Articles | Volume 19, issue 20
https://doi.org/10.5194/acp-19-13037-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-19-13037-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
22 Oct 2019
Research article |
| 22 Oct 2019
| 22 Oct 2019
Carboxylic acids from limonene oxidation by ozone and hydroxyl radicals: insights into mechanisms derived using a FIGAERO-CIMS
Julia Hammes
Department of Chemistry and Molecular Biology, University of
Gothenburg, Gothenburg, Sweden
Anna Lutz
Department of Chemistry and Molecular Biology, University of
Gothenburg, Gothenburg, Sweden
Thomas Mentel
Department of Chemistry and Molecular Biology, University of
Gothenburg, Gothenburg, Sweden
Institute of Energy and Climate Research, Troposphere (IEK-8),
Forschungszentrum Jülich GmbH, Jülich, Germany
Cameron Faxon
Department of Chemistry and Molecular Biology, University of
Gothenburg, Gothenburg, Sweden
Department of Chemistry and Molecular Biology, University of
Gothenburg, Gothenburg, Sweden
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Cited
36 citations as recorded by crossref.
- Evaluating Organic Aerosol Sources and Evolution with a Combined Molecular Composition and Volatility Framework Using the Filter Inlet for Gases and Aerosols (FIGAERO) J. Thornton et al. 10.1021/acs.accounts.0c00259
- Hydroxyl, hydroperoxyl free radicals determination methods in atmosphere and troposphere G. Wang et al. 10.1016/j.jes.2020.06.038
- Mass spectrometry-based Aerosolomics: a new approach to resolve sources, composition, and partitioning of secondary organic aerosol M. Thoma et al. 10.5194/amt-15-7137-2022
- QSAR models for the ozonation of diverse volatile organic compounds at different temperatures A. Azimi et al. 10.1039/D3RA08805G
- Nitrogen-containing organic aerosols and highly oxidized molecules produced by reaction of ozone with floor cleaning detergent J. Xu et al. 10.1039/D4EA00076E
- Molecular characterization of gaseous and particulate oxygenated compounds at a remote site in Cape Corsica in the western Mediterranean Basin V. Michoud et al. 10.5194/acp-21-8067-2021
- Exploring the influence of physical and chemical factors on new particle formation in a polluted megacity U. Ali et al. 10.1039/D4EA00114A
- Characterization of thermal decomposition of oxygenated organic compounds in FIGAERO-CIMS L. Yang et al. 10.1080/02786826.2021.1945529
- On the formation of highly oxidized pollutants by autoxidation of terpenes under low-temperature-combustion conditions: the case of limonene and α-pinene R. Benoit et al. 10.5194/acp-23-5715-2023
- A Near-Explicit Reaction Mechanism of Chlorine-Initiated Limonene: Implications for Health Risks Associated with the Concurrent Use of Cleaning Agents and Disinfectants Z. Fu et al. 10.1021/acs.est.4c04388
- Emissions of carboxylic acids, hydrogen cyanide (HCN) and isocyanic acid (HNCO) from vehicle exhaust T. Li et al. 10.1016/j.atmosenv.2021.118218
- Molecular and Structural Characterization of Isomeric Compounds in Atmospheric Organic Aerosol Using Ion Mobility-Mass Spectrometry C. West et al. 10.1021/acs.jpca.2c06459
- Limonene: A scented and versatile tropospheric free radical deactivator M. Francisco‐Márquez & A. Galano 10.1002/qua.27103
- A review of indoor Gaseous organic compounds and human chemical Exposure: Insights from Real-time measurements B. You et al. 10.1016/j.envint.2022.107611
- The oxidation mechanism and kinetics of limononic acid by hydroxyl radical in atmospheric aqueous phase Y. Chen et al. 10.1016/j.atmosenv.2022.119527
- Large differences of highly oxygenated organic molecules (HOMs) and low-volatile species in secondary organic aerosols (SOAs) formed from ozonolysis of β-pinene and limonene D. Liu et al. 10.5194/acp-23-8383-2023
- Water Plays Multifunctional Roles in the Intervening Formation of Secondary Organic Aerosols in Ozonolysis of Limonene: A Valence Photoelectron Spectroscopy and Density Functional Theory Study J. Huang et al. 10.1021/acs.jpclett.3c00560
- Unimolecular Reactions Following Indoor and Outdoor Limonene Ozonolysis J. Chen et al. 10.1021/acs.jpca.0c09882
- Measurement report: Molecular composition and volatility of gaseous organic compounds in a boreal forest – from volatile organic compounds to highly oxygenated organic molecules W. Huang et al. 10.5194/acp-21-8961-2021
- Combined application of online FIGAERO-CIMS and offline LC-Orbitrap mass spectrometry (MS) to characterize the chemical composition of secondary organic aerosol (SOA) in smog chamber studies M. Du et al. 10.5194/amt-15-4385-2022
- Contrasting impacts of humidity on the ozonolysis of monoterpenes: insights into the multi-generation chemical mechanism S. Zhang et al. 10.5194/acp-23-10809-2023
- Variation in chemical composition and volatility of oxygenated organic aerosol in different rural, urban, and mountain environments W. Huang et al. 10.5194/acp-24-2607-2024
- Chemical characterization of oxygenated organic compounds in the gas phase and particle phase using iodide CIMS with FIGAERO in urban air C. Ye et al. 10.5194/acp-21-8455-2021
- Nitrate radical, ozone and hydroxyl radical initiated aging of limonene secondary organic aerosol S. Ramasamy et al. 10.1016/j.aeaoa.2021.100102
- Simulation of Monoterpene SOA Formation by Multiphase Reactions Using Explicit Mechanisms Z. Yu et al. 10.1021/acsearthspacechem.1c00056
- On the similarities and differences between the products of oxidation of hydrocarbons under simulated atmospheric conditions and cool flames R. Benoit et al. 10.5194/acp-21-7845-2021
- Chemistry and human exposure implications of secondary organic aerosol production from indoor terpene ozonolysis C. Rosales et al. 10.1126/sciadv.abj9156
- Introducing the extended volatility range proton-transfer-reaction mass spectrometer (EVR PTR-MS) F. Piel et al. 10.5194/amt-14-1355-2021
- New insights into the chemical composition and formation mechanisms of secondary organic aerosols produced in the ozonolysis of limonene F. Jacob et al. 10.1016/j.jaerosci.2023.106214
- Exploring the composition and volatility of secondary organic aerosols in mixed anthropogenic and biogenic precursor systems A. Voliotis et al. 10.5194/acp-21-14251-2021
- The importance of sesquiterpene oxidation products for secondary organic aerosol formation in a springtime hemiboreal forest L. Barreira et al. 10.5194/acp-21-11781-2021
- Overcoming the lack of authentic standards for the quantification of biogenic secondary organic aerosol markers D. Bryant et al. 10.1039/D2EA00074A
- Volatility and chemical composition of secondary organic aerosol derived from acenaphthylene and acenaphthene under various oxidant conditions W. Xiang et al. 10.1016/j.atmosenv.2024.120563
- Molecular composition of organic aerosols in urban and marine atmosphere: A comparison study using FIGAERO-I-CIMS, ESI-FT-ICR MS, and GC × GC-EI-ToF-MS X. Xin et al. 10.1080/02786826.2024.2377394
- Formation of highly oxygenated organic molecules from the oxidation of limonene by OH radical: significant contribution of H-abstraction pathway H. Luo et al. 10.5194/acp-23-7297-2023
- Secondary Ion Chemistry Mediated by Ozone and Acidic Organic Molecules in Iodide-Adduct Chemical Ionization Mass Spectrometry W. Zhang & H. Zhang 10.1021/acs.analchem.1c01486
36 citations as recorded by crossref.
- Evaluating Organic Aerosol Sources and Evolution with a Combined Molecular Composition and Volatility Framework Using the Filter Inlet for Gases and Aerosols (FIGAERO) J. Thornton et al. 10.1021/acs.accounts.0c00259
- Hydroxyl, hydroperoxyl free radicals determination methods in atmosphere and troposphere G. Wang et al. 10.1016/j.jes.2020.06.038
- Mass spectrometry-based Aerosolomics: a new approach to resolve sources, composition, and partitioning of secondary organic aerosol M. Thoma et al. 10.5194/amt-15-7137-2022
- QSAR models for the ozonation of diverse volatile organic compounds at different temperatures A. Azimi et al. 10.1039/D3RA08805G
- Nitrogen-containing organic aerosols and highly oxidized molecules produced by reaction of ozone with floor cleaning detergent J. Xu et al. 10.1039/D4EA00076E
- Molecular characterization of gaseous and particulate oxygenated compounds at a remote site in Cape Corsica in the western Mediterranean Basin V. Michoud et al. 10.5194/acp-21-8067-2021
- Exploring the influence of physical and chemical factors on new particle formation in a polluted megacity U. Ali et al. 10.1039/D4EA00114A
- Characterization of thermal decomposition of oxygenated organic compounds in FIGAERO-CIMS L. Yang et al. 10.1080/02786826.2021.1945529
- On the formation of highly oxidized pollutants by autoxidation of terpenes under low-temperature-combustion conditions: the case of limonene and α-pinene R. Benoit et al. 10.5194/acp-23-5715-2023
- A Near-Explicit Reaction Mechanism of Chlorine-Initiated Limonene: Implications for Health Risks Associated with the Concurrent Use of Cleaning Agents and Disinfectants Z. Fu et al. 10.1021/acs.est.4c04388
- Emissions of carboxylic acids, hydrogen cyanide (HCN) and isocyanic acid (HNCO) from vehicle exhaust T. Li et al. 10.1016/j.atmosenv.2021.118218
- Molecular and Structural Characterization of Isomeric Compounds in Atmospheric Organic Aerosol Using Ion Mobility-Mass Spectrometry C. West et al. 10.1021/acs.jpca.2c06459
- Limonene: A scented and versatile tropospheric free radical deactivator M. Francisco‐Márquez & A. Galano 10.1002/qua.27103
- A review of indoor Gaseous organic compounds and human chemical Exposure: Insights from Real-time measurements B. You et al. 10.1016/j.envint.2022.107611
- The oxidation mechanism and kinetics of limononic acid by hydroxyl radical in atmospheric aqueous phase Y. Chen et al. 10.1016/j.atmosenv.2022.119527
- Large differences of highly oxygenated organic molecules (HOMs) and low-volatile species in secondary organic aerosols (SOAs) formed from ozonolysis of β-pinene and limonene D. Liu et al. 10.5194/acp-23-8383-2023
- Water Plays Multifunctional Roles in the Intervening Formation of Secondary Organic Aerosols in Ozonolysis of Limonene: A Valence Photoelectron Spectroscopy and Density Functional Theory Study J. Huang et al. 10.1021/acs.jpclett.3c00560
- Unimolecular Reactions Following Indoor and Outdoor Limonene Ozonolysis J. Chen et al. 10.1021/acs.jpca.0c09882
- Measurement report: Molecular composition and volatility of gaseous organic compounds in a boreal forest – from volatile organic compounds to highly oxygenated organic molecules W. Huang et al. 10.5194/acp-21-8961-2021
- Combined application of online FIGAERO-CIMS and offline LC-Orbitrap mass spectrometry (MS) to characterize the chemical composition of secondary organic aerosol (SOA) in smog chamber studies M. Du et al. 10.5194/amt-15-4385-2022
- Contrasting impacts of humidity on the ozonolysis of monoterpenes: insights into the multi-generation chemical mechanism S. Zhang et al. 10.5194/acp-23-10809-2023
- Variation in chemical composition and volatility of oxygenated organic aerosol in different rural, urban, and mountain environments W. Huang et al. 10.5194/acp-24-2607-2024
- Chemical characterization of oxygenated organic compounds in the gas phase and particle phase using iodide CIMS with FIGAERO in urban air C. Ye et al. 10.5194/acp-21-8455-2021
- Nitrate radical, ozone and hydroxyl radical initiated aging of limonene secondary organic aerosol S. Ramasamy et al. 10.1016/j.aeaoa.2021.100102
- Simulation of Monoterpene SOA Formation by Multiphase Reactions Using Explicit Mechanisms Z. Yu et al. 10.1021/acsearthspacechem.1c00056
- On the similarities and differences between the products of oxidation of hydrocarbons under simulated atmospheric conditions and cool flames R. Benoit et al. 10.5194/acp-21-7845-2021
- Chemistry and human exposure implications of secondary organic aerosol production from indoor terpene ozonolysis C. Rosales et al. 10.1126/sciadv.abj9156
- Introducing the extended volatility range proton-transfer-reaction mass spectrometer (EVR PTR-MS) F. Piel et al. 10.5194/amt-14-1355-2021
- New insights into the chemical composition and formation mechanisms of secondary organic aerosols produced in the ozonolysis of limonene F. Jacob et al. 10.1016/j.jaerosci.2023.106214
- Exploring the composition and volatility of secondary organic aerosols in mixed anthropogenic and biogenic precursor systems A. Voliotis et al. 10.5194/acp-21-14251-2021
- The importance of sesquiterpene oxidation products for secondary organic aerosol formation in a springtime hemiboreal forest L. Barreira et al. 10.5194/acp-21-11781-2021
- Overcoming the lack of authentic standards for the quantification of biogenic secondary organic aerosol markers D. Bryant et al. 10.1039/D2EA00074A
- Volatility and chemical composition of secondary organic aerosol derived from acenaphthylene and acenaphthene under various oxidant conditions W. Xiang et al. 10.1016/j.atmosenv.2024.120563
- Molecular composition of organic aerosols in urban and marine atmosphere: A comparison study using FIGAERO-I-CIMS, ESI-FT-ICR MS, and GC × GC-EI-ToF-MS X. Xin et al. 10.1080/02786826.2024.2377394
- Formation of highly oxygenated organic molecules from the oxidation of limonene by OH radical: significant contribution of H-abstraction pathway H. Luo et al. 10.5194/acp-23-7297-2023
- Secondary Ion Chemistry Mediated by Ozone and Acidic Organic Molecules in Iodide-Adduct Chemical Ionization Mass Spectrometry W. Zhang & H. Zhang 10.1021/acs.analchem.1c01486
Latest update: 13 Jul 2025
Short summary
Identifying the chemical pathways of condensable products such as carboxylic acids is essential for predicting SOA formation. This identification is inherently difficult, as such products reside in both the gas and particulate phases. We measured acids, produced from atmospheric oxidation of limonene, in both phases and scrutinised the mechanistic understanding of their formation. The mechanisms explain nearly 75 % of the gas-phase signal at the lowest concentration (8.4 ppb, 23 % acid yield).
Identifying the chemical pathways of condensable products such as carboxylic acids is essential...
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