Atmospheric Chemistry and Physics
Atmospheric Chemistry and Physics
ACP
Articles | Volume 18, issue 20
Articles | Volume 18, issue 20
https://doi.org/10.5194/acp-18-15105-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-18-15105-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
Articles | Volume 18, issue 20
Research article
 | 
19 Oct 2018
Research article |  | 19 Oct 2018

The oxidation regime and SOA composition in limonene ozonolysis: roles of different double bonds, radicals, and water

Yiwei Gong, Zhongming Chen, and Huan Li

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Short summary
In limonene ozonolysis, the endocyclic double bond is inclined to generate hydroxy radicals, while the exocyclic double bond has a higher fraction of forming stabilized Criegee intermediates. The oxidation that happens on the exocyclic double bond greatly contributes to the organic peroxides, which account for a considerable proportion of secondary organic aerosol. Terpenes with multiple double bonds may have more complex effects on the atmosphere than previously thought.
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