Articles | Volume 18, issue 4
https://doi.org/10.5194/acp-18-2809-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-18-2809-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Importance of sulfate radical anion formation and chemistry in heterogeneous OH oxidation of sodium methyl sulfate, the smallest organosulfate
Kai Chung Kwong
Earth System Science Programme, Faculty of Science, The Chinese
University of Hong Kong, Hong Kong, China
Man Mei Chim
Earth System Science Programme, Faculty of Science, The Chinese
University of Hong Kong, Hong Kong, China
James F. Davies
Chemical Sciences
Division, Lawrence Berkeley National Laboratory, Berkeley, CA, USA
now at: Department of Chemistry, University of California
Riverside, Riverside, CA, USA
Kevin R. Wilson
Chemical Sciences
Division, Lawrence Berkeley National Laboratory, Berkeley, CA, USA
Man Nin Chan
CORRESPONDING AUTHOR
Earth System Science Programme, Faculty of Science, The Chinese
University of Hong Kong, Hong Kong, China
The Institute of Environment, Energy and Sustainability, The Chinese University
of Hong Kong, Hong Kong, China
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43 citations as recorded by crossref.
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- In-situ electrogenerated persulfate activated by co-existing Cu(II) for sustainable removal of sulfonamides from environmental waters Y. Zhou et al. 10.1016/j.jece.2024.114754
- OH Radical Oxidation of Organosulfates in the Atmospheric Aqueous Phase D. Gweme & S. Styler 10.1021/acs.jpca.4c02877
- Organosulfates in the Midwestern United States: abundance, composition and stability D. Hughes & E. Stone 10.1071/EN18260
- Photochemistry of the Cloud Aqueous Phase: A Review A. Bianco et al. 10.3390/molecules25020423
- Inorganic Sulfur Species Formed upon Heterogeneous OH Oxidation of Organosulfates: A Case Study of Methyl Sulfate R. Xu et al. 10.1021/acsearthspacechem.0c00209
- Photodegradation of Mixtures of Tetracycline, Sulfathiazole, and Triton X-100 in Water S. Yun et al. 10.5338/KJEA.2021.40.1.2
- Chemical transformation of <i>α</i>-pinene-derived organosulfate via heterogeneous OH oxidation: implications for sources and environmental fates of atmospheric organosulfates R. Xu et al. 10.5194/acp-22-5685-2022
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- Effects of NO and SO2 on the secondary organic aerosol formation from isoprene photooxidation Z. Zhang et al. 10.1016/j.atmosenv.2023.120248
- Second-Order Kinetic Rate Coefficients for the Aqueous-Phase Sulfate Radical (SO4•–) Oxidation of Some Atmospherically Relevant Organic Compounds L. Tran et al. 10.1021/acs.jpca.2c04964
- Phase State and Relative Humidity Regulate the Heterogeneous Oxidation Kinetics and Pathways of Organic-Inorganic Mixed Aerosols C. Shen et al. 10.1021/acs.est.2c04670
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- Recent advances in mass spectrometry techniques for atmospheric chemistry research on molecular‐level W. Zhang et al. 10.1002/mas.21857
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- Study on heterogeneous OH oxidation of 3-methyltetraol sulfate in the atmosphere under high NO conditions C. Guo et al. 10.1039/D2RA02958H
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- Effects of inorganic salts on the heterogeneous OH oxidation of organic compounds: insights from methylglutaric acid–ammonium sulfate H. Lam et al. 10.5194/acp-19-9581-2019
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- Organosulfates in Ambient Aerosol: State of Knowledge and Future Research Directions on Formation, Abundance, Fate, and Importance M. Brüggemann et al. 10.1021/acs.est.9b06751
- Effect of inorganic-to-organic mass ratio on the heterogeneous OH reaction rates of erythritol: implications for atmospheric chemical stability of 2-methyltetrols R. Xu et al. 10.5194/acp-20-3879-2020
- Beyond the formation: unveiling the atmospheric transformation of organosulfatesviaheterogeneous OH oxidation S. Ng & M. Chan 10.1039/D3CC03700B
- Production of Atmospheric Organosulfates via Mineral-Mediated Photochemistry M. Schmidt et al. 10.1021/acsearthspacechem.8b00178
- Growth Mechanisms of Nano-to Micro-Sized Lead Sulfate Particles M. Wall et al. 10.1021/acsomega.0c05722
- Chemical transformation of a long-chain alkyl organosulfate via heterogeneous OH oxidation: a case study of sodium dodecyl sulfate S. Madeleine Ng et al. 10.1039/D2EA00026A
- Visible light induced efficient activation of persulfate by a carbon quantum dots (CQDs) modified γ-Fe2O3 catalyst Y. Li et al. 10.1016/j.cclet.2020.01.032
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42 citations as recorded by crossref.
- Characterization of Organosulfates (OSs) in typical urban areas in Eastern China: Source, Process, and Volatility Y. Du et al. 10.1016/j.atmosres.2024.107258
- Radical oxidation of methyl vinyl ketone and methacrolein in aqueous droplets: Characterization of organosulfates and atmospheric implications P. Wach et al. 10.1016/j.chemosphere.2018.09.026
- In-situ electrogenerated persulfate activated by co-existing Cu(II) for sustainable removal of sulfonamides from environmental waters Y. Zhou et al. 10.1016/j.jece.2024.114754
- OH Radical Oxidation of Organosulfates in the Atmospheric Aqueous Phase D. Gweme & S. Styler 10.1021/acs.jpca.4c02877
- Organosulfates in the Midwestern United States: abundance, composition and stability D. Hughes & E. Stone 10.1071/EN18260
- Photochemistry of the Cloud Aqueous Phase: A Review A. Bianco et al. 10.3390/molecules25020423
- Inorganic Sulfur Species Formed upon Heterogeneous OH Oxidation of Organosulfates: A Case Study of Methyl Sulfate R. Xu et al. 10.1021/acsearthspacechem.0c00209
- Photodegradation of Mixtures of Tetracycline, Sulfathiazole, and Triton X-100 in Water S. Yun et al. 10.5338/KJEA.2021.40.1.2
- Chemical transformation of <i>α</i>-pinene-derived organosulfate via heterogeneous OH oxidation: implications for sources and environmental fates of atmospheric organosulfates R. Xu et al. 10.5194/acp-22-5685-2022
- Brown Carbon from Photo-Oxidation of Glyoxal and SO2 in Aqueous Aerosol D. De Haan et al. 10.1021/acsearthspacechem.3c00035
- Effects of NO and SO2 on the secondary organic aerosol formation from isoprene photooxidation Z. Zhang et al. 10.1016/j.atmosenv.2023.120248
- Second-Order Kinetic Rate Coefficients for the Aqueous-Phase Sulfate Radical (SO4•–) Oxidation of Some Atmospherically Relevant Organic Compounds L. Tran et al. 10.1021/acs.jpca.2c04964
- Phase State and Relative Humidity Regulate the Heterogeneous Oxidation Kinetics and Pathways of Organic-Inorganic Mixed Aerosols C. Shen et al. 10.1021/acs.est.2c04670
- Analytical methods for organosulfate detection in aerosol particles: Current status and future perspectives K. Gao & T. Zhu 10.1016/j.scitotenv.2021.147244
- A review of secondary organic aerosols formation focusing on organosulfates and organic nitrates W. Fan et al. 10.1016/j.jhazmat.2022.128406
- Heterogeneous OH oxidation of isoprene-epoxydiol-derived organosulfates: kinetics, chemistry and formation of inorganic sulfate H. Lam et al. 10.5194/acp-19-2433-2019
- PM2.5-bound organosulfates in two Eastern Mediterranean cities: The dominance of isoprene organosulfates P. Kanellopoulos et al. 10.1016/j.chemosphere.2022.134103
- Distribution characteristics of organosulfates (OSs) in PM2.5 in Tianjin, Northern China: Quantitative analysis of total and three OS species S. Ding et al. 10.1016/j.scitotenv.2022.155314
- General Mechanism for Sulfate Radical Addition to Olefinic Volatile Organic Compounds in Secondary Organic Aerosol H. Ren et al. 10.1021/acs.est.0c05256
- Recent advances in mass spectrometry techniques for atmospheric chemistry research on molecular‐level W. Zhang et al. 10.1002/mas.21857
- Photochemical Degradation of Organic Matter in the Atmosphere W. Hu et al. 10.1002/adsu.202100027
- Molecular characterization of atmospheric particulate organosulfates in a port environment using ultrahigh resolution mass spectrometry: Identification of traffic emissions L. Qi et al. 10.1016/j.jhazmat.2021.126431
- Study on heterogeneous OH oxidation of 3-methyltetraol sulfate in the atmosphere under high NO conditions C. Guo et al. 10.1039/D2RA02958H
- Formation of Inorganic Sulfate and Volatile Nonsulfated Products from Heterogeneous Hydroxyl Radical Oxidation of 2-Methyltetrol Sulfate Aerosols: Mechanisms and Atmospheric Implications R. Xu et al. 10.1021/acs.estlett.4c00451
- Stability assessment of organic sulfur and organosulfate compounds in filter samples for quantification by Fourier- transform infrared spectroscopy M. Anunciado et al. 10.5194/amt-16-3515-2023
- Tracing the biogenic secondary organic aerosol markers in rain, snow and hail G. Spolnik et al. 10.1016/j.chemosphere.2020.126439
- Interactions of organosulfates with water vapor under sub- and supersaturated conditions C. Peng et al. 10.5194/acp-21-7135-2021
- pH regulates the formation of organosulfates and inorganic sulfate from organic peroxide reaction with dissolved SO2 in aquatic media L. Du et al. 10.5194/acp-24-1841-2024
- Effects of inorganic salts on the heterogeneous OH oxidation of organic compounds: insights from methylglutaric acid–ammonium sulfate H. Lam et al. 10.5194/acp-19-9581-2019
- Chemical Transformation of Methanesulfonic Acid and Sodium Methanesulfonate through Heterogeneous OH Oxidation K. Kwong et al. 10.1021/acsearthspacechem.8b00072
- Reaction dynamics of the nonvalence bound states of the anions D. Kang & S. Kim 10.1063/5.0220345
- Molecular characteristics of ambient organic aerosols in Shanghai winter before and after the COVID-19 outbreak W. Wen et al. 10.1016/j.scitotenv.2023.161811
- Hydration of glycolic acid sulfate and lactic acid sulfate: Atmospheric implications N. Tsona & L. Du 10.1016/j.atmosenv.2019.116921
- Physical properties of short chain aqueous organosulfate aerosol A. Bain et al. 10.1039/D3EA00088E
- Organosulfates in Ambient Aerosol: State of Knowledge and Future Research Directions on Formation, Abundance, Fate, and Importance M. Brüggemann et al. 10.1021/acs.est.9b06751
- Effect of inorganic-to-organic mass ratio on the heterogeneous OH reaction rates of erythritol: implications for atmospheric chemical stability of 2-methyltetrols R. Xu et al. 10.5194/acp-20-3879-2020
- Beyond the formation: unveiling the atmospheric transformation of organosulfatesviaheterogeneous OH oxidation S. Ng & M. Chan 10.1039/D3CC03700B
- Production of Atmospheric Organosulfates via Mineral-Mediated Photochemistry M. Schmidt et al. 10.1021/acsearthspacechem.8b00178
- Growth Mechanisms of Nano-to Micro-Sized Lead Sulfate Particles M. Wall et al. 10.1021/acsomega.0c05722
- Chemical transformation of a long-chain alkyl organosulfate via heterogeneous OH oxidation: a case study of sodium dodecyl sulfate S. Madeleine Ng et al. 10.1039/D2EA00026A
- Visible light induced efficient activation of persulfate by a carbon quantum dots (CQDs) modified γ-Fe2O3 catalyst Y. Li et al. 10.1016/j.cclet.2020.01.032
- Photo-persulfate oxidation and mineralization of benzoic acid: Kinetics and optimization under UVC irradiation V. Sugihartono et al. 10.1016/j.chemosphere.2022.133663
Latest update: 14 Dec 2024
Short summary
To date, it remains unclear how organosulfates evolve over time in the atmosphere. We demonstrate that heterogeneous OH oxidation of sodium methyl sulfate, the smallest organosulfate found in atmospheric aerosols, is efficient. The oxidation can lead to the formation of sulfate radical anion and produce inorganic sulfate. In addition to OH radicals, sulfate radical anion chemistry can play a role in determining the evolution of sodium methyl sulfate and other organosulfates during oxidation.
To date, it remains unclear how organosulfates evolve over time in the atmosphere. We...
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