Articles | Volume 18, issue 13
https://doi.org/10.5194/acp-18-9955-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-18-9955-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Investigating the yield of H2O and H2 from methane oxidation in the stratosphere
Deutsches Zentrum für Luft- und Raumfahrt (DLR), Institut für Physik der Atmosphäre, Oberpfaffenhofen, Germany
Patrick Jöckel
Deutsches Zentrum für Luft- und Raumfahrt (DLR), Institut für Physik der Atmosphäre, Oberpfaffenhofen, Germany
Sergey Gromov
Max-Planck-Institute for Chemistry, Air Chemistry Department, Mainz, Germany
Institute of Global Climate and Ecology Roshydromet & RAS (IGCE), Moscow, Russia
Martin Dameris
Deutsches Zentrum für Luft- und Raumfahrt (DLR), Institut für Physik der Atmosphäre, Oberpfaffenhofen, Germany
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Cited
14 citations as recorded by crossref.
- The SPARC water vapour assessment II: profile-to-profile comparisons of stratospheric and lower mesospheric water vapour data sets obtained from satellites S. Lossow et al. 10.5194/amt-12-2693-2019
- Methane chemistry in a nutshell – the new submodels CH4 (v1.0) and TRSYNC (v1.0) in MESSy (v2.54.0) F. Winterstein & P. Jöckel 10.5194/gmd-14-661-2021
- Environmental effects of stratospheric ozone depletion, UV radiation and interactions with climate change: UNEP Environmental Effects Assessment Panel, update 2019 G. Bernhard et al. 10.1039/d0pp90011g
- Stratospheric distribution of methane over a tropical region as observed by MIPAS on board ENVISAT P. Nair & M. Kavitha 10.1080/01431161.2020.1779376
- The climate impact of hydrogen-powered hypersonic transport J. Pletzer et al. 10.5194/acp-22-14323-2022
- Implication of strongly increased atmospheric methane concentrations for chemistry–climate connections F. Winterstein et al. 10.5194/acp-19-7151-2019
- How can Brewer–Dobson circulation trends be estimated from changes in stratospheric water vapour and methane? L. Poshyvailo-Strube et al. 10.5194/acp-22-9895-2022
- Multifractal Detrended Cross-Correlation Analysis of Global Methane and Temperature C. Tzanis et al. 10.3390/rs12030557
- Pursuing Truth: Improving Retrievals on Mid-infrared Exo-Earth Spectra with Physically Motivated Water Abundance Profiles and Cloud Models B. Konrad et al. 10.3847/1538-4357/ad74f7
- The SPARC water vapour assessment II: profile-to-profile and climatological comparisons of stratospheric <i>δ</i>D(H<sub>2</sub>O) observations from satellite C. Högberg et al. 10.5194/acp-19-2497-2019
- The community atmospheric chemistry box model CAABA/MECCA-4.0 R. Sander et al. 10.5194/gmd-12-1365-2019
- Slow feedbacks resulting from strongly enhanced atmospheric methane mixing ratios in a chemistry–climate model with mixed-layer ocean L. Stecher et al. 10.5194/acp-21-731-2021
- The Impact on the Ozone Layer of a Potential Fleet of Civil Hypersonic Aircraft D. Kinnison et al. 10.1029/2020EF001626
- The Runaway Greenhouse Effect on Hycean Worlds H. Innes et al. 10.3847/1538-4357/ace346
14 citations as recorded by crossref.
- The SPARC water vapour assessment II: profile-to-profile comparisons of stratospheric and lower mesospheric water vapour data sets obtained from satellites S. Lossow et al. 10.5194/amt-12-2693-2019
- Methane chemistry in a nutshell – the new submodels CH4 (v1.0) and TRSYNC (v1.0) in MESSy (v2.54.0) F. Winterstein & P. Jöckel 10.5194/gmd-14-661-2021
- Environmental effects of stratospheric ozone depletion, UV radiation and interactions with climate change: UNEP Environmental Effects Assessment Panel, update 2019 G. Bernhard et al. 10.1039/d0pp90011g
- Stratospheric distribution of methane over a tropical region as observed by MIPAS on board ENVISAT P. Nair & M. Kavitha 10.1080/01431161.2020.1779376
- The climate impact of hydrogen-powered hypersonic transport J. Pletzer et al. 10.5194/acp-22-14323-2022
- Implication of strongly increased atmospheric methane concentrations for chemistry–climate connections F. Winterstein et al. 10.5194/acp-19-7151-2019
- How can Brewer–Dobson circulation trends be estimated from changes in stratospheric water vapour and methane? L. Poshyvailo-Strube et al. 10.5194/acp-22-9895-2022
- Multifractal Detrended Cross-Correlation Analysis of Global Methane and Temperature C. Tzanis et al. 10.3390/rs12030557
- Pursuing Truth: Improving Retrievals on Mid-infrared Exo-Earth Spectra with Physically Motivated Water Abundance Profiles and Cloud Models B. Konrad et al. 10.3847/1538-4357/ad74f7
- The SPARC water vapour assessment II: profile-to-profile and climatological comparisons of stratospheric <i>δ</i>D(H<sub>2</sub>O) observations from satellite C. Högberg et al. 10.5194/acp-19-2497-2019
- The community atmospheric chemistry box model CAABA/MECCA-4.0 R. Sander et al. 10.5194/gmd-12-1365-2019
- Slow feedbacks resulting from strongly enhanced atmospheric methane mixing ratios in a chemistry–climate model with mixed-layer ocean L. Stecher et al. 10.5194/acp-21-731-2021
- The Impact on the Ozone Layer of a Potential Fleet of Civil Hypersonic Aircraft D. Kinnison et al. 10.1029/2020EF001626
- The Runaway Greenhouse Effect on Hycean Worlds H. Innes et al. 10.3847/1538-4357/ace346
Latest update: 20 Nov 2024
Short summary
It is frequently assumed that one methane molecule produces two water molecules. Applying various modeling concepts, we find that the yield of water from methane is vertically not constantly 2. In the upper stratosphere and lower mesosphere, transport of intermediate H2 molecules even led to a yield greater than 2. We conclude that for a realistic chemical source of stratospheric water vapor, one must also take other sources (H2), intermediates and the chemical removal of water into account.
It is frequently assumed that one methane molecule produces two water molecules. Applying...
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