Articles | Volume 18, issue 16
Atmos. Chem. Phys., 18, 11581–11597, 2018
https://doi.org/10.5194/acp-18-11581-2018
© Author(s) 2018. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Special issue: In-depth study of air pollution sources and processes within...
Research article
16 Aug 2018
Research article
| 16 Aug 2018
Production of N2O5 and ClNO2 in summer in urban Beijing, China
Wei Zhou et al.
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38 citations as recorded by crossref.
- Global tropospheric halogen (Cl, Br, I) chemistry and its impact on oxidants X. Wang et al. 10.5194/acp-21-13973-2021
- Significant impact of heterogeneous reactions of reactive chlorine species on summertime atmospheric ozone and free-radical formation in north China X. Qiu et al. 10.1016/j.scitotenv.2019.133580
- Seasonal characterization of aerosol composition and sources in a polluted city in Central China Q. Wang et al. 10.1016/j.chemosphere.2020.127310
- Wintertime nitrate formation pathways in the north China plain: Importance of N2O5 heterogeneous hydrolysis L. Liu et al. 10.1016/j.envpol.2020.115287
- Impacts of chlorine chemistry and anthropogenic emissions on secondary pollutants in the Yangtze river delta region J. Li et al. 10.1016/j.envpol.2021.117624
- Heterogeneous Uptake of N2O5 in Sand Dust and Urban Aerosols Observed during the Dry Season in Beijing M. Xia et al. 10.3390/atmos10040204
- Halogens Enhance Haze Pollution in China Q. Li et al. 10.1021/acs.est.1c01949
- Vertical characterization of aerosol optical properties and brown carbon in winter in urban Beijing, China C. Xie et al. 10.5194/acp-19-165-2019
- Modeling the impact of heterogeneous reactions of chlorine on summertime nitrate formation in Beijing, China X. Qiu et al. 10.5194/acp-19-6737-2019
- Anthropogenic emissions of atomic chlorine precursors in the Yangtze River Delta region, China X. Yi et al. 10.1016/j.scitotenv.2020.144644
- Assessment of the seasonal cycle of nitrate in PM2.5 using chemical compositions and stable nitrogen and oxygen isotopes at Nanchang, China L. Luo et al. 10.1016/j.atmosenv.2020.117371
- Seasonal effects of additional HONO sources and the heterogeneous reactions of N2O5 on nitrate in the North China Plain Y. Qu et al. 10.1016/j.scitotenv.2019.06.436
- Key Role of NO3 Radicals in the Production of Isoprene Nitrates and Nitrooxyorganosulfates in Beijing J. Hamilton et al. 10.1021/acs.est.0c05689
- Long-term characterization of aerosol chemistry in cold season from 2013 to 2020 in Beijing, China L. Lei et al. 10.1016/j.envpol.2020.115952
- Low-NO atmospheric oxidation pathways in a polluted megacity M. Newland et al. 10.5194/acp-21-1613-2021
- Stable oxygen isotope constraints on nitrate formation in Beijing in springtime L. Luo et al. 10.1016/j.envpol.2020.114515
- Atmospheric gaseous hydrochloric and hydrobromic acid in urban Beijing, China: detection, source identification and potential atmospheric impacts X. Fan et al. 10.5194/acp-21-11437-2021
- Introduction to the special issue “In-depth study of air pollution sources and processes within Beijing and its surrounding region (APHH-Beijing)” Z. Shi et al. 10.5194/acp-19-7519-2019
- Shipborne measurements of ClNO<sub>2</sub> in the Mediterranean Sea and around the Arabian Peninsula during summer P. Eger et al. 10.5194/acp-19-12121-2019
- Effects of Anthropogenic Chlorine on PM2.5 and Ozone Air Quality in China X. Wang et al. 10.1021/acs.est.0c02296
- Hygroscopic Properties of Saline Mineral Dust From Different Regions in China: Geographical Variations, Compositional Dependence, and Atmospheric Implications M. Tang et al. 10.1029/2019JD031128
- Observations of N2O5 and NO3 at a suburban environment in Yangtze river delta in China: Estimating heterogeneous N2O5 uptake coefficients Z. Li et al. 10.1016/j.jes.2020.04.041
- Submicron-scale aerosol above the city canopy in Beijing in spring based on in-situ meteorological tower measurements Q. Wang et al. 10.1016/j.atmosres.2022.106128
- Nocturnal atmospheric chemistry of NO3 and N2O5 over Changzhou in the Yangtze River Delta in China C. Lin et al. 10.1016/j.jes.2021.09.016
- Fast sulfate formation from oxidation of SO2 by NO2 and HONO observed in Beijing haze J. Wang et al. 10.1038/s41467-020-16683-x
- Role of Gas-Phase Halogen Bonding in Ambient Chemical Ionization Mass Spectrometry Utilizing Iodine J. Ganske et al. 10.1021/acsearthspacechem.9b00030
- Wintertime N2O5 uptake coefficients over the North China Plain H. Wang et al. 10.1016/j.scib.2020.02.006
- Evaluating the sensitivity of radical chemistry and ozone formation to ambient VOCs and NO<sub><i>x</i></sub> in Beijing L. Whalley et al. 10.5194/acp-21-2125-2021
- Response of aerosol chemistry to clean air action in Beijing, China: Insights from two-year ACSM measurements and model simulations W. Zhou et al. 10.1016/j.envpol.2019.113345
- Strong anthropogenic control of secondary organic aerosol formation from isoprene in Beijing D. Bryant et al. 10.5194/acp-20-7531-2020
- Multiphase Oxidation of Sulfur Dioxide in Aerosol Particles: Implications for Sulfate Formation in Polluted Environments T. Liu et al. 10.1021/acs.est.0c06496
- Heterogeneous Nitrate Production Mechanisms in Intense Haze Events in the North China Plain Y. Chan et al. 10.1029/2021JD034688
- A Large Source of Atomic Chlorine From ClNO 2 Photolysis at a U.K. Landfill Site T. Bannan et al. 10.1029/2019GL083764
- Nitrate formation from heterogeneous uptake of dinitrogen pentoxide during a severe winter haze in southern China H. Yun et al. 10.5194/acp-18-17515-2018
- Explosive Secondary Aerosol Formation during Severe Haze in the North China Plain J. Peng et al. 10.1021/acs.est.0c07204
- Intercomparison of nitrous acid (HONO) measurement techniques in a megacity (Beijing) L. Crilley et al. 10.5194/amt-12-6449-2019
- Winter ClNO<sub>2</sub> formation in the region of fresh anthropogenic emissions: seasonal variability and insights into daytime peaks in northern China M. Xia et al. 10.5194/acp-21-15985-2021
- Potential Effect of Halogens on Atmospheric Oxidation and Air Quality in China Q. Li et al. 10.1029/2019JD032058
38 citations as recorded by crossref.
- Global tropospheric halogen (Cl, Br, I) chemistry and its impact on oxidants X. Wang et al. 10.5194/acp-21-13973-2021
- Significant impact of heterogeneous reactions of reactive chlorine species on summertime atmospheric ozone and free-radical formation in north China X. Qiu et al. 10.1016/j.scitotenv.2019.133580
- Seasonal characterization of aerosol composition and sources in a polluted city in Central China Q. Wang et al. 10.1016/j.chemosphere.2020.127310
- Wintertime nitrate formation pathways in the north China plain: Importance of N2O5 heterogeneous hydrolysis L. Liu et al. 10.1016/j.envpol.2020.115287
- Impacts of chlorine chemistry and anthropogenic emissions on secondary pollutants in the Yangtze river delta region J. Li et al. 10.1016/j.envpol.2021.117624
- Heterogeneous Uptake of N2O5 in Sand Dust and Urban Aerosols Observed during the Dry Season in Beijing M. Xia et al. 10.3390/atmos10040204
- Halogens Enhance Haze Pollution in China Q. Li et al. 10.1021/acs.est.1c01949
- Vertical characterization of aerosol optical properties and brown carbon in winter in urban Beijing, China C. Xie et al. 10.5194/acp-19-165-2019
- Modeling the impact of heterogeneous reactions of chlorine on summertime nitrate formation in Beijing, China X. Qiu et al. 10.5194/acp-19-6737-2019
- Anthropogenic emissions of atomic chlorine precursors in the Yangtze River Delta region, China X. Yi et al. 10.1016/j.scitotenv.2020.144644
- Assessment of the seasonal cycle of nitrate in PM2.5 using chemical compositions and stable nitrogen and oxygen isotopes at Nanchang, China L. Luo et al. 10.1016/j.atmosenv.2020.117371
- Seasonal effects of additional HONO sources and the heterogeneous reactions of N2O5 on nitrate in the North China Plain Y. Qu et al. 10.1016/j.scitotenv.2019.06.436
- Key Role of NO3 Radicals in the Production of Isoprene Nitrates and Nitrooxyorganosulfates in Beijing J. Hamilton et al. 10.1021/acs.est.0c05689
- Long-term characterization of aerosol chemistry in cold season from 2013 to 2020 in Beijing, China L. Lei et al. 10.1016/j.envpol.2020.115952
- Low-NO atmospheric oxidation pathways in a polluted megacity M. Newland et al. 10.5194/acp-21-1613-2021
- Stable oxygen isotope constraints on nitrate formation in Beijing in springtime L. Luo et al. 10.1016/j.envpol.2020.114515
- Atmospheric gaseous hydrochloric and hydrobromic acid in urban Beijing, China: detection, source identification and potential atmospheric impacts X. Fan et al. 10.5194/acp-21-11437-2021
- Introduction to the special issue “In-depth study of air pollution sources and processes within Beijing and its surrounding region (APHH-Beijing)” Z. Shi et al. 10.5194/acp-19-7519-2019
- Shipborne measurements of ClNO<sub>2</sub> in the Mediterranean Sea and around the Arabian Peninsula during summer P. Eger et al. 10.5194/acp-19-12121-2019
- Effects of Anthropogenic Chlorine on PM2.5 and Ozone Air Quality in China X. Wang et al. 10.1021/acs.est.0c02296
- Hygroscopic Properties of Saline Mineral Dust From Different Regions in China: Geographical Variations, Compositional Dependence, and Atmospheric Implications M. Tang et al. 10.1029/2019JD031128
- Observations of N2O5 and NO3 at a suburban environment in Yangtze river delta in China: Estimating heterogeneous N2O5 uptake coefficients Z. Li et al. 10.1016/j.jes.2020.04.041
- Submicron-scale aerosol above the city canopy in Beijing in spring based on in-situ meteorological tower measurements Q. Wang et al. 10.1016/j.atmosres.2022.106128
- Nocturnal atmospheric chemistry of NO3 and N2O5 over Changzhou in the Yangtze River Delta in China C. Lin et al. 10.1016/j.jes.2021.09.016
- Fast sulfate formation from oxidation of SO2 by NO2 and HONO observed in Beijing haze J. Wang et al. 10.1038/s41467-020-16683-x
- Role of Gas-Phase Halogen Bonding in Ambient Chemical Ionization Mass Spectrometry Utilizing Iodine J. Ganske et al. 10.1021/acsearthspacechem.9b00030
- Wintertime N2O5 uptake coefficients over the North China Plain H. Wang et al. 10.1016/j.scib.2020.02.006
- Evaluating the sensitivity of radical chemistry and ozone formation to ambient VOCs and NO<sub><i>x</i></sub> in Beijing L. Whalley et al. 10.5194/acp-21-2125-2021
- Response of aerosol chemistry to clean air action in Beijing, China: Insights from two-year ACSM measurements and model simulations W. Zhou et al. 10.1016/j.envpol.2019.113345
- Strong anthropogenic control of secondary organic aerosol formation from isoprene in Beijing D. Bryant et al. 10.5194/acp-20-7531-2020
- Multiphase Oxidation of Sulfur Dioxide in Aerosol Particles: Implications for Sulfate Formation in Polluted Environments T. Liu et al. 10.1021/acs.est.0c06496
- Heterogeneous Nitrate Production Mechanisms in Intense Haze Events in the North China Plain Y. Chan et al. 10.1029/2021JD034688
- A Large Source of Atomic Chlorine From ClNO 2 Photolysis at a U.K. Landfill Site T. Bannan et al. 10.1029/2019GL083764
- Nitrate formation from heterogeneous uptake of dinitrogen pentoxide during a severe winter haze in southern China H. Yun et al. 10.5194/acp-18-17515-2018
- Explosive Secondary Aerosol Formation during Severe Haze in the North China Plain J. Peng et al. 10.1021/acs.est.0c07204
- Intercomparison of nitrous acid (HONO) measurement techniques in a megacity (Beijing) L. Crilley et al. 10.5194/amt-12-6449-2019
- Winter ClNO<sub>2</sub> formation in the region of fresh anthropogenic emissions: seasonal variability and insights into daytime peaks in northern China M. Xia et al. 10.5194/acp-21-15985-2021
- Potential Effect of Halogens on Atmospheric Oxidation and Air Quality in China Q. Li et al. 10.1029/2019JD032058
Latest update: 02 Jul 2022
Short summary
We present measurements of gas-phase N2O5 and ClNO2 by ToF-CIMS during summer in urban Beijing as part of the APHH campaign. High reactivity of N2O5 indicative of active nocturnal chemistry was observed. The lifetime of N2O5 as a function of aerosol surface area and relative humidity was characterized, and N2O5 uptake coefficients were estimated. We also found that the N2O5 loss in this study is mainly attributed to its indirect loss via reactions of NO3 with VOCs and NO.
We present measurements of gas-phase N2O5 and ClNO2 by ToF-CIMS during summer in urban Beijing...
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