Articles | Volume 19, issue 23
https://doi.org/10.5194/acp-19-14777-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Special issue:
https://doi.org/10.5194/acp-19-14777-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
09 Dec 2019
Research article |
| 09 Dec 2019
| 09 Dec 2019
Effects of NO2 and C3H6 on the heterogeneous oxidation of SO2 on TiO2 in the presence or absence of UV–Vis irradiation
State Key Joint Laboratory of Environment Simulation and Pollution
Control, Research Center for Eco-Environmental Sciences, Chinese Academy of
Sciences, Beijing 100085, China
Center for Excellence in Regional Atmospheric Environment, Institute
of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China
University of Chinese Academy of Sciences, Beijing 100049, China
Yali Wang
State Key Joint Laboratory of Environment Simulation and Pollution
Control, Research Center for Eco-Environmental Sciences, Chinese Academy of
Sciences, Beijing 100085, China
University of Chinese Academy of Sciences, Beijing 100049, China
Chinese Research Academy of Environmental Sciences, Beijing 100012, China
Weiwei Yang
State Key Joint Laboratory of Environment Simulation and Pollution
Control, Research Center for Eco-Environmental Sciences, Chinese Academy of
Sciences, Beijing 100085, China
University of Chinese Academy of Sciences, Beijing 100049, China
Key Laboratory of Pesticide and Chemical Biology of Ministry of
Education, Institute of Environmental and Applied Chemistry, College of
Chemistry, Central China Normal University, Wuhan 430079, China
Jinzhu Ma
State Key Joint Laboratory of Environment Simulation and Pollution
Control, Research Center for Eco-Environmental Sciences, Chinese Academy of
Sciences, Beijing 100085, China
Center for Excellence in Regional Atmospheric Environment, Institute
of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China
University of Chinese Academy of Sciences, Beijing 100049, China
State Key Joint Laboratory of Environment Simulation and Pollution
Control, Research Center for Eco-Environmental Sciences, Chinese Academy of
Sciences, Beijing 100085, China
Center for Excellence in Regional Atmospheric Environment, Institute
of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China
University of Chinese Academy of Sciences, Beijing 100049, China
Peng Zhang
State Key Joint Laboratory of Environment Simulation and Pollution
Control, Research Center for Eco-Environmental Sciences, Chinese Academy of
Sciences, Beijing 100085, China
Yongchun Liu
State Key Joint Laboratory of Environment Simulation and Pollution
Control, Research Center for Eco-Environmental Sciences, Chinese Academy of
Sciences, Beijing 100085, China
Aerosol and Haze Laboratory, Beijing Advanced Innovation Center for
Soft Matter Science and Engineering, Beijing University of Chemical
Technology, Beijing 100029, China
State Key Joint Laboratory of Environment Simulation and Pollution
Control, Research Center for Eco-Environmental Sciences, Chinese Academy of
Sciences, Beijing 100085, China
Center for Excellence in Regional Atmospheric Environment, Institute
of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China
University of Chinese Academy of Sciences, Beijing 100049, China
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24 citations as recorded by crossref.
- Heterogeneous Formation of Sulfur Species on Manganese Oxides: Effects of Particle Type and Moisture Condition T. Wang et al. 10.1021/acs.jpca.0c04483
- Significant formation of sulfate aerosols contributed by the heterogeneous drivers of dust surface T. Wang et al. 10.5194/acp-22-13467-2022
- Influence of temperature on the heterogeneous reaction of toluene to N-containing organic compounds using in situ DRIFTS X. He et al. 10.1016/j.atmosenv.2023.120084
- Heterogeneous reactions of toluene/NO2/NH3 on α-Fe2O3/α-Al2O3 particles: The effects of pollutant content and temperature changes on the formation of N-containing organic compounds (NOCs) S. Wen et al. 10.1016/j.atmosenv.2025.121195
- Significant concurrent decrease in PM2.5 and NO2 concentrations in China during COVID-19 epidemic B. Chu et al. 10.1016/j.jes.2020.06.031
- Heterogeneous reaction of toluene/NO2/O3 on α-Fe2O3 nanoparticles: the impacts of O3, light illumination, and relative humidity on the formation of N-containing organic compounds (NOC) X. He et al. 10.1039/D2EN00426G
- Unveiling the Role of Carbonate Radical Anions in Dust‐Driven SO2 Oxidation Y. Liu et al. 10.1029/2023JD040017
- Air Pollutant Correlations in China: Secondary Air Pollutant Responses to NOx and SO2 Control B. Chu et al. 10.1021/acs.estlett.0c00403
- Enhanced secondary organic aerosol formation during dust episodes by photochemical reactions in the winter in Wuhan K. Xu et al. 10.1016/j.jes.2022.04.018
- Critical Roles of Surface-Enhanced Heterogeneous Oxidation of SO2 in Haze Chemistry: Review of Extended Pathways for Complex Air Pollution Z. Zhang et al. 10.1007/s40726-023-00287-2
- Significant roles of aged dust aerosols on rapid nitrate formation under dry conditions in a semi-arid city J. Li et al. 10.1016/j.envpol.2023.122395
- Interaction of Acrylic Acid and SO2 on the Surface of Mineral Dust Aerosol R. Wang et al. 10.1021/acsearthspacechem.2c00323
- The heterogeneous reactions of toluene/O3/NH3 on hematite nanoparticles: the impact of light illumination on organic ammonium salt formation X. Liu et al. 10.1039/D3EN00625E
- A review on the heterogeneous oxidation of SO2 on solid atmospheric particles: Implications for sulfate formation in haze chemistry Q. Ma et al. 10.1080/10643389.2023.2190315
- Spatiotemporal variations and trends of air quality in major cities in Guizhou F. Lu et al. 10.3389/fenvs.2023.1254390
- Formation processes of nitrogen-containing organic compounds from heterogeneous reactions of C3H6/NO2/O3 with α-Fe2O3 particles X. Xi et al. 10.1016/j.atmosenv.2022.119567
- Summer urban synergistic effects of anthropogenic pollutants and low-molecular-weight biogenic volatile organic compounds on secondary organic aerosol presented by PM1 Y. Long et al. 10.1016/j.scitotenv.2025.178572
- Photochemical reaction of NO2 on photoactive mineral dust: Mechanism and irradiation intensity dependence T. Wang et al. 10.1016/j.jphotochem.2021.113319
- NH3-promoted heterogeneous reaction of SO2 to sulfate on α-Fe2O3 particles with coexistence of NO2 under different relative humidities X. He et al. 10.1016/j.atmosenv.2021.118622
- Photoenhanced sulfate formation by the heterogeneous uptake of SO2 on non-photoactive mineral dust W. Yang et al. 10.5194/acp-24-6757-2024
- Research Progress on Heterogeneous Reactions of Pollutant Gases on the Surface of Atmospheric Mineral Particulate Matter in China F. Zheng et al. 10.3390/atmos13081283
- Origin and transformation of ambient volatile organic compounds during a dust-to-haze episode in northwest China Y. Xue et al. 10.5194/acp-20-5425-2020
- Reinterpret the heterogeneous reaction of α-Fe2O3 and NO2 with 2D-COS: The role of SDS, UV and SO2 H. Duan et al. 10.1016/j.cclet.2023.109038
- Gel-state MOFs for environmental decontamination: Synthesis, application and optimization X. Wang et al. 10.1016/j.cej.2024.156241
24 citations as recorded by crossref.
- Heterogeneous Formation of Sulfur Species on Manganese Oxides: Effects of Particle Type and Moisture Condition T. Wang et al. 10.1021/acs.jpca.0c04483
- Significant formation of sulfate aerosols contributed by the heterogeneous drivers of dust surface T. Wang et al. 10.5194/acp-22-13467-2022
- Influence of temperature on the heterogeneous reaction of toluene to N-containing organic compounds using in situ DRIFTS X. He et al. 10.1016/j.atmosenv.2023.120084
- Heterogeneous reactions of toluene/NO2/NH3 on α-Fe2O3/α-Al2O3 particles: The effects of pollutant content and temperature changes on the formation of N-containing organic compounds (NOCs) S. Wen et al. 10.1016/j.atmosenv.2025.121195
- Significant concurrent decrease in PM2.5 and NO2 concentrations in China during COVID-19 epidemic B. Chu et al. 10.1016/j.jes.2020.06.031
- Heterogeneous reaction of toluene/NO2/O3 on α-Fe2O3 nanoparticles: the impacts of O3, light illumination, and relative humidity on the formation of N-containing organic compounds (NOC) X. He et al. 10.1039/D2EN00426G
- Unveiling the Role of Carbonate Radical Anions in Dust‐Driven SO2 Oxidation Y. Liu et al. 10.1029/2023JD040017
- Air Pollutant Correlations in China: Secondary Air Pollutant Responses to NOx and SO2 Control B. Chu et al. 10.1021/acs.estlett.0c00403
- Enhanced secondary organic aerosol formation during dust episodes by photochemical reactions in the winter in Wuhan K. Xu et al. 10.1016/j.jes.2022.04.018
- Critical Roles of Surface-Enhanced Heterogeneous Oxidation of SO2 in Haze Chemistry: Review of Extended Pathways for Complex Air Pollution Z. Zhang et al. 10.1007/s40726-023-00287-2
- Significant roles of aged dust aerosols on rapid nitrate formation under dry conditions in a semi-arid city J. Li et al. 10.1016/j.envpol.2023.122395
- Interaction of Acrylic Acid and SO2 on the Surface of Mineral Dust Aerosol R. Wang et al. 10.1021/acsearthspacechem.2c00323
- The heterogeneous reactions of toluene/O3/NH3 on hematite nanoparticles: the impact of light illumination on organic ammonium salt formation X. Liu et al. 10.1039/D3EN00625E
- A review on the heterogeneous oxidation of SO2 on solid atmospheric particles: Implications for sulfate formation in haze chemistry Q. Ma et al. 10.1080/10643389.2023.2190315
- Spatiotemporal variations and trends of air quality in major cities in Guizhou F. Lu et al. 10.3389/fenvs.2023.1254390
- Formation processes of nitrogen-containing organic compounds from heterogeneous reactions of C3H6/NO2/O3 with α-Fe2O3 particles X. Xi et al. 10.1016/j.atmosenv.2022.119567
- Summer urban synergistic effects of anthropogenic pollutants and low-molecular-weight biogenic volatile organic compounds on secondary organic aerosol presented by PM1 Y. Long et al. 10.1016/j.scitotenv.2025.178572
- Photochemical reaction of NO2 on photoactive mineral dust: Mechanism and irradiation intensity dependence T. Wang et al. 10.1016/j.jphotochem.2021.113319
- NH3-promoted heterogeneous reaction of SO2 to sulfate on α-Fe2O3 particles with coexistence of NO2 under different relative humidities X. He et al. 10.1016/j.atmosenv.2021.118622
- Photoenhanced sulfate formation by the heterogeneous uptake of SO2 on non-photoactive mineral dust W. Yang et al. 10.5194/acp-24-6757-2024
- Research Progress on Heterogeneous Reactions of Pollutant Gases on the Surface of Atmospheric Mineral Particulate Matter in China F. Zheng et al. 10.3390/atmos13081283
- Origin and transformation of ambient volatile organic compounds during a dust-to-haze episode in northwest China Y. Xue et al. 10.5194/acp-20-5425-2020
- Reinterpret the heterogeneous reaction of α-Fe2O3 and NO2 with 2D-COS: The role of SDS, UV and SO2 H. Duan et al. 10.1016/j.cclet.2023.109038
- Gel-state MOFs for environmental decontamination: Synthesis, application and optimization X. Wang et al. 10.1016/j.cej.2024.156241
Latest update: 26 Jul 2025
Short summary
This study found that the coexisting NO2 and/or C2H2 had significant influences on heterogeneous oxidation of SO2 due to the ubiquitous interactions between organic and inorganic species, and their effects were different under dark conditions or with UV irradiation. The experimental results of this study highlighted the requirement to consider the influence of coexisting organics and other inorganic gases in the heterogeneous oxidation kinetics of SO2.
This study found that the coexisting NO2 and/or C2H2 had significant influences on heterogeneous...
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