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Atmospheric Chemistry and Physics An interactive open-access journal of the European Geosciences Union
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Volume 17, issue 12
Atmos. Chem. Phys., 17, 7529–7540, 2017
https://doi.org/10.5194/acp-17-7529-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
Atmos. Chem. Phys., 17, 7529–7540, 2017
https://doi.org/10.5194/acp-17-7529-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.

Research article 22 Jun 2017

Research article | 22 Jun 2017

Uncertain Henry's law constants compromise equilibrium partitioning calculations of atmospheric oxidation products

Chen Wang et al.

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Short summary
Three property prediction methods are used to predict equilibrium partitioning coefficients for a set of 3414 compounds implicated in secondary organic aerosol formation. Partitioning from the gas phase to water is found to be much more uncertain than estimates of partitioning into the organic matter of aerosol. This uncertainty matters, as phase distribution is very different depending on which prediction method is applied.
Three property prediction methods are used to predict equilibrium partitioning coefficients for...
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