Articles | Volume 20, issue 20
https://doi.org/10.5194/acp-20-11729-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-20-11729-2020
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Aerosol pH and chemical regimes of sulfate formation in aerosol water during winter haze in the North China Plain
Wei Tao
Multiphase Chemistry Department, Max Planck Institute for Chemistry,
55128 Mainz, Germany
Minerva Research Group, Max Planck Institute for Chemistry, 55128 Mainz, Germany
Multiphase Chemistry Department, Max Planck Institute for Chemistry,
55128 Mainz, Germany
Guangjie Zheng
Minerva Research Group, Max Planck Institute for Chemistry, 55128 Mainz, Germany
Jiandong Wang
Minerva Research Group, Max Planck Institute for Chemistry, 55128 Mainz, Germany
Chao Wei
Multiphase Chemistry Department, Max Planck Institute for Chemistry,
55128 Mainz, Germany
Lixia Liu
Minerva Research Group, Max Planck Institute for Chemistry, 55128 Mainz, Germany
Nan Ma
Institute for Environmental and Climate Research, Jinan University,
Guangzhou 511443, China
Multiphase Chemistry Department, Max Planck Institute for Chemistry,
55128 Mainz, Germany
Qiang Zhang
Department of Earth System Science, Tsinghua University, Beijing
100084, China
Ulrich Pöschl
Multiphase Chemistry Department, Max Planck Institute for Chemistry,
55128 Mainz, Germany
Minerva Research Group, Max Planck Institute for Chemistry, 55128 Mainz, Germany
Multiphase Chemistry Department, Max Planck Institute for Chemistry,
55128 Mainz, Germany
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Latest update: 29 Sep 2023
Short summary
We simulated the thermodynamic and multiphase reactions in aerosol water during a wintertime haze event over the North China Plain. It was found that aerosol pH exhibited a strong spatiotemporal variability, and multiple oxidation pathways were predominant for particulate sulfate formation in different locations. Sensitivity tests further showed that ammonia, crustal particles, and dissolved transition metal ions were important factors for multiphase chemistry during haze episodes.
We simulated the thermodynamic and multiphase reactions in aerosol water during a wintertime...
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