Articles | Volume 18, issue 6
https://doi.org/10.5194/acp-18-3987-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-18-3987-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Relationship between chemical composition and oxidative potential of secondary organic aerosol from polycyclic aromatic hydrocarbons
Shunyao Wang
Department of Chemical Engineering & Applied Chemistry, University
of Toronto, Toronto, Ontario, Canada
Jianhuai Ye
Department of Chemical Engineering & Applied Chemistry, University
of Toronto, Toronto, Ontario, Canada
Ronald Soong
Environmental NMR Centre, Department of Physical and Environmental
Sciences, University of Toronto Scarborough, Toronto, Ontario, Canada
Bing Wu
Environmental NMR Centre, Department of Physical and Environmental
Sciences, University of Toronto Scarborough, Toronto, Ontario, Canada
Legeng Yu
Department of Chemical Engineering & Applied Chemistry, University
of Toronto, Toronto, Ontario, Canada
André J. Simpson
Environmental NMR Centre, Department of Physical and Environmental
Sciences, University of Toronto Scarborough, Toronto, Ontario, Canada
Arthur W. H. Chan
CORRESPONDING AUTHOR
Department of Chemical Engineering & Applied Chemistry, University
of Toronto, Toronto, Ontario, Canada
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Latest update: 20 Nov 2024
Short summary
Linkages between the chemical composition of PAH-derived SOA and oxidative potential (OP) were investigated under various atmospheric aging processes. Peroxides were found to be an insignificant OP contributor. Oligomerization and heterogeneous ozonolysis may enhance the OP of SOA. Mixing with Cu reduces the OP of PAH-derived SOA. Binding between redox-active Cu(II) and quinone was proved by NMR. Results highlighted the essential role of aerosol chemical composition in its health impact.
Linkages between the chemical composition of PAH-derived SOA and oxidative potential (OP) were...
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