Articles | Volume 18, issue 8
https://doi.org/10.5194/acp-18-5549-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-18-5549-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Novel pathway of SO2 oxidation in the atmosphere: reactions with monoterpene ozonolysis intermediates and secondary organic aerosol
Jianhuai Ye
Department of Chemical Engineering & Applied Chemistry, University
of Toronto, Toronto, Canada
Jonathan P. D. Abbatt
Department of Chemistry, University of Toronto, Toronto, Canada
Arthur W. H. Chan
CORRESPONDING AUTHOR
Department of Chemical Engineering & Applied Chemistry, University
of Toronto, Toronto, Canada
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Latest update: 29 May 2023
Short summary
Synergistic effects between SOA formation and SO2 oxidation through Criegee chemistry and reactive uptake by organic peroxides were observed. The relative importance of these two pathways (Criegee vs. peroxide) varies with relative humidity. The latter SO2 loss mechanism to organic peroxides in SOA has not previously been identified. Our results suggest a new pathway of atmospheric SO2 oxidation, which may contribute to the missing mechanisms of high-sulfate production in the polluted areas.
Synergistic effects between SOA formation and SO2 oxidation through Criegee chemistry and...
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