Articles | Volume 18, issue 16
https://doi.org/10.5194/acp-18-12315-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-18-12315-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
24 Aug 2018
Research article |
| 24 Aug 2018
| 24 Aug 2018
Tropospheric sources and sinks of gas-phase acids in the Colorado Front Range
James M. Mattila
Department of Chemistry, Colorado State University, Fort Collins, CO,
USA
Patrick Brophy
Department of Chemistry, Colorado State University, Fort Collins, CO,
USA
Jeffrey Kirkland
Department of Chemistry, Colorado State University, Fort Collins, CO,
USA
Samuel Hall
Atmospheric Chemistry Division, National Center for Atmospheric Research, Boulder, CO, USA
Kirk Ullmann
Atmospheric Chemistry Division, National Center for Atmospheric Research, Boulder, CO, USA
Emily V. Fischer
Department of Atmospheric Science, Colorado State University, Fort
Collins, CO, USA
Steve Brown
NOAA Earth System Research Laboratory, Chemical Sciences Division,
Boulder, CO, USA
Department of Chemistry and Biochemistry, University of Colorado
Boulder, Boulder, CO, USA
Erin McDuffie
NOAA Earth System Research Laboratory, Chemical Sciences Division,
Boulder, CO, USA
Department of Chemistry and Biochemistry, University of Colorado
Boulder, Boulder, CO, USA
Cooperative Institute for Research in Environmental Sciences,
University of Colorado Boulder, Boulder, CO, USA
Alex Tevlin
Department of Chemistry, University of Toronto, Toronto, ON, Canada
Delphine K. Farmer
CORRESPONDING AUTHOR
Department of Chemistry, Colorado State University, Fort Collins, CO,
USA
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Cited
21 citations as recorded by crossref.
- Behavior of Isocyanic Acid and Other Nitrogen-Containing Volatile Organic Compounds in The Indoor Environment C. Wang et al. 10.1021/acs.est.1c08182
- Concentration levels of atmospheric contaminants in Brazilian cities measured by passive sampling F. Campos da Rocha et al. 10.1016/j.uclim.2023.101739
- Volatility Change during Droplet Evaporation of Pyruvic Acid S. Petters et al. 10.1021/acsearthspacechem.0c00044
- Isoprene versus Monoterpenes as Gas-Phase Organic Acid Precursors in the Atmosphere M. Link et al. 10.1021/acsearthspacechem.1c00093
- Atmospheric gaseous organic acids in winter in a rural site of the North China Plain X. Hu et al. 10.1016/j.jes.2021.05.035
- Closing the Reactive Carbon Flux Budget: Observations From Dual Mass Spectrometers Over a Coniferous Forest M. Vermeuel et al. 10.1029/2023JD038753
- Overview of HOMEChem: House Observations of Microbial and Environmental Chemistry D. Farmer et al. 10.1039/C9EM00228F
- Surface Wetness as an Unexpected Control on Forest Exchange of Volatile Organic Acids S. Fulgham et al. 10.1029/2020GL088745
- Underrated primary biogenic origin and lifetime of atmospheric formic and acetic acid X. Lee et al. 10.1038/s41598-021-86542-2
- Chemical characterization of oxygenated organic compounds in the gas phase and particle phase using iodide CIMS with FIGAERO in urban air C. Ye et al. 10.5194/acp-21-8455-2021
- Isocyanic acid (HNCO) and its fate in the atmosphere: a review M. Leslie et al. 10.1039/C9EM00003H
- Seasonal Flux Measurements over a Colorado Pine Forest Demonstrate a Persistent Source of Organic Acids S. Fulgham et al. 10.1021/acsearthspacechem.9b00182
- Sulfuric acid–dimethylamine particle formation enhanced by functional organic acids: an integrated experimental and theoretical study C. Wang et al. 10.1039/D2CP01671K
- Pyruvic acid in the boreal forest: gas-phase mixing ratios and impact on radical chemistry P. Eger et al. 10.5194/acp-20-3697-2020
- Oxidation of Volatile Organic Compounds as the Major Source of Formic Acid in a Mixed Forest Canopy H. Alwe et al. 10.1029/2018GL081526
- Pyruvic acid, an efficient catalyst in SO<sub>3</sub> hydrolysis and effective clustering agent in sulfuric-acid-based new particle formation N. Tsona Tchinda et al. 10.5194/acp-22-1951-2022
- Solubility and solution-phase chemistry of isocyanic acid, methyl isocyanate, and cyanogen halides J. Roberts & Y. Liu 10.5194/acp-19-4419-2019
- Measuring Biosphere–Atmosphere Exchange of Short-Lived Climate Forcers and Their Precursors D. Farmer & M. Riches 10.1021/acs.accounts.0c00203
- Simultaneous leaf-level measurement of trace gas emissions and photosynthesis with a portable photosynthesis system M. Riches et al. 10.5194/amt-13-4123-2020
- Sources of elevated organic acids in the mountainous background atmosphere of southern China Y. Guo et al. 10.1016/j.scitotenv.2023.169673
- Emission of formic and acetic acids from two Colorado soils A. Mielnik et al. 10.1039/C8EM00356D
21 citations as recorded by crossref.
- Behavior of Isocyanic Acid and Other Nitrogen-Containing Volatile Organic Compounds in The Indoor Environment C. Wang et al. 10.1021/acs.est.1c08182
- Concentration levels of atmospheric contaminants in Brazilian cities measured by passive sampling F. Campos da Rocha et al. 10.1016/j.uclim.2023.101739
- Volatility Change during Droplet Evaporation of Pyruvic Acid S. Petters et al. 10.1021/acsearthspacechem.0c00044
- Isoprene versus Monoterpenes as Gas-Phase Organic Acid Precursors in the Atmosphere M. Link et al. 10.1021/acsearthspacechem.1c00093
- Atmospheric gaseous organic acids in winter in a rural site of the North China Plain X. Hu et al. 10.1016/j.jes.2021.05.035
- Closing the Reactive Carbon Flux Budget: Observations From Dual Mass Spectrometers Over a Coniferous Forest M. Vermeuel et al. 10.1029/2023JD038753
- Overview of HOMEChem: House Observations of Microbial and Environmental Chemistry D. Farmer et al. 10.1039/C9EM00228F
- Surface Wetness as an Unexpected Control on Forest Exchange of Volatile Organic Acids S. Fulgham et al. 10.1029/2020GL088745
- Underrated primary biogenic origin and lifetime of atmospheric formic and acetic acid X. Lee et al. 10.1038/s41598-021-86542-2
- Chemical characterization of oxygenated organic compounds in the gas phase and particle phase using iodide CIMS with FIGAERO in urban air C. Ye et al. 10.5194/acp-21-8455-2021
- Isocyanic acid (HNCO) and its fate in the atmosphere: a review M. Leslie et al. 10.1039/C9EM00003H
- Seasonal Flux Measurements over a Colorado Pine Forest Demonstrate a Persistent Source of Organic Acids S. Fulgham et al. 10.1021/acsearthspacechem.9b00182
- Sulfuric acid–dimethylamine particle formation enhanced by functional organic acids: an integrated experimental and theoretical study C. Wang et al. 10.1039/D2CP01671K
- Pyruvic acid in the boreal forest: gas-phase mixing ratios and impact on radical chemistry P. Eger et al. 10.5194/acp-20-3697-2020
- Oxidation of Volatile Organic Compounds as the Major Source of Formic Acid in a Mixed Forest Canopy H. Alwe et al. 10.1029/2018GL081526
- Pyruvic acid, an efficient catalyst in SO<sub>3</sub> hydrolysis and effective clustering agent in sulfuric-acid-based new particle formation N. Tsona Tchinda et al. 10.5194/acp-22-1951-2022
- Solubility and solution-phase chemistry of isocyanic acid, methyl isocyanate, and cyanogen halides J. Roberts & Y. Liu 10.5194/acp-19-4419-2019
- Measuring Biosphere–Atmosphere Exchange of Short-Lived Climate Forcers and Their Precursors D. Farmer & M. Riches 10.1021/acs.accounts.0c00203
- Simultaneous leaf-level measurement of trace gas emissions and photosynthesis with a portable photosynthesis system M. Riches et al. 10.5194/amt-13-4123-2020
- Sources of elevated organic acids in the mountainous background atmosphere of southern China Y. Guo et al. 10.1016/j.scitotenv.2023.169673
- Emission of formic and acetic acids from two Colorado soils A. Mielnik et al. 10.1039/C8EM00356D
Latest update: 23 Apr 2024
Short summary
Molecular acids in the atmosphere have implications for human health and air quality. Measurements of various acidic molecules were performed in the Colorado Front Range. Atmospheric concentrations of many acids increased during the day, indicative of sunlight-related production sources. A surface-level source of many acids persisting throughout day and night was observed. Traffic and agricultural activity were important anthropogenic sources of several acids near the measurement site.
Molecular acids in the atmosphere have implications for human health and air quality....
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