Articles | Volume 18, issue 9
https://doi.org/10.5194/acp-18-6331-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-18-6331-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Predicting the glass transition temperature and viscosity of secondary organic material using molecular composition
Wing-Sy Wong DeRieux
Department of Chemistry, University of California, Irvine, CA
92697-2025, USA
Department of Chemistry, University of California, Irvine, CA
92697-2025, USA
Department of Chemistry, Purdue University, West Lafayette, IN
47907-2084, USA
Julia Laskin
Department of Chemistry, Purdue University, West Lafayette, IN
47907-2084, USA
Alexander Laskin
Department of Chemistry, Purdue University, West Lafayette, IN
47907-2084, USA
Allan K. Bertram
Department of Chemistry, University of British Columbia, Vancouver, BC
V6T 1Z1, Canada
Sergey A. Nizkorodov
Department of Chemistry, University of California, Irvine, CA
92697-2025, USA
Department of Chemistry, University of California, Irvine, CA
92697-2025, USA
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- Morphology and Viscosity Changes after Reactive Uptake of Isoprene Epoxydiols in Submicrometer Phase Separated Particles with Secondary Organic Aerosol Formed from Different Volatile Organic Compounds Z. Lei et al. 10.1021/acsearthspacechem.1c00156
- Modeling the effect of non-ideality, dynamic mass transfer and viscosity on SOA formation in a 3-D air quality model Y. Kim et al. 10.5194/acp-19-1241-2019
- Insect Infestation Increases Viscosity of Biogenic Secondary Organic Aerosol N. Smith et al. 10.1021/acsearthspacechem.3c00007
- Recent advances in experimental techniques for investigating aerosol surface tension A. Bain 10.1080/02786826.2024.2373907
- A binary resin system of epoxy and phenol-formaldehyde for improving the thermo-mechanical behavior of FRP composites T. Liu et al. 10.1016/j.conbuildmat.2023.131790
- Enhanced Nitrate Fraction: Enabling Urban Aerosol Particles to Remain in a Liquid State at Reduced Relative Humidity Y. Liu et al. 10.1029/2023GL105505
- Investigating the role of solvents in modulating glass transition and dynamic mechanical characteristics of polystyrene film N. Patra & P. Ramesh 10.1016/j.colsurfa.2024.135230
- Aging of Atmospheric Brown Carbon Aerosol R. Hems et al. 10.1021/acsearthspacechem.0c00346
- Predictions of the glass transition temperature and viscosity of organic aerosols from volatility distributions Y. Li et al. 10.5194/acp-20-8103-2020
- Gas-Particle Uptake and Hygroscopic Growth by Organosulfate Particles P. Ohno et al. 10.1021/acsearthspacechem.2c00195
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Discussed (final revised paper)
Latest update: 11 Dec 2024
Short summary
The phase transition of organic particles between glassy and semi-solid states occurs at the glass transition temperature. We developed a method to predict glass transition temperatures and the viscosity of secondary organic aerosols using molecular composition, with consistent results with viscosity measurements. The viscosity of biomass burning particles was also estimated using the chemical composition measured by high-resolution mass spectrometry with two different ionization techniques.
The phase transition of organic particles between glassy and semi-solid states occurs at the...
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