Articles | Volume 18, issue 11
https://doi.org/10.5194/acp-18-8001-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-18-8001-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
07 Jun 2018
Research article |
| 07 Jun 2018
| 07 Jun 2018
Investigation of the oxidation of methyl vinyl ketone (MVK) by OH radicals in the atmospheric simulation chamber SAPHIR
Institute of Energy and Climate Research, IEK-8: Troposphere, Forschungszentrum Jülich GmbH, Jülich, Germany
Sascha Albrecht
Institute of Energy and Climate Research, IEK-8: Troposphere, Forschungszentrum Jülich GmbH, Jülich, Germany
Ismail–Hakki Acir
Institute of Energy and Climate Research, IEK-8: Troposphere, Forschungszentrum Jülich GmbH, Jülich, Germany
now at: Institute of Nutrition and Food Sciences, Food Chemistry, University of Bonn, Germany
Birger Bohn
Institute of Energy and Climate Research, IEK-8: Troposphere, Forschungszentrum Jülich GmbH, Jülich, Germany
Martin Breitenlechner
School of Engineering and Applied Sciences and Department of Chemistry and Chemical Biology, Harvard University, Cambridge, MA, USA
Hans-Peter Dorn
Institute of Energy and Climate Research, IEK-8: Troposphere, Forschungszentrum Jülich GmbH, Jülich, Germany
Georgios I. Gkatzelis
Institute of Energy and Climate Research, IEK-8: Troposphere, Forschungszentrum Jülich GmbH, Jülich, Germany
Andreas Hofzumahaus
Institute of Energy and Climate Research, IEK-8: Troposphere, Forschungszentrum Jülich GmbH, Jülich, Germany
Frank Holland
Institute of Energy and Climate Research, IEK-8: Troposphere, Forschungszentrum Jülich GmbH, Jülich, Germany
Martin Kaminski
Institute of Energy and Climate Research, IEK-8: Troposphere, Forschungszentrum Jülich GmbH, Jülich, Germany
now at: Bundesamt für Verbraucherschutz, Abteilung 5 – Methodenstandardisierung, Berlin, Germany
Frank N. Keutsch
School of Engineering and Applied Sciences and Department of Chemistry and Chemical Biology, Harvard University, Cambridge, MA, USA
Anna Novelli
Institute of Energy and Climate Research, IEK-8: Troposphere, Forschungszentrum Jülich GmbH, Jülich, Germany
David Reimer
Institute of Energy and Climate Research, IEK-8: Troposphere, Forschungszentrum Jülich GmbH, Jülich, Germany
Franz Rohrer
Institute of Energy and Climate Research, IEK-8: Troposphere, Forschungszentrum Jülich GmbH, Jülich, Germany
Ralf Tillmann
Institute of Energy and Climate Research, IEK-8: Troposphere, Forschungszentrum Jülich GmbH, Jülich, Germany
Luc Vereecken
Institute of Energy and Climate Research, IEK-8: Troposphere, Forschungszentrum Jülich GmbH, Jülich, Germany
Robert Wegener
Institute of Energy and Climate Research, IEK-8: Troposphere, Forschungszentrum Jülich GmbH, Jülich, Germany
Alexander Zaytsev
School of Engineering and Applied Sciences and Department of Chemistry and Chemical Biology, Harvard University, Cambridge, MA, USA
Astrid Kiendler-Scharr
Institute of Energy and Climate Research, IEK-8: Troposphere, Forschungszentrum Jülich GmbH, Jülich, Germany
Andreas Wahner
Institute of Energy and Climate Research, IEK-8: Troposphere, Forschungszentrum Jülich GmbH, Jülich, Germany
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Cited
18 citations as recorded by crossref.
- Experimental and theoretical study on the impact of a nitrate group on the chemistry of alkoxy radicals A. Novelli et al. 10.1039/D0CP05555G
- Sources of methacrolein and methyl vinyl ketone and their contributions to methylglyoxal and formaldehyde at a receptor site in Pearl River Delta Z. Ling et al. 10.1016/j.jes.2018.12.001
- Atmospheric oxidation of <i>α</i>,<i>β</i>-unsaturated ketones: kinetics and mechanism of the OH radical reaction N. Illmann et al. 10.5194/acp-21-13667-2021
- Experimental chemical budgets of OH, HO2, and RO2 radicals in rural air in western Germany during the JULIAC campaign 2019 C. Cho et al. 10.5194/acp-23-2003-2023
- On the photolysis branching ratio of methyl ethyl ketone A. Zborowska et al. 10.1016/j.atmosenv.2021.118383
- Photooxidation of pinonaldehyde at ambient conditions investigated in the atmospheric simulation chamber SAPHIR M. Rolletter et al. 10.5194/acp-20-13701-2020
- Theoretical exploration of new particle formation from glycol aldehyde in the atmosphere – A temperature-dependent study K. Shashikala et al. 10.1016/j.comptc.2023.114057
- OH measurements in the coastal atmosphere of South China: possible missing OH sinks in aged air masses Z. Zou et al. 10.5194/acp-23-7057-2023
- Theoretical Spectroscopic Study of Two Ketones of Atmospheric Interest: Methyl Glyoxal (CH3COCHO) and Methyl Vinyl Ketone (CH3COCH═CH2) I. Toumi et al. 10.1021/acs.jpca.2c05653
- Experimental budgets of OH, HO<sub>2</sub>, and RO<sub>2</sub> radicals and implications for ozone formation in the Pearl River Delta in China 2014 Z. Tan et al. 10.5194/acp-19-7129-2019
- Kinetic Study of OH Radical Reactions with Cyclopentenone Derivatives P. Rutto et al. 10.1021/acs.jpca.4c04060
- Reaction Rate Coefficient of OH Radicals with d9-Butanol as a Function of Temperature A. Allani et al. 10.1021/acsomega.1c01942
- Atmospheric photo-oxidation of myrcene: OH reaction rate constant, gas-phase oxidation products and radical budgets Z. Tan et al. 10.5194/acp-21-16067-2021
- H migration in peroxy radicals under atmospheric conditions L. Vereecken & B. Nozière 10.5194/acp-20-7429-2020
- Characterization of a chemical modulation reactor (CMR) for the measurement of atmospheric concentrations of hydroxyl radicals with a laser-induced fluorescence instrument C. Cho et al. 10.5194/amt-14-1851-2021
- Radical chemistry in the Pearl River Delta: observations and modeling of OH and HO2 radicals in Shenzhen in 2018 X. Yang et al. 10.5194/acp-22-12525-2022
- Implementation of a chemical background method for atmospheric OH measurements by laser-induced fluorescence: characterisation and observations from the UK and China R. Woodward-Massey et al. 10.5194/amt-13-3119-2020
- Theoretical and experimental study of peroxy and alkoxy radicals in the NO3-initiated oxidation of isoprene L. Vereecken et al. 10.1039/D0CP06267G
18 citations as recorded by crossref.
- Experimental and theoretical study on the impact of a nitrate group on the chemistry of alkoxy radicals A. Novelli et al. 10.1039/D0CP05555G
- Sources of methacrolein and methyl vinyl ketone and their contributions to methylglyoxal and formaldehyde at a receptor site in Pearl River Delta Z. Ling et al. 10.1016/j.jes.2018.12.001
- Atmospheric oxidation of <i>α</i>,<i>β</i>-unsaturated ketones: kinetics and mechanism of the OH radical reaction N. Illmann et al. 10.5194/acp-21-13667-2021
- Experimental chemical budgets of OH, HO2, and RO2 radicals in rural air in western Germany during the JULIAC campaign 2019 C. Cho et al. 10.5194/acp-23-2003-2023
- On the photolysis branching ratio of methyl ethyl ketone A. Zborowska et al. 10.1016/j.atmosenv.2021.118383
- Photooxidation of pinonaldehyde at ambient conditions investigated in the atmospheric simulation chamber SAPHIR M. Rolletter et al. 10.5194/acp-20-13701-2020
- Theoretical exploration of new particle formation from glycol aldehyde in the atmosphere – A temperature-dependent study K. Shashikala et al. 10.1016/j.comptc.2023.114057
- OH measurements in the coastal atmosphere of South China: possible missing OH sinks in aged air masses Z. Zou et al. 10.5194/acp-23-7057-2023
- Theoretical Spectroscopic Study of Two Ketones of Atmospheric Interest: Methyl Glyoxal (CH3COCHO) and Methyl Vinyl Ketone (CH3COCH═CH2) I. Toumi et al. 10.1021/acs.jpca.2c05653
- Experimental budgets of OH, HO<sub>2</sub>, and RO<sub>2</sub> radicals and implications for ozone formation in the Pearl River Delta in China 2014 Z. Tan et al. 10.5194/acp-19-7129-2019
- Kinetic Study of OH Radical Reactions with Cyclopentenone Derivatives P. Rutto et al. 10.1021/acs.jpca.4c04060
- Reaction Rate Coefficient of OH Radicals with d9-Butanol as a Function of Temperature A. Allani et al. 10.1021/acsomega.1c01942
- Atmospheric photo-oxidation of myrcene: OH reaction rate constant, gas-phase oxidation products and radical budgets Z. Tan et al. 10.5194/acp-21-16067-2021
- H migration in peroxy radicals under atmospheric conditions L. Vereecken & B. Nozière 10.5194/acp-20-7429-2020
- Characterization of a chemical modulation reactor (CMR) for the measurement of atmospheric concentrations of hydroxyl radicals with a laser-induced fluorescence instrument C. Cho et al. 10.5194/amt-14-1851-2021
- Radical chemistry in the Pearl River Delta: observations and modeling of OH and HO2 radicals in Shenzhen in 2018 X. Yang et al. 10.5194/acp-22-12525-2022
- Implementation of a chemical background method for atmospheric OH measurements by laser-induced fluorescence: characterisation and observations from the UK and China R. Woodward-Massey et al. 10.5194/amt-13-3119-2020
- Theoretical and experimental study of peroxy and alkoxy radicals in the NO3-initiated oxidation of isoprene L. Vereecken et al. 10.1039/D0CP06267G
Latest update: 25 Dec 2024
Short summary
The photooxidation of methyl vinyl ketone MVK, one of the most important products of isoprene that is emitted by plants, was investigated in the atmospheric simulation chamber SAPHIR for conditions found in forested areas. The comparison of measured trace gas time series with model calculations shows a gap in the understanding of radical chemistry in the MVK oxidation scheme. The possibility of unimolecular isomerization reactions were investigated by means of quantum-chemical calculations.
The photooxidation of methyl vinyl ketone MVK, one of the most important products of isoprene...
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