Articles | Volume 18, issue 4
https://doi.org/10.5194/acp-18-2883-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-18-2883-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
α-Pinene secondary organic aerosol at low temperature: chemical composition and implications for particle viscosity
Wei Huang
Institute of Meteorology and Climate Research, Karlsruhe Institute of
Technology, 76344 Eggenstein-Leopoldshafen, Germany
Institute of Geography and Geoecology, Karlsruhe Institute of
Technology, 76131 Karlsruhe, Germany
Harald Saathoff
Institute of Meteorology and Climate Research, Karlsruhe Institute of
Technology, 76344 Eggenstein-Leopoldshafen, Germany
Aki Pajunoja
Department of Applied Physics, University of Eastern Finland, Kuopio,
80101, Finland
Xiaoli Shen
Institute of Meteorology and Climate Research, Karlsruhe Institute of
Technology, 76344 Eggenstein-Leopoldshafen, Germany
Institute of Geography and Geoecology, Karlsruhe Institute of
Technology, 76131 Karlsruhe, Germany
Karl-Heinz Naumann
Institute of Meteorology and Climate Research, Karlsruhe Institute of
Technology, 76344 Eggenstein-Leopoldshafen, Germany
Robert Wagner
Institute of Meteorology and Climate Research, Karlsruhe Institute of
Technology, 76344 Eggenstein-Leopoldshafen, Germany
Annele Virtanen
Department of Applied Physics, University of Eastern Finland, Kuopio,
80101, Finland
Thomas Leisner
Institute of Meteorology and Climate Research, Karlsruhe Institute of
Technology, 76344 Eggenstein-Leopoldshafen, Germany
Institute of Meteorology and Climate Research, Karlsruhe Institute of
Technology, 76344 Eggenstein-Leopoldshafen, Germany
Department of Environmental Science and Analytical Chemistry,
Stockholm University, Stockholm, 11418, Sweden
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Cited
65 citations as recorded by crossref.
- A new aerosol flow reactor to study secondary organic aerosol K. Pereira et al.
- Gas to Particle Partitioning of Organic Acids in the Boreal Atmosphere A. Lutz et al.
- Characterization of thermal decomposition of oxygenated organic compounds in FIGAERO-CIMS L. Yang et al.
- Local Arctic Air Pollution: A Neglected but Serious Problem J. Schmale et al.
- Changes in Secondary Organic Aerosol Composition and Volatility Going from a Low to a High HO2/RO2 Regime in α-Pinene Photooxidation V. Geretti et al.
- Diverse Reactions in Highly Functionalized Organic Aerosols during Thermal Desorption Z. Zhao et al.
- A model framework to retrieve thermodynamic and kinetic properties of organic aerosol from composition-resolved thermal desorption measurements S. Schobesberger et al.
- Comparing secondary organic aerosol (SOA) volatility distributions derived from isothermal SOA particle evaporation data and FIGAERO–CIMS measurements O. Tikkanen et al.
- Molecular composition and gas-particle partitioning of indoor cooking aerosol: Insights from a FIGAERO-CIMS and kinetic aerosol modeling C. Masoud et al.
- Probing the Fate of Highly Oxygenated Molecules in Atmospheric Aerosols P. Hao et al.
- Exploring the composition and volatility of secondary organic aerosols in mixed anthropogenic and biogenic precursor systems A. Voliotis et al.
- Enhanced daytime secondary aerosol formation driven by gas–particle partitioning in downwind urban plumes M. Cai et al.
- Review of Smog Chamber Research Trends J. Kim et al.
- Gas-to-Particle Partitioning of Products from Ozonolysis of Δ3-Carene and the Effect of Temperature and Relative Humidity L. Li et al.
- Isothermal Evaporation of α-Pinene Ozonolysis SOA: Volatility, Phase State, and Oligomeric Composition E. D’Ambro et al.
- Hydration of 3-Methyl-1,2,3-butanetricarboxylic Acid Evidenced by Matrix-Isolation Infrared Spectroscopy S. Coussan et al.
- Chlorine-initiated oxidation of n-alkanes under high-NOx conditions: insights into secondary organic aerosol composition and volatility using a FIGAERO–CIMS D. Wang & L. Hildebrandt Ruiz
- Impacts of α-pinene ozonolysis products on the morphology and optical properties of black carbon C. Yuan et al.
- On the calibration of FIGAERO-ToF-CIMS: importance and impact of calibrant delivery for the particle-phase calibration A. Ylisirniö et al.
- Kinetics, SOA yields, and chemical composition of secondary organic aerosol from β-caryophyllene ozonolysis with and without nitrogen oxides between 213 and 313 K L. Gao et al.
- Chemical Characterization of Highly Functionalized Organonitrates Contributing to Night-Time Organic Aerosol Mass Loadings and Particle Growth W. Huang et al.
- Oligomer and highly oxygenated organic molecule formation from oxidation of oxygenated monoterpenes emitted by California sage plants A. Mehra et al.
- Combined application of online FIGAERO-CIMS and offline LC-Orbitrap mass spectrometry (MS) to characterize the chemical composition of secondary organic aerosol (SOA) in smog chamber studies M. Du et al.
- Wall loss of semi-volatile organic compounds in a Teflon bag chamber for the temperature range of 262–298 K: mechanistic insight on temperature dependence L. He et al.
- Composition and volatility of secondary organic aerosol (SOA) formed from oxidation of real tree emissions compared to simplified volatile organic compound (VOC) systems A. Ylisirniö et al.
- Morphology and Viscosity Changes after Reactive Uptake of Isoprene Epoxydiols in Submicrometer Phase Separated Particles with Secondary Organic Aerosol Formed from Different Volatile Organic Compounds Z. Lei et al.
- Nitrate Radicals Suppress Biogenic New Particle Formation from Monoterpene Oxidation D. Li et al.
- Evidence and evolution of Criegee intermediates, hydroperoxides and secondary organic aerosols formedviaozonolysis of α-pinene A. Bagchi et al.
- On the formation of highly oxidized pollutants by autoxidation of terpenes under low-temperature-combustion conditions: the case of limonene and α-pinene R. Benoit et al.
- The phase state and viscosity of organic aerosol and related impacts on atmospheric physicochemical processes: A review Y. Gou et al.
- Evaluating Organic Aerosol Sources and Evolution with a Combined Molecular Composition and Volatility Framework Using the Filter Inlet for Gases and Aerosols (FIGAERO) J. Thornton et al.
- The pinene scaffold: its occurrence, chemistry, synthetic utility, and pharmacological importance R. Nyamwihura & I. Ogungbe
- Using highly time-resolved online mass spectrometry to examine biogenic and anthropogenic contributions to organic aerosol in Beijing A. Mehra et al.
- Heavy Ion Radiolysis of the Chiral Terpene α-pinene A. de Barros et al.
- Evaluation of Biogenic Organic Aerosols in the Amazon Rainforest Using WRF‐Chem With MOSAIC J. Mao et al.
- Predicting secondary organic aerosol phase state and viscosity and its effect on multiphase chemistry in a regional-scale air quality model R. Schmedding et al.
- Online Characterization of Organic Aerosol by Condensational Growth into Aqueous Droplets Coupled with Droplet-Assisted Ionization D. Kerecman et al.
- Gas-Phase Chlorine Radical Oxidation of Alkanes: Effects of Structural Branching, NOx, and Relative Humidity Observed during Environmental Chamber Experiments L. Jahn et al.
- Modelling the effect of condensed-phase diffusion on the homogeneous nucleation of ice in ultra-viscous particles K. Fowler et al.
- Temperature effects on optical properties and chemical composition of secondary organic aerosol derived from n-dodecane J. Li et al.
- Vapors Are Lost to Walls, Not to Particles on the Wall: Artifact-Corrected Parameters from Chamber Experiments and Implications for Global Secondary Organic Aerosol K. Bilsback et al.
- A robust clustering algorithm for analysis of composition-dependent organic aerosol thermal desorption measurements Z. Li et al.
- Ice nucleation ability of ammonium sulfate aerosol particles internally mixed with secondary organics B. Bertozzi et al.
- Chemical composition of nanoparticles from α-pinene nucleation and the influence of isoprene and relative humidity at low temperature L. Caudillo et al.
- A simple, versatile approach for coupling a liquid chromatograph and chemical ionization mass spectrometer for offline analysis of organic aerosol A. Schaum et al.
- Variation in chemical composition and volatility of oxygenated organic aerosol in different rural, urban, and mountain environments W. Huang et al.
- Insights into the O : C-dependent mechanisms controlling the evaporation of α-pinene secondary organic aerosol particles A. Buchholz et al.
- The saturation vapor pressures of higher-order polyethylene glycols and achieving a wide calibration range for volatility measurements by FIGAERO-CIMS A. Ylisirniö et al.
- Photolytically induced changes in composition and volatility of biogenic secondary organic aerosol from nitrate radical oxidation during night-to-day transition C. Wu et al.
- Measurement report: Brown carbon aerosol in rural Germany – sources, chemistry, and diurnal variations F. Jiang et al.
- Volatility parameterization of ambient organic aerosols at a rural site of the North China Plain S. Ren et al.
- Chlorine-Initiated Oxidation of α-Pinene: Formation of Secondary Organic Aerosol and Highly Oxygenated Organic Molecules C. Masoud & L. Ruiz
- Impact of temperature on the role of Criegee intermediates and peroxy radicals in dimer formation from β-pinene ozonolysis Y. Gong et al.
- Characterization of offline analysis of particulate matter with FIGAERO-CIMS J. Cai et al.
- Volatility Parametrization of Low-Volatile Components of Ambient Organic Aerosols Based on Molecular Formulas X. Yang et al.
- Coupling Filter-Based Thermal Desorption Chemical Ionization Mass Spectrometry with Liquid Chromatography/Electrospray Ionization Mass Spectrometry for Molecular Analysis of Secondary Organic Aerosol Y. Huang et al.
- The Aarhus Chamber Campaign on Highly Oxygenated Organic Molecules and Aerosols (ACCHA): particle formation, organic acids, and dimer esters from α-pinene ozonolysis at different temperatures K. Kristensen et al.
- Online gas- and particle-phase measurements of organosulfates, organosulfonates and nitrooxy organosulfates in Beijing utilizing a FIGAERO ToF-CIMS M. Le Breton et al.
- Seasonal characteristics of organic aerosol chemical composition and volatility in Stuttgart, Germany W. Huang et al.
- Predicting the glass transition temperature and viscosity of secondary organic material using molecular composition W. DeRieux et al.
- High-molecular-weight esters in α-pinene ozonolysis secondary organic aerosol: structural characterization and mechanistic proposal for their formation from highly oxygenated molecules A. Kahnt et al.
- Saturation vapor pressure characterization of selected low-volatility organic compounds using a residence time chamber Z. Li et al.
- Volatility Basis Set Distributions and Viscosity of Organic Aerosol Mixtures: Insights from Chemical Characterization Using Temperature-Programmed Desorption–Direct Analysis in Real-Time High-Resolution Mass Spectrometry Q. Xie et al.
- Comparison of saturation vapor pressures of α-pinene + O3 oxidation products derived from COSMO-RS computations and thermal desorption experiments N. Hyttinen et al.
- Estimating viscosity of individual substrate-deposited particles from measurements of their height-to-width ratios F. Rivera-Adorno et al.
65 citations as recorded by crossref.
- A new aerosol flow reactor to study secondary organic aerosol K. Pereira et al.
- Gas to Particle Partitioning of Organic Acids in the Boreal Atmosphere A. Lutz et al.
- Characterization of thermal decomposition of oxygenated organic compounds in FIGAERO-CIMS L. Yang et al.
- Local Arctic Air Pollution: A Neglected but Serious Problem J. Schmale et al.
- Changes in Secondary Organic Aerosol Composition and Volatility Going from a Low to a High HO2/RO2 Regime in α-Pinene Photooxidation V. Geretti et al.
- Diverse Reactions in Highly Functionalized Organic Aerosols during Thermal Desorption Z. Zhao et al.
- A model framework to retrieve thermodynamic and kinetic properties of organic aerosol from composition-resolved thermal desorption measurements S. Schobesberger et al.
- Comparing secondary organic aerosol (SOA) volatility distributions derived from isothermal SOA particle evaporation data and FIGAERO–CIMS measurements O. Tikkanen et al.
- Molecular composition and gas-particle partitioning of indoor cooking aerosol: Insights from a FIGAERO-CIMS and kinetic aerosol modeling C. Masoud et al.
- Probing the Fate of Highly Oxygenated Molecules in Atmospheric Aerosols P. Hao et al.
- Exploring the composition and volatility of secondary organic aerosols in mixed anthropogenic and biogenic precursor systems A. Voliotis et al.
- Enhanced daytime secondary aerosol formation driven by gas–particle partitioning in downwind urban plumes M. Cai et al.
- Review of Smog Chamber Research Trends J. Kim et al.
- Gas-to-Particle Partitioning of Products from Ozonolysis of Δ3-Carene and the Effect of Temperature and Relative Humidity L. Li et al.
- Isothermal Evaporation of α-Pinene Ozonolysis SOA: Volatility, Phase State, and Oligomeric Composition E. D’Ambro et al.
- Hydration of 3-Methyl-1,2,3-butanetricarboxylic Acid Evidenced by Matrix-Isolation Infrared Spectroscopy S. Coussan et al.
- Chlorine-initiated oxidation of n-alkanes under high-NOx conditions: insights into secondary organic aerosol composition and volatility using a FIGAERO–CIMS D. Wang & L. Hildebrandt Ruiz
- Impacts of α-pinene ozonolysis products on the morphology and optical properties of black carbon C. Yuan et al.
- On the calibration of FIGAERO-ToF-CIMS: importance and impact of calibrant delivery for the particle-phase calibration A. Ylisirniö et al.
- Kinetics, SOA yields, and chemical composition of secondary organic aerosol from β-caryophyllene ozonolysis with and without nitrogen oxides between 213 and 313 K L. Gao et al.
- Chemical Characterization of Highly Functionalized Organonitrates Contributing to Night-Time Organic Aerosol Mass Loadings and Particle Growth W. Huang et al.
- Oligomer and highly oxygenated organic molecule formation from oxidation of oxygenated monoterpenes emitted by California sage plants A. Mehra et al.
- Combined application of online FIGAERO-CIMS and offline LC-Orbitrap mass spectrometry (MS) to characterize the chemical composition of secondary organic aerosol (SOA) in smog chamber studies M. Du et al.
- Wall loss of semi-volatile organic compounds in a Teflon bag chamber for the temperature range of 262–298 K: mechanistic insight on temperature dependence L. He et al.
- Composition and volatility of secondary organic aerosol (SOA) formed from oxidation of real tree emissions compared to simplified volatile organic compound (VOC) systems A. Ylisirniö et al.
- Morphology and Viscosity Changes after Reactive Uptake of Isoprene Epoxydiols in Submicrometer Phase Separated Particles with Secondary Organic Aerosol Formed from Different Volatile Organic Compounds Z. Lei et al.
- Nitrate Radicals Suppress Biogenic New Particle Formation from Monoterpene Oxidation D. Li et al.
- Evidence and evolution of Criegee intermediates, hydroperoxides and secondary organic aerosols formedviaozonolysis of α-pinene A. Bagchi et al.
- On the formation of highly oxidized pollutants by autoxidation of terpenes under low-temperature-combustion conditions: the case of limonene and α-pinene R. Benoit et al.
- The phase state and viscosity of organic aerosol and related impacts on atmospheric physicochemical processes: A review Y. Gou et al.
- Evaluating Organic Aerosol Sources and Evolution with a Combined Molecular Composition and Volatility Framework Using the Filter Inlet for Gases and Aerosols (FIGAERO) J. Thornton et al.
- The pinene scaffold: its occurrence, chemistry, synthetic utility, and pharmacological importance R. Nyamwihura & I. Ogungbe
- Using highly time-resolved online mass spectrometry to examine biogenic and anthropogenic contributions to organic aerosol in Beijing A. Mehra et al.
- Heavy Ion Radiolysis of the Chiral Terpene α-pinene A. de Barros et al.
- Evaluation of Biogenic Organic Aerosols in the Amazon Rainforest Using WRF‐Chem With MOSAIC J. Mao et al.
- Predicting secondary organic aerosol phase state and viscosity and its effect on multiphase chemistry in a regional-scale air quality model R. Schmedding et al.
- Online Characterization of Organic Aerosol by Condensational Growth into Aqueous Droplets Coupled with Droplet-Assisted Ionization D. Kerecman et al.
- Gas-Phase Chlorine Radical Oxidation of Alkanes: Effects of Structural Branching, NOx, and Relative Humidity Observed during Environmental Chamber Experiments L. Jahn et al.
- Modelling the effect of condensed-phase diffusion on the homogeneous nucleation of ice in ultra-viscous particles K. Fowler et al.
- Temperature effects on optical properties and chemical composition of secondary organic aerosol derived from n-dodecane J. Li et al.
- Vapors Are Lost to Walls, Not to Particles on the Wall: Artifact-Corrected Parameters from Chamber Experiments and Implications for Global Secondary Organic Aerosol K. Bilsback et al.
- A robust clustering algorithm for analysis of composition-dependent organic aerosol thermal desorption measurements Z. Li et al.
- Ice nucleation ability of ammonium sulfate aerosol particles internally mixed with secondary organics B. Bertozzi et al.
- Chemical composition of nanoparticles from α-pinene nucleation and the influence of isoprene and relative humidity at low temperature L. Caudillo et al.
- A simple, versatile approach for coupling a liquid chromatograph and chemical ionization mass spectrometer for offline analysis of organic aerosol A. Schaum et al.
- Variation in chemical composition and volatility of oxygenated organic aerosol in different rural, urban, and mountain environments W. Huang et al.
- Insights into the O : C-dependent mechanisms controlling the evaporation of α-pinene secondary organic aerosol particles A. Buchholz et al.
- The saturation vapor pressures of higher-order polyethylene glycols and achieving a wide calibration range for volatility measurements by FIGAERO-CIMS A. Ylisirniö et al.
- Photolytically induced changes in composition and volatility of biogenic secondary organic aerosol from nitrate radical oxidation during night-to-day transition C. Wu et al.
- Measurement report: Brown carbon aerosol in rural Germany – sources, chemistry, and diurnal variations F. Jiang et al.
- Volatility parameterization of ambient organic aerosols at a rural site of the North China Plain S. Ren et al.
- Chlorine-Initiated Oxidation of α-Pinene: Formation of Secondary Organic Aerosol and Highly Oxygenated Organic Molecules C. Masoud & L. Ruiz
- Impact of temperature on the role of Criegee intermediates and peroxy radicals in dimer formation from β-pinene ozonolysis Y. Gong et al.
- Characterization of offline analysis of particulate matter with FIGAERO-CIMS J. Cai et al.
- Volatility Parametrization of Low-Volatile Components of Ambient Organic Aerosols Based on Molecular Formulas X. Yang et al.
- Coupling Filter-Based Thermal Desorption Chemical Ionization Mass Spectrometry with Liquid Chromatography/Electrospray Ionization Mass Spectrometry for Molecular Analysis of Secondary Organic Aerosol Y. Huang et al.
- The Aarhus Chamber Campaign on Highly Oxygenated Organic Molecules and Aerosols (ACCHA): particle formation, organic acids, and dimer esters from α-pinene ozonolysis at different temperatures K. Kristensen et al.
- Online gas- and particle-phase measurements of organosulfates, organosulfonates and nitrooxy organosulfates in Beijing utilizing a FIGAERO ToF-CIMS M. Le Breton et al.
- Seasonal characteristics of organic aerosol chemical composition and volatility in Stuttgart, Germany W. Huang et al.
- Predicting the glass transition temperature and viscosity of secondary organic material using molecular composition W. DeRieux et al.
- High-molecular-weight esters in α-pinene ozonolysis secondary organic aerosol: structural characterization and mechanistic proposal for their formation from highly oxygenated molecules A. Kahnt et al.
- Saturation vapor pressure characterization of selected low-volatility organic compounds using a residence time chamber Z. Li et al.
- Volatility Basis Set Distributions and Viscosity of Organic Aerosol Mixtures: Insights from Chemical Characterization Using Temperature-Programmed Desorption–Direct Analysis in Real-Time High-Resolution Mass Spectrometry Q. Xie et al.
- Comparison of saturation vapor pressures of α-pinene + O3 oxidation products derived from COSMO-RS computations and thermal desorption experiments N. Hyttinen et al.
- Estimating viscosity of individual substrate-deposited particles from measurements of their height-to-width ratios F. Rivera-Adorno et al.
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