Articles | Volume 18, issue 20
https://doi.org/10.5194/acp-18-14965-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-18-14965-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
18 Oct 2018
Research article |
| 18 Oct 2018
| 18 Oct 2018
The quasi-liquid layer of ice revisited: the role of temperature gradients and tip chemistry in AFM studies
Julián Gelman Constantin
CORRESPONDING AUTHOR
Departamento de Física de la Materia Condensada, Centro Atómico Constituyentes,
Comisión Nacional de Energía Atómica, San Martín, B1650KNA, Buenos Aires, Argentina
Instituto de Química Física de los Materiales, Medio Ambiente y
Energía (UBA-CONICET), Facultad de Ciencias Exactas y Naturales, Universidad
de Buenos Aires, Pabellón II, Ciudad Universitaria, C1428EGA, Buenos Aires, Argentina
current address: División de Química Atmosférica, Centro Atómico
Constituyentes, Comisión Nacional de Energía Atómica, San Martín, B1650KNA, Buenos Aires, Argentina
Melisa M. Gianetti
Instituto de Química Física de los Materiales, Medio Ambiente y
Energía (UBA-CONICET), Facultad de Ciencias Exactas y Naturales, Universidad
de Buenos Aires, Pabellón II, Ciudad Universitaria, C1428EGA, Buenos Aires, Argentina
María P. Longinotti
CORRESPONDING AUTHOR
Instituto de Química Física de los Materiales, Medio Ambiente y
Energía (UBA-CONICET), Facultad de Ciencias Exactas y Naturales, Universidad
de Buenos Aires, Pabellón II, Ciudad Universitaria, C1428EGA, Buenos Aires, Argentina
Horacio R. Corti
Departamento de Física de la Materia Condensada, Centro Atómico Constituyentes,
Comisión Nacional de Energía Atómica, San Martín, B1650KNA, Buenos Aires, Argentina
Instituto de Química Física de los Materiales, Medio Ambiente y
Energía (UBA-CONICET), Facultad de Ciencias Exactas y Naturales, Universidad
de Buenos Aires, Pabellón II, Ciudad Universitaria, C1428EGA, Buenos Aires, Argentina
Viewed
Total article views: 2,834 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 08 May 2018)
| HTML | XML | Total | Supplement | BibTeX | EndNote | |
|---|---|---|---|---|---|---|
| 1,756 | 988 | 90 | 2,834 | 422 | 77 | 87 |
- HTML: 1,756
- PDF: 988
- XML: 90
- Total: 2,834
- Supplement: 422
- BibTeX: 77
- EndNote: 87
Total article views: 2,175 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 18 Oct 2018)
| HTML | XML | Total | Supplement | BibTeX | EndNote | |
|---|---|---|---|---|---|---|
| 1,360 | 741 | 74 | 2,175 | 183 | 66 | 77 |
- HTML: 1,360
- PDF: 741
- XML: 74
- Total: 2,175
- Supplement: 183
- BibTeX: 66
- EndNote: 77
Total article views: 659 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 08 May 2018)
| HTML | XML | Total | Supplement | BibTeX | EndNote | |
|---|---|---|---|---|---|---|
| 396 | 247 | 16 | 659 | 239 | 11 | 10 |
- HTML: 396
- PDF: 247
- XML: 16
- Total: 659
- Supplement: 239
- BibTeX: 11
- EndNote: 10
Viewed (geographical distribution)
Total article views: 2,834 (including HTML, PDF, and XML)
Thereof 2,827 with geography defined
and 7 with unknown origin.
Total article views: 2,175 (including HTML, PDF, and XML)
Thereof 2,170 with geography defined
and 5 with unknown origin.
Total article views: 659 (including HTML, PDF, and XML)
Thereof 657 with geography defined
and 2 with unknown origin.
| Country | # | Views | % |
|---|
| Country | # | Views | % |
|---|
| Country | # | Views | % |
|---|
| Total: | 0 |
| HTML: | 0 |
| PDF: | 0 |
| XML: | 0 |
- 1
1
| Total: | 0 |
| HTML: | 0 |
| PDF: | 0 |
| XML: | 0 |
- 1
1
| Total: | 0 |
| HTML: | 0 |
| PDF: | 0 |
| XML: | 0 |
- 1
1
Cited
31 citations as recorded by crossref.
- Icephobic properties of aqueous self-lubricating coatings containing PEG-PDMS copolymers M. Shamshiri et al. 10.1016/j.porgcoat.2021.106466
- Investigating the quasi-liquid layer on ice surfaces: a comparison of order parameters J. Shi et al. 10.1039/D2CP00752E
- Rounded Layering Transitions on the Surface of Ice P. Llombart et al. 10.1103/PhysRevLett.124.065702
- Investigating ice surfaces formed near the freezing point in the vapor phase via atomic force microscopy Y. Miyato et al. 10.7567/1347-4065/ab203d
- Insights into the interface during ice adhesion measurements S. Apelt & U. Bergmann 10.1088/2632-959X/ad12da
- Electron microscope loading and in situ nanoindentation of water ice at cryogenic temperatures R. Dubosq et al. 10.1371/journal.pone.0281703
- On Calculating Deposition Coefficients and Aspect-Ratio Evolution in Approximate Models of Ice Crystal Vapor Growth J. Harrington et al. 10.1175/JAS-D-18-0319.1
- Potential use of smart coatings for icephobic applications: A review M. Shamshiri et al. 10.1016/j.surfcoat.2021.127656
- Premelting of ice adsorbed on a rock surface V. Esteso et al. 10.1039/C9CP06836H
- Water-solid interfaces probed by high-resolution atomic force microscopy J. Peng et al. 10.1016/j.surfrep.2021.100549
- Anomalously High Proton Conduction of Interfacial Water V. Artemov et al. 10.1021/acs.jpclett.0c00910
- Deposition freezing, pore condensation freezing and adsorption: three processes, one description? M. Lbadaoui-Darvas et al. 10.5194/acp-23-10057-2023
- Molecular dynamics simulation study on the gas hydrate formation in pores of sediment J. Zhong et al. 10.1016/j.marpetgeo.2025.107299
- Correlations between curling stone frictions and tribology’s Stribeck curve: concepts to consider A. Brown 10.1139/cjp-2024-0095
- Soot PCF: pore condensation and freezing framework for soot aggregates C. Marcolli et al. 10.5194/acp-21-7791-2021
- A Case Study of Cloud-Top Kelvin–Helmholtz Instability Waves near the Dendritic Growth Zone M. Cann et al. 10.1175/JAS-D-21-0106.1
- Approximate Models for Lateral Growth on Ice Crystal Surfaces during Vapor Depositional Growth J. Harrington & G. Pokrifka 10.1175/JAS-D-20-0228.1
- Transition dynamics and metastable states during premelting and freezing of ice surfaces S. Cui & H. Chen 10.1103/PhysRevB.108.045413
- Asymmetric Hydrogen-Bonding Structure at a Water/Ice Interface T. Ishiyama & K. Kitanaka 10.1021/acs.jpcc.0c08173
- Scratch-Healing Behavior of Ice by Local Sublimation and Condensation M. Demmenie et al. 10.1021/acs.jpcc.1c09590
- Topology-Based Phase Identification of Bulk, Interface, and Confined Water Using an Edge-Conditioned Convolutional Graph Neural Network A. Moradzadeh et al. 10.1021/acs.jpcc.2c07423
- Probing the instability of surface structure on solid Hydrates: A microscopic perspective through experiment and simulation W. Li et al. 10.1016/j.apsusc.2023.158971
- Perspective on sum frequency generation spectroscopy of ice surfaces and interfaces S. Yamaguchi et al. 10.1016/j.chemphys.2019.03.005
- Appearance and Disappearance of Quasi-Liquid Layers on Ice Crystals in the Presence of Nitric Acid Gas K. Nagashima et al. 10.3390/cryst10020072
- Environmental chamber with controlled temperature and relative humidity for ice crystallization kinetic measurements by atomic force microscopy M. Gianetti et al. 10.1063/1.5132537
- Atomistic Simulation of Nanoindentation of Ice Ih P. Santos-Flórez et al. 10.1021/acs.jpcc.0c00255
- Surface Science in the Research and Development of Hydrate-Based Sustainable Technologies N. Nguyen et al. 10.1021/acssuschemeng.2c00028
- HCl Droplets Induced Bunched Steps on Ice Crystal Surfaces under Atmospheric-Concentration HCl Gas K. Nagashima et al. 10.1021/acs.cgd.1c00172
- Intermolecular forces at ice and water interfaces: Premelting, surface freezing, and regelation J. Luengo-Márquez et al. 10.1063/5.0097378
- Atomic force microscopy imaging of ice crystal surfaces formed in aqueous solutions containing ice-binding proteins M. Chasnitsky et al. 10.1016/j.jcrysgro.2022.126961
- A novel hybrid anti-icing surface combining an aqueous self-lubricating coating and phase-change materials M. Shamshiri et al. 10.1016/j.porgcoat.2023.107414
31 citations as recorded by crossref.
- Icephobic properties of aqueous self-lubricating coatings containing PEG-PDMS copolymers M. Shamshiri et al. 10.1016/j.porgcoat.2021.106466
- Investigating the quasi-liquid layer on ice surfaces: a comparison of order parameters J. Shi et al. 10.1039/D2CP00752E
- Rounded Layering Transitions on the Surface of Ice P. Llombart et al. 10.1103/PhysRevLett.124.065702
- Investigating ice surfaces formed near the freezing point in the vapor phase via atomic force microscopy Y. Miyato et al. 10.7567/1347-4065/ab203d
- Insights into the interface during ice adhesion measurements S. Apelt & U. Bergmann 10.1088/2632-959X/ad12da
- Electron microscope loading and in situ nanoindentation of water ice at cryogenic temperatures R. Dubosq et al. 10.1371/journal.pone.0281703
- On Calculating Deposition Coefficients and Aspect-Ratio Evolution in Approximate Models of Ice Crystal Vapor Growth J. Harrington et al. 10.1175/JAS-D-18-0319.1
- Potential use of smart coatings for icephobic applications: A review M. Shamshiri et al. 10.1016/j.surfcoat.2021.127656
- Premelting of ice adsorbed on a rock surface V. Esteso et al. 10.1039/C9CP06836H
- Water-solid interfaces probed by high-resolution atomic force microscopy J. Peng et al. 10.1016/j.surfrep.2021.100549
- Anomalously High Proton Conduction of Interfacial Water V. Artemov et al. 10.1021/acs.jpclett.0c00910
- Deposition freezing, pore condensation freezing and adsorption: three processes, one description? M. Lbadaoui-Darvas et al. 10.5194/acp-23-10057-2023
- Molecular dynamics simulation study on the gas hydrate formation in pores of sediment J. Zhong et al. 10.1016/j.marpetgeo.2025.107299
- Correlations between curling stone frictions and tribology’s Stribeck curve: concepts to consider A. Brown 10.1139/cjp-2024-0095
- Soot PCF: pore condensation and freezing framework for soot aggregates C. Marcolli et al. 10.5194/acp-21-7791-2021
- A Case Study of Cloud-Top Kelvin–Helmholtz Instability Waves near the Dendritic Growth Zone M. Cann et al. 10.1175/JAS-D-21-0106.1
- Approximate Models for Lateral Growth on Ice Crystal Surfaces during Vapor Depositional Growth J. Harrington & G. Pokrifka 10.1175/JAS-D-20-0228.1
- Transition dynamics and metastable states during premelting and freezing of ice surfaces S. Cui & H. Chen 10.1103/PhysRevB.108.045413
- Asymmetric Hydrogen-Bonding Structure at a Water/Ice Interface T. Ishiyama & K. Kitanaka 10.1021/acs.jpcc.0c08173
- Scratch-Healing Behavior of Ice by Local Sublimation and Condensation M. Demmenie et al. 10.1021/acs.jpcc.1c09590
- Topology-Based Phase Identification of Bulk, Interface, and Confined Water Using an Edge-Conditioned Convolutional Graph Neural Network A. Moradzadeh et al. 10.1021/acs.jpcc.2c07423
- Probing the instability of surface structure on solid Hydrates: A microscopic perspective through experiment and simulation W. Li et al. 10.1016/j.apsusc.2023.158971
- Perspective on sum frequency generation spectroscopy of ice surfaces and interfaces S. Yamaguchi et al. 10.1016/j.chemphys.2019.03.005
- Appearance and Disappearance of Quasi-Liquid Layers on Ice Crystals in the Presence of Nitric Acid Gas K. Nagashima et al. 10.3390/cryst10020072
- Environmental chamber with controlled temperature and relative humidity for ice crystallization kinetic measurements by atomic force microscopy M. Gianetti et al. 10.1063/1.5132537
- Atomistic Simulation of Nanoindentation of Ice Ih P. Santos-Flórez et al. 10.1021/acs.jpcc.0c00255
- Surface Science in the Research and Development of Hydrate-Based Sustainable Technologies N. Nguyen et al. 10.1021/acssuschemeng.2c00028
- HCl Droplets Induced Bunched Steps on Ice Crystal Surfaces under Atmospheric-Concentration HCl Gas K. Nagashima et al. 10.1021/acs.cgd.1c00172
- Intermolecular forces at ice and water interfaces: Premelting, surface freezing, and regelation J. Luengo-Márquez et al. 10.1063/5.0097378
- Atomic force microscopy imaging of ice crystal surfaces formed in aqueous solutions containing ice-binding proteins M. Chasnitsky et al. 10.1016/j.jcrysgro.2022.126961
- A novel hybrid anti-icing surface combining an aqueous self-lubricating coating and phase-change materials M. Shamshiri et al. 10.1016/j.porgcoat.2023.107414
Latest update: 16 Mar 2025
Short summary
Numerous studies have shown that ice surface is actually coated by a thin layer of water even for temperatures below melting temperature. This quasi-liquid layer is relevant in the atmospheric chemistry of clouds, polar regions, glaciers, and other cold regions. We present new results of atomic force microscopy on pure ice, which suggests a thickness for this layer below 1 nm between -7 ºC and -2 ºC. We propose that in many cases previous authors have overestimated this thickness.
Numerous studies have shown that ice surface is actually coated by a thin layer of water even...
Altmetrics
Final-revised paper
Preprint