Articles | Volume 18, issue 20
https://doi.org/10.5194/acp-18-15105-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-18-15105-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
19 Oct 2018
Research article |
| 19 Oct 2018
| 19 Oct 2018
The oxidation regime and SOA composition in limonene ozonolysis: roles of different double bonds, radicals, and water
Yiwei Gong
State Key Laboratory of Environmental Simulation and Pollution
Control, College of Environmental Sciences and Engineering, Peking University,
Beijing 100871, China
Zhongming Chen
CORRESPONDING AUTHOR
State Key Laboratory of Environmental Simulation and Pollution
Control, College of Environmental Sciences and Engineering, Peking University,
Beijing 100871, China
Huan Li
State Key Laboratory of Environmental Simulation and Pollution
Control, College of Environmental Sciences and Engineering, Peking University,
Beijing 100871, China
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Cited
33 citations as recorded by crossref.
- Quantification of the role of stabilized Criegee intermediates in the formation of aerosols in limonene ozonolysis Y. Gong & Z. Chen https://doi.org/10.5194/acp-21-813-2021
- Compilation of reaction kinetics parameters determined in the Key Development Project for Air Pollution Formation Mechanism and Control Technologies in China Y. Liu et al. https://doi.org/10.1016/j.jes.2022.06.021
- Unveiling the Role of Chirality in the Oxidation of Monoterpenes L. Gao et al. https://doi.org/10.1021/jacs.5c06118
- Tobacco-specific alkaloid (TSA) formation in aged e-cigarette juices: mechanistic insights into hydroxyl radical-initiated nicotine oxidation X. Guo et al. https://doi.org/10.1039/D5EM01030F
- Measurements and Modeling of GUV222-Driven Increases in SOA Concentrations in an Unoccupied Office M. Rutherford et al. https://doi.org/10.1021/acsestair.5c00475
- Carboxylic acids from limonene oxidation by ozone and hydroxyl radicals: insights into mechanisms derived using a FIGAERO-CIMS J. Hammes et al. https://doi.org/10.5194/acp-19-13037-2019
- Hydrolysis reactivity reveals significant seasonal variation in the composition of organic peroxides in ambient PM2.5 Y. Dai et al. https://doi.org/10.1016/j.scitotenv.2024.172143
- Rapid Nucleation and Growth of Indoor Atmospheric Nanocluster Aerosol during the Use of Scented Volatile Chemical Products in Residential Buildings S. Patra et al. https://doi.org/10.1021/acsestair.4c00118
- Ozonolysis of β-Caryophyllonic and Limononic Acids in the Aqueous Phase: Kinetics, Product Yield, and Mechanism B. Witkowski et al. https://doi.org/10.1021/acs.est.9b02471
- Quantifying bimolecular reaction kinetics of isoprene hydroxy peroxy radical: From dry to highly humid atmospheric environment J. Xu & Z. Chen https://doi.org/10.1016/j.atmosenv.2024.120627
- Large differences of highly oxygenated organic molecules (HOMs) and low-volatile species in secondary organic aerosols (SOAs) formed from ozonolysis of β-pinene and limonene D. Liu et al. https://doi.org/10.5194/acp-23-8383-2023
- Importance of secondary organic aerosol formation of α-pinene, limonene, and m-cresol comparing day- and nighttime radical chemistry A. Mutzel et al. https://doi.org/10.5194/acp-21-8479-2021
- Analytical methodologies for oxidized organic compounds in the atmosphere A. Tiusanen et al. https://doi.org/10.1039/D3EM00163F
- Partitioning of hydrogen peroxide in gas-liquid and gas-aerosol phases X. Xuan et al. https://doi.org/10.5194/acp-20-5513-2020
- Water Plays Multifunctional Roles in the Intervening Formation of Secondary Organic Aerosols in Ozonolysis of Limonene: A Valence Photoelectron Spectroscopy and Density Functional Theory Study J. Huang et al. https://doi.org/10.1021/acs.jpclett.3c00560
- Atmospheric fate of ketolimonene part 2: Highly oxygenated molecules (HOMs) and secondary organic aerosol (SOA) formation from NO3-initiated oxidation S. Solaiman et al. https://doi.org/10.1016/j.jes.2026.105636
- Organic Peroxides in Aerosol: Key Reactive Intermediates for Multiphase Processes in the Atmosphere S. Wang et al. https://doi.org/10.1021/acs.chemrev.2c00430
- The oxidation mechanism of gas-phase ozonolysis of limonene in the atmosphere L. Wang & L. Wang https://doi.org/10.1039/D0CP05803C
- Investigation of the limonene photooxidation by OH at different NO concentrations in the atmospheric simulation chamber SAPHIR (Simulation of Atmospheric PHotochemistry In a large Reaction Chamber) J. Pang et al. https://doi.org/10.5194/acp-22-8497-2022
- New insights into the chemical composition and formation mechanisms of secondary organic aerosols produced in the ozonolysis of limonene F. Jacob et al. https://doi.org/10.1016/j.jaerosci.2023.106214
- Stability of Monoterpene-Derived α‑Hydroxyalkyl-Hydroperoxides in Aqueous Organic Media: Relevance to the Fate of Hydroperoxides in Aerosol Particle Phases J. Qiu et al. https://doi.org/10.1021/acs.est.9b07497
- Formation pathways of aldehydes from heated cooking oils M. Takhar et al. https://doi.org/10.1039/D1EM00532D
- Technical note: Characterization of a single-beam gradient force aerosol optical tweezer for droplet trapping, phase transition monitoring, and morphology studies X. Pei et al. https://doi.org/10.5194/acp-24-5235-2024
- Nitrate radical, ozone and hydroxyl radical initiated aging of limonene secondary organic aerosol S. Ramasamy et al. https://doi.org/10.1016/j.aeaoa.2021.100102
- Formation of secondary organic aerosols from the reaction of γ-terpinene with ozone: yields and morphology L. Fayad et al. https://doi.org/10.1016/j.atmosenv.2021.118600
- Investigation of RH effect on uncommon limonene ozonolysis products and SOA formation in indoor air with real time measurement techniques K. Pytel & B. Zabiegała https://doi.org/10.1016/j.chemosphere.2023.140854
- Conformational landscape and internal dynamics of limona ketone, a key oxidation product of limonene N. Osseiran et al. https://doi.org/10.1016/j.jms.2022.111643
- Formation of highly oxygenated organic molecules from the oxidation of limonene by OH radical: significant contribution of H-abstraction pathway H. Luo et al. https://doi.org/10.5194/acp-23-7297-2023
- Contrasting impacts of humidity on the ozonolysis of monoterpenes: insights into the multi-generation chemical mechanism S. Zhang et al. https://doi.org/10.5194/acp-23-10809-2023
- Atmospheric aging suppresses the formation of limonene-derived organic peroxides X. Chen et al. https://doi.org/10.1039/D5EM00823A
- A new iodometric microwave-assisted method for peroxide determination in Secondary Organic Aerosols D. Alba-Elena et al. https://doi.org/10.1016/j.atmosenv.2023.119960
- Waste aroma profile in the framework of food waste management through household composting A. Agapios et al. https://doi.org/10.1016/j.jclepro.2020.120340
- Photooxidation-Initiated Aqueous-Phase Formation of Organic Peroxides: Delving into Formation Mechanisms T. Gautam et al. https://doi.org/10.1021/acs.est.3c01162
33 citations as recorded by crossref.
- Quantification of the role of stabilized Criegee intermediates in the formation of aerosols in limonene ozonolysis Y. Gong & Z. Chen https://doi.org/10.5194/acp-21-813-2021
- Compilation of reaction kinetics parameters determined in the Key Development Project for Air Pollution Formation Mechanism and Control Technologies in China Y. Liu et al. https://doi.org/10.1016/j.jes.2022.06.021
- Unveiling the Role of Chirality in the Oxidation of Monoterpenes L. Gao et al. https://doi.org/10.1021/jacs.5c06118
- Tobacco-specific alkaloid (TSA) formation in aged e-cigarette juices: mechanistic insights into hydroxyl radical-initiated nicotine oxidation X. Guo et al. https://doi.org/10.1039/D5EM01030F
- Measurements and Modeling of GUV222-Driven Increases in SOA Concentrations in an Unoccupied Office M. Rutherford et al. https://doi.org/10.1021/acsestair.5c00475
- Carboxylic acids from limonene oxidation by ozone and hydroxyl radicals: insights into mechanisms derived using a FIGAERO-CIMS J. Hammes et al. https://doi.org/10.5194/acp-19-13037-2019
- Hydrolysis reactivity reveals significant seasonal variation in the composition of organic peroxides in ambient PM2.5 Y. Dai et al. https://doi.org/10.1016/j.scitotenv.2024.172143
- Rapid Nucleation and Growth of Indoor Atmospheric Nanocluster Aerosol during the Use of Scented Volatile Chemical Products in Residential Buildings S. Patra et al. https://doi.org/10.1021/acsestair.4c00118
- Ozonolysis of β-Caryophyllonic and Limononic Acids in the Aqueous Phase: Kinetics, Product Yield, and Mechanism B. Witkowski et al. https://doi.org/10.1021/acs.est.9b02471
- Quantifying bimolecular reaction kinetics of isoprene hydroxy peroxy radical: From dry to highly humid atmospheric environment J. Xu & Z. Chen https://doi.org/10.1016/j.atmosenv.2024.120627
- Large differences of highly oxygenated organic molecules (HOMs) and low-volatile species in secondary organic aerosols (SOAs) formed from ozonolysis of β-pinene and limonene D. Liu et al. https://doi.org/10.5194/acp-23-8383-2023
- Importance of secondary organic aerosol formation of α-pinene, limonene, and m-cresol comparing day- and nighttime radical chemistry A. Mutzel et al. https://doi.org/10.5194/acp-21-8479-2021
- Analytical methodologies for oxidized organic compounds in the atmosphere A. Tiusanen et al. https://doi.org/10.1039/D3EM00163F
- Partitioning of hydrogen peroxide in gas-liquid and gas-aerosol phases X. Xuan et al. https://doi.org/10.5194/acp-20-5513-2020
- Water Plays Multifunctional Roles in the Intervening Formation of Secondary Organic Aerosols in Ozonolysis of Limonene: A Valence Photoelectron Spectroscopy and Density Functional Theory Study J. Huang et al. https://doi.org/10.1021/acs.jpclett.3c00560
- Atmospheric fate of ketolimonene part 2: Highly oxygenated molecules (HOMs) and secondary organic aerosol (SOA) formation from NO3-initiated oxidation S. Solaiman et al. https://doi.org/10.1016/j.jes.2026.105636
- Organic Peroxides in Aerosol: Key Reactive Intermediates for Multiphase Processes in the Atmosphere S. Wang et al. https://doi.org/10.1021/acs.chemrev.2c00430
- The oxidation mechanism of gas-phase ozonolysis of limonene in the atmosphere L. Wang & L. Wang https://doi.org/10.1039/D0CP05803C
- Investigation of the limonene photooxidation by OH at different NO concentrations in the atmospheric simulation chamber SAPHIR (Simulation of Atmospheric PHotochemistry In a large Reaction Chamber) J. Pang et al. https://doi.org/10.5194/acp-22-8497-2022
- New insights into the chemical composition and formation mechanisms of secondary organic aerosols produced in the ozonolysis of limonene F. Jacob et al. https://doi.org/10.1016/j.jaerosci.2023.106214
- Stability of Monoterpene-Derived α‑Hydroxyalkyl-Hydroperoxides in Aqueous Organic Media: Relevance to the Fate of Hydroperoxides in Aerosol Particle Phases J. Qiu et al. https://doi.org/10.1021/acs.est.9b07497
- Formation pathways of aldehydes from heated cooking oils M. Takhar et al. https://doi.org/10.1039/D1EM00532D
- Technical note: Characterization of a single-beam gradient force aerosol optical tweezer for droplet trapping, phase transition monitoring, and morphology studies X. Pei et al. https://doi.org/10.5194/acp-24-5235-2024
- Nitrate radical, ozone and hydroxyl radical initiated aging of limonene secondary organic aerosol S. Ramasamy et al. https://doi.org/10.1016/j.aeaoa.2021.100102
- Formation of secondary organic aerosols from the reaction of γ-terpinene with ozone: yields and morphology L. Fayad et al. https://doi.org/10.1016/j.atmosenv.2021.118600
- Investigation of RH effect on uncommon limonene ozonolysis products and SOA formation in indoor air with real time measurement techniques K. Pytel & B. Zabiegała https://doi.org/10.1016/j.chemosphere.2023.140854
- Conformational landscape and internal dynamics of limona ketone, a key oxidation product of limonene N. Osseiran et al. https://doi.org/10.1016/j.jms.2022.111643
- Formation of highly oxygenated organic molecules from the oxidation of limonene by OH radical: significant contribution of H-abstraction pathway H. Luo et al. https://doi.org/10.5194/acp-23-7297-2023
- Contrasting impacts of humidity on the ozonolysis of monoterpenes: insights into the multi-generation chemical mechanism S. Zhang et al. https://doi.org/10.5194/acp-23-10809-2023
- Atmospheric aging suppresses the formation of limonene-derived organic peroxides X. Chen et al. https://doi.org/10.1039/D5EM00823A
- A new iodometric microwave-assisted method for peroxide determination in Secondary Organic Aerosols D. Alba-Elena et al. https://doi.org/10.1016/j.atmosenv.2023.119960
- Waste aroma profile in the framework of food waste management through household composting A. Agapios et al. https://doi.org/10.1016/j.jclepro.2020.120340
- Photooxidation-Initiated Aqueous-Phase Formation of Organic Peroxides: Delving into Formation Mechanisms T. Gautam et al. https://doi.org/10.1021/acs.est.3c01162
Saved (final revised paper)
Latest update: 03 Nov 2026
Short summary
In limonene ozonolysis, the endocyclic double bond is inclined to generate hydroxy radicals, while the exocyclic double bond has a higher fraction of forming stabilized Criegee intermediates. The oxidation that happens on the exocyclic double bond greatly contributes to the organic peroxides, which account for a considerable proportion of secondary organic aerosol. Terpenes with multiple double bonds may have more complex effects on the atmosphere than previously thought.
In limonene ozonolysis, the endocyclic double bond is inclined to generate hydroxy radicals,...
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