Molecular understanding of new-particle formation from α-pinene between −50 and +25 °C M. Simon et al. 10.5194/acp-20-9183-2020
- Linking Precursors and Volatility of Ambient Oxygenated Organic Aerosols Using Thermal Desorption Measurement and Machine Learning X. Wang et al. 10.1021/acsestair.4c00076
- Chemical composition of secondary organic aerosol particles formed from mixtures of anthropogenic and biogenic precursors Y. Shao et al. 10.5194/acp-22-9799-2022
- Modeling the Impact of the Organic Aerosol Phase State on Multiphase OH Reactive Uptake Kinetics and the Resultant Heterogeneous Oxidation Timescale of Organic Aerosol in the Amazon Rainforest Q. Rasool et al. 10.1021/acsearthspacechem.2c00366
- Fostering a Holistic Understanding of the Full Volatility Spectrum of Organic Compounds from Benzene Series Precursors through Mechanistic Modeling D. Yin et al. 10.1021/acs.est.3c07128
- Formation of Substituted Alkyls as Precursors of Peroxy Radicals with a Rapid H-Shift in the Atmosphere X. Wu et al. 10.1021/acs.jpclett.1c02503
- Limited Secondary Organic Aerosol Production from Acyclic Oxygenated Volatile Chemical Products M. Humes et al. 10.1021/acs.est.1c07354
- Intense formation of secondary ultrafine particles from Amazonian vegetation fires and their invigoration of deep clouds and precipitation M. Shrivastava et al. 10.1016/j.oneear.2024.05.015
- Global variability in atmospheric new particle formation mechanisms B. Zhao et al. 10.1038/s41586-024-07547-1
- Evaluating Indoor Air Chemical Diversity, Indoor-to-Outdoor Emissions, and Surface Reservoirs Using High-Resolution Mass Spectrometry R. Sheu et al. 10.1021/acs.est.1c01337
- Development of a multiphase chemical mechanism to improve secondary organic aerosol formation in CAABA/MECCA (version 4.7.0) F. Wieser et al. 10.5194/gmd-17-4311-2024
- Large differences of highly oxygenated organic molecules (HOMs) and low-volatile species in secondary organic aerosols (SOAs) formed from ozonolysis of β-pinene and limonene D. Liu et al. 10.5194/acp-23-8383-2023
- New particle formation induced by anthropogenic–biogenic interactions on the southeastern Tibetan Plateau S. Lai et al. 10.5194/acp-24-2535-2024
- Modeling the Formation of Organic Compounds across Full Volatility Ranges and Their Contribution to Nanoparticle Growth in a Polluted Atmosphere Z. Li et al. 10.1021/acs.est.3c06708
- Insights into the role of the H-abstraction reaction kinetics of amines in understanding their degeneration fates under atmospheric and combustion conditions Y. Shang & S. Luo 10.1039/D4CP02187H
- Secondary Organic Aerosol from OH-Initiated Oxidation of Mixtures of d-Limonene and β-Myrcene S. Liu et al. 10.1021/acs.est.4c04870
- Global modeling of aerosol nucleation with a semi-explicit chemical mechanism for highly oxygenated organic molecules (HOMs) X. Shao et al. 10.5194/acp-24-11365-2024
- OH Kinetics with a Range of Nitrogen-Containing Compounds: N-Methylformamide, t-Butylamine, and N-Methyl-propane Diamine T. Speak et al. 10.1021/acs.jpca.1c08104
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- Peroxy radical kinetics and new particle formation M. Schervish & N. Donahue 10.1039/D0EA00017E
- Future changes in isoprene-epoxydiol-derived secondary organic aerosol (IEPOX SOA) under the Shared Socioeconomic Pathways: the importance of physicochemical dependency D. Jo et al. 10.5194/acp-21-3395-2021
- High concentration of ultrafine particles in the Amazon free troposphere produced by organic new particle formation B. Zhao et al. 10.1073/pnas.2006716117
- Gas-to-Particle Partitioning of Cyclohexene- and α-Pinene-Derived Highly Oxygenated Dimers Evaluated Using COSMOtherm N. Hyttinen et al. 10.1021/acs.jpca.0c11328
- NO at low concentration can enhance the formation of highly oxygenated biogenic molecules in the atmosphere W. Nie et al. 10.1038/s41467-023-39066-4
- Chlorine-Initiated Oxidation of α-Pinene: Formation of Secondary Organic Aerosol and Highly Oxygenated Organic Molecules C. Masoud & L. Ruiz 10.1021/acsearthspacechem.1c00150
- Effect of OH scavengers on the chemical composition of α-pinene secondary organic aerosol D. Bell et al. 10.1039/D2EA00105E
- Data‐Driven Compound Identification in Atmospheric Mass Spectrometry H. Sandström et al. 10.1002/advs.202306235
- Comparison of saturation vapor pressures of <i>α</i>-pinene + O<sub>3</sub> oxidation products derived from COSMO-RS computations and thermal desorption experiments N. Hyttinen et al. 10.5194/acp-22-1195-2022
81 citations as recorded by crossref.
- Modeling Volatility-Based Aerosol Phase State Predictions in the Amazon Rainforest Q. Rasool et al. 10.1021/acsearthspacechem.1c00255
- Production of Peroxy Radicals from the Photochemical Reaction of Fatty Acids at the Air–Water Interface N. Hayeck et al. 10.1021/acsearthspacechem.0c00048
- Probing key organic substances driving new particle growth initiated by iodine nucleation in coastal atmosphere Y. Wan et al. 10.5194/acp-20-9821-2020
- Seasonal variation in oxygenated organic molecules in urban Beijing and their contribution to secondary organic aerosol Y. Guo et al. 10.5194/acp-22-10077-2022
- Suppression of anthropogenic secondary organic aerosol formation by isoprene K. Li et al. 10.1038/s41612-022-00233-x
- Direct Measurements of Isoprene Autoxidation: Pinpointing Atmospheric Oxidation in Tropical Forests D. J. Medeiros et al. 10.1021/jacsau.1c00525
- Photo-oxidation of Aromatic Hydrocarbons Produces Low-Volatility Organic Compounds M. Wang et al. 10.1021/acs.est.0c02100
- Shelf-Life Prediction of Peanut Oil (Arachis hypogaea L.) Using an Accelerated Shelf-Life Testing (ASLT) Method in the Polypropylene Packaging S. Nurhasanah et al. 10.1088/1755-1315/1024/1/012056
- Oxygenated organic molecules produced by low-NOx photooxidation of aromatic compounds: contributions to secondary organic aerosol and steric hindrance X. Cheng et al. 10.5194/acp-24-2099-2024
- Formation Process of Particles and Cloud Condensation Nuclei Over the Amazon Rainforest: The Role of Local and Remote New‐Particle Formation B. Zhao et al. 10.1029/2022GL100940
- Molecular Composition of Anthropogenic Oxygenated Organic Molecules and Their Contribution to Organic Aerosol in a Coastal City C. Yang et al. 10.1021/acs.est.3c03244
- The INNpinJeR: a new wall-free reactor for studying gas-phase reactions W. Scholz et al. 10.1039/D1EA00072A
- Massive Assessment of the Geometries of Atmospheric Molecular Clusters A. Jensen & J. Elm 10.1021/acs.jctc.4c01046
- Molecular insights into new particle formation in Barcelona, Spain J. Brean et al. 10.5194/acp-20-10029-2020
- Dimeric product formation in the self-reaction of small peroxy radicals using synchrotron radiation vacuum ultraviolet photoionization mass spectrometry L. Liu et al. 10.1016/j.chemosphere.2024.142846
- Dynamic Oxidative Potential of Organic Aerosol from Heated Cooking Oil S. Wang et al. 10.1021/acsearthspacechem.1c00038
- Chamber investigation of the formation and transformation of secondary organic aerosol in mixtures of biogenic and anthropogenic volatile organic compounds A. Voliotis et al. 10.5194/acp-22-14147-2022
- Quantum chemical modeling of organic enhanced atmospheric nucleation: A critical review J. Elm et al. 10.1002/wcms.1662
- Isoprene nitrates drive new particle formation in Amazon’s upper troposphere J. Curtius et al. 10.1038/s41586-024-08192-4
- Exploring the composition and volatility of secondary organic aerosols in mixed anthropogenic and biogenic precursor systems A. Voliotis et al. 10.5194/acp-21-14251-2021
- The Synergistic Role of Sulfuric Acid, Bases, and Oxidized Organics Governing New‐Particle Formation in Beijing C. Yan et al. 10.1029/2020GL091944
- Volatility of Secondary Organic Aerosol from β-Caryophyllene Ozonolysis over a Wide Tropospheric Temperature Range L. Gao et al. 10.1021/acs.est.3c01151
- Atmospheric new particle formation from the CERN CLOUD experiment J. Kirkby et al. 10.1038/s41561-023-01305-0
- The importance of sesquiterpene oxidation products for secondary organic aerosol formation in a springtime hemiboreal forest L. Barreira et al. 10.5194/acp-21-11781-2021
- Nocturnal atmospheric synergistic oxidation reduces the formation of low-volatility organic compounds from biogenic emissions H. Zang et al. 10.5194/acp-24-11701-2024
- Effects of Nitrogen Oxides on the Production of Reactive Oxygen Species and Environmentally Persistent Free Radicals from α-Pinene and Naphthalene Secondary Organic Aerosols K. Edwards et al. 10.1021/acs.jpca.2c05532
- Interactions of peroxy radicals from monoterpene and isoprene oxidation simulated in the radical volatility basis set M. Schervish et al. 10.1039/D4EA00056K
- Measurement report: Molecular composition and volatility of gaseous organic compounds in a boreal forest – from volatile organic compounds to highly oxygenated organic molecules W. Huang et al. 10.5194/acp-21-8961-2021
- Nontrivial Impact of Relative Humidity on Organic New Particle Formation from Ozonolysis of cis-3-Hexenyl Acetate A. Flueckiger et al. 10.3390/air1040017
- Organic aerosol volatility and viscosity in the North China Plain: contrast between summer and winter W. Xu et al. 10.5194/acp-21-5463-2021
- HO2 + NO2: Kinetics, Thermochemistry, and Evidence for a Bimolecular Product Channel K. McKee et al. 10.1021/acs.jpca.2c04601
- Unraveling the atmospheric oxidation mechanism and kinetics of naphthalene: Insights from theoretical exploration X. Wu et al. 10.1016/j.chemosphere.2024.141356
- CRI-HOM: A novel chemical mechanism for simulating highly oxygenated organic molecules (HOMs) in global chemistry–aerosol–climate models J. Weber et al. 10.5194/acp-20-10889-2020
- Impact of Urban Pollution on Organic-Mediated New-Particle Formation and Particle Number Concentration in the Amazon Rainforest B. Zhao et al. 10.1021/acs.est.0c07465
- Nitrate Radicals Suppress Biogenic New Particle Formation from Monoterpene Oxidation D. Li et al. 10.1021/acs.est.3c07958
- Rapid Nucleation and Growth of Indoor Atmospheric Nanocluster Aerosol during the Use of Scented Volatile Chemical Products in Residential Buildings S. Patra et al. 10.1021/acsestair.4c00118
- The influence of the addition of isoprene on the volatility of particles formed from the photo-oxidation of anthropogenic–biogenic mixtures A. Voliotis et al. 10.5194/acp-22-13677-2022
- Linking gas, particulate, and toxic endpoints to air emissions in the Community Regional Atmospheric Chemistry Multiphase Mechanism (CRACMM) H. Pye et al. 10.5194/acp-23-5043-2023
- Mass spectrometry-based Aerosolomics: a new approach to resolve sources, composition, and partitioning of secondary organic aerosol M. Thoma et al. 10.5194/amt-15-7137-2022
- New Particle Formation Promoted by OH Reactions during α-Pinene Ozonolysis S. Inomata 10.1021/acsearthspacechem.1c00142
- Variability in Aromatic Aerosol Yields under Very Low NOxConditions at Different HO2/RO2Regimes W. Peng et al. 10.1021/acs.est.1c04392
- Identification of highly oxygenated organic molecules and their role in aerosol formation in the reaction of limonene with nitrate radical Y. Guo et al. 10.5194/acp-22-11323-2022
- Role of sesquiterpenes in biogenic new particle formation L. Dada et al. 10.1126/sciadv.adi5297
- Fragmentation inside proton-transfer-reaction-based mass spectrometers limits the detection of ROOR and ROOH peroxides H. Li et al. 10.5194/amt-15-1811-2022
- Secondary organic aerosol formation from camphene oxidation: measurements and modeling Q. Li et al. 10.5194/acp-22-3131-2022
- Unambiguous identification of N-containing oxygenated organic molecules using a chemical-ionization Orbitrap (CI-Orbitrap) in an eastern Chinese megacity Y. Lu et al. 10.5194/acp-23-3233-2023
- The search for sparse data in molecular datasets: Application of active learning to identify extremely low volatile organic compounds V. Besel et al. 10.1016/j.jaerosci.2024.106375
- Hygroscopic growth and CCN activity of secondary organic aerosol produced from dark ozonolysis of γ-terpinene H. Bouzidi et al. 10.1016/j.scitotenv.2022.153010
- Potential pre-industrial–like new particle formation induced by pure biogenic organic vapors in Finnish peatland W. Huang et al. 10.1126/sciadv.adm9191
- Chemical composition of nanoparticles from <i>α</i>-pinene nucleation and the influence of isoprene and relative humidity at low temperature L. Caudillo et al. 10.5194/acp-21-17099-2021
- Formation of secondary organic aerosol from wildfire emissions enhanced by long-time ageing Y. He et al. 10.1038/s41561-023-01355-4
- Particle Formation from Photooxidation of αpinene, Limonene, and Myrcene D. Hanson et al. 10.1021/acs.jpca.1c08427
- Molecular understanding of new-particle formation from α-pinene between −50 and +25 °C M. Simon et al. 10.5194/acp-20-9183-2020
- Linking Precursors and Volatility of Ambient Oxygenated Organic Aerosols Using Thermal Desorption Measurement and Machine Learning X. Wang et al. 10.1021/acsestair.4c00076
- Chemical composition of secondary organic aerosol particles formed from mixtures of anthropogenic and biogenic precursors Y. Shao et al. 10.5194/acp-22-9799-2022
- Modeling the Impact of the Organic Aerosol Phase State on Multiphase OH Reactive Uptake Kinetics and the Resultant Heterogeneous Oxidation Timescale of Organic Aerosol in the Amazon Rainforest Q. Rasool et al. 10.1021/acsearthspacechem.2c00366
- Fostering a Holistic Understanding of the Full Volatility Spectrum of Organic Compounds from Benzene Series Precursors through Mechanistic Modeling D. Yin et al. 10.1021/acs.est.3c07128
- Formation of Substituted Alkyls as Precursors of Peroxy Radicals with a Rapid H-Shift in the Atmosphere X. Wu et al. 10.1021/acs.jpclett.1c02503
- Limited Secondary Organic Aerosol Production from Acyclic Oxygenated Volatile Chemical Products M. Humes et al. 10.1021/acs.est.1c07354
- Intense formation of secondary ultrafine particles from Amazonian vegetation fires and their invigoration of deep clouds and precipitation M. Shrivastava et al. 10.1016/j.oneear.2024.05.015
- Global variability in atmospheric new particle formation mechanisms B. Zhao et al. 10.1038/s41586-024-07547-1
- Evaluating Indoor Air Chemical Diversity, Indoor-to-Outdoor Emissions, and Surface Reservoirs Using High-Resolution Mass Spectrometry R. Sheu et al. 10.1021/acs.est.1c01337
- Development of a multiphase chemical mechanism to improve secondary organic aerosol formation in CAABA/MECCA (version 4.7.0) F. Wieser et al. 10.5194/gmd-17-4311-2024
- Large differences of highly oxygenated organic molecules (HOMs) and low-volatile species in secondary organic aerosols (SOAs) formed from ozonolysis of β-pinene and limonene D. Liu et al. 10.5194/acp-23-8383-2023
- New particle formation induced by anthropogenic–biogenic interactions on the southeastern Tibetan Plateau S. Lai et al. 10.5194/acp-24-2535-2024
- Modeling the Formation of Organic Compounds across Full Volatility Ranges and Their Contribution to Nanoparticle Growth in a Polluted Atmosphere Z. Li et al. 10.1021/acs.est.3c06708
- Insights into the role of the H-abstraction reaction kinetics of amines in understanding their degeneration fates under atmospheric and combustion conditions Y. Shang & S. Luo 10.1039/D4CP02187H
- Secondary Organic Aerosol from OH-Initiated Oxidation of Mixtures of d-Limonene and β-Myrcene S. Liu et al. 10.1021/acs.est.4c04870
- Global modeling of aerosol nucleation with a semi-explicit chemical mechanism for highly oxygenated organic molecules (HOMs) X. Shao et al. 10.5194/acp-24-11365-2024
- OH Kinetics with a Range of Nitrogen-Containing Compounds: N-Methylformamide, t-Butylamine, and N-Methyl-propane Diamine T. Speak et al. 10.1021/acs.jpca.1c08104
- Analysis of reduced and oxidized nitrogen-containing organic compounds at a coastal site in summer and winter J. Ditto et al. 10.5194/acp-22-3045-2022
- Desorption lifetimes and activation energies influencing gas–surface interactions and multiphase chemical kinetics D. Knopf et al. 10.5194/acp-24-3445-2024
- Peroxy radical kinetics and new particle formation M. Schervish & N. Donahue 10.1039/D0EA00017E
- Future changes in isoprene-epoxydiol-derived secondary organic aerosol (IEPOX SOA) under the Shared Socioeconomic Pathways: the importance of physicochemical dependency D. Jo et al. 10.5194/acp-21-3395-2021
- High concentration of ultrafine particles in the Amazon free troposphere produced by organic new particle formation B. Zhao et al. 10.1073/pnas.2006716117
- Gas-to-Particle Partitioning of Cyclohexene- and α-Pinene-Derived Highly Oxygenated Dimers Evaluated Using COSMOtherm N. Hyttinen et al. 10.1021/acs.jpca.0c11328
- NO at low concentration can enhance the formation of highly oxygenated biogenic molecules in the atmosphere W. Nie et al. 10.1038/s41467-023-39066-4
- Chlorine-Initiated Oxidation of α-Pinene: Formation of Secondary Organic Aerosol and Highly Oxygenated Organic Molecules C. Masoud & L. Ruiz 10.1021/acsearthspacechem.1c00150
- Effect of OH scavengers on the chemical composition of α-pinene secondary organic aerosol D. Bell et al. 10.1039/D2EA00105E
- Data‐Driven Compound Identification in Atmospheric Mass Spectrometry H. Sandström et al. 10.1002/advs.202306235
- Comparison of saturation vapor pressures of <i>α</i>-pinene + O<sub>3</sub> oxidation products derived from COSMO-RS computations and thermal desorption experiments N. Hyttinen et al. 10.5194/acp-22-1195-2022
Latest update: 14 Dec 2024
Short summary
Gas-phase autoxidation of organics can generate highly oxygenated organic molecules (HOMs) and thus increase secondary organic aerosol production and enable new-particle formation. Here we explicitly represent the generation of HOMs via peroxy radical chemistry and resolve the products based on volatility and O : C. Using experimentally constrained assumptions about autoxidation and dimerization reactions, we see suppression of HOM formation under low-temperature and high-NOx conditions.
Gas-phase autoxidation of organics can generate highly oxygenated organic molecules (HOMs) and...
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