Articles | Volume 19, issue 19
https://doi.org/10.5194/acp-19-12235-2019
https://doi.org/10.5194/acp-19-12235-2019
Research article
 | 
02 Oct 2019
Research article |  | 02 Oct 2019

Controls on the water vapor isotopic composition near the surface of tropical oceans and role of boundary layer mixing processes

Camille Risi, Joseph Galewsky, Gilles Reverdin, and Florent Brient

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Cited articles

Aemisegger, F., Sturm, P., Graf, P., Sodemann, H., Pfahl, S., Knohl, A., and Wernli, H.: Measuring variations of δ18O and δ2H in atmospheric water vapour using two commercial laser-based spectrometers: an instrument characterisation study, Atmos. Meas. Tech., 5, 1491–1511, https://doi.org/10.5194/amt-5-1491-2012, 2012. a
Aggarwal, P. K., Romatschke, U., Araguas-Araguas, L., Belachew, D., Longstaffe, F. J., Berg, P., Schumacher, C., and Funk, A.: Proportions of convective and stratiform precipitation revealed in water isotope ratios, Nat. Geosci., 9, 624–629, https://doi.org/10.1038/ngeo2739, 2016. a
Bailey, A., Toohey, D., and Noone, D.: Characterizing moisture exchange between the Hawaiian convective boundary layer and free troposphere using stable isotopes in water, J. Geophys. Res.-Atmos., 118, 8208–8221, 2013. a
Benetti, M., Reverdin, G., Pierre, C., Merlivat, L., Risi, C., and Vimeux., F.: Deuterium excess in marine water vapor: Dependency on relative humidity and surface wind speed during evaporation, J. Geophys. Res, 119, 584–593, https://doi.org/10.1002/2013JD020535, 2014. a, b, c, d, e, f, g
Benetti, M., Aloisi, G., Reverdin, G., Risi, C., and Sèze, G.: Importance of boundary layer mixing for the isotopic composition of surface vapor over the subtropical North Atlantic Ocean, J. Geophys. Res.-Atmos., 120, 2190–2209, 2015. a, b, c
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Short summary
Water molecules can be light (one oxygen atom and two hydrogen atoms) or heavy (one hydrogen atom is replaced by a deuterium atom). These different molecules are called water isotopes. The isotopic composition of water vapor can potentially provide information about physical processes along the water cycle, but the factors controlling it are complex. As a first step, we propose an equation to predict the water vapor isotopic composition near the surface of tropical oceans.
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