Articles | Volume 17, issue 13
https://doi.org/10.5194/acp-17-8453-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-17-8453-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Diffusivity measurements of volatile organics in levitated viscous aerosol particles
Sandra Bastelberger
CORRESPONDING AUTHOR
Institute for Atmospheric and Climate Science, ETH Zurich, 8092 Zurich, Switzerland
Ulrich K. Krieger
Institute for Atmospheric and Climate Science, ETH Zurich, 8092 Zurich, Switzerland
Beiping Luo
Institute for Atmospheric and Climate Science, ETH Zurich, 8092 Zurich, Switzerland
Thomas Peter
Institute for Atmospheric and Climate Science, ETH Zurich, 8092 Zurich, Switzerland
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34 citations as recorded by crossref.
- Unified Description of Diffusion Coefficients from Small to Large Molecules in Organic–Water Mixtures E. Evoy et al. 10.1021/acs.jpca.9b11271
- Timescales of secondary organic aerosols to reach equilibrium at various temperatures and relative humidities Y. Li & M. Shiraiwa 10.5194/acp-19-5959-2019
- Transient cavity dynamics and divergence from the Stokes–Einstein equation in organic aerosol Y. Song et al. 10.1039/C9SC06228A
- Predictions of diffusion rates of large organic molecules in secondary organic aerosols using the Stokes–Einstein and fractional Stokes–Einstein relations E. Evoy et al. 10.5194/acp-19-10073-2019
- Non-Fickian diffusion in viscous aerosol particles T. Preston 10.1139/cjc-2021-0187
- Condensation Kinetics of Water on Amorphous Aerosol Particles N. Rothfuss et al. 10.1021/acs.jpclett.8b01365
- Effect of Decreased Temperature on the Evaporation of α-Pinene Secondary Organic Aerosol Particles Z. Li et al. 10.1021/acsearthspacechem.9b00240
- Kinetic Limitation to Inorganic Ion Diffusivity and to Coalescence of Inorganic Inclusions in Viscous Liquid–Liquid Phase-Separated Particles M. Fard et al. 10.1021/acs.jpca.7b05242
- Characterizing the hygroscopicity and volatility of single levitated aerosol dropletsviaoptical tweezers-Raman spectroscopy Y. Tong et al. 10.1039/D2VA00175F
- Global Distribution of the Phase State and Mixing Times within Secondary Organic Aerosol Particles in the Troposphere Based on Room-Temperature Viscosity Measurements A. Maclean et al. 10.1021/acsearthspacechem.1c00296
- The viscosity of atmospherically relevant organic particles J. Reid et al. 10.1038/s41467-018-03027-z
- Viscosity of erythritol and erythritol–water particles as a function of water activity: new results and an intercomparison of techniques for measuring the viscosity of particles Y. Chu et al. 10.5194/amt-11-4809-2018
- Mass, charge, and radius of droplets in a linear quadrupole electrodynamic balance J. Davies 10.1080/02786826.2018.1559921
- Photolytic radical persistence due to anoxia in viscous aerosol particles P. Alpert et al. 10.1038/s41467-021-21913-x
- Viscosities, diffusion coefficients, and mixing times of intrinsic fluorescent organic molecules in brown limonene secondary organic aerosol and tests of the Stokes–Einstein equation D. Ullmann et al. 10.5194/acp-19-1491-2019
- Diffusion of Organic Molecules as a Function of Temperature in a Sucrose Matrix (a Proxy for Secondary Organic Aerosol) K. Kiland et al. 10.1021/acs.jpclett.9b02182
- Exploring the hygroscopicity, water diffusivity, and viscosity of organic–inorganic aerosols – a case study on internally-mixed citric acid and ammonium sulfate particles C. Sheldon et al. 10.1039/D2EA00116K
- Correlating the Viscosity and Rate of Water Diffusion in Semisolid Gel-Forming Aerosol Particles C. Sheldon et al. 10.1021/acsearthspacechem.3c00241
- Electrodynamic balance–mass spectrometry of single particles as a new platform for atmospheric chemistry research A. Birdsall et al. 10.5194/amt-11-33-2018
- A rapid scan vacuum FTIR method for determining diffusion coefficients in viscous and glassy aerosol particles Y. Zhang et al. 10.1039/C7CP04473A
- Diffusion Coefficients and Mixing Times of Organic Molecules in β-Caryophyllene Secondary Organic Aerosol (SOA) and Biomass Burning Organic Aerosol (BBOA) E. Evoy et al. 10.1021/acsearthspacechem.1c00317
- Translation–deformation coupling effects on the Rayleigh instability of an electrodynamically levitated charged droplet N. Gawande et al. 10.1140/epje/s10189-022-00203-4
- Chemically Resolved Evaporation Dynamics of Dicarboxylic Acid Mixtures in Solid Particles R. Kaur Kohli et al. 10.1021/acs.analchem.3c02475
- Expiratory Aerosol pH: The Overlooked Driver of Airborne Virus Inactivation B. Luo et al. 10.1021/acs.est.2c05777
- Perspective: Aerosol microphysics: From molecules to the chemical physics of aerosols B. Bzdek & J. Reid 10.1063/1.5002641
- Predicting the glass transition temperature and viscosity of secondary organic material using molecular composition W. DeRieux et al. 10.5194/acp-18-6331-2018
- Amorphous phase state diagrams and viscosity of ternary aqueous organic/organic and inorganic/organic mixtures A. Marsh et al. 10.1039/C8CP00760H
- Liquid–liquid phase separation and viscosity within secondary organic aerosol generated from diesel fuel vapors M. Song et al. 10.5194/acp-19-12515-2019
- Breakdown of the Stokes–Einstein Equation for Solutions of Water in Oil Reverse Micelles M. Hoffmann et al. 10.1021/acs.jpcb.0c06124
- Carbon Dioxide Diffusivity in Single, Levitated Organic Aerosol Particles J. Dou et al. 10.1021/acs.jpclett.9b01389
- The relative humidity-dependent viscosity of single quasi aerosol particles and possible implications for atmospheric aerosol chemistry Y. Tong et al. 10.1039/D2CP00740A
- <i>α</i>-Pinene secondary organic aerosol at low temperature: chemical composition and implications for particle viscosity W. Huang et al. 10.5194/acp-18-2883-2018
- Modeling Volatility-Based Aerosol Phase State Predictions in the Amazon Rainforest Q. Rasool et al. 10.1021/acsearthspacechem.1c00255
- Evaporation of mixed citric acid/(NH4)2SO4/H2O particles: Volatility of organic aerosol by using optical tweezers X. Lv et al. 10.1016/j.saa.2019.117552
33 citations as recorded by crossref.
- Unified Description of Diffusion Coefficients from Small to Large Molecules in Organic–Water Mixtures E. Evoy et al. 10.1021/acs.jpca.9b11271
- Timescales of secondary organic aerosols to reach equilibrium at various temperatures and relative humidities Y. Li & M. Shiraiwa 10.5194/acp-19-5959-2019
- Transient cavity dynamics and divergence from the Stokes–Einstein equation in organic aerosol Y. Song et al. 10.1039/C9SC06228A
- Predictions of diffusion rates of large organic molecules in secondary organic aerosols using the Stokes–Einstein and fractional Stokes–Einstein relations E. Evoy et al. 10.5194/acp-19-10073-2019
- Non-Fickian diffusion in viscous aerosol particles T. Preston 10.1139/cjc-2021-0187
- Condensation Kinetics of Water on Amorphous Aerosol Particles N. Rothfuss et al. 10.1021/acs.jpclett.8b01365
- Effect of Decreased Temperature on the Evaporation of α-Pinene Secondary Organic Aerosol Particles Z. Li et al. 10.1021/acsearthspacechem.9b00240
- Kinetic Limitation to Inorganic Ion Diffusivity and to Coalescence of Inorganic Inclusions in Viscous Liquid–Liquid Phase-Separated Particles M. Fard et al. 10.1021/acs.jpca.7b05242
- Characterizing the hygroscopicity and volatility of single levitated aerosol dropletsviaoptical tweezers-Raman spectroscopy Y. Tong et al. 10.1039/D2VA00175F
- Global Distribution of the Phase State and Mixing Times within Secondary Organic Aerosol Particles in the Troposphere Based on Room-Temperature Viscosity Measurements A. Maclean et al. 10.1021/acsearthspacechem.1c00296
- The viscosity of atmospherically relevant organic particles J. Reid et al. 10.1038/s41467-018-03027-z
- Viscosity of erythritol and erythritol–water particles as a function of water activity: new results and an intercomparison of techniques for measuring the viscosity of particles Y. Chu et al. 10.5194/amt-11-4809-2018
- Mass, charge, and radius of droplets in a linear quadrupole electrodynamic balance J. Davies 10.1080/02786826.2018.1559921
- Photolytic radical persistence due to anoxia in viscous aerosol particles P. Alpert et al. 10.1038/s41467-021-21913-x
- Viscosities, diffusion coefficients, and mixing times of intrinsic fluorescent organic molecules in brown limonene secondary organic aerosol and tests of the Stokes–Einstein equation D. Ullmann et al. 10.5194/acp-19-1491-2019
- Diffusion of Organic Molecules as a Function of Temperature in a Sucrose Matrix (a Proxy for Secondary Organic Aerosol) K. Kiland et al. 10.1021/acs.jpclett.9b02182
- Exploring the hygroscopicity, water diffusivity, and viscosity of organic–inorganic aerosols – a case study on internally-mixed citric acid and ammonium sulfate particles C. Sheldon et al. 10.1039/D2EA00116K
- Correlating the Viscosity and Rate of Water Diffusion in Semisolid Gel-Forming Aerosol Particles C. Sheldon et al. 10.1021/acsearthspacechem.3c00241
- Electrodynamic balance–mass spectrometry of single particles as a new platform for atmospheric chemistry research A. Birdsall et al. 10.5194/amt-11-33-2018
- A rapid scan vacuum FTIR method for determining diffusion coefficients in viscous and glassy aerosol particles Y. Zhang et al. 10.1039/C7CP04473A
- Diffusion Coefficients and Mixing Times of Organic Molecules in β-Caryophyllene Secondary Organic Aerosol (SOA) and Biomass Burning Organic Aerosol (BBOA) E. Evoy et al. 10.1021/acsearthspacechem.1c00317
- Translation–deformation coupling effects on the Rayleigh instability of an electrodynamically levitated charged droplet N. Gawande et al. 10.1140/epje/s10189-022-00203-4
- Chemically Resolved Evaporation Dynamics of Dicarboxylic Acid Mixtures in Solid Particles R. Kaur Kohli et al. 10.1021/acs.analchem.3c02475
- Expiratory Aerosol pH: The Overlooked Driver of Airborne Virus Inactivation B. Luo et al. 10.1021/acs.est.2c05777
- Perspective: Aerosol microphysics: From molecules to the chemical physics of aerosols B. Bzdek & J. Reid 10.1063/1.5002641
- Predicting the glass transition temperature and viscosity of secondary organic material using molecular composition W. DeRieux et al. 10.5194/acp-18-6331-2018
- Amorphous phase state diagrams and viscosity of ternary aqueous organic/organic and inorganic/organic mixtures A. Marsh et al. 10.1039/C8CP00760H
- Liquid–liquid phase separation and viscosity within secondary organic aerosol generated from diesel fuel vapors M. Song et al. 10.5194/acp-19-12515-2019
- Breakdown of the Stokes–Einstein Equation for Solutions of Water in Oil Reverse Micelles M. Hoffmann et al. 10.1021/acs.jpcb.0c06124
- Carbon Dioxide Diffusivity in Single, Levitated Organic Aerosol Particles J. Dou et al. 10.1021/acs.jpclett.9b01389
- The relative humidity-dependent viscosity of single quasi aerosol particles and possible implications for atmospheric aerosol chemistry Y. Tong et al. 10.1039/D2CP00740A
- <i>α</i>-Pinene secondary organic aerosol at low temperature: chemical composition and implications for particle viscosity W. Huang et al. 10.5194/acp-18-2883-2018
- Modeling Volatility-Based Aerosol Phase State Predictions in the Amazon Rainforest Q. Rasool et al. 10.1021/acsearthspacechem.1c00255
Latest update: 23 Nov 2024
Short summary
We present quantitative condensed-phase diffusivity measurements of a volatile organic (tetraethylene glycol) in highly viscous single aerosol particles (aqueous sucrose). The condensed-phase diffusivity exhibits a strong temperature and humidity dependence. Our results suggest that diffusion limitations of volatile organics in highly viscous organic aerosol may severely impact gas–particle partitioning under cold and dry conditions.
We present quantitative condensed-phase diffusivity measurements of a volatile organic...
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