Articles | Volume 18, issue 9
https://doi.org/10.5194/acp-18-6331-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-18-6331-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Predicting the glass transition temperature and viscosity of secondary organic material using molecular composition
Wing-Sy Wong DeRieux
Department of Chemistry, University of California, Irvine, CA
92697-2025, USA
Department of Chemistry, University of California, Irvine, CA
92697-2025, USA
Department of Chemistry, Purdue University, West Lafayette, IN
47907-2084, USA
Julia Laskin
Department of Chemistry, Purdue University, West Lafayette, IN
47907-2084, USA
Alexander Laskin
Department of Chemistry, Purdue University, West Lafayette, IN
47907-2084, USA
Allan K. Bertram
Department of Chemistry, University of British Columbia, Vancouver, BC
V6T 1Z1, Canada
Sergey A. Nizkorodov
Department of Chemistry, University of California, Irvine, CA
92697-2025, USA
Department of Chemistry, University of California, Irvine, CA
92697-2025, USA
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- Humidity-Dependent Viscosity of Secondary Organic Aerosol from Ozonolysis of β-Caryophyllene: Measurements, Predictions, and Implications A. Maclean et al. 10.1021/acsearthspacechem.0c00296
- Modeling the Effects of Dimerization and Bulk Diffusion on the Evaporative Behavior of Secondary Organic Aerosol Formed from α-Pinene and 1,3,5-Trimethylbenzene Y. Morino et al. 10.1021/acsearthspacechem.0c00106
- Isomer-Resolved Reactivity of Organic Peroxides in Monoterpene-Derived Secondary Organic Aerosol M. Yao et al. 10.1021/acs.est.2c01297
- Effects of Phase State and Phase Separation on Dimethylamine Uptake of Ammonium Sulfate and Ammonium Sulfate–Sucrose Mixed Particles W. DeRieux et al. 10.1021/acsearthspacechem.9b00142
- Emerging investigator series: heterogeneous OH oxidation of primary brown carbon aerosol: effects of relative humidity and volatility E. Schnitzler et al. 10.1039/D0EM00311E
- Emerging investigator series: deposited particles and human lung lining fluid are dynamic, chemically-complex reservoirs leading to thirdhand smoke emissions and exposure R. Sheu et al. 10.1039/D1EA00107H
- Modeling the Impact of the Organic Aerosol Phase State on Multiphase OH Reactive Uptake Kinetics and the Resultant Heterogeneous Oxidation Timescale of Organic Aerosol in the Amazon Rainforest Q. Rasool et al. 10.1021/acsearthspacechem.2c00366
- Simulated phase state and viscosity of secondary organic aerosols over China Z. Zhang et al. 10.5194/acp-24-4809-2024
- Heterogeneous oxidation of amorphous organic aerosol surrogates by O<sub>3</sub>, NO<sub>3</sub>, and OH at typical tropospheric temperatures J. Li et al. 10.5194/acp-20-6055-2020
- Seeded Crystal Growth of Internally Mixed Organic–Inorganic Aerosols: Impact of Organic Phase State S. Ushijima et al. 10.1021/acs.jpca.1c04471
- Molecular and Structural Characterization of Isomeric Compounds in Atmospheric Organic Aerosol Using Ion Mobility-Mass Spectrometry C. West et al. 10.1021/acs.jpca.2c06459
- Extreme Molecular Complexity Resulting in a Continuum of Carbonaceous Species in Biomass Burning Tar Balls from Wildfire Smoke M. Brege et al. 10.1021/acsearthspacechem.1c00141
- Molecular Characterization of Organosulfate-Dominated Aerosols over Agricultural Fields from the Southern Great Plains by High-Resolution Mass Spectrometry G. Vandergrift et al. 10.1021/acsearthspacechem.2c00043
- Molecular Insights into Gas–Particle Partitioning and Viscosity of Atmospheric Brown Carbon Q. Xie et al. 10.1021/acs.est.4c05650
- Diversity of organic components in airborne waste discharged from sewer pipe repairs A. Morales et al. 10.1039/D3EM00084B
- Particle Size Distribution Dynamics Can Help Constrain the Phase State of Secondary Organic Aerosol Y. He et al. 10.1021/acs.est.0c05796
- The effects of morphology, mobility size, and secondary organic aerosol (SOA) material coating on the ice nucleation activity of black carbon in the cirrus regime C. Zhang et al. 10.5194/acp-20-13957-2020
- Volatility Basis Set Distributions and Viscosity of Organic Aerosol Mixtures: Insights from Chemical Characterization Using Temperature-Programmed Desorption–Direct Analysis in Real-Time High-Resolution Mass Spectrometry Q. Xie et al. 10.1021/acs.analchem.4c01003
- Representation of Multiphase OH Oxidation of Amorphous Organic Aerosol for Tropospheric Conditions J. Li & D. Knopf 10.1021/acs.est.0c07668
- Bouncier Particles at Night: Biogenic Secondary Organic Aerosol Chemistry and Sulfate Drive Diel Variations in the Aerosol Phase in a Mixed Forest J. Slade et al. 10.1021/acs.est.8b07319
- Volatility and Viscosity Are Correlated in Terpene Secondary Organic Aerosol Formed in a Flow Reactor W. Champion et al. 10.1021/acs.estlett.9b00412
- Immersion ice nucleation of atmospherically relevant lipid particles L. Mehndiratta et al. 10.1039/D4EA00066H
- Understanding functionality of sucrose in cake for reformulation purposes R. van der Sman & S. Renzetti 10.1080/10408398.2020.1786003
- Glyoxal as a Potential Source of Highly Viscous Aerosol Particles J. Peters et al. 10.1021/acsearthspacechem.1c00245
- Heterogeneous and Photosensitized Oxidative Degradation Kinetics of the Plastic Additive Bisphenol-A in Sea Spray Aerosol Mimics S. Kruse & J. Slade 10.1021/acs.jpca.3c00127
- Molecular and physical composition of tar balls in wildfire smoke: an investigation with complementary ionisation methods and 15-Tesla FT-ICR mass spectrometry A. Ijaz et al. 10.1039/D3EA00085K
- The Cooling Rate- and Volatility-Dependent Glass-Forming Properties of Organic Aerosols Measured by Broadband Dielectric Spectroscopy Y. Zhang et al. 10.1021/acs.est.9b03317
- Effect of acid proticity on the thermodynamic parameters of charge transfer resistance in corrosion and passivation of nickel based glass alloy K. Emran & N. Ouerfelli 10.1038/s41598-024-52036-0
- Effects of Photolysis on the Chemical and Optical Properties of Secondary Organic Material Over Extended Time Scales E. Walhout et al. 10.1021/acsearthspacechem.9b00109
- A comprehensive evaluation of enhanced temperature influence on gas and aerosol chemistry in the lamp-enclosed oxidation flow reactor (OFR) system T. Pan et al. 10.5194/amt-17-4915-2024
- Liquid–liquid phase separation and viscosity within secondary organic aerosol generated from diesel fuel vapors M. Song et al. 10.5194/acp-19-12515-2019
- Single particle measurements of mixing between mimics for biomass burning and aged secondary organic aerosols L. Habib & N. Donahue 10.1039/D2EA00017B
- Secondary Organic Aerosol from OH-Initiated Oxidation of Mixtures of d-Limonene and β-Myrcene S. Liu et al. 10.1021/acs.est.4c04870
- A predictive group-contribution model for the viscosity of aqueous organic aerosol N. Gervasi et al. 10.5194/acp-20-2987-2020
- Investigating the Heterogeneous Ice Nucleation of Sea Spray Aerosols Using Prochlorococcus as a Model Source of Marine Organic Matter M. Wolf et al. 10.1021/acs.est.8b05150
- Decreasing the Uncertainty in the Comparison of Molecular Fingerprints of Organic Aerosols with H/D Exchange Mass Spectrometry A. Zherebker et al. 10.1021/acs.est.4c06749
- Indoor aerosol water content and phase state in U.S. residences: impacts of relative humidity, aerosol mass and composition, and mechanical system operation B. Cummings et al. 10.1039/D0EM00122H
- Opinion: Atmospheric multiphase chemistry – past, present, and future J. Abbatt & A. Ravishankara 10.5194/acp-23-9765-2023
- Comparing secondary organic aerosol (SOA) volatility distributions derived from isothermal SOA particle evaporation data and FIGAERO–CIMS measurements O. Tikkanen et al. 10.5194/acp-20-10441-2020
- Chemical characterization of microplastic particles formed in airborne waste discharged from sewer pipe repairs B. Peterson et al. 10.1039/D3EM00193H
- Impact of aging on the sources, volatility, and viscosity of organic aerosols in Chinese outflows T. Feng et al. 10.5194/acp-23-611-2023
- Applying a Phase-Separation Parameterization in Modeling Secondary Organic Aerosol Formation from Acid-Driven Reactive Uptake of Isoprene Epoxydiols under Humid Conditions Y. Chen et al. 10.1021/acsestair.4c00002
- Relationship between Structure, Functionality, and Viscosity for Aerosol-Mimicking Solutions Containing Ammonium Sulfate, Glyoxal, and a Series of Oxidized C1–C5 Compounds E. Gubbins et al. 10.1021/acsearthspacechem.9b00119
- Estimation of secondary organic aerosol viscosity from explicit modeling of gas-phase oxidation of isoprene and <i>α</i>-pinene T. Galeazzo et al. 10.5194/acp-21-10199-2021
- Emerging investigator series: secondary organic aerosol formation from photooxidation of acyclic terpenes in an oxidation flow reactor S. Gu et al. 10.1039/D4EM00063C
- Formation of MoO3/Organic Interfaces Y. Wu et al. 10.1002/admi.202101423
- Radical chemistry in oxidation flow reactors for atmospheric chemistry research Z. Peng & J. Jimenez 10.1039/C9CS00766K
- Suppressed atmospheric chemical aging of cooking organic aerosol particles in wintertime conditions W. Liu et al. 10.5194/acp-24-5625-2024
- Emerging investigator series: chemical and physical properties of organic mixtures on indoor surfaces during HOMEChem R. O'Brien et al. 10.1039/D1EM00060H
- Viscosity and liquid–liquid phase separation in healthy and stressed plant SOA N. Smith et al. 10.1039/D0EA00020E
- Non-linear effects of secondary organic aerosol formation and properties in multi-precursor systems M. Takeuchi et al. 10.1038/s41467-022-35546-1
- Molecular Understanding of the Enhancement in Organic Aerosol Mass at High Relative Humidity M. Surdu et al. 10.1021/acs.est.2c04587
- A new aerosol flow reactor to study secondary organic aerosol K. Pereira et al. 10.5194/amt-12-4519-2019
- Machine-Learning-Based Prediction of the Glass Transition Temperature of Organic Compounds Using Experimental Data G. Armeli et al. 10.1021/acsomega.2c08146
- Efficiency Roll-off Suppression in Solution-Processed Organic Light-Emitting Diodes through a Bipolar Host Design T. Le et al. 10.1021/acsmaterialslett.3c01334
- Effects of Molecular-Level Compositional Variability in Organic Aerosol on Phase State and Thermodynamic Mixing Behavior J. Ditto et al. 10.1021/acs.est.9b02664
- Viscosity and physical state of sucrose mixed with ammonium sulfate droplets R. Jeong et al. 10.5194/acp-22-8805-2022
- Accurate Prediction of Organic Aerosol Evaporation Using Kinetic Multilayer Modeling and the Stokes–Einstein Equation S. Ingram et al. 10.1021/acs.jpca.1c00986
- Joint Impacts of Acidity and Viscosity on the Formation of Secondary Organic Aerosol from Isoprene Epoxydiols (IEPOX) in Phase Separated Particles Y. Zhang et al. 10.1021/acsearthspacechem.9b00209
- Nonequilibrium Behavior in Isoprene Secondary Organic Aerosol Y. Chen et al. 10.1021/acs.est.3c03532
- Atmospheric evolution of emissions from a boreal forest fire: the formation of highly functionalized oxygen-, nitrogen-, and sulfur-containing organic compounds J. Ditto et al. 10.5194/acp-21-255-2021
- Phase Behavior and Viscosity in Biomass Burning Organic Aerosol and Climatic Impacts F. Gregson et al. 10.1021/acs.est.3c03231
- Predicting the influence of particle size on the glass transition temperature and viscosity of secondary organic material M. Petters & S. Kasparoglu 10.1038/s41598-020-71490-0
- Secondary organic aerosols derived from intermediate-volatility n-alkanes adopt low-viscous phase state T. Galeazzo et al. 10.5194/acp-24-5549-2024
- Reactive Uptake of Isoprene Epoxydiols Increases the Viscosity of the Core of Phase-Separated Aerosol Particles N. Olson et al. 10.1021/acsearthspacechem.9b00138
- Chemical characterization of biomass pyrolysis oil facilitated by aerosolization and size separation E. Halpern et al. 10.1080/02786826.2023.2254355
- Molecular and physical characteristics of aerosol at a remote free troposphere site: implications for atmospheric aging S. Schum et al. 10.5194/acp-18-14017-2018
- Size Dependence of Organic/Inorganic Aerosol Morphology and the Role of Oxidation and Aromaticity of the Organic Component E. Tackman et al. 10.1021/acsestair.3c00099
- Molecular Dynamics and Near-Tg Phenomena of Cyclic Thioethers H. Hellwig et al. 10.3390/ijms242417166
- A biogenic secondary organic aerosol source of cirrus ice nucleating particles M. Wolf et al. 10.1038/s41467-020-18424-6
- Diurnal and Seasonal Variations in the Phase State of Secondary Organic Aerosol Material over the Contiguous US Simulated in CMAQ Y. Li et al. 10.1021/acsearthspacechem.1c00094
- Vapors Are Lost to Walls, Not to Particles on the Wall: Artifact-Corrected Parameters from Chamber Experiments and Implications for Global Secondary Organic Aerosol K. Bilsback et al. 10.1021/acs.est.2c03967
- Effects of Organic Matrices on Nucleophilic Aqueous Aerosol Chemistry: Yields and Mechanistic Insight for Brown Carbon Formation from Glyoxal and Ammonia G. Drozd et al. 10.1021/acsearthspacechem.2c00068
- Increasing Isoprene Epoxydiol-to-Inorganic Sulfate Aerosol Ratio Results in Extensive Conversion of Inorganic Sulfate to Organosulfur Forms: Implications for Aerosol Physicochemical Properties M. Riva et al. 10.1021/acs.est.9b01019
- Kinetic modeling of formation and evaporation of secondary organic aerosol from NO<sub>3</sub> oxidation of pure and mixed monoterpenes T. Berkemeier et al. 10.5194/acp-20-15513-2020
- Direct target and non-target analysis of urban aerosol sample extracts using atmospheric pressure photoionisation high-resolution mass spectrometry C. Giorio et al. 10.1016/j.chemosphere.2019.02.151
- Predicting secondary organic aerosol phase state and viscosity and its effect on multiphase chemistry in a regional-scale air quality model R. Schmedding et al. 10.5194/acp-20-8201-2020
- Predicting glass transition temperature and melting point of organic compounds via machine learning and molecular embeddings T. Galeazzo & M. Shiraiwa 10.1039/D1EA00090J
- The particle phase state during the biomass burning events Y. Liu et al. 10.1016/j.scitotenv.2021.148035
- Modelling consortium for chemistry of indoor environments (MOCCIE): integrating chemical processes from molecular to room scales M. Shiraiwa et al. 10.1039/C9EM00123A
- Timescales of secondary organic aerosols to reach equilibrium at various temperatures and relative humidities Y. Li & M. Shiraiwa 10.5194/acp-19-5959-2019
- Light Absorption and Chemical Composition of Brown Carbon Organic Aerosol Produced from Burning of Selected Biofuels K. Siemens et al. 10.1021/acsearthspacechem.4c00056
- Chemical Composition and Molecular-Specific Optical Properties of Atmospheric Brown Carbon Associated with Biomass Burning A. Hettiyadura et al. 10.1021/acs.est.0c05883
- Organic aerosol volatility and viscosity in the North China Plain: contrast between summer and winter W. Xu et al. 10.5194/acp-21-5463-2021
- Structure – Glass transition temperature relationship for non-polymeric molecules: The concept of internal plasticizing effect A. Nowok et al. 10.1016/j.molliq.2024.124222
- Enhanced Light Absorption and Elevated Viscosity of Atmospheric Brown Carbon through Evaporation of Volatile Components D. Calderon-Arrieta et al. 10.1021/acs.est.3c10184
- Toward closure between predicted and observed particle viscosity over a wide range of temperatures and relative humidity S. Kasparoglu et al. 10.5194/acp-21-1127-2021
- Glass Transition Temperatures of Individual Submicrometer Atmospheric Particles: Direct Measurement via Heated Atomic Force Microscopy Probe Z. Lei et al. 10.1021/acs.analchem.2c01979
- The effect of functional groups on the glass transition temperature of atmospheric organic compounds: a molecular dynamics study P. Siachouli et al. 10.1039/D4SM00405A
- Predicting Atmospheric Particle Phase State Using an Explainable Machine Learning Approach Based on Particle Rebound Measurements Y. Qiu et al. 10.1021/acs.est.3c05284
- The atmospheric chemistry of indoor environments J. Abbatt & C. Wang 10.1039/C9EM00386J
- A Near-Explicit Mechanistic Evaluation of Isoprene Photochemical Secondary Organic Aerosol Formation and Evolution: Simulations of Multiple Chamber Experiments with and without Added NOx J. Thornton et al. 10.1021/acsearthspacechem.0c00118
- Estimating mean molecular weight, carbon number, and OM∕OC with mid-infrared spectroscopy in organic particulate matter samples from a monitoring network A. Yazdani et al. 10.5194/amt-14-4805-2021
- Condensation Kinetics of Water on Amorphous Aerosol Particles N. Rothfuss et al. 10.1021/acs.jpclett.8b01365
- Partitioning of secondary organic aerosol onto nanoplastics leading to hygroscopic partially-engulfed particles K. Raincrow et al. 10.1039/D3EA00103B
- Modeling the molecular composition of secondary organic aerosol under highly polluted conditions: A case study in the Yangtze River Delta Region in China Q. Huang et al. 10.1016/j.scitotenv.2024.173327
Discussed (final revised paper)
Latest update: 20 Nov 2024
Short summary
The phase transition of organic particles between glassy and semi-solid states occurs at the glass transition temperature. We developed a method to predict glass transition temperatures and the viscosity of secondary organic aerosols using molecular composition, with consistent results with viscosity measurements. The viscosity of biomass burning particles was also estimated using the chemical composition measured by high-resolution mass spectrometry with two different ionization techniques.
The phase transition of organic particles between glassy and semi-solid states occurs at the...
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