Articles | Volume 18, issue 5
https://doi.org/10.5194/acp-18-3541-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-18-3541-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Impacts of bromine and iodine chemistry on tropospheric OH and HO2: comparing observations with box and global model perspectives
School of Chemistry, University of Leeds, Leeds, UK
Tomás Sherwen
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry, University of York, York, UK
Mathew J. Evans
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry, University of York, York, UK
National Centre for Atmospheric Science, University of York, York, UK
Stewart Vaughan
School of Chemistry, University of Leeds, Leeds, UK
Trevor Ingham
School of Chemistry, University of Leeds, Leeds, UK
National Centre for Atmospheric Science, University of Leeds, Leeds, UK
Lisa K. Whalley
School of Chemistry, University of Leeds, Leeds, UK
National Centre for Atmospheric Science, University of Leeds, Leeds, UK
Peter M. Edwards
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry, University of York, York, UK
Katie A. Read
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry, University of York, York, UK
National Centre for Atmospheric Science, University of York, York, UK
James D. Lee
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry, University of York, York, UK
National Centre for Atmospheric Science, University of York, York, UK
Sarah J. Moller
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry, University of York, York, UK
National Centre for Atmospheric Science, University of York, York, UK
Lucy J. Carpenter
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry, University of York, York, UK
National Centre for Atmospheric Science, University of York, York, UK
Alastair C. Lewis
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry, University of York, York, UK
National Centre for Atmospheric Science, University of York, York, UK
Dwayne E. Heard
School of Chemistry, University of Leeds, Leeds, UK
National Centre for Atmospheric Science, University of Leeds, Leeds, UK
Viewed
Total article views: 3,420 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 10 Oct 2017)
HTML | XML | Total | Supplement | BibTeX | EndNote | |
---|---|---|---|---|---|---|
2,235 | 1,110 | 75 | 3,420 | 264 | 76 | 103 |
- HTML: 2,235
- PDF: 1,110
- XML: 75
- Total: 3,420
- Supplement: 264
- BibTeX: 76
- EndNote: 103
Total article views: 2,751 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 12 Mar 2018)
HTML | XML | Total | Supplement | BibTeX | EndNote | |
---|---|---|---|---|---|---|
1,829 | 855 | 67 | 2,751 | 168 | 70 | 99 |
- HTML: 1,829
- PDF: 855
- XML: 67
- Total: 2,751
- Supplement: 168
- BibTeX: 70
- EndNote: 99
Total article views: 669 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 10 Oct 2017)
HTML | XML | Total | Supplement | BibTeX | EndNote | |
---|---|---|---|---|---|---|
406 | 255 | 8 | 669 | 96 | 6 | 4 |
- HTML: 406
- PDF: 255
- XML: 8
- Total: 669
- Supplement: 96
- BibTeX: 6
- EndNote: 4
Viewed (geographical distribution)
Total article views: 3,420 (including HTML, PDF, and XML)
Thereof 3,440 with geography defined
and -20 with unknown origin.
Total article views: 2,751 (including HTML, PDF, and XML)
Thereof 2,772 with geography defined
and -21 with unknown origin.
Total article views: 669 (including HTML, PDF, and XML)
Thereof 668 with geography defined
and 1 with unknown origin.
Country | # | Views | % |
---|
Country | # | Views | % |
---|
Country | # | Views | % |
---|
Total: | 0 |
HTML: | 0 |
PDF: | 0 |
XML: | 0 |
- 1
1
Total: | 0 |
HTML: | 0 |
PDF: | 0 |
XML: | 0 |
- 1
1
Total: | 0 |
HTML: | 0 |
PDF: | 0 |
XML: | 0 |
- 1
1
Cited
27 citations as recorded by crossref.
- Impact of halogen chemistry on summertime air quality in coastal and continental Europe: application of the CMAQ model and implications for regulation Q. Li et al. 10.5194/acp-19-15321-2019
- Influence of Sea Ice‐Derived Halogens on Atmospheric HOx as Observed in Springtime Coastal Antarctica N. Brough et al. 10.1029/2019GL083825
- Observations and modelling of glyoxal in the tropical Atlantic marine boundary layer H. Walker et al. 10.5194/acp-22-5535-2022
- Influence of the Sea Surface Microlayer on Oceanic Iodine Emissions L. Tinel et al. 10.1021/acs.est.0c02736
- Chlorinated and brominated polycyclic aromatic hydrocarbons: Sources, formation mechanisms, and occurrence in the environment R. Jin et al. 10.1016/j.pecs.2019.100803
- Observed versus simulated OH reactivity during KORUS-AQ campaign: Implications for emission inventory and chemical environment in East Asia H. Kim et al. 10.1525/elementa.2022.00030
- Midlatitude Ozone Depletion and Air Quality Impacts from Industrial Halogen Emissions in the Great Salt Lake Basin C. Womack et al. 10.1021/acs.est.2c05376
- Box modelling of gas-phase atmospheric iodine chemical reactivity in case of a nuclear accident C. Fortin et al. 10.1016/j.atmosenv.2019.116838
- Role of Iodine Recycling on Sea‐Salt Aerosols in the Global Marine Boundary Layer Q. Li et al. 10.1029/2021GL097567
- Exploring Oxidation in the Remote Free Troposphere: Insights From Atmospheric Tomography (ATom) W. Brune et al. 10.1029/2019JD031685
- Climate and Tropospheric Oxidizing Capacity A. Fiore et al. 10.1146/annurev-earth-032320-090307
- Chemical Interactions Between Ship‐Originated Air Pollutants and Ocean‐Emitted Halogens Q. Li et al. 10.1029/2020JD034175
- Unclassical Radical Generation Mechanisms in the Troposphere: A Review X. Yang et al. 10.1021/acs.est.4c00742
- Impact and pathway of halogens on atmospheric oxidants in coastal city clusters in the Yangtze River Delta region in China H. Chen et al. 10.1016/j.apr.2023.101979
- Diurnal emission variation of ozone precursors: Impacts on ozone formation during Sep. 2019 Y. Tang et al. 10.1016/j.scitotenv.2024.172591
- Experimental chemical budgets of OH, HO2, and RO2 radicals in rural air in western Germany during the JULIAC campaign 2019 C. Cho et al. 10.5194/acp-23-2003-2023
- Estimation of reactive inorganic iodine fluxes in the Indian and Southern Ocean marine boundary layer S. Inamdar et al. 10.5194/acp-20-12093-2020
- Troposphere–stratosphere-integrated bromine monoxide (BrO) profile retrieval over the central Pacific Ocean T. Koenig et al. 10.5194/amt-17-5911-2024
- Vibrational mode-specific quasi-classical trajectory studies for the two-channel HI + C2H5reaction C. Yin & G. Czakó 10.1039/D2CP05993B
- Halogen activation and radical cycling initiated by imidazole-2-carboxaldehyde photochemistry P. Corral Arroyo et al. 10.5194/acp-19-10817-2019
- Distinguishing Surface and Bulk Reactivity: Concentration-Dependent Kinetics of Iodide Oxidation by Ozone in Microdroplets A. Prophet et al. 10.1021/acs.jpca.4c05129
- The impacts of marine-emitted halogens on OH radicals in East Asia during summer S. Fan & Y. Li 10.5194/acp-22-7331-2022
- Natural short-lived halogens exert an indirect cooling effect on climate A. Saiz-Lopez et al. 10.1038/s41586-023-06119-z
- Radical chemistry and ozone production at a UK coastal receptor site R. Woodward-Massey et al. 10.5194/acp-23-14393-2023
- New processing methodology to incorporate marine halocarbons and dimethyl sulfide (DMS) emissions from the CAMS-GLOB-OCE dataset in air quality modeling studies E. Pino-Cortés et al. 10.1007/s11869-022-01301-0
- Long-term time series of Arctic tropospheric BrO derived from UV–VIS satellite remote sensing and its relation to first-year sea ice I. Bougoudis et al. 10.5194/acp-20-11869-2020
- Modelling the impacts of iodine chemistry on the northern Indian Ocean marine boundary layer A. Mahajan et al. 10.5194/acp-21-8437-2021
27 citations as recorded by crossref.
- Impact of halogen chemistry on summertime air quality in coastal and continental Europe: application of the CMAQ model and implications for regulation Q. Li et al. 10.5194/acp-19-15321-2019
- Influence of Sea Ice‐Derived Halogens on Atmospheric HOx as Observed in Springtime Coastal Antarctica N. Brough et al. 10.1029/2019GL083825
- Observations and modelling of glyoxal in the tropical Atlantic marine boundary layer H. Walker et al. 10.5194/acp-22-5535-2022
- Influence of the Sea Surface Microlayer on Oceanic Iodine Emissions L. Tinel et al. 10.1021/acs.est.0c02736
- Chlorinated and brominated polycyclic aromatic hydrocarbons: Sources, formation mechanisms, and occurrence in the environment R. Jin et al. 10.1016/j.pecs.2019.100803
- Observed versus simulated OH reactivity during KORUS-AQ campaign: Implications for emission inventory and chemical environment in East Asia H. Kim et al. 10.1525/elementa.2022.00030
- Midlatitude Ozone Depletion and Air Quality Impacts from Industrial Halogen Emissions in the Great Salt Lake Basin C. Womack et al. 10.1021/acs.est.2c05376
- Box modelling of gas-phase atmospheric iodine chemical reactivity in case of a nuclear accident C. Fortin et al. 10.1016/j.atmosenv.2019.116838
- Role of Iodine Recycling on Sea‐Salt Aerosols in the Global Marine Boundary Layer Q. Li et al. 10.1029/2021GL097567
- Exploring Oxidation in the Remote Free Troposphere: Insights From Atmospheric Tomography (ATom) W. Brune et al. 10.1029/2019JD031685
- Climate and Tropospheric Oxidizing Capacity A. Fiore et al. 10.1146/annurev-earth-032320-090307
- Chemical Interactions Between Ship‐Originated Air Pollutants and Ocean‐Emitted Halogens Q. Li et al. 10.1029/2020JD034175
- Unclassical Radical Generation Mechanisms in the Troposphere: A Review X. Yang et al. 10.1021/acs.est.4c00742
- Impact and pathway of halogens on atmospheric oxidants in coastal city clusters in the Yangtze River Delta region in China H. Chen et al. 10.1016/j.apr.2023.101979
- Diurnal emission variation of ozone precursors: Impacts on ozone formation during Sep. 2019 Y. Tang et al. 10.1016/j.scitotenv.2024.172591
- Experimental chemical budgets of OH, HO2, and RO2 radicals in rural air in western Germany during the JULIAC campaign 2019 C. Cho et al. 10.5194/acp-23-2003-2023
- Estimation of reactive inorganic iodine fluxes in the Indian and Southern Ocean marine boundary layer S. Inamdar et al. 10.5194/acp-20-12093-2020
- Troposphere–stratosphere-integrated bromine monoxide (BrO) profile retrieval over the central Pacific Ocean T. Koenig et al. 10.5194/amt-17-5911-2024
- Vibrational mode-specific quasi-classical trajectory studies for the two-channel HI + C2H5reaction C. Yin & G. Czakó 10.1039/D2CP05993B
- Halogen activation and radical cycling initiated by imidazole-2-carboxaldehyde photochemistry P. Corral Arroyo et al. 10.5194/acp-19-10817-2019
- Distinguishing Surface and Bulk Reactivity: Concentration-Dependent Kinetics of Iodide Oxidation by Ozone in Microdroplets A. Prophet et al. 10.1021/acs.jpca.4c05129
- The impacts of marine-emitted halogens on OH radicals in East Asia during summer S. Fan & Y. Li 10.5194/acp-22-7331-2022
- Natural short-lived halogens exert an indirect cooling effect on climate A. Saiz-Lopez et al. 10.1038/s41586-023-06119-z
- Radical chemistry and ozone production at a UK coastal receptor site R. Woodward-Massey et al. 10.5194/acp-23-14393-2023
- New processing methodology to incorporate marine halocarbons and dimethyl sulfide (DMS) emissions from the CAMS-GLOB-OCE dataset in air quality modeling studies E. Pino-Cortés et al. 10.1007/s11869-022-01301-0
- Long-term time series of Arctic tropospheric BrO derived from UV–VIS satellite remote sensing and its relation to first-year sea ice I. Bougoudis et al. 10.5194/acp-20-11869-2020
- Modelling the impacts of iodine chemistry on the northern Indian Ocean marine boundary layer A. Mahajan et al. 10.5194/acp-21-8437-2021
Latest update: 23 Nov 2024
Short summary
Halogen chemistry in the troposphere impacts oxidising capacity, but model studies assessing the nature of these impacts can vary according to the model framework used. In this work we present simulations of OH and HO2 radicals using both box and global model frameworks, and compare to observations made at the Cape Verde Atmospheric Observatory. We highlight, and rationalise, differences between the model frameworks.
Halogen chemistry in the troposphere impacts oxidising capacity, but model studies assessing the...
Altmetrics
Final-revised paper
Preprint