Articles | Volume 19, issue 2
https://doi.org/10.5194/acp-19-1241-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-19-1241-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
31 Jan 2019
Research article |
| 31 Jan 2019
| 31 Jan 2019
Modeling the effect of non-ideality, dynamic mass transfer and viscosity on SOA formation in a 3-D air quality model
CEREA, Joint Laboratory École des Ponts ParisTech/EDF R&D,
Université Paris-Est, 77455 Champs-sur-Marne, France
Karine Sartelet
CEREA, Joint Laboratory École des Ponts ParisTech/EDF R&D,
Université Paris-Est, 77455 Champs-sur-Marne, France
Florian Couvidat
Institut National de l'Environnement Industriel et des Risques, 60550 Verneuil-en-Halatte, France
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Cited
29 citations as recorded by crossref.
- Global Distribution of the Phase State and Mixing Times within Secondary Organic Aerosol Particles in the Troposphere Based on Room-Temperature Viscosity Measurements A. Maclean et al. https://doi.org/10.1021/acsearthspacechem.1c00296
- Species-specific effect of particle viscosity and particle-phase reactions on the formation of secondary organic aerosol Z. Luo et al. https://doi.org/10.1016/j.scitotenv.2024.175207
- GENerator of reduced Organic Aerosol mechanism (GENOA v1.0): an automatic generation tool of semi-explicit mechanisms Z. Wang et al. https://doi.org/10.5194/gmd-15-8957-2022
- Diffusion of Organic Molecules as a Function of Temperature in a Sucrose Matrix (a Proxy for Secondary Organic Aerosol) K. Kiland et al. https://doi.org/10.1021/acs.jpclett.9b02182
- The CHIMERE v2020r1 online chemistry-transport model L. Menut et al. https://doi.org/10.5194/gmd-14-6781-2021
- Effects of volatility, viscosity, and non-ideality on particle–particle mixing timescales of secondary organic aerosols M. Schervish et al. https://doi.org/10.1080/02786826.2023.2256827
- Extension of the AIOMFAC Model for Atmospheric Aerosols Containing Partially Dissociating Organosulfates and Dicarboxylic Acids B. Bergen et al. https://doi.org/10.1021/acsearthspacechem.5c00146
- Insights into the aging of biomass burning aerosol from satellite observations and 3D atmospheric modeling: evolution of the aerosol optical properties in Siberian wildfire plumes I. Konovalov et al. https://doi.org/10.5194/acp-21-357-2021
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- Morphology and phase state of PM2.5 in urban and coastal-rural areas during summer S. Gaikwad et al. https://doi.org/10.3389/fenvs.2023.1142941
- Advanced modeling of gas chemistry and aerosol dynamics with SSH-aerosol v2.0 K. Sartelet et al. https://doi.org/10.5194/gmd-19-389-2026
- SSH-Aerosol v1.1: A Modular Box Model to Simulate the Evolution of Primary and Secondary Aerosols K. Sartelet et al. https://doi.org/10.3390/atmos11050525
- Secondary Organic Aerosol from Biomass Burning Phenolic Compounds and Nitrate Radicals can be Highly Viscous over a Wide Relative Humidity Range S. Nikkho et al. https://doi.org/10.1021/acs.est.4c06235
- Modeling Secondary Organic Aerosols in China: State of the Art and Perspectives J. Li et al. https://doi.org/10.1007/s40726-022-00246-3
- Impacts of water partitioning and polarity of organic compounds on secondary organic aerosol over eastern China J. Li et al. https://doi.org/10.5194/acp-20-7291-2020
- Surprising Crystallinity of Biomass Burning Secondary Organic Aerosol from Catechol and Nitrate Radical Reactions: Evidence and Possible Implications F. Mahrt et al. https://doi.org/10.1021/acs.est.5c06834
- Two-phase morphology and drastic viscosity changes in biomass burning organic aerosol after hydroxyl radical aging N. Gerrebos et al. https://doi.org/10.1039/D5EA00084J
- Diffusion Coefficients and Mixing Times of Organic Molecules in β-Caryophyllene Secondary Organic Aerosol (SOA) and Biomass Burning Organic Aerosol (BBOA) E. Evoy et al. https://doi.org/10.1021/acsearthspacechem.1c00317
- A new hot-stage microscopy technique for measuring temperature-dependent viscosities of aerosol particles and its application to farnesene secondary organic aerosol K. Kiland et al. https://doi.org/10.5194/amt-15-5545-2022
- Ion-molecule interactions enable unexpected phase transitions in organic-inorganic aerosol D. Richards et al. https://doi.org/10.1126/sciadv.abb5643
- Liquid–liquid phase separation and viscosity within secondary organic aerosol generated from diesel fuel vapors M. Song et al. https://doi.org/10.5194/acp-19-12515-2019
- Revisiting wintertime nitrate formation and recirculation in Seoul using box model simulations S. Park et al. https://doi.org/10.1007/s44273-026-00089-0
- Impact of the Atmospheric Photochemical Evolution of the Organic Component of Biomass Burning Aerosol on Its Radiative Forcing Efficiency: A Box Model Analysis T. Zhuravleva et al. https://doi.org/10.3390/atmos12121555
- Unified Description of Diffusion Coefficients from Small to Large Molecules in Organic–Water Mixtures E. Evoy et al. https://doi.org/10.1021/acs.jpca.9b11271
- Viscosity and phase state of aerosol particles consisting of sucrose mixed with inorganic salts Y. Song et al. https://doi.org/10.5194/acp-21-10215-2021
- Relative-humidity-dependent organic aerosol thermodynamics via an efficient reduced-complexity model K. Gorkowski et al. https://doi.org/10.5194/acp-19-13383-2019
- Humidity-Dependent Viscosity of Secondary Organic Aerosol from Ozonolysis of β-Caryophyllene: Measurements, Predictions, and Implications A. Maclean et al. https://doi.org/10.1021/acsearthspacechem.0c00296
- Viscosity, Glass Formation, and Mixing Times within Secondary Organic Aerosol from Biomass Burning Phenolics K. Kiland et al. https://doi.org/10.1021/acsearthspacechem.3c00039
- High Viscosity and Two Phases Observed over a Range of Relative Humidities in Biomass Burning Organic Aerosol from Canadian Wildfires N. Gerrebos et al. https://doi.org/10.1021/acs.est.4c09148
29 citations as recorded by crossref.
- Global Distribution of the Phase State and Mixing Times within Secondary Organic Aerosol Particles in the Troposphere Based on Room-Temperature Viscosity Measurements A. Maclean et al. https://doi.org/10.1021/acsearthspacechem.1c00296
- Species-specific effect of particle viscosity and particle-phase reactions on the formation of secondary organic aerosol Z. Luo et al. https://doi.org/10.1016/j.scitotenv.2024.175207
- GENerator of reduced Organic Aerosol mechanism (GENOA v1.0): an automatic generation tool of semi-explicit mechanisms Z. Wang et al. https://doi.org/10.5194/gmd-15-8957-2022
- Diffusion of Organic Molecules as a Function of Temperature in a Sucrose Matrix (a Proxy for Secondary Organic Aerosol) K. Kiland et al. https://doi.org/10.1021/acs.jpclett.9b02182
- The CHIMERE v2020r1 online chemistry-transport model L. Menut et al. https://doi.org/10.5194/gmd-14-6781-2021
- Effects of volatility, viscosity, and non-ideality on particle–particle mixing timescales of secondary organic aerosols M. Schervish et al. https://doi.org/10.1080/02786826.2023.2256827
- Extension of the AIOMFAC Model for Atmospheric Aerosols Containing Partially Dissociating Organosulfates and Dicarboxylic Acids B. Bergen et al. https://doi.org/10.1021/acsearthspacechem.5c00146
- Insights into the aging of biomass burning aerosol from satellite observations and 3D atmospheric modeling: evolution of the aerosol optical properties in Siberian wildfire plumes I. Konovalov et al. https://doi.org/10.5194/acp-21-357-2021
- Precursors and formation of secondary organic aerosols from wildfires in the Euro-Mediterranean region M. Majdi et al. https://doi.org/10.5194/acp-19-5543-2019
- Morphology and phase state of PM2.5 in urban and coastal-rural areas during summer S. Gaikwad et al. https://doi.org/10.3389/fenvs.2023.1142941
- Advanced modeling of gas chemistry and aerosol dynamics with SSH-aerosol v2.0 K. Sartelet et al. https://doi.org/10.5194/gmd-19-389-2026
- SSH-Aerosol v1.1: A Modular Box Model to Simulate the Evolution of Primary and Secondary Aerosols K. Sartelet et al. https://doi.org/10.3390/atmos11050525
- Secondary Organic Aerosol from Biomass Burning Phenolic Compounds and Nitrate Radicals can be Highly Viscous over a Wide Relative Humidity Range S. Nikkho et al. https://doi.org/10.1021/acs.est.4c06235
- Modeling Secondary Organic Aerosols in China: State of the Art and Perspectives J. Li et al. https://doi.org/10.1007/s40726-022-00246-3
- Impacts of water partitioning and polarity of organic compounds on secondary organic aerosol over eastern China J. Li et al. https://doi.org/10.5194/acp-20-7291-2020
- Surprising Crystallinity of Biomass Burning Secondary Organic Aerosol from Catechol and Nitrate Radical Reactions: Evidence and Possible Implications F. Mahrt et al. https://doi.org/10.1021/acs.est.5c06834
- Two-phase morphology and drastic viscosity changes in biomass burning organic aerosol after hydroxyl radical aging N. Gerrebos et al. https://doi.org/10.1039/D5EA00084J
- Diffusion Coefficients and Mixing Times of Organic Molecules in β-Caryophyllene Secondary Organic Aerosol (SOA) and Biomass Burning Organic Aerosol (BBOA) E. Evoy et al. https://doi.org/10.1021/acsearthspacechem.1c00317
- A new hot-stage microscopy technique for measuring temperature-dependent viscosities of aerosol particles and its application to farnesene secondary organic aerosol K. Kiland et al. https://doi.org/10.5194/amt-15-5545-2022
- Ion-molecule interactions enable unexpected phase transitions in organic-inorganic aerosol D. Richards et al. https://doi.org/10.1126/sciadv.abb5643
- Liquid–liquid phase separation and viscosity within secondary organic aerosol generated from diesel fuel vapors M. Song et al. https://doi.org/10.5194/acp-19-12515-2019
- Revisiting wintertime nitrate formation and recirculation in Seoul using box model simulations S. Park et al. https://doi.org/10.1007/s44273-026-00089-0
- Impact of the Atmospheric Photochemical Evolution of the Organic Component of Biomass Burning Aerosol on Its Radiative Forcing Efficiency: A Box Model Analysis T. Zhuravleva et al. https://doi.org/10.3390/atmos12121555
- Unified Description of Diffusion Coefficients from Small to Large Molecules in Organic–Water Mixtures E. Evoy et al. https://doi.org/10.1021/acs.jpca.9b11271
- Viscosity and phase state of aerosol particles consisting of sucrose mixed with inorganic salts Y. Song et al. https://doi.org/10.5194/acp-21-10215-2021
- Relative-humidity-dependent organic aerosol thermodynamics via an efficient reduced-complexity model K. Gorkowski et al. https://doi.org/10.5194/acp-19-13383-2019
- Humidity-Dependent Viscosity of Secondary Organic Aerosol from Ozonolysis of β-Caryophyllene: Measurements, Predictions, and Implications A. Maclean et al. https://doi.org/10.1021/acsearthspacechem.0c00296
- Viscosity, Glass Formation, and Mixing Times within Secondary Organic Aerosol from Biomass Burning Phenolics K. Kiland et al. https://doi.org/10.1021/acsearthspacechem.3c00039
- High Viscosity and Two Phases Observed over a Range of Relative Humidities in Biomass Burning Organic Aerosol from Canadian Wildfires N. Gerrebos et al. https://doi.org/10.1021/acs.est.4c09148
Saved (final revised paper)
Latest update: 15 Jul 2026
Short summary
Assumptions (ideality and thermodynamic equilibrium) commonly made in 3-dimensional air quality models were reconsidered to evaluate their impacts on secondary organic aerosol (SOA) formation. Non-ideality (short-, medium- and long-range interactions of organics and inorganics) influences SOA concentrations by about 30 % over Europe. If SOA are highly viscous rather than inviscid, hydrophobic SOA concentrations increase by 6 % but can increase by an order of magnitude for volatile compounds.
Assumptions (ideality and thermodynamic equilibrium) commonly made in 3-dimensional air quality...
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