Articles | Volume 19, issue 7
https://doi.org/10.5194/acp-19-5033-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Special issue:
https://doi.org/10.5194/acp-19-5033-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
12 Apr 2019
Research article |
| 12 Apr 2019
| 12 Apr 2019
New particle formation from sulfuric acid and ammonia: nucleation and growth model based on thermodynamics derived from CLOUD measurements for a wide range of conditions
Andreas Kürten
CORRESPONDING AUTHOR
Institute for Atmospheric and Environmental Sciences, Goethe University
Frankfurt, 60438 Frankfurt am Main, Germany
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- Role of iodine oxoacids in atmospheric aerosol nucleation X. He et al. 10.1126/science.abe0298
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- A consistent formation free energy definition for multicomponent clusters in quantum thermochemistry R. Halonen 10.1016/j.jaerosci.2022.105974
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- Influence of vegetation on occurrence and time distributions of regional new aerosol particle formation and growth I. Salma et al. 10.5194/acp-21-2861-2021
- Modeling the formation and growth of atmospheric molecular clusters: A review J. Elm et al. 10.1016/j.jaerosci.2020.105621
- Real-time monitoring of aerosol particle formation from sulfuric acid vapor at elevated concentrations and temperatures D. Becker et al. 10.1039/D1CP04580F
- Boundary layer versus free tropospheric submicron particle formation: A case study from NASA DC-8 observations in the Asian continental outflow during the KORUS-AQ campaign D. Park et al. 10.1016/j.atmosres.2021.105857
- Chemistry of new particle formation and growth events during wintertime in suburban area of Beijing: Insights from highly polluted atmosphere S. Yang et al. 10.1016/j.atmosres.2021.105553
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- Atmospheric new particle formation from the CERN CLOUD experiment J. Kirkby et al. 10.1038/s41561-023-01305-0
- Investigation of new particle formation mechanisms and aerosol processes at Marambio Station, Antarctic Peninsula L. Quéléver et al. 10.5194/acp-22-8417-2022
- An extraction method for nitrogen isotope measurement of ammonium in a low-concentration environment A. Lamothe et al. 10.5194/amt-16-4015-2023
- Atmospheric nanoparticle growth D. Stolzenburg et al. 10.1103/RevModPhys.95.045002
- Technical note: Emission factors, chemical composition, and morphology of particles emitted from Euro 5 diesel and gasoline light-duty vehicles during transient cycles E. Kostenidou et al. 10.5194/acp-21-4779-2021
- H<sub>2</sub>SO<sub>4</sub> and particle production in a photolytic flow reactor: chemical modeling, cluster thermodynamics and contamination issues D. Hanson et al. 10.5194/acp-19-8999-2019
- The driving factors of new particle formation and growth in the polluted boundary layer M. Xiao et al. 10.5194/acp-21-14275-2021
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- In situ observation of new particle formation (NPF) in the tropical tropopause layer of the 2017 Asian monsoon anticyclone – Part 1: Summary of StratoClim results R. Weigel et al. 10.5194/acp-21-11689-2021
- Atmospheric Bases-Enhanced Iodic Acid Nucleation: Altitude-Dependent Characteristics and Molecular Mechanisms J. Li et al. 10.1021/acs.est.4c06053
- Clustering of HClO4 with Brønsted (H2SO4, HClO4, HNO3) and Lewis acids BX3 (X = H, F, Cl, Br, OH): a DFT study Y. Valadbeigi & T. Kurtén 10.1039/C9NJ04694A
- Structural Diversity of Protonated Citric Acid-Ammonia Clusters and Its Atmospheric Implication S. Zhou et al. 10.1021/acs.jpca.3c05160
- Exploring the hydrogen-bonded interactions of vanillic acid with atmospheric bases: a DFT study T. de Oliveira et al. 10.1007/s11224-024-02307-3
- Measurement report: Sulfuric acid nucleation and experimental conditions in a photolytic flow reactor D. Hanson et al. 10.5194/acp-21-1987-2021
- Measurement of ammonia, amines and iodine compounds using protonated water cluster chemical ionization mass spectrometry J. Pfeifer et al. 10.5194/amt-13-2501-2020
- Quantum Machine Learning Approach for Studying Atmospheric Cluster Formation J. Kubečka et al. 10.1021/acs.estlett.1c00997
- Reduction of anthropogenic emissions enhanced atmospheric new particle formation: Observational evidence during the Beijing 2022 Winter Olympics W. Zhu et al. 10.1016/j.atmosenv.2023.120094
- Evidence of nitrate-based nighttime atmospheric nucleation driven by marine microorganisms in the South Pacific G. Chamba et al. 10.1073/pnas.2308696120
- Potential enhancement in atmospheric new particle formation by amine-assisted nitric acid condensation at room temperature K. Chen et al. 10.1016/j.atmosenv.2022.119252
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Short summary
New particle formation and growth are important processes affecting climate and air quality. A significant fraction of newly formed particles originates from sulfuric acid, water, and ammonia. The present study introduces a new process model for the calculation of aerosol nucleation and growth rates for the sulfuric acid–ammonia system. The thermodynamic parameters enabling these calculations are derived from laboratory (CLOUD chamber) measurements.
New particle formation and growth are important processes affecting climate and air quality. A...
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