Articles | Volume 19, issue 20
Atmos. Chem. Phys., 19, 13037–13052, 2019
https://doi.org/10.5194/acp-19-13037-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Atmos. Chem. Phys., 19, 13037–13052, 2019
https://doi.org/10.5194/acp-19-13037-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
22 Oct 2019
Research article
| 22 Oct 2019
Carboxylic acids from limonene oxidation by ozone and hydroxyl radicals: insights into mechanisms derived using a FIGAERO-CIMS
Julia Hammes et al.
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Cited
16 citations as recorded by crossref.
- Evaluating Organic Aerosol Sources and Evolution with a Combined Molecular Composition and Volatility Framework Using the Filter Inlet for Gases and Aerosols (FIGAERO) J. Thornton et al. 10.1021/acs.accounts.0c00259
- Measurement report: Molecular composition and volatility of gaseous organic compounds in a boreal forest – from volatile organic compounds to highly oxygenated organic molecules W. Huang et al. 10.5194/acp-21-8961-2021
- Chemical characterization of oxygenated organic compounds in the gas phase and particle phase using iodide CIMS with FIGAERO in urban air C. Ye et al. 10.5194/acp-21-8455-2021
- Hydroxyl, hydroperoxyl free radicals determination methods in atmosphere and troposphere G. Wang et al. 10.1016/j.jes.2020.06.038
- Nitrate radical, ozone and hydroxyl radical initiated aging of limonene secondary organic aerosol S. Ramasamy et al. 10.1016/j.aeaoa.2021.100102
- Simulation of Monoterpene SOA Formation by Multiphase Reactions Using Explicit Mechanisms Z. Yu et al. 10.1021/acsearthspacechem.1c00056
- On the similarities and differences between the products of oxidation of hydrocarbons under simulated atmospheric conditions and cool flames R. Benoit et al. 10.5194/acp-21-7845-2021
- Chemistry and human exposure implications of secondary organic aerosol production from indoor terpene ozonolysis C. Rosales et al. 10.1126/sciadv.abj9156
- Introducing the extended volatility range proton-transfer-reaction mass spectrometer (EVR PTR-MS) F. Piel et al. 10.5194/amt-14-1355-2021
- Molecular characterization of gaseous and particulate oxygenated compounds at a remote site in Cape Corsica in the western Mediterranean Basin V. Michoud et al. 10.5194/acp-21-8067-2021
- Exploring the composition and volatility of secondary organic aerosols in mixed anthropogenic and biogenic precursor systems A. Voliotis et al. 10.5194/acp-21-14251-2021
- Characterization of thermal decomposition of oxygenated organic compounds in FIGAERO-CIMS L. Yang et al. 10.1080/02786826.2021.1945529
- Emissions of carboxylic acids, hydrogen cyanide (HCN) and isocyanic acid (HNCO) from vehicle exhaust T. Li et al. 10.1016/j.atmosenv.2021.118218
- The importance of sesquiterpene oxidation products for secondary organic aerosol formation in a springtime hemiboreal forest L. Barreira et al. 10.5194/acp-21-11781-2021
- Secondary Ion Chemistry Mediated by Ozone and Acidic Organic Molecules in Iodide-Adduct Chemical Ionization Mass Spectrometry W. Zhang & H. Zhang 10.1021/acs.analchem.1c01486
- Unimolecular Reactions Following Indoor and Outdoor Limonene Ozonolysis J. Chen et al. 10.1021/acs.jpca.0c09882
16 citations as recorded by crossref.
- Evaluating Organic Aerosol Sources and Evolution with a Combined Molecular Composition and Volatility Framework Using the Filter Inlet for Gases and Aerosols (FIGAERO) J. Thornton et al. 10.1021/acs.accounts.0c00259
- Measurement report: Molecular composition and volatility of gaseous organic compounds in a boreal forest – from volatile organic compounds to highly oxygenated organic molecules W. Huang et al. 10.5194/acp-21-8961-2021
- Chemical characterization of oxygenated organic compounds in the gas phase and particle phase using iodide CIMS with FIGAERO in urban air C. Ye et al. 10.5194/acp-21-8455-2021
- Hydroxyl, hydroperoxyl free radicals determination methods in atmosphere and troposphere G. Wang et al. 10.1016/j.jes.2020.06.038
- Nitrate radical, ozone and hydroxyl radical initiated aging of limonene secondary organic aerosol S. Ramasamy et al. 10.1016/j.aeaoa.2021.100102
- Simulation of Monoterpene SOA Formation by Multiphase Reactions Using Explicit Mechanisms Z. Yu et al. 10.1021/acsearthspacechem.1c00056
- On the similarities and differences between the products of oxidation of hydrocarbons under simulated atmospheric conditions and cool flames R. Benoit et al. 10.5194/acp-21-7845-2021
- Chemistry and human exposure implications of secondary organic aerosol production from indoor terpene ozonolysis C. Rosales et al. 10.1126/sciadv.abj9156
- Introducing the extended volatility range proton-transfer-reaction mass spectrometer (EVR PTR-MS) F. Piel et al. 10.5194/amt-14-1355-2021
- Molecular characterization of gaseous and particulate oxygenated compounds at a remote site in Cape Corsica in the western Mediterranean Basin V. Michoud et al. 10.5194/acp-21-8067-2021
- Exploring the composition and volatility of secondary organic aerosols in mixed anthropogenic and biogenic precursor systems A. Voliotis et al. 10.5194/acp-21-14251-2021
- Characterization of thermal decomposition of oxygenated organic compounds in FIGAERO-CIMS L. Yang et al. 10.1080/02786826.2021.1945529
- Emissions of carboxylic acids, hydrogen cyanide (HCN) and isocyanic acid (HNCO) from vehicle exhaust T. Li et al. 10.1016/j.atmosenv.2021.118218
- The importance of sesquiterpene oxidation products for secondary organic aerosol formation in a springtime hemiboreal forest L. Barreira et al. 10.5194/acp-21-11781-2021
- Secondary Ion Chemistry Mediated by Ozone and Acidic Organic Molecules in Iodide-Adduct Chemical Ionization Mass Spectrometry W. Zhang & H. Zhang 10.1021/acs.analchem.1c01486
- Unimolecular Reactions Following Indoor and Outdoor Limonene Ozonolysis J. Chen et al. 10.1021/acs.jpca.0c09882
Latest update: 06 Feb 2023
Short summary
Identifying the chemical pathways of condensable products such as carboxylic acids is essential for predicting SOA formation. This identification is inherently difficult, as such products reside in both the gas and particulate phases. We measured acids, produced from atmospheric oxidation of limonene, in both phases and scrutinised the mechanistic understanding of their formation. The mechanisms explain nearly 75 % of the gas-phase signal at the lowest concentration (8.4 ppb, 23 % acid yield).
Identifying the chemical pathways of condensable products such as carboxylic acids is essential...
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