Articles | Volume 17, issue 11
https://doi.org/10.5194/acp-17-6631-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-17-6631-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
06 Jun 2017
Research article |
| 06 Jun 2017
Investigation of the β-pinene photooxidation by OH in the atmosphere simulation chamber SAPHIR
Martin Kaminski
Institute of Energy and Climate Research, IEK-8:
Troposphere, Forschungszentrum Jülich GmbH, Jülich, Germany
now at: Bundesamt für Verbraucherschutz, Abteilung 5 – Methodenstandardisierung, Referenzlaboratorien und Antibiotikaresistenz, Berlin, Germany
Hendrik Fuchs
Institute of Energy and Climate Research, IEK-8:
Troposphere, Forschungszentrum Jülich GmbH, Jülich, Germany
Ismail-Hakki Acir
Institute of Energy and Climate Research, IEK-8:
Troposphere, Forschungszentrum Jülich GmbH, Jülich, Germany
now at: Institute of Nutrition and Food Sciences, Food Chemistry, University of Bonn, Bonn, Germany
Birger Bohn
Institute of Energy and Climate Research, IEK-8:
Troposphere, Forschungszentrum Jülich GmbH, Jülich, Germany
Theo Brauers
Institute of Energy and Climate Research, IEK-8:
Troposphere, Forschungszentrum Jülich GmbH, Jülich, Germany
deceased
Hans-Peter Dorn
Institute of Energy and Climate Research, IEK-8:
Troposphere, Forschungszentrum Jülich GmbH, Jülich, Germany
Rolf Häseler
Institute of Energy and Climate Research, IEK-8:
Troposphere, Forschungszentrum Jülich GmbH, Jülich, Germany
Andreas Hofzumahaus
Institute of Energy and Climate Research, IEK-8:
Troposphere, Forschungszentrum Jülich GmbH, Jülich, Germany
Institute of Energy and Climate Research, IEK-8:
Troposphere, Forschungszentrum Jülich GmbH, Jülich, Germany
now at: State Key Joint Laboratory of Environmental Simulation and Pollution Control, College of Environmental Sciences and Engineering, Peking University, Beijing, China
Anna Lutz
Department of Chemistry and Molecular Biology, University of Gothenburg, Gothenburg, Sweden
Sascha Nehr
Institute of Energy and Climate Research, IEK-8:
Troposphere, Forschungszentrum Jülich GmbH, Jülich, Germany
now at: Verein Deutscher Ingenieure
e.V., Kommission Reinhaltung der Luft, Düsseldorf, Germany
Franz Rohrer
Institute of Energy and Climate Research, IEK-8:
Troposphere, Forschungszentrum Jülich GmbH, Jülich, Germany
Ralf Tillmann
Institute of Energy and Climate Research, IEK-8:
Troposphere, Forschungszentrum Jülich GmbH, Jülich, Germany
Luc Vereecken
Institute of Energy and Climate Research, IEK-8:
Troposphere, Forschungszentrum Jülich GmbH, Jülich, Germany
Institute of Energy and Climate Research, IEK-8:
Troposphere, Forschungszentrum Jülich GmbH, Jülich, Germany
Andreas Wahner
Institute of Energy and Climate Research, IEK-8:
Troposphere, Forschungszentrum Jülich GmbH, Jülich, Germany
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Cited
22 citations as recorded by crossref.
- Investigation of the <i>α</i>-pinene photooxidation by OH in the atmospheric simulation chamber SAPHIR M. Rolletter et al. 10.5194/acp-19-11635-2019
- Characterization of volatile organic compounds and submicron organic aerosol in a traffic environment S. Saarikoski et al. 10.5194/acp-23-2963-2023
- Synergistic O 3 + OH oxidation pathway to extremely low-volatility dimers revealed in β-pinene secondary organic aerosol C. Kenseth et al. 10.1073/pnas.1804671115
- Photooxidation of pinonaldehyde at ambient conditions investigated in the atmospheric simulation chamber SAPHIR M. Rolletter et al. 10.5194/acp-20-13701-2020
- A structure activity relationship for ring closure reactions in unsaturated alkylperoxy radicals L. Vereecken et al. 10.1039/D1CP02758A
- Long-term measurements of volatile organic compounds highlight the importance of sesquiterpenes for the atmospheric chemistry of a boreal forest H. Hellén et al. 10.5194/acp-18-13839-2018
- Characterization of trace aerosol compositions produced during the OH radical-initiated photooxidation of β-pinene P. Zhang et al. 10.1016/j.atmosenv.2019.04.060
- Impacts of six potential HONO sources on HOx budgets and SOA formation during a wintertime heavy haze period in the North China Plain J. Zhang et al. 10.1016/j.scitotenv.2019.05.100
- Investigation of the oxidation of methyl vinyl ketone (MVK) by OH radicals in the atmospheric simulation chamber SAPHIR H. Fuchs et al. 10.5194/acp-18-8001-2018
- Atmospheric photo-oxidation of myrcene: OH reaction rate constant, gas-phase oxidation products and radical budgets Z. Tan et al. 10.5194/acp-21-16067-2021
- Experimental and theoretical study on the impact of a nitrate group on the chemistry of alkoxy radicals A. Novelli et al. 10.1039/D0CP05555G
- Experimental chemical budgets of OH, HO2, and RO2 radicals in rural air in western Germany during the JULIAC campaign 2019 C. Cho et al. 10.5194/acp-23-2003-2023
- Evaluation of OH and HO<sub>2</sub> concentrations and their budgets during photooxidation of 2-methyl-3-butene-2-ol (MBO) in the atmospheric simulation chamber SAPHIR A. Novelli et al. 10.5194/acp-18-11409-2018
- Highly Oxygenated Organic Nitrates Formed from NO3 Radical-Initiated Oxidation of β-Pinene H. Shen et al. 10.1021/acs.est.1c03978
- Atmospheric photooxidation and ozonolysis of sabinene: reaction rate coefficients, product yields, and chemical budget of radicals J. Pang et al. 10.5194/acp-23-12631-2023
- Atmospheric photooxidation and ozonolysis of Δ<sup>3</sup>-carene and 3-caronaldehyde: rate constants and product yields L. Hantschke et al. 10.5194/acp-21-12665-2021
- Highly oxygenated organic molecule (HOM) formation in the isoprene oxidation by NO<sub>3</sub> radical D. Zhao et al. 10.5194/acp-21-9681-2021
- Perspective on Mechanism Development and Structure‐Activity Relationships for Gas‐Phase Atmospheric Chemistry L. Vereecken et al. 10.1002/kin.21172
- Investigation of the limonene photooxidation by OH at different NO concentrations in the atmospheric simulation chamber SAPHIR (Simulation of Atmospheric PHotochemistry In a large Reaction Chamber) J. Pang et al. 10.5194/acp-22-8497-2022
- Effect of Atmospheric Aging on Soot Particle Toxicity in Lung Cell Models at the Air–Liquid Interface: Differential Toxicological Impacts of Biogenic and Anthropogenic Secondary Organic Aerosols (SOAs) S. Offer et al. 10.1289/EHP9413
- Importance of isomerization reactions for OH radical regeneration from the photo-oxidation of isoprene investigated in the atmospheric simulation chamber SAPHIR A. Novelli et al. 10.5194/acp-20-3333-2020
- The Optical Properties of Limonene Secondary Organic Aerosols: The Role of NO3, OH, and O3 in the Oxidation Processes C. Peng et al. 10.1002/2017JD028090
21 citations as recorded by crossref.
- Investigation of the <i>α</i>-pinene photooxidation by OH in the atmospheric simulation chamber SAPHIR M. Rolletter et al. 10.5194/acp-19-11635-2019
- Characterization of volatile organic compounds and submicron organic aerosol in a traffic environment S. Saarikoski et al. 10.5194/acp-23-2963-2023
- Synergistic O 3 + OH oxidation pathway to extremely low-volatility dimers revealed in β-pinene secondary organic aerosol C. Kenseth et al. 10.1073/pnas.1804671115
- Photooxidation of pinonaldehyde at ambient conditions investigated in the atmospheric simulation chamber SAPHIR M. Rolletter et al. 10.5194/acp-20-13701-2020
- A structure activity relationship for ring closure reactions in unsaturated alkylperoxy radicals L. Vereecken et al. 10.1039/D1CP02758A
- Long-term measurements of volatile organic compounds highlight the importance of sesquiterpenes for the atmospheric chemistry of a boreal forest H. Hellén et al. 10.5194/acp-18-13839-2018
- Characterization of trace aerosol compositions produced during the OH radical-initiated photooxidation of β-pinene P. Zhang et al. 10.1016/j.atmosenv.2019.04.060
- Impacts of six potential HONO sources on HOx budgets and SOA formation during a wintertime heavy haze period in the North China Plain J. Zhang et al. 10.1016/j.scitotenv.2019.05.100
- Investigation of the oxidation of methyl vinyl ketone (MVK) by OH radicals in the atmospheric simulation chamber SAPHIR H. Fuchs et al. 10.5194/acp-18-8001-2018
- Atmospheric photo-oxidation of myrcene: OH reaction rate constant, gas-phase oxidation products and radical budgets Z. Tan et al. 10.5194/acp-21-16067-2021
- Experimental and theoretical study on the impact of a nitrate group on the chemistry of alkoxy radicals A. Novelli et al. 10.1039/D0CP05555G
- Experimental chemical budgets of OH, HO2, and RO2 radicals in rural air in western Germany during the JULIAC campaign 2019 C. Cho et al. 10.5194/acp-23-2003-2023
- Evaluation of OH and HO<sub>2</sub> concentrations and their budgets during photooxidation of 2-methyl-3-butene-2-ol (MBO) in the atmospheric simulation chamber SAPHIR A. Novelli et al. 10.5194/acp-18-11409-2018
- Highly Oxygenated Organic Nitrates Formed from NO3 Radical-Initiated Oxidation of β-Pinene H. Shen et al. 10.1021/acs.est.1c03978
- Atmospheric photooxidation and ozonolysis of sabinene: reaction rate coefficients, product yields, and chemical budget of radicals J. Pang et al. 10.5194/acp-23-12631-2023
- Atmospheric photooxidation and ozonolysis of Δ<sup>3</sup>-carene and 3-caronaldehyde: rate constants and product yields L. Hantschke et al. 10.5194/acp-21-12665-2021
- Highly oxygenated organic molecule (HOM) formation in the isoprene oxidation by NO<sub>3</sub> radical D. Zhao et al. 10.5194/acp-21-9681-2021
- Perspective on Mechanism Development and Structure‐Activity Relationships for Gas‐Phase Atmospheric Chemistry L. Vereecken et al. 10.1002/kin.21172
- Investigation of the limonene photooxidation by OH at different NO concentrations in the atmospheric simulation chamber SAPHIR (Simulation of Atmospheric PHotochemistry In a large Reaction Chamber) J. Pang et al. 10.5194/acp-22-8497-2022
- Effect of Atmospheric Aging on Soot Particle Toxicity in Lung Cell Models at the Air–Liquid Interface: Differential Toxicological Impacts of Biogenic and Anthropogenic Secondary Organic Aerosols (SOAs) S. Offer et al. 10.1289/EHP9413
- Importance of isomerization reactions for OH radical regeneration from the photo-oxidation of isoprene investigated in the atmospheric simulation chamber SAPHIR A. Novelli et al. 10.5194/acp-20-3333-2020
Latest update: 23 Apr 2024
Short summary
Monoterpenes emitted by trees are among the volatile organic compounds with the highest global emission rates. The atmospheric degradation of the monoterpene β-pinene was investigated in the atmosphere simulation chamber SAPHIR in Jülich under low NOx and atmospheric β-pinene concentrations. While the budget of OH was balanced, both OH and HO2 concentrations were underestimated in the simulation results. These observations suggest the existence of unaccounted sources of HO2.
Monoterpenes emitted by trees are among the volatile organic compounds with the highest global...
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