Articles | Volume 19, issue 2
https://doi.org/10.5194/acp-19-813-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-19-813-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
22 Jan 2019
Research article |
| 22 Jan 2019
| 22 Jan 2019
Organic peroxy radical chemistry in oxidation flow reactors and environmental chambers and their atmospheric relevance
Cooperative Institute for Research in Environmental Sciences and
Department of Chemistry, University of Colorado, Boulder, Colorado 80309,
USA
Julia Lee-Taylor
Cooperative Institute for Research in Environmental Sciences and
Department of Chemistry, University of Colorado, Boulder, Colorado 80309,
USA
Atmospheric Chemistry Observation and Modeling Laboratory, National
Center for Atmospheric Research, Boulder, Colorado 80307, USA
John J. Orlando
Atmospheric Chemistry Observation and Modeling Laboratory, National
Center for Atmospheric Research, Boulder, Colorado 80307, USA
Geoffrey S. Tyndall
Atmospheric Chemistry Observation and Modeling Laboratory, National
Center for Atmospheric Research, Boulder, Colorado 80307, USA
Jose L. Jimenez
CORRESPONDING AUTHOR
Cooperative Institute for Research in Environmental Sciences and
Department of Chemistry, University of Colorado, Boulder, Colorado 80309,
USA
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Latest update: 11 May 2025
Short summary
The use of oxidation flow reactors (OFRs) has been rapidly increasing. We investigate organic peroxy radical (RO2) chemistry in OFRs by kinetic modeling. It is found that, at low NO, UV intensity should be limited to avoid high radical levels leading to significant reaction of RO2 with OH and negligible RO2 isomerization, both of which are atmospherically irrelevant. We also develop two RO2 fate estimators (for general use and for OFRs) to aid experiment design and interpretation.
The use of oxidation flow reactors (OFRs) has been rapidly increasing. We investigate organic...
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