Articles | Volume 19, issue 19
https://doi.org/10.5194/acp-19-12397-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-19-12397-2019
© Author(s) 2019. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
08 Oct 2019
Research article |
| 08 Oct 2019
| 08 Oct 2019
Photomineralization mechanism changes the ability of dissolved organic matter to activate cloud droplets and to nucleate ice crystals
Nadine Borduas-Dedekind
CORRESPONDING AUTHOR
Institute for Biogeochemistry and Pollutant Dynamics, ETH Zurich,
Zurich, 8092, Switzerland
Institute for Atmospheric and Climate Sciences, ETH Zurich, Zurich,
8092, Switzerland
Rachele Ossola
Institute for Biogeochemistry and Pollutant Dynamics, ETH Zurich,
Zurich, 8092, Switzerland
Robert O. David
Institute for Atmospheric and Climate Sciences, ETH Zurich, Zurich,
8092, Switzerland
Lin S. Boynton
Institute for Biogeochemistry and Pollutant Dynamics, ETH Zurich,
Zurich, 8092, Switzerland
Vera Weichlinger
Institute for Atmospheric and Climate Sciences, ETH Zurich, Zurich,
8092, Switzerland
Institute for Atmospheric and Climate Sciences, ETH Zurich, Zurich,
8092, Switzerland
Kristopher McNeill
Institute for Biogeochemistry and Pollutant Dynamics, ETH Zurich,
Zurich, 8092, Switzerland
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Cited
32 citations as recorded by crossref.
- Changes in tropospheric air quality related to the protection of stratospheric ozone in a changing climate S. Madronich et al. 10.1007/s43630-023-00369-6
- Atmospheric oxidation impact on sea spray produced ice nucleating particles P. DeMott et al. 10.1039/D3EA00060E
- Aging induced changes in ice nucleation activity of combustion aerosol as determined by near edge X-ray absorption fine structure (NEXAFS) spectroscopy F. Mahrt et al. 10.1039/C9EM00525K
- Fresh versus Photo-recalcitrant Secondary Organic Aerosol: Effects of Organic Mixtures on Aqueous Photodegradation of 4-Nitrophenol T. Braman et al. 10.1021/acs.estlett.0c00177
- Photochemical Production of Carbon Monoxide from Dissolved Organic Matter: Role of Lignin Methoxyarene Functional Groups R. Ossola et al. 10.1021/acs.est.2c03762
- The Urmia playa as a source of airborne dust and ice-nucleating particles – Part 2: Unraveling the relationship between soil dust composition and ice nucleation activity N. Hamzehpour et al. 10.5194/acp-22-14931-2022
- Development of the drop Freezing Ice Nuclei Counter (FINC), intercomparison of droplet freezing techniques, and use of soluble lignin as an atmospheric ice nucleation standard A. Miller et al. 10.5194/amt-14-3131-2021
- Intermolecular Interactions Enhance the Light Absorption of a Methoxyphenol Constituent of Biomass Burning Emissions C. Calvert et al. 10.1021/acsestair.4c00294
- Observational Evidence of Brown Carbon Photobleaching in Urban Atmosphere at Molecular Level Y. Qiu et al. 10.1021/acs.estlett.4c00647
- The effect of (NH4)2SO4 on the freezing properties of non-mineral dust ice-nucleating substances of atmospheric relevance S. Worthy et al. 10.5194/acp-21-14631-2021
- Molecular investigation of the multi-phase photochemistry of Fe(iii)–citrate in aqueous solution C. West et al. 10.1039/D1EM00503K
- High-speed cryo-microscopy reveals that ice-nucleating proteins of Pseudomonas syringae trigger freezing at hydrophobic interfaces P. Bieber & N. Borduas-Dedekind 10.1126/sciadv.adn6606
- Isolation of subpollen particles (SPPs) of birch: SPPs are potential carriers of ice nucleating macromolecules J. Burkart et al. 10.5194/bg-18-5751-2021
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- Spatio-temporal characteristics and source apportionment of water-soluble organic acids in PM2.5 in the North China Plain Y. Li et al. 10.1016/j.apr.2022.101540
- Lake Spray Aerosol Incorporated into Great Lakes Clouds N. Olson et al. 10.1021/acsearthspacechem.9b00258
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- Molecular-Level Study of the Photo-Oxidation of Aqueous-Phase Guaiacyl Acetone in the Presence of 3C*: Formation of Brown Carbon Products M. Misovich et al. 10.1021/acsearthspacechem.1c00103
- Atmospheric Humic‐Like Substances (HULIS) Act as Ice Active Entities J. Chen et al. 10.1029/2021GL092443
- Tracking the Photomineralization Mechanism in Irradiated Lab-Generated and Field-Collected Brown Carbon Samples and Its Effect on Cloud Condensation Nuclei Abilities S. Müller et al. 10.1021/acsenvironau.2c00055
- Triplet-state organic matter in atmospheric aerosols: Formation characteristics and potential effects on aerosol aging Q. Chen et al. 10.1016/j.atmosenv.2021.118343
- Ice Nucleation Ability of Tree Pollen Altered by Atmospheric Processing E. Gute et al. 10.1021/acsearthspacechem.0c00218
- Spatial and temporal variability in the ice-nucleating ability of alpine snowmelt and extension to frozen cloud fraction K. Brennan et al. 10.5194/acp-20-163-2020
- Role of Direct and Sensitized Photolysis in the Photomineralization of Dissolved Organic Matter and Model Chromophores to Carbon Dioxide S. Buckley et al. 10.1021/acs.est.4c01530
- The presence of nanoparticles in aqueous droplets containing plant-derived biopolymers plays a role in heterogeneous ice nucleation P. Bieber et al. 10.1063/5.0213171
- The impact of (bio-)organic substances on the ice nucleation activity of the K-feldspar microcline in aqueous solutions K. Klumpp et al. 10.5194/acp-22-3655-2022
- Macromolecular fungal ice nuclei in Fusarium: effects of physical and chemical processing A. Kunert et al. 10.5194/bg-16-4647-2019
- Export of ice-nucleating particles from watersheds: results from the Amazon and Tocantins river plumes A. Einbock et al. 10.1098/rsos.220878
- Ultraviolet Irradiation Can Increase the Light Absorption and Viscosity of Primary Brown Carbon from Biomass Burning H. Al-Mashala et al. 10.1021/acsearthspacechem.3c00155
- Photomineralization mechanism changes the ability of dissolved organic matter to activate cloud droplets and to nucleate ice crystals N. Borduas-Dedekind et al. 10.5194/acp-19-12397-2019
31 citations as recorded by crossref.
- Changes in tropospheric air quality related to the protection of stratospheric ozone in a changing climate S. Madronich et al. 10.1007/s43630-023-00369-6
- Atmospheric oxidation impact on sea spray produced ice nucleating particles P. DeMott et al. 10.1039/D3EA00060E
- Aging induced changes in ice nucleation activity of combustion aerosol as determined by near edge X-ray absorption fine structure (NEXAFS) spectroscopy F. Mahrt et al. 10.1039/C9EM00525K
- Fresh versus Photo-recalcitrant Secondary Organic Aerosol: Effects of Organic Mixtures on Aqueous Photodegradation of 4-Nitrophenol T. Braman et al. 10.1021/acs.estlett.0c00177
- Photochemical Production of Carbon Monoxide from Dissolved Organic Matter: Role of Lignin Methoxyarene Functional Groups R. Ossola et al. 10.1021/acs.est.2c03762
- The Urmia playa as a source of airborne dust and ice-nucleating particles – Part 2: Unraveling the relationship between soil dust composition and ice nucleation activity N. Hamzehpour et al. 10.5194/acp-22-14931-2022
- Development of the drop Freezing Ice Nuclei Counter (FINC), intercomparison of droplet freezing techniques, and use of soluble lignin as an atmospheric ice nucleation standard A. Miller et al. 10.5194/amt-14-3131-2021
- Intermolecular Interactions Enhance the Light Absorption of a Methoxyphenol Constituent of Biomass Burning Emissions C. Calvert et al. 10.1021/acsestair.4c00294
- Observational Evidence of Brown Carbon Photobleaching in Urban Atmosphere at Molecular Level Y. Qiu et al. 10.1021/acs.estlett.4c00647
- The effect of (NH4)2SO4 on the freezing properties of non-mineral dust ice-nucleating substances of atmospheric relevance S. Worthy et al. 10.5194/acp-21-14631-2021
- Molecular investigation of the multi-phase photochemistry of Fe(iii)–citrate in aqueous solution C. West et al. 10.1039/D1EM00503K
- High-speed cryo-microscopy reveals that ice-nucleating proteins of Pseudomonas syringae trigger freezing at hydrophobic interfaces P. Bieber & N. Borduas-Dedekind 10.1126/sciadv.adn6606
- Isolation of subpollen particles (SPPs) of birch: SPPs are potential carriers of ice nucleating macromolecules J. Burkart et al. 10.5194/bg-18-5751-2021
- Lake Spray Aerosol Emissions Alter Nitrogen Partitioning in the Great Lakes Region A. Amiri‐Farahani et al. 10.1029/2021GL093727
- Molecular level insights into the direct health impacts of some organic aerosol components F. Keshavarz 10.1039/D1NJ00231G
- Singlet oxygen is produced from brown carbon-containing cooking organic aerosols (BrCOA) under indoor lighting N. Borduas-Dedekind et al. 10.1039/D3EA00167A
- Spatio-temporal characteristics and source apportionment of water-soluble organic acids in PM2.5 in the North China Plain Y. Li et al. 10.1016/j.apr.2022.101540
- Lake Spray Aerosol Incorporated into Great Lakes Clouds N. Olson et al. 10.1021/acsearthspacechem.9b00258
- Lignin's ability to nucleate ice via immersion freezing and its stability towards physicochemical treatments and atmospheric processing S. Bogler & N. Borduas-Dedekind 10.5194/acp-20-14509-2020
- Molecular-Level Study of the Photo-Oxidation of Aqueous-Phase Guaiacyl Acetone in the Presence of 3C*: Formation of Brown Carbon Products M. Misovich et al. 10.1021/acsearthspacechem.1c00103
- Atmospheric Humic‐Like Substances (HULIS) Act as Ice Active Entities J. Chen et al. 10.1029/2021GL092443
- Tracking the Photomineralization Mechanism in Irradiated Lab-Generated and Field-Collected Brown Carbon Samples and Its Effect on Cloud Condensation Nuclei Abilities S. Müller et al. 10.1021/acsenvironau.2c00055
- Triplet-state organic matter in atmospheric aerosols: Formation characteristics and potential effects on aerosol aging Q. Chen et al. 10.1016/j.atmosenv.2021.118343
- Ice Nucleation Ability of Tree Pollen Altered by Atmospheric Processing E. Gute et al. 10.1021/acsearthspacechem.0c00218
- Spatial and temporal variability in the ice-nucleating ability of alpine snowmelt and extension to frozen cloud fraction K. Brennan et al. 10.5194/acp-20-163-2020
- Role of Direct and Sensitized Photolysis in the Photomineralization of Dissolved Organic Matter and Model Chromophores to Carbon Dioxide S. Buckley et al. 10.1021/acs.est.4c01530
- The presence of nanoparticles in aqueous droplets containing plant-derived biopolymers plays a role in heterogeneous ice nucleation P. Bieber et al. 10.1063/5.0213171
- The impact of (bio-)organic substances on the ice nucleation activity of the K-feldspar microcline in aqueous solutions K. Klumpp et al. 10.5194/acp-22-3655-2022
- Macromolecular fungal ice nuclei in Fusarium: effects of physical and chemical processing A. Kunert et al. 10.5194/bg-16-4647-2019
- Export of ice-nucleating particles from watersheds: results from the Amazon and Tocantins river plumes A. Einbock et al. 10.1098/rsos.220878
- Ultraviolet Irradiation Can Increase the Light Absorption and Viscosity of Primary Brown Carbon from Biomass Burning H. Al-Mashala et al. 10.1021/acsearthspacechem.3c00155
Latest update: 02 Apr 2025
Short summary
During atmospheric transport, dissolved organic matter (DOM) within aqueous aerosols undergoes photochemistry. We find that photochemical processing of DOM increases its ability to form cloud droplets but decreases its ability to form ice crystals over a simulated 4.6 days in the atmosphere. A photomineralization mechanism involving the loss of organic carbon and the production of organic acids, CO and CO2 explains the observed changes and affects the liquid-water-to-ice ratio in clouds.
During atmospheric transport, dissolved organic matter (DOM) within aqueous aerosols undergoes...
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