Articles | Volume 19, issue 4
https://doi.org/10.5194/acp-19-2433-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-19-2433-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
26 Feb 2019
Research article |
| 26 Feb 2019
| 26 Feb 2019
Heterogeneous OH oxidation of isoprene-epoxydiol-derived organosulfates: kinetics, chemistry and formation of inorganic sulfate
Hoi Ki Lam
Earth System Science Programme, Faculty of Science, The Chinese
University of Hong Kong, Hong Kong, China
Kai Chung Kwong
Earth System Science Programme, Faculty of Science, The Chinese
University of Hong Kong, Hong Kong, China
Hon Yin Poon
Earth System Science Programme, Faculty of Science, The Chinese
University of Hong Kong, Hong Kong, China
James F. Davies
Department of Chemistry, UC Riverside, Riverside, USA
Zhenfa Zhang
Department of Environmental Sciences and Engineering, Gillings School
of Global Public Health, The University of North Carolina at Chapel Hill,
Chapel Hill, USA
Avram Gold
Department of Environmental Sciences and Engineering, Gillings School
of Global Public Health, The University of North Carolina at Chapel Hill,
Chapel Hill, USA
Jason D. Surratt
Department of Environmental Sciences and Engineering, Gillings School
of Global Public Health, The University of North Carolina at Chapel Hill,
Chapel Hill, USA
Man Nin Chan
CORRESPONDING AUTHOR
Earth System Science Programme, Faculty of Science, The Chinese
University of Hong Kong, Hong Kong, China
The Institute of Environment, Energy and Sustainability, The Chinese
University of Hong Kong, Hong Kong, China
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27 citations as recorded by crossref.
- Near-canopy horizontal concentration heterogeneity of semivolatile oxygenated organic compounds and implications for 2-methyltetrols primary emissions J. Ye et al. 10.1039/D0EA00006J
- Study on heterogeneous OH oxidation of 3-methyltetraol sulfate in the atmosphere under high NO conditions C. Guo et al. 10.1039/D2RA02958H
- CHEMICAL REACTION MONITORING BY AMBIENT MASS SPECTROMETRY J. Sun et al. 10.1002/mas.21668
- Organosulfates in Ambient Aerosol: State of Knowledge and Future Research Directions on Formation, Abundance, Fate, and Importance M. Brüggemann et al. 10.1021/acs.est.9b06751
- Recent advances in mass spectrometry techniques for atmospheric chemistry research on molecular‐level W. Zhang et al. 10.1002/mas.21857
- Molecular characteristics and formation mechanisms of biogenic secondary organic aerosols in the mountainous background atmosphere of southern China S. Zhang et al. 10.1016/j.atmosenv.2024.120540
- PM2.5-bound organosulfates in two Eastern Mediterranean cities: The dominance of isoprene organosulfates P. Kanellopoulos et al. 10.1016/j.chemosphere.2022.134103
- Heterogeneous Hydroxyl Radical Oxidation of Isoprene-Epoxydiol-Derived Methyltetrol Sulfates: Plausible Formation Mechanisms of Previously Unexplained Organosulfates in Ambient Fine Aerosols Y. Chen et al. 10.1021/acs.estlett.0c00276
- Kinetics and Products of Heterogeneous Hydroxyl Radical Oxidation of Isoprene Epoxydiol-Derived Secondary Organic Aerosol J. Yan et al. 10.1021/acsearthspacechem.3c00073
- Investigation of the kinetics of conjugated diolefins using UV absorption spectroscopy D. Liu & A. Farooq 10.1016/j.proci.2022.07.071
- Structural Characterization of Lactone-Containing MW 212 Organosulfates Originating from Isoprene Oxidation in Ambient Fine Aerosol P. Wach et al. 10.1021/acs.est.9b06190
- Isoprene Epoxydiol-Derived Sulfated and Nonsulfated Oligomers Suppress Particulate Mass Loss during Oxidative Aging of Secondary Organic Aerosol N. Armstrong et al. 10.1021/acs.est.2c03200
- Organosulfates from Dark Aqueous Reactions of Isoprene-Derived Epoxydiols Under Cloud and Fog Conditions: Kinetics, Mechanism, and Effect of Reaction Environment on Regioselectivity of Sulfate Addition S. Petters et al. 10.1021/acsearthspacechem.0c00293
- Chemical characteristics and sources of organosulfates, organosulfonates, and carboxylic acids in aerosols in urban Xi'an, Northwest China M. Glasius et al. 10.1016/j.scitotenv.2021.151187
- Aerosol characteristics at the Southern Great Plains site during the HI-SCALE campaign J. Liu et al. 10.5194/acp-21-5101-2021
- Chemical transformation of <i>α</i>-pinene-derived organosulfate via heterogeneous OH oxidation: implications for sources and environmental fates of atmospheric organosulfates R. Xu et al. 10.5194/acp-22-5685-2022
- Molecular characteristics, sources, and formation pathways of organosulfur compounds in ambient aerosol in Guangzhou, South China H. Jiang et al. 10.5194/acp-22-6919-2022
- Effect of inorganic-to-organic mass ratio on the heterogeneous OH reaction rates of erythritol: implications for atmospheric chemical stability of 2-methyltetrols R. Xu et al. 10.5194/acp-20-3879-2020
- Beyond the formation: unveiling the atmospheric transformation of organosulfatesviaheterogeneous OH oxidation S. Ng & M. Chan 10.1039/D3CC03700B
- Chemical transformation of a long-chain alkyl organosulfate via heterogeneous OH oxidation: a case study of sodium dodecyl sulfate S. Madeleine Ng et al. 10.1039/D2EA00026A
- Future changes in isoprene-epoxydiol-derived secondary organic aerosol (IEPOX SOA) under the Shared Socioeconomic Pathways: the importance of physicochemical dependency D. Jo et al. 10.5194/acp-21-3395-2021
- Comparative Study of Particulate Organosulfates in Contrasting Atmospheric Environments: Field Evidence for the Significant Influence of Anthropogenic Sulfate and NOx Y. Wang et al. 10.1021/acs.estlett.0c00550
- Effects of NO and SO2 on the secondary organic aerosol formation from isoprene photooxidation Z. Zhang et al. 10.1016/j.atmosenv.2023.120248
- Inorganic Sulfur Species Formed upon Heterogeneous OH Oxidation of Organosulfates: A Case Study of Methyl Sulfate R. Xu et al. 10.1021/acsearthspacechem.0c00209
- Analytical methods for organosulfate detection in aerosol particles: Current status and future perspectives K. Gao & T. Zhu 10.1016/j.scitotenv.2021.147244
- Emerging investigator series: aqueous oxidation of isoprene-derived organic aerosol species as a source of atmospheric formic and acetic acids K. Bates et al. 10.1039/D3EA00076A
- Production of Atmospheric Organosulfates via Mineral-Mediated Photochemistry M. Schmidt et al. 10.1021/acsearthspacechem.8b00178
26 citations as recorded by crossref.
- Near-canopy horizontal concentration heterogeneity of semivolatile oxygenated organic compounds and implications for 2-methyltetrols primary emissions J. Ye et al. 10.1039/D0EA00006J
- Study on heterogeneous OH oxidation of 3-methyltetraol sulfate in the atmosphere under high NO conditions C. Guo et al. 10.1039/D2RA02958H
- CHEMICAL REACTION MONITORING BY AMBIENT MASS SPECTROMETRY J. Sun et al. 10.1002/mas.21668
- Organosulfates in Ambient Aerosol: State of Knowledge and Future Research Directions on Formation, Abundance, Fate, and Importance M. Brüggemann et al. 10.1021/acs.est.9b06751
- Recent advances in mass spectrometry techniques for atmospheric chemistry research on molecular‐level W. Zhang et al. 10.1002/mas.21857
- Molecular characteristics and formation mechanisms of biogenic secondary organic aerosols in the mountainous background atmosphere of southern China S. Zhang et al. 10.1016/j.atmosenv.2024.120540
- PM2.5-bound organosulfates in two Eastern Mediterranean cities: The dominance of isoprene organosulfates P. Kanellopoulos et al. 10.1016/j.chemosphere.2022.134103
- Heterogeneous Hydroxyl Radical Oxidation of Isoprene-Epoxydiol-Derived Methyltetrol Sulfates: Plausible Formation Mechanisms of Previously Unexplained Organosulfates in Ambient Fine Aerosols Y. Chen et al. 10.1021/acs.estlett.0c00276
- Kinetics and Products of Heterogeneous Hydroxyl Radical Oxidation of Isoprene Epoxydiol-Derived Secondary Organic Aerosol J. Yan et al. 10.1021/acsearthspacechem.3c00073
- Investigation of the kinetics of conjugated diolefins using UV absorption spectroscopy D. Liu & A. Farooq 10.1016/j.proci.2022.07.071
- Structural Characterization of Lactone-Containing MW 212 Organosulfates Originating from Isoprene Oxidation in Ambient Fine Aerosol P. Wach et al. 10.1021/acs.est.9b06190
- Isoprene Epoxydiol-Derived Sulfated and Nonsulfated Oligomers Suppress Particulate Mass Loss during Oxidative Aging of Secondary Organic Aerosol N. Armstrong et al. 10.1021/acs.est.2c03200
- Organosulfates from Dark Aqueous Reactions of Isoprene-Derived Epoxydiols Under Cloud and Fog Conditions: Kinetics, Mechanism, and Effect of Reaction Environment on Regioselectivity of Sulfate Addition S. Petters et al. 10.1021/acsearthspacechem.0c00293
- Chemical characteristics and sources of organosulfates, organosulfonates, and carboxylic acids in aerosols in urban Xi'an, Northwest China M. Glasius et al. 10.1016/j.scitotenv.2021.151187
- Aerosol characteristics at the Southern Great Plains site during the HI-SCALE campaign J. Liu et al. 10.5194/acp-21-5101-2021
- Chemical transformation of <i>α</i>-pinene-derived organosulfate via heterogeneous OH oxidation: implications for sources and environmental fates of atmospheric organosulfates R. Xu et al. 10.5194/acp-22-5685-2022
- Molecular characteristics, sources, and formation pathways of organosulfur compounds in ambient aerosol in Guangzhou, South China H. Jiang et al. 10.5194/acp-22-6919-2022
- Effect of inorganic-to-organic mass ratio on the heterogeneous OH reaction rates of erythritol: implications for atmospheric chemical stability of 2-methyltetrols R. Xu et al. 10.5194/acp-20-3879-2020
- Beyond the formation: unveiling the atmospheric transformation of organosulfatesviaheterogeneous OH oxidation S. Ng & M. Chan 10.1039/D3CC03700B
- Chemical transformation of a long-chain alkyl organosulfate via heterogeneous OH oxidation: a case study of sodium dodecyl sulfate S. Madeleine Ng et al. 10.1039/D2EA00026A
- Future changes in isoprene-epoxydiol-derived secondary organic aerosol (IEPOX SOA) under the Shared Socioeconomic Pathways: the importance of physicochemical dependency D. Jo et al. 10.5194/acp-21-3395-2021
- Comparative Study of Particulate Organosulfates in Contrasting Atmospheric Environments: Field Evidence for the Significant Influence of Anthropogenic Sulfate and NOx Y. Wang et al. 10.1021/acs.estlett.0c00550
- Effects of NO and SO2 on the secondary organic aerosol formation from isoprene photooxidation Z. Zhang et al. 10.1016/j.atmosenv.2023.120248
- Inorganic Sulfur Species Formed upon Heterogeneous OH Oxidation of Organosulfates: A Case Study of Methyl Sulfate R. Xu et al. 10.1021/acsearthspacechem.0c00209
- Analytical methods for organosulfate detection in aerosol particles: Current status and future perspectives K. Gao & T. Zhu 10.1016/j.scitotenv.2021.147244
- Emerging investigator series: aqueous oxidation of isoprene-derived organic aerosol species as a source of atmospheric formic and acetic acids K. Bates et al. 10.1039/D3EA00076A
1 citations as recorded by crossref.
Latest update: 17 Jul 2024
Short summary
Organosulfates are ubiquitous in the atmosphere. We find that chemical transformation of IEPOX-derived organosulfates, one of the most abundant organosulfates, can generate inorganic sulfate through heterogeneous OH oxidation. The findings of this work provide new reaction pathways for recycling of inorganic and organic sulfur and may suggest that organosulfates could be reservoirs of inorganic sulfates in the atmosphere.
Organosulfates are ubiquitous in the atmosphere. We find that chemical transformation of...
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