Articles | Volume 18, issue 4
https://doi.org/10.5194/acp-18-2363-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Special issue:
https://doi.org/10.5194/acp-18-2363-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
19 Feb 2018
Research article |
| 19 Feb 2018
| 19 Feb 2018
Measurement–model comparison of stabilized Criegee intermediate and highly oxygenated molecule production in the CLOUD chamber
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, P.O. Box 64, 00014 Helsinki, Finland
Tuija Jokinen
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, P.O. Box 64, 00014 Helsinki, Finland
Jonathan Duplissy
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, P.O. Box 64, 00014 Helsinki, Finland
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, P.O. Box 64, 00014 Helsinki, Finland
Tuomo Nieminen
University of Eastern Finland, Department of Applied Physics, P.O. Box 1627, 70211 Kuopio, Finland
Mikael Ehn
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, P.O. Box 64, 00014 Helsinki, Finland
Siegfried Schobesberger
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, P.O. Box 64, 00014 Helsinki, Finland
University of Eastern Finland, Department of Applied Physics, P.O. Box 1627, 70211 Kuopio, Finland
Department of Atmospheric Sciences, University of Washington, 408 ATG Bldg, Box 351640, Seattle, WA 98195, USA
Martin Heinritzi
Institute for Atmospheric and Environmental Sciences, Goethe University Frankfurt, Altenhöferallee 1, 60438 Frankfurt am Main, Germany
Sebastian Ehrhart
Institute for Atmospheric and Environmental Sciences, Goethe University Frankfurt, Altenhöferallee 1, 60438 Frankfurt am Main, Germany
now at: Max-Planck Institute of Chemistry, Atmospheric Chemistry Department,
Hahn-Meitner-Weg 1, 55128 Mainz, Germany
Katrianne Lehtipalo
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, P.O. Box 64, 00014 Helsinki, Finland
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, 5232 Villigen PSI, Switzerland
Jasmin Tröstl
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, 5232 Villigen PSI, Switzerland
Mario Simon
Institute for Atmospheric and Environmental Sciences, Goethe University Frankfurt, Altenhöferallee 1, 60438 Frankfurt am Main, Germany
Andreas Kürten
Institute for Atmospheric and Environmental Sciences, Goethe University Frankfurt, Altenhöferallee 1, 60438 Frankfurt am Main, Germany
Markus Leiminger
University of Innsbruck, Institute for Ion Physics and Applied Physics, Technikerstraße 25, 6020 Innsbruck, Austria
Michael J. Lawler
University of California, Irvine, Department of Chemistry, Irvine, CA 92697, USA
Matti P. Rissanen
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, P.O. Box 64, 00014 Helsinki, Finland
Federico Bianchi
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, P.O. Box 64, 00014 Helsinki, Finland
Arnaud P. Praplan
Finnish Meteorological Institute, P.O. Box 503, 00101 Helsinki, Finland
Jani Hakala
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, P.O. Box 64, 00014 Helsinki, Finland
Antonio Amorim
CENTRA, Faculdade de Ciencias da Universidade de Lisboa, Lisbon, Portugal
Marc Gonin
Tofwerk AG, 3600 Thun, Switzerland
Armin Hansel
University of Innsbruck, Institute for Ion Physics and Applied Physics, Technikerstraße 25, 6020 Innsbruck, Austria
Jasper Kirkby
Institute for Atmospheric and Environmental Sciences, Goethe University Frankfurt, Altenhöferallee 1, 60438 Frankfurt am Main, Germany
CERN, 1211 Geneva, Switzerland
Josef Dommen
Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, 5232 Villigen PSI, Switzerland
Joachim Curtius
Institute for Atmospheric and Environmental Sciences, Goethe University Frankfurt, Altenhöferallee 1, 60438 Frankfurt am Main, Germany
James N. Smith
University of California, Irvine, Department of Chemistry, Irvine, CA 92697, USA
Tuukka Petäjä
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, P.O. Box 64, 00014 Helsinki, Finland
Douglas R. Worsnop
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, P.O. Box 64, 00014 Helsinki, Finland
Aerodyne Research, Inc., Billerica, MA 01821, USA
Markku Kulmala
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, P.O. Box 64, 00014 Helsinki, Finland
Neil M. Donahue
Carnegie Mellon University Center for Atmospheric Particle Studies, 5000 Forbes Ave, Pittsburgh, PA 15213, USA
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, P.O. Box 64, 00014 Helsinki, Finland
Mikko Sipilä
Institute for Atmospheric and Earth System Research/Physics, Faculty of Science, University of Helsinki, P.O. Box 64, 00014 Helsinki, Finland
Viewed
Total article views: 4,975 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 13 Sep 2017)
| HTML | XML | Total | BibTeX | EndNote | |
|---|---|---|---|---|---|
| 3,182 | 1,700 | 93 | 4,975 | 114 | 163 |
- HTML: 3,182
- PDF: 1,700
- XML: 93
- Total: 4,975
- BibTeX: 114
- EndNote: 163
Total article views: 4,077 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 19 Feb 2018)
| HTML | XML | Total | BibTeX | EndNote | |
|---|---|---|---|---|---|
| 2,784 | 1,209 | 84 | 4,077 | 99 | 143 |
- HTML: 2,784
- PDF: 1,209
- XML: 84
- Total: 4,077
- BibTeX: 99
- EndNote: 143
Total article views: 898 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 13 Sep 2017)
| HTML | XML | Total | BibTeX | EndNote | |
|---|---|---|---|---|---|
| 398 | 491 | 9 | 898 | 15 | 20 |
- HTML: 398
- PDF: 491
- XML: 9
- Total: 898
- BibTeX: 15
- EndNote: 20
Viewed (geographical distribution)
Total article views: 4,975 (including HTML, PDF, and XML)
Thereof 4,923 with geography defined
and 52 with unknown origin.
Total article views: 4,077 (including HTML, PDF, and XML)
Thereof 4,051 with geography defined
and 26 with unknown origin.
Total article views: 898 (including HTML, PDF, and XML)
Thereof 872 with geography defined
and 26 with unknown origin.
| Country | # | Views | % |
|---|
| Country | # | Views | % |
|---|
| Country | # | Views | % |
|---|
| Total: | 0 |
| HTML: | 0 |
| PDF: | 0 |
| XML: | 0 |
- 1
1
| Total: | 0 |
| HTML: | 0 |
| PDF: | 0 |
| XML: | 0 |
- 1
1
| Total: | 0 |
| HTML: | 0 |
| PDF: | 0 |
| XML: | 0 |
- 1
1
Cited
22 citations as recorded by crossref.
- Large Gas-Phase Source of Esters and Other Accretion Products in the Atmosphere O. Peräkylä et al. 10.1021/jacs.2c10398
- Trimethylamine Outruns Terpenes and Aromatics in Atmospheric Autoxidation T. Berndt et al. 10.1021/acs.jpca.1c02465
- Modelling ultrafine particle growth in a flow tube reactor M. Taylor Jr. et al. 10.5194/amt-15-4663-2022
- High concentration of ultrafine particles in the Amazon free troposphere produced by organic new particle formation B. Zhao et al. 10.1073/pnas.2006716117
- Highly oxygenated organic molecules produced by the oxidation of benzene and toluene in a wide range of OH exposure and NOx conditions X. Cheng et al. 10.5194/acp-21-12005-2021
- Types of regional and localised new aerosol particle formation and growth processes: Atmospheric Banana Atlas I. Salma et al. 10.1038/s41612-025-01149-y
- Thermodynamic and experimental evaluation of a cloud chamber for ultrafine particle detection W. Yang & A. Boies 10.1016/j.sna.2020.111986
- Direct measurement of the Criegee intermediate CH2OO in ozonolysis of ethene M. Campos-Pineda et al. 10.1038/s41467-025-61739-5
- Effect of temperature on the formation of highly oxygenated organic molecules (HOMs) from alpha-pinene ozonolysis L. Quéléver et al. 10.5194/acp-19-7609-2019
- Atmospheric new particle formation from the CERN CLOUD experiment J. Kirkby et al. 10.1038/s41561-023-01305-0
- Growth of Aitken mode ammonium sulfate particles by α-pinene ozonolysis J. Krasnomowitz et al. 10.1080/02786826.2019.1568381
- Enigma of Urban Gaseous Oxygenated Organic Molecules: Precursor Type, Role of NOx, and Degree of Oxygenation L. Tian et al. 10.1021/acs.est.2c05047
- Kinetics for the reaction of Criegee intermediate CH2OO with n-butyraldehyde and its atmospheric implications S. Liu et al. 10.1016/j.atmosenv.2023.120012
- The atmospheric importance of methylamine additions to Criegee intermediates H. Mull et al. 10.1039/D0CP03781H
- Observational evidence for Criegee intermediate oligomerization reactions relevant to aerosol formation in the troposphere R. Caravan et al. 10.1038/s41561-023-01361-6
- Highly Oxygenated Organic Molecules (HOM) from Gas-Phase Autoxidation Involving Peroxy Radicals: A Key Contributor to Atmospheric Aerosol F. Bianchi et al. 10.1021/acs.chemrev.8b00395
- Long-term measurement of sub-3 nm particles and their precursor gases in the boreal forest J. Sulo et al. 10.5194/acp-21-695-2021
- Soft X-ray Atmospheric Pressure Photoionization in Liquid Chromatography–Mass Spectrometry J. Hieta et al. 10.1021/acs.analchem.1c01127
- Carbonyl Oxide Stabilization from Trans Alkene and Terpene Ozonolysis J. Hakala & N. Donahue 10.1021/acs.jpca.3c03650
- CRI-HOM: A novel chemical mechanism for simulating highly oxygenated organic molecules (HOMs) in global chemistry–aerosol–climate models J. Weber et al. 10.5194/acp-20-10889-2020
- Peroxy Radical and Product Formation in the Gas-Phase Ozonolysis of α-Pinene under Near-Atmospheric Conditions: Occurrence of an Additional Series of Peroxy Radicals O,O–C10H15O(O2)yO2 with y = 1–3 T. Berndt 10.1021/acs.jpca.2c05094
- Measurement–model comparison of stabilized Criegee intermediate and highly oxygenated molecule production in the CLOUD chamber N. Sarnela et al. 10.5194/acp-18-2363-2018
21 citations as recorded by crossref.
- Large Gas-Phase Source of Esters and Other Accretion Products in the Atmosphere O. Peräkylä et al. 10.1021/jacs.2c10398
- Trimethylamine Outruns Terpenes and Aromatics in Atmospheric Autoxidation T. Berndt et al. 10.1021/acs.jpca.1c02465
- Modelling ultrafine particle growth in a flow tube reactor M. Taylor Jr. et al. 10.5194/amt-15-4663-2022
- High concentration of ultrafine particles in the Amazon free troposphere produced by organic new particle formation B. Zhao et al. 10.1073/pnas.2006716117
- Highly oxygenated organic molecules produced by the oxidation of benzene and toluene in a wide range of OH exposure and NOx conditions X. Cheng et al. 10.5194/acp-21-12005-2021
- Types of regional and localised new aerosol particle formation and growth processes: Atmospheric Banana Atlas I. Salma et al. 10.1038/s41612-025-01149-y
- Thermodynamic and experimental evaluation of a cloud chamber for ultrafine particle detection W. Yang & A. Boies 10.1016/j.sna.2020.111986
- Direct measurement of the Criegee intermediate CH2OO in ozonolysis of ethene M. Campos-Pineda et al. 10.1038/s41467-025-61739-5
- Effect of temperature on the formation of highly oxygenated organic molecules (HOMs) from alpha-pinene ozonolysis L. Quéléver et al. 10.5194/acp-19-7609-2019
- Atmospheric new particle formation from the CERN CLOUD experiment J. Kirkby et al. 10.1038/s41561-023-01305-0
- Growth of Aitken mode ammonium sulfate particles by α-pinene ozonolysis J. Krasnomowitz et al. 10.1080/02786826.2019.1568381
- Enigma of Urban Gaseous Oxygenated Organic Molecules: Precursor Type, Role of NOx, and Degree of Oxygenation L. Tian et al. 10.1021/acs.est.2c05047
- Kinetics for the reaction of Criegee intermediate CH2OO with n-butyraldehyde and its atmospheric implications S. Liu et al. 10.1016/j.atmosenv.2023.120012
- The atmospheric importance of methylamine additions to Criegee intermediates H. Mull et al. 10.1039/D0CP03781H
- Observational evidence for Criegee intermediate oligomerization reactions relevant to aerosol formation in the troposphere R. Caravan et al. 10.1038/s41561-023-01361-6
- Highly Oxygenated Organic Molecules (HOM) from Gas-Phase Autoxidation Involving Peroxy Radicals: A Key Contributor to Atmospheric Aerosol F. Bianchi et al. 10.1021/acs.chemrev.8b00395
- Long-term measurement of sub-3 nm particles and their precursor gases in the boreal forest J. Sulo et al. 10.5194/acp-21-695-2021
- Soft X-ray Atmospheric Pressure Photoionization in Liquid Chromatography–Mass Spectrometry J. Hieta et al. 10.1021/acs.analchem.1c01127
- Carbonyl Oxide Stabilization from Trans Alkene and Terpene Ozonolysis J. Hakala & N. Donahue 10.1021/acs.jpca.3c03650
- CRI-HOM: A novel chemical mechanism for simulating highly oxygenated organic molecules (HOMs) in global chemistry–aerosol–climate models J. Weber et al. 10.5194/acp-20-10889-2020
- Peroxy Radical and Product Formation in the Gas-Phase Ozonolysis of α-Pinene under Near-Atmospheric Conditions: Occurrence of an Additional Series of Peroxy Radicals O,O–C10H15O(O2)yO2 with y = 1–3 T. Berndt 10.1021/acs.jpca.2c05094
Latest update: 31 Oct 2025
Short summary
Atmospheric trace gases can form small molecular clusters, which can grow to larger sizes through the condensation of vapours. This process is called new particle formation. In this paper we studied the formation of sulfuric acid and highly oxygenated molecules, the key compounds in atmospheric new particle formation, in chamber experiments and introduced a way to simulate these ozonolysis products of α-pinene in a simple manner.
Atmospheric trace gases can form small molecular clusters, which can grow to larger sizes...
Special issue
Altmetrics
Final-revised paper
Preprint