Articles | Volume 18, issue 13
https://doi.org/10.5194/acp-18-9831-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-18-9831-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
12 Jul 2018
Research article |
| 12 Jul 2018
| 12 Jul 2018
A very limited role of tropospheric chlorine as a sink of the greenhouse gas methane
Max Planck Institute for Chemistry, Atmospheric Chemistry
Department, Mainz, Germany
Institute of Global Climate and Ecology Roshydromet & RAS (IGCE), Moscow,
Russia
Carl A. M. Brenninkmeijer
Max Planck Institute for Chemistry, Atmospheric Chemistry
Department, Mainz, Germany
Patrick Jöckel
Deutsches Zentrum für Luft- und
Raumfahrt (DLR), Institut für Physik der Atmosphäre,
Oberpfaffenhofen, Weßling, Germany
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Cited
32 citations as recorded by crossref.
- What do we know about the global methane budget? Results from four decades of atmospheric CH4observations and the way forward X. Lan et al. 10.1098/rsta.2020.0440
- Large Daytime Molecular Chlorine Missing Source at a Suburban Site in East China Q. Chen et al. 10.1029/2021JD035796
- Global and Regional CH4 Emissions for 1995–2013 Derived From Atmospheric CH4, δ13C‐CH4, and δD‐CH4 Observations and a Chemical Transport Model R. Fujita et al. 10.1029/2020JD032903
- Photocatalytic chlorine atom production on mineral dust–sea spray aerosols over the North Atlantic M. van Herpen et al. 10.1073/pnas.2303974120
- The use of δ 13C in CO to determine removal of CH4 by Cl radicals in the atmosphere * T. Röckmann et al. 10.1088/1748-9326/ad4375
- The Global Methane Budget 2000–2017 M. Saunois et al. 10.5194/essd-12-1561-2020
- Widespread detection of chlorine oxyacids in the Arctic atmosphere Y. Tham et al. 10.1038/s41467-023-37387-y
- Improved Constraints on Global Methane Emissions and Sinks Using δ13C‐CH4 X. Lan et al. 10.1029/2021GB007000
- Northern hemispheric atmospheric ethane trends in the upper troposphere and lower stratosphere (2006–2016) with reference to methane and propane M. Li et al. 10.5194/essd-14-4351-2022
- How do Cl concentrations matter for the simulation of CH4 and δ13C(CH4) and estimation of the CH4 budget through atmospheric inversions? J. Thanwerdas et al. 10.5194/acp-22-15489-2022
- DMS oxidation and sulfur aerosol formation in the marine troposphere: a focus on reactive halogen and multiphase chemistry Q. Chen et al. 10.5194/acp-18-13617-2018
- The Role of Emission Sources and Atmospheric Sink in the Seasonal Cycle of CH4 and δ13-CH4: Analysis Based on the Atmospheric Chemistry Transport Model TM5 V. Kangasaho et al. 10.3390/atmos13060888
- Impact of interannual and multidecadal trends on methane-climate feedbacks and sensitivity C. Cheng & S. Redfern 10.1038/s41467-022-31345-w
- Amazon methane budget derived from multi-year airborne observations highlights regional variations in emissions L. Basso et al. 10.1038/s43247-021-00314-4
- Primary Radical Effectiveness: Do the Different Chemical Reactivities of Hydroxyl and Chlorine Radicals Matter for Tropospheric Oxidation? P. Edwards & C. Young 10.1021/acsestair.3c00108
- Integrated Analysis of Methane Cycles and Trends at the WMO/GAW Station of Lamezia Terme (Calabria, Southern Italy) F. D’Amico et al. 10.3390/atmos15080946
- Attribution of the accelerating increase in atmospheric methane during 2010–2018 by inverse analysis of GOSAT observations Y. Zhang et al. 10.5194/acp-21-3643-2021
- On the Causes and Consequences of Recent Trends in Atmospheric Methane H. Schaefer 10.1007/s40641-019-00140-z
- Global Atmospheric δ13CH4 and CH4 Trends for 2000–2020 from the Atmospheric Transport Model TM5 Using CH4 from Carbon Tracker Europe–CH4 Inversions V. Mannisenaho et al. 10.3390/atmos14071121
- Tropospheric OH and stratospheric OH and Cl concentrations determined from CH4, CH3Cl, and SF6 measurements M. Li et al. 10.1038/s41612-018-0041-9
- Photocatalytic chloride-to-chlorine conversion by ionic iron in aqueous aerosols: a combined experimental, quantum chemical, and chemical equilibrium model study M. Mikkelsen et al. 10.5194/ar-2-31-2024
- Estimating emissions of methane consistent with atmospheric measurements of methane and δ13C of methane S. Basu et al. 10.5194/acp-22-15351-2022
- Strong sensitivity of the isotopic composition of methane to the plausible range of tropospheric chlorine S. Strode et al. 10.5194/acp-20-8405-2020
- Near-Explicit Multiphase Modeling of Halogen Chemistry in a Mixed Urban and Maritime Coastal Area E. Hoffmann et al. 10.1021/acsearthspacechem.9b00184
- The role of chlorine in global tropospheric chemistry X. Wang et al. 10.5194/acp-19-3981-2019
- Emissions from the Oil and Gas Sectors, Coal Mining and Ruminant Farming Drive Methane Growth over the Past Three Decades N. CHANDRA et al. 10.2151/jmsj.2021-015
- Methane emissions decreased in fossil fuel exploitation and sustainably increased in microbial source sectors during 1990–2020 N. Chandra et al. 10.1038/s43247-024-01286-x
- Trends in global tropospheric hydroxyl radical and methane lifetime since 1850 from AerChemMIP D. Stevenson et al. 10.5194/acp-20-12905-2020
- Isotopic Signatures of Methane Emissions From Dairy Farms in California’s San Joaquin Valley V. Carranza et al. 10.1029/2021JG006675
- Reactive halogens increase the global methane lifetime and radiative forcing in the 21st century Q. Li et al. 10.1038/s41467-022-30456-8
- Global tropospheric halogen (Cl, Br, I) chemistry and its impact on oxidants X. Wang et al. 10.5194/acp-21-13973-2021
- Investigation of the global methane budget over 1980–2017 using GFDL-AM4.1 J. He et al. 10.5194/acp-20-805-2020
32 citations as recorded by crossref.
- What do we know about the global methane budget? Results from four decades of atmospheric CH4observations and the way forward X. Lan et al. 10.1098/rsta.2020.0440
- Large Daytime Molecular Chlorine Missing Source at a Suburban Site in East China Q. Chen et al. 10.1029/2021JD035796
- Global and Regional CH4 Emissions for 1995–2013 Derived From Atmospheric CH4, δ13C‐CH4, and δD‐CH4 Observations and a Chemical Transport Model R. Fujita et al. 10.1029/2020JD032903
- Photocatalytic chlorine atom production on mineral dust–sea spray aerosols over the North Atlantic M. van Herpen et al. 10.1073/pnas.2303974120
- The use of δ 13C in CO to determine removal of CH4 by Cl radicals in the atmosphere * T. Röckmann et al. 10.1088/1748-9326/ad4375
- The Global Methane Budget 2000–2017 M. Saunois et al. 10.5194/essd-12-1561-2020
- Widespread detection of chlorine oxyacids in the Arctic atmosphere Y. Tham et al. 10.1038/s41467-023-37387-y
- Improved Constraints on Global Methane Emissions and Sinks Using δ13C‐CH4 X. Lan et al. 10.1029/2021GB007000
- Northern hemispheric atmospheric ethane trends in the upper troposphere and lower stratosphere (2006–2016) with reference to methane and propane M. Li et al. 10.5194/essd-14-4351-2022
- How do Cl concentrations matter for the simulation of CH4 and δ13C(CH4) and estimation of the CH4 budget through atmospheric inversions? J. Thanwerdas et al. 10.5194/acp-22-15489-2022
- DMS oxidation and sulfur aerosol formation in the marine troposphere: a focus on reactive halogen and multiphase chemistry Q. Chen et al. 10.5194/acp-18-13617-2018
- The Role of Emission Sources and Atmospheric Sink in the Seasonal Cycle of CH4 and δ13-CH4: Analysis Based on the Atmospheric Chemistry Transport Model TM5 V. Kangasaho et al. 10.3390/atmos13060888
- Impact of interannual and multidecadal trends on methane-climate feedbacks and sensitivity C. Cheng & S. Redfern 10.1038/s41467-022-31345-w
- Amazon methane budget derived from multi-year airborne observations highlights regional variations in emissions L. Basso et al. 10.1038/s43247-021-00314-4
- Primary Radical Effectiveness: Do the Different Chemical Reactivities of Hydroxyl and Chlorine Radicals Matter for Tropospheric Oxidation? P. Edwards & C. Young 10.1021/acsestair.3c00108
- Integrated Analysis of Methane Cycles and Trends at the WMO/GAW Station of Lamezia Terme (Calabria, Southern Italy) F. D’Amico et al. 10.3390/atmos15080946
- Attribution of the accelerating increase in atmospheric methane during 2010–2018 by inverse analysis of GOSAT observations Y. Zhang et al. 10.5194/acp-21-3643-2021
- On the Causes and Consequences of Recent Trends in Atmospheric Methane H. Schaefer 10.1007/s40641-019-00140-z
- Global Atmospheric δ13CH4 and CH4 Trends for 2000–2020 from the Atmospheric Transport Model TM5 Using CH4 from Carbon Tracker Europe–CH4 Inversions V. Mannisenaho et al. 10.3390/atmos14071121
- Tropospheric OH and stratospheric OH and Cl concentrations determined from CH4, CH3Cl, and SF6 measurements M. Li et al. 10.1038/s41612-018-0041-9
- Photocatalytic chloride-to-chlorine conversion by ionic iron in aqueous aerosols: a combined experimental, quantum chemical, and chemical equilibrium model study M. Mikkelsen et al. 10.5194/ar-2-31-2024
- Estimating emissions of methane consistent with atmospheric measurements of methane and δ13C of methane S. Basu et al. 10.5194/acp-22-15351-2022
- Strong sensitivity of the isotopic composition of methane to the plausible range of tropospheric chlorine S. Strode et al. 10.5194/acp-20-8405-2020
- Near-Explicit Multiphase Modeling of Halogen Chemistry in a Mixed Urban and Maritime Coastal Area E. Hoffmann et al. 10.1021/acsearthspacechem.9b00184
- The role of chlorine in global tropospheric chemistry X. Wang et al. 10.5194/acp-19-3981-2019
- Emissions from the Oil and Gas Sectors, Coal Mining and Ruminant Farming Drive Methane Growth over the Past Three Decades N. CHANDRA et al. 10.2151/jmsj.2021-015
- Methane emissions decreased in fossil fuel exploitation and sustainably increased in microbial source sectors during 1990–2020 N. Chandra et al. 10.1038/s43247-024-01286-x
- Trends in global tropospheric hydroxyl radical and methane lifetime since 1850 from AerChemMIP D. Stevenson et al. 10.5194/acp-20-12905-2020
- Isotopic Signatures of Methane Emissions From Dairy Farms in California’s San Joaquin Valley V. Carranza et al. 10.1029/2021JG006675
- Reactive halogens increase the global methane lifetime and radiative forcing in the 21st century Q. Li et al. 10.1038/s41467-022-30456-8
- Global tropospheric halogen (Cl, Br, I) chemistry and its impact on oxidants X. Wang et al. 10.5194/acp-21-13973-2021
- Investigation of the global methane budget over 1980–2017 using GFDL-AM4.1 J. He et al. 10.5194/acp-20-805-2020
Latest update: 24 Dec 2024
Short summary
Using the observational data on 13C (CO) and 13C (CH4) from the extra-tropical Southern Hemisphere (ETSH) and EMAC model we (1) provide an independent, observation-based evaluation of Cl atom concentration variations in the ETSH throughout 1994–2000, (2) show that the role of tropospheric Cl as a sink of CH4 is seriously overestimated in the literature, (3) demonstrate that the 13C/12C ratio of CO is a sensitive indicator for the isotopic composition of reacted CH4 and therefore for its sources.
Using the observational data on 13C (CO) and 13C (CH4) from the extra-tropical Southern...
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