Articles | Volume 18, issue 18
https://doi.org/10.5194/acp-18-13617-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-18-13617-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
DMS oxidation and sulfur aerosol formation in the marine troposphere: a focus on reactive halogen and multiphase chemistry
Qianjie Chen
Department of Atmospheric Sciences, University of Washington, Seattle, WA, USA
now at: Department of Chemistry, University of Michigan, Ann Arbor, MI, USA
Tomás Sherwen
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry, University of York, York, UK
National Centre for Atmospheric Science (NCAS), University of York, York, UK
Mathew Evans
Wolfson Atmospheric Chemistry Laboratories, Department of Chemistry, University of York, York, UK
National Centre for Atmospheric Science (NCAS), University of York, York, UK
Becky Alexander
CORRESPONDING AUTHOR
Department of Atmospheric Sciences, University of Washington, Seattle, WA, USA
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- Increased oceanic dimethyl sulfide emissions in areas of sea ice retreat inferred from a Greenland ice core Y. Kurosaki et al. 10.1038/s43247-022-00661-w
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- Overview of the Antarctic Circumnavigation Expedition: Study of Preindustrial-like Aerosols and Their Climate Effects (ACE-SPACE) J. Schmale et al. 10.1175/BAMS-D-18-0187.1
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- Formation of organic sulfur compounds through SO<sub>2</sub>-initiated photochemistry of PAHs and dimethylsulfoxide at the air-water interface H. Jiang et al. 10.5194/acp-22-4237-2022
- Isotopic Evidence for the High Contribution of Wintertime Photochemistry to Particulate Nitrate Formation in Northern China Z. Zhang et al. 10.1029/2021JD035324
- Aerosol Properties and Their Influences on Marine Boundary Layer Cloud Condensation Nuclei over the Southern Ocean X. Zhang et al. 10.3390/atmos14081246
- Diverse sources and aging change the mixing state and ice nucleation properties of aerosol particles over the western Pacific and Southern Ocean J. Xue et al. 10.5194/acp-24-7731-2024
- Near-Explicit Multiphase Modeling of Halogen Chemistry in a Mixed Urban and Maritime Coastal Area E. Hoffmann et al. 10.1021/acsearthspacechem.9b00184
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- Impact of Molecular Chlorine Production from Aerosol Iron Photochemistry on Atmospheric Oxidative Capacity in North China Q. Chen et al. 10.1021/acs.est.4c02534
- Measurement report: Long-range transport and the fate of dimethyl sulfide oxidation products in the free troposphere derived from observations at the high-altitude research station Chacaltaya (5240 m a.s.l.) in the Bolivian Andes W. Scholz et al. 10.5194/acp-23-895-2023
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- Differing Mechanisms of New Particle Formation at Two Arctic Sites L. Beck et al. 10.1029/2020GL091334
- Modification of the Conversion of Dimethylsulfide to Methanesulfonic Acid by Anthropogenic Pollution as Revealed by Long-Term Observations B. Jiang et al. 10.1021/acsearthspacechem.1c00222
- Heterogeneous Reaction of Dimethyl Sulfide with a Chlorine Atom I. Larin et al. 10.1134/S1990793124700209
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Discussed (final revised paper)
Latest update: 25 Dec 2024
Short summary
Uncertainty in the natural tropospheric sulfur cycle represents the largest source of uncertainty in radiative forcing estimates of sulfate aerosol. This study investigates the natural sulfur cycle in the marine troposphere using the GEOS-Chem model. We found that BrO is important for DMS oxidation and multiphase chemistry is important for MSA production and loss, which have implications for the yield of SO2 and MSA from DMS oxidation and the radiative effect of DMS-derived sulfate aerosol.
Uncertainty in the natural tropospheric sulfur cycle represents the largest source of...
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