Articles | Volume 20, issue 2
https://doi.org/10.5194/acp-20-1183-2020
https://doi.org/10.5194/acp-20-1183-2020
Research article
 | 
31 Jan 2020
Research article |  | 31 Jan 2020

Peroxy radical chemistry and the volatility basis set

Meredith Schervish and Neil M. Donahue

Viewed

Total article views: 6,542 (including HTML, PDF, and XML)
HTML PDF XML Total Supplement BibTeX EndNote
4,394 2,017 131 6,542 721 173 288
  • HTML: 4,394
  • PDF: 2,017
  • XML: 131
  • Total: 6,542
  • Supplement: 721
  • BibTeX: 173
  • EndNote: 288
Views and downloads (calculated since 17 Jul 2019)
Cumulative views and downloads (calculated since 17 Jul 2019)

Viewed (geographical distribution)

Total article views: 6,542 (including HTML, PDF, and XML) Thereof 6,444 with geography defined and 98 with unknown origin.
Country # Views %
  • 1
1
 
 
 
 

Cited

Saved (final revised paper)

Latest update: 05 Aug 2026
Download
Short summary
Gas-phase autoxidation of organics can generate highly oxygenated organic molecules (HOMs) and thus increase secondary organic aerosol production and enable new-particle formation. Here we explicitly represent the generation of HOMs via peroxy radical chemistry and resolve the products based on volatility and O : C. Using experimentally constrained assumptions about autoxidation and dimerization reactions, we see suppression of HOM formation under low-temperature and high-NOx conditions.
Share
Altmetrics
Final-revised paper
Preprint