Articles | Volume 18, issue 16
Atmos. Chem. Phys., 18, 11647–11661, 2018
https://doi.org/10.5194/acp-18-11647-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Special issue: Multiphase chemistry of secondary aerosol formation under...
Research article
16 Aug 2018
Research article
| 16 Aug 2018
Nitrogen isotope fractionation during gas-to-particle conversion of NOx to NO3− in the atmosphere – implications for isotope-based NOx source apportionment
Yunhua Chang et al.
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Cited
44 citations as recorded by crossref.
- Stable isotope ratio of atmospheric and seawater nitrate in the East Sea in the northwestern Pacific ocean H. Kim et al. 10.1016/j.marpolbul.2019.110610
- Agriculture driven nitrogen wet deposition in a karst catchment in southwest China J. Zeng et al. 10.1016/j.agee.2020.106883
- Characterization of organic aerosols from a Chinese megacity during winter: predominance of fossil fuel combustion M. Haque et al. 10.5194/acp-19-5147-2019
- Formation Mechanisms and Source Apportionments of Airborne Nitrate Aerosols at a Himalayan-Tibetan Plateau Site: Insights from Nitrogen and Oxygen Isotopic Compositions Y. Lin et al. 10.1021/acs.est.1c03957
- Formation pathways and sources of size-segregated nitrate aerosols in a megacity identified by dual isotopes Y. Zhu et al. 10.1016/j.atmosenv.2021.118708
- Important contribution of N2O5 hydrolysis to the daytime nitrate in Xi'an, China during haze periods: Isotopic analysis and WRF-Chem model simulation C. Wu et al. 10.1016/j.envpol.2021.117712
- Isotopic evaluation on relative contributions of major NOx sources to nitrate of PM2.5 in Beijing W. Song et al. 10.1016/j.envpol.2019.01.081
- Changes of Emission Sources to Nitrate Aerosols in Beijing After the Clean Air Actions: Evidence From Dual Isotope Compositions M. Fan et al. 10.1029/2019JD031998
- Comprehensive Insights Into O 3 Changes During the COVID‐19 From O 3 Formation Regime and Atmospheric Oxidation Capacity S. Zhu et al. 10.1029/2021GL093668
- Seasonal differences in sources and formation processes of PM2.5 nitrate in an urban environment of North China Y. Li et al. 10.1016/j.jes.2021.08.020
- Dual-modelling-based source apportionment of NOx in five Chinese megacities: Providing the isotopic footprint from 2013 to 2014 Z. Zong et al. 10.1016/j.envint.2020.105592
- Combining dual isotopes and a Bayesian isotope mixing model to quantify the nitrate sources of precipitation in Ningbo, East China Y. Shi et al. 10.1016/j.scitotenv.2021.146297
- Fossil-driven secondary inorganic PM2.5 enhancement in the North China Plain: Evidence from carbon and nitrogen isotopes S. Lim et al. 10.1016/j.envpol.2020.115163
- Nitrogen isotopes in nitrate aerosols collected in the remote marine boundary layer: Implications for nitrogen isotopic fractionations among atmospheric reactive nitrogen species J. Li et al. 10.1016/j.atmosenv.2020.118028
- Differentiation Between Nitrate Aerosol Formation Pathways in a Southeast Chinese City by Dual Isotope and Modeling Studies H. Xiao et al. 10.1029/2020JD032604
- Nitrate sources and formation of rainwater constrained by dual isotopes in Southeast Asia: Example from Singapore C. Li et al. 10.1016/j.chemosphere.2019.125024
- Diurnal and seasonal variations in water-soluble inorganic ions and nitrate dual isotopes of PM2.5: Implications for source apportionment and formation processes of urban aerosol nitrate Q. Li et al. 10.1016/j.atmosres.2020.105197
- Assessing Contributions of Agricultural and Nonagricultural Emissions to Atmospheric Ammonia in a Chinese Megacity Y. Chang et al. 10.1021/acs.est.8b05984
- Stable carbon and nitrogen isotope ratio in PM1 and size segregated aerosol particles over the Baltic Sea I. Garbarienė et al. 10.3952/physics.v59i3.4082
- Enhanced Primary Production in the Oligotrophic South China Sea Related to Southeast Asian Forest Fires H. Xiao et al. 10.1029/2019JC015663
- Isotopic constraints on the atmospheric sources and formation of nitrogenous species in clouds influenced by biomass burning Y. Chang et al. 10.5194/acp-19-12221-2019
- Evidence of a Large Bias in Rooftop Measurements of Atmospheric Ammonia Y. Kuang et al. 10.1021/acsearthspacechem.1c00331
- Multi isotope systematics of precipitation to trace the sources of air pollutants in Seoul, Korea Y. Kim et al. 10.1016/j.envpol.2021.117548
- The observation of isotopic compositions of atmospheric nitrate in Shanghai China and its implication for reactive nitrogen chemistry P. He et al. 10.1016/j.scitotenv.2020.136727
- Impact of Coal Replacing Project on atmospheric fine aerosol nitrate loading and formation pathways in urban Tianjin: Insights from chemical composition and 15N and 18O isotope ratios X. Feng et al. 10.1016/j.scitotenv.2019.134797
- Isotopic advances in understanding reactive nitrogen deposition and atmospheric processing E. Elliott et al. 10.1016/j.scitotenv.2018.12.177
- High resolution, extreme isotopic variability of precipitation nitrate L. Rose et al. 10.1016/j.atmosenv.2019.03.012
- Quantifying the nitrogen isotope effects during photochemical equilibrium between NO and NO<sub>2</sub>: implications for <i>δ</i><sup>15</sup>N in tropospheric reactive nitrogen J. Li et al. 10.5194/acp-20-9805-2020
- Heterogeneous formation of particulate nitrate under ammonium-rich regimes during the high-PM<sub>2.5</sub> events in Nanjing, China Y. Lin et al. 10.5194/acp-20-3999-2020
- Nitrogen isotope differences between atmospheric nitrate and corresponding nitrogen oxides: A new constraint using oxygen isotopes W. Song et al. 10.1016/j.scitotenv.2019.134515
- Ion‐exchange resin and denitrification pretreatment for determining δ 15 N‐NH 4 + , δ 15 N‐NO 3 − , and δ 18 O‐NO 3 − values H. Kawashima et al. 10.1002/rcm.9027
- Insight into the Variability of the Nitrogen Isotope Composition of Vehicular NOx in China Z. Zong et al. 10.1021/acs.est.0c04749
- The importance of coal combustion and heterogeneous reaction for atmospheric nitrate pollution in a cold metropolis in China: Insights from isotope fractionation and Bayesian mixing model X. Sun et al. 10.1016/j.atmosenv.2020.117730
- New Constraints on Isotopic Effects and Major Sources of Nitrate in Atmospheric Particulates by Combining δ 15 N and Δ 17 O Signatures W. Song et al. 10.1029/2020JD034168
- Nitrate aerosol formation and source assessment in winter at different regions in Northeast China Z. Zhao et al. 10.1016/j.atmosenv.2021.118767
- Nitrate isotopic composition of sequential Hurricane Harvey wet deposition: Low latitude NOx sources and oxidation chemistry J. David Felix & D. Murgulet 10.1016/j.atmosenv.2020.117748
- Coal and biomass burning as major emissions of NOX in Northeast China: Implication from dual isotopes analysis of fine nitrate aerosols Z. Zhao et al. 10.1016/j.atmosenv.2020.117762
- Stable 15N isotopes in fine and coarse urban particulate matter H. Wiedenhaus et al. 10.1080/02786826.2021.1905150
- Isotope-based source apportionment of nitrogen-containing aerosols: A case study in an industrial city in China M. Fan et al. 10.1016/j.atmosenv.2019.05.020
- Determination of Stable Nitrogen and Oxygen Isotope Ratios in Atmospheric Aerosol Nitrates Z. ZHAO et al. 10.1016/S1872-2040(19)61166-7
- Chemical characterization and stable nitrogen isotope composition of nitrogenous component of ambient aerosols from Kanpur in the Indo-Gangetic Plains G. Singh et al. 10.1016/j.scitotenv.2020.143032
- The use of stable oxygen and nitrogen isotopic signatures to reveal variations in the nitrate formation pathways and sources in different seasons and regions in China W. Guo et al. 10.1016/j.envres.2021.111537
- Nitrate Isotopic Composition in Precipitation at a Chinese Megacity: Seasonal Variations, Atmospheric Processes, and Implications for Sources Z. Li et al. 10.1029/2019EA000759
- Using nitrogen and oxygen stable isotopes to analyze the major NOx sources to nitrate of PM2.5 in Lanzhou, northwest China, in winter-spring periods M. Yin et al. 10.1016/j.atmosenv.2022.119036
44 citations as recorded by crossref.
- Stable isotope ratio of atmospheric and seawater nitrate in the East Sea in the northwestern Pacific ocean H. Kim et al. 10.1016/j.marpolbul.2019.110610
- Agriculture driven nitrogen wet deposition in a karst catchment in southwest China J. Zeng et al. 10.1016/j.agee.2020.106883
- Characterization of organic aerosols from a Chinese megacity during winter: predominance of fossil fuel combustion M. Haque et al. 10.5194/acp-19-5147-2019
- Formation Mechanisms and Source Apportionments of Airborne Nitrate Aerosols at a Himalayan-Tibetan Plateau Site: Insights from Nitrogen and Oxygen Isotopic Compositions Y. Lin et al. 10.1021/acs.est.1c03957
- Formation pathways and sources of size-segregated nitrate aerosols in a megacity identified by dual isotopes Y. Zhu et al. 10.1016/j.atmosenv.2021.118708
- Important contribution of N2O5 hydrolysis to the daytime nitrate in Xi'an, China during haze periods: Isotopic analysis and WRF-Chem model simulation C. Wu et al. 10.1016/j.envpol.2021.117712
- Isotopic evaluation on relative contributions of major NOx sources to nitrate of PM2.5 in Beijing W. Song et al. 10.1016/j.envpol.2019.01.081
- Changes of Emission Sources to Nitrate Aerosols in Beijing After the Clean Air Actions: Evidence From Dual Isotope Compositions M. Fan et al. 10.1029/2019JD031998
- Comprehensive Insights Into O 3 Changes During the COVID‐19 From O 3 Formation Regime and Atmospheric Oxidation Capacity S. Zhu et al. 10.1029/2021GL093668
- Seasonal differences in sources and formation processes of PM2.5 nitrate in an urban environment of North China Y. Li et al. 10.1016/j.jes.2021.08.020
- Dual-modelling-based source apportionment of NOx in five Chinese megacities: Providing the isotopic footprint from 2013 to 2014 Z. Zong et al. 10.1016/j.envint.2020.105592
- Combining dual isotopes and a Bayesian isotope mixing model to quantify the nitrate sources of precipitation in Ningbo, East China Y. Shi et al. 10.1016/j.scitotenv.2021.146297
- Fossil-driven secondary inorganic PM2.5 enhancement in the North China Plain: Evidence from carbon and nitrogen isotopes S. Lim et al. 10.1016/j.envpol.2020.115163
- Nitrogen isotopes in nitrate aerosols collected in the remote marine boundary layer: Implications for nitrogen isotopic fractionations among atmospheric reactive nitrogen species J. Li et al. 10.1016/j.atmosenv.2020.118028
- Differentiation Between Nitrate Aerosol Formation Pathways in a Southeast Chinese City by Dual Isotope and Modeling Studies H. Xiao et al. 10.1029/2020JD032604
- Nitrate sources and formation of rainwater constrained by dual isotopes in Southeast Asia: Example from Singapore C. Li et al. 10.1016/j.chemosphere.2019.125024
- Diurnal and seasonal variations in water-soluble inorganic ions and nitrate dual isotopes of PM2.5: Implications for source apportionment and formation processes of urban aerosol nitrate Q. Li et al. 10.1016/j.atmosres.2020.105197
- Assessing Contributions of Agricultural and Nonagricultural Emissions to Atmospheric Ammonia in a Chinese Megacity Y. Chang et al. 10.1021/acs.est.8b05984
- Stable carbon and nitrogen isotope ratio in PM1 and size segregated aerosol particles over the Baltic Sea I. Garbarienė et al. 10.3952/physics.v59i3.4082
- Enhanced Primary Production in the Oligotrophic South China Sea Related to Southeast Asian Forest Fires H. Xiao et al. 10.1029/2019JC015663
- Isotopic constraints on the atmospheric sources and formation of nitrogenous species in clouds influenced by biomass burning Y. Chang et al. 10.5194/acp-19-12221-2019
- Evidence of a Large Bias in Rooftop Measurements of Atmospheric Ammonia Y. Kuang et al. 10.1021/acsearthspacechem.1c00331
- Multi isotope systematics of precipitation to trace the sources of air pollutants in Seoul, Korea Y. Kim et al. 10.1016/j.envpol.2021.117548
- The observation of isotopic compositions of atmospheric nitrate in Shanghai China and its implication for reactive nitrogen chemistry P. He et al. 10.1016/j.scitotenv.2020.136727
- Impact of Coal Replacing Project on atmospheric fine aerosol nitrate loading and formation pathways in urban Tianjin: Insights from chemical composition and 15N and 18O isotope ratios X. Feng et al. 10.1016/j.scitotenv.2019.134797
- Isotopic advances in understanding reactive nitrogen deposition and atmospheric processing E. Elliott et al. 10.1016/j.scitotenv.2018.12.177
- High resolution, extreme isotopic variability of precipitation nitrate L. Rose et al. 10.1016/j.atmosenv.2019.03.012
- Quantifying the nitrogen isotope effects during photochemical equilibrium between NO and NO<sub>2</sub>: implications for <i>δ</i><sup>15</sup>N in tropospheric reactive nitrogen J. Li et al. 10.5194/acp-20-9805-2020
- Heterogeneous formation of particulate nitrate under ammonium-rich regimes during the high-PM<sub>2.5</sub> events in Nanjing, China Y. Lin et al. 10.5194/acp-20-3999-2020
- Nitrogen isotope differences between atmospheric nitrate and corresponding nitrogen oxides: A new constraint using oxygen isotopes W. Song et al. 10.1016/j.scitotenv.2019.134515
- Ion‐exchange resin and denitrification pretreatment for determining δ 15 N‐NH 4 + , δ 15 N‐NO 3 − , and δ 18 O‐NO 3 − values H. Kawashima et al. 10.1002/rcm.9027
- Insight into the Variability of the Nitrogen Isotope Composition of Vehicular NOx in China Z. Zong et al. 10.1021/acs.est.0c04749
- The importance of coal combustion and heterogeneous reaction for atmospheric nitrate pollution in a cold metropolis in China: Insights from isotope fractionation and Bayesian mixing model X. Sun et al. 10.1016/j.atmosenv.2020.117730
- New Constraints on Isotopic Effects and Major Sources of Nitrate in Atmospheric Particulates by Combining δ 15 N and Δ 17 O Signatures W. Song et al. 10.1029/2020JD034168
- Nitrate aerosol formation and source assessment in winter at different regions in Northeast China Z. Zhao et al. 10.1016/j.atmosenv.2021.118767
- Nitrate isotopic composition of sequential Hurricane Harvey wet deposition: Low latitude NOx sources and oxidation chemistry J. David Felix & D. Murgulet 10.1016/j.atmosenv.2020.117748
- Coal and biomass burning as major emissions of NOX in Northeast China: Implication from dual isotopes analysis of fine nitrate aerosols Z. Zhao et al. 10.1016/j.atmosenv.2020.117762
- Stable 15N isotopes in fine and coarse urban particulate matter H. Wiedenhaus et al. 10.1080/02786826.2021.1905150
- Isotope-based source apportionment of nitrogen-containing aerosols: A case study in an industrial city in China M. Fan et al. 10.1016/j.atmosenv.2019.05.020
- Determination of Stable Nitrogen and Oxygen Isotope Ratios in Atmospheric Aerosol Nitrates Z. ZHAO et al. 10.1016/S1872-2040(19)61166-7
- Chemical characterization and stable nitrogen isotope composition of nitrogenous component of ambient aerosols from Kanpur in the Indo-Gangetic Plains G. Singh et al. 10.1016/j.scitotenv.2020.143032
- The use of stable oxygen and nitrogen isotopic signatures to reveal variations in the nitrate formation pathways and sources in different seasons and regions in China W. Guo et al. 10.1016/j.envres.2021.111537
- Nitrate Isotopic Composition in Precipitation at a Chinese Megacity: Seasonal Variations, Atmospheric Processes, and Implications for Sources Z. Li et al. 10.1029/2019EA000759
- Using nitrogen and oxygen stable isotopes to analyze the major NOx sources to nitrate of PM2.5 in Lanzhou, northwest China, in winter-spring periods M. Yin et al. 10.1016/j.atmosenv.2022.119036
Latest update: 02 Feb 2023
Short summary
We demonstrate that it is imperative that future studies, making use of isotope mixing models to gain conclusive constraints on the source partitioning of atmospheric NOx, consider this N isotope fractionation. Future assessments of NOx emissions in China (and elsewhere) should involve simultaneous δ15N and δ18O measurements of atmospheric nitrate and NOx at high spatiotemporal resolution, allowing former N-isotope-based NOx source partitioning estimates to be reevaluated more quantitatively.
We demonstrate that it is imperative that future studies, making use of isotope mixing models to...
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