Articles | Volume 17, issue 11 
            
                
                    
                    
            
            
            https://doi.org/10.5194/acp-17-6611-2017
                    © Author(s) 2017. This work is distributed under 
the Creative Commons Attribution 3.0 License.
                the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-17-6611-2017
                    © Author(s) 2017. This work is distributed under 
the Creative Commons Attribution 3.0 License.
                the Creative Commons Attribution 3.0 License.
Influence of urban pollution on the production of organic particulate matter from isoprene epoxydiols in central Amazonia
Suzane S. de Sá
                                            School of Engineering and Applied Sciences, Harvard University, Cambridge,
Massachusetts, USA
                                        
                                    Brett B. Palm
                                            Department. of Chemistry & Biochemistry and Cooperative Institute for
Research in Environmental Sciences, University of Colorado, Boulder,
Colorado, USA
                                        
                                    Pedro Campuzano-Jost
                                            Department. of Chemistry & Biochemistry and Cooperative Institute for
Research in Environmental Sciences, University of Colorado, Boulder,
Colorado, USA
                                        
                                    Douglas A. Day
                                            Department. of Chemistry & Biochemistry and Cooperative Institute for
Research in Environmental Sciences, University of Colorado, Boulder,
Colorado, USA
                                        
                                    Matthew K. Newburn
                                            Environmental Molecular Sciences Laboratory, Pacific Northwest National
Laboratory, Richland, Washington, USA
                                        
                                    Weiwei Hu
                                            Department. of Chemistry & Biochemistry and Cooperative Institute for
Research in Environmental Sciences, University of Colorado, Boulder,
Colorado, USA
                                        
                                    Gabriel Isaacman-VanWertz
                                            Dept. of Environmental Science, Policy, and Management, University of
California, Berkeley, California, USA
                                        
                                    
                                            now at: Massachusetts Institute of Technology, Cambridge,
Massachusetts, USA
                                        
                                    Lindsay D. Yee
                                            Dept. of Environmental Science, Policy, and Management, University of
California, Berkeley, California, USA
                                        
                                    Ryan Thalman
                                            Brookhaven National Laboratory, Upton, New York, USA
                                        
                                    Joel Brito
                                            Departamento de Física Aplicada, Universidade de São Paulo, São
Paulo, Brazil
                                        
                                    
                                            now at: Laboratory for Meteorological Physics (LaMP), University
Blaise Pascal, Aubière, France
                                        
                                    Samara Carbone
                                            Departamento de Física Aplicada, Universidade de São Paulo, São
Paulo, Brazil
                                        
                                    Paulo Artaxo
                                            Departamento de Física Aplicada, Universidade de São Paulo, São
Paulo, Brazil
                                        
                                    Allen H. Goldstein
                                            Dept. of Environmental Science, Policy, and Management, University of
California, Berkeley, California, USA
                                        
                                    Antonio O. Manzi
                                            Instituto Nacional de Pesquisas da Amazonia, Manaus, Amazonas, Brazil
                                        
                                    Rodrigo A. F. Souza
                                            Escola Superior de Tecnologia, Universidade do Estado do Amazonas, Manaus,
Amazonas, Brazil
                                        
                                    
                                            Atmospheric Sciences and Global Change Division, Pacific Northwest National
Laboratory, Richland, WA, USA
                                        
                                    John E. Shilling
                                            Environmental Molecular Sciences Laboratory, Pacific Northwest National
Laboratory, Richland, Washington, USA
                                        
                                    
                                            Atmospheric Sciences and Global Change Division, Pacific Northwest National
Laboratory, Richland, WA, USA
                                        
                                    Stephen R. Springston
                                            Brookhaven National Laboratory, Upton, New York, USA
                                        
                                    Jian Wang
                                            Brookhaven National Laboratory, Upton, New York, USA
                                        
                                    Jason D. Surratt
                                            Department of Environmental Sciences and Engineering, Gillings School of
Global Public Health, The University of North Carolina at Chapel Hill,
Chapel Hill, North Carolina, USA
                                        
                                    M. Lizabeth Alexander
                                            Environmental Molecular Sciences Laboratory, Pacific Northwest National
Laboratory, Richland, Washington, USA
                                        
                                    Jose L. Jimenez
                                            Department. of Chemistry & Biochemistry and Cooperative Institute for
Research in Environmental Sciences, University of Colorado, Boulder,
Colorado, USA
                                        
                                    Scot T. Martin
CORRESPONDING AUTHOR
                                            
                                    
                                            School of Engineering and Applied Sciences, Harvard University, Cambridge,
Massachusetts, USA
                                        
                                    
                                            Department of Earth and Planetary Sciences, Harvard University, Cambridge,
Massachusetts, USA
                                        
                                    Viewed
                        
                            Total article views: 5,089 (including HTML, PDF, and XML)
                        
                            
                                
                                
                            
                                
                                
                            
                        
                        
                            Cumulative views and downloads 
                                         (calculated since 13 Dec 2016)
                        
                        
                            
                                
                            
                    
        
                    
                    | HTML | XML | Total | Supplement | BibTeX | EndNote | |
|---|---|---|---|---|---|---|
| 3,299 | 1,645 | 145 | 5,089 | 608 | 145 | 229 | 
- HTML: 3,299
 - PDF: 1,645
 - XML: 145
 - Total: 5,089
 - Supplement: 608
 - BibTeX: 145
 - EndNote: 229
 
                        
                            Total article views: 4,247 (including HTML, PDF, and XML)
                        
                            
                                
                                
                            
                                
                                
                            
                        
                        
                            Cumulative views and downloads 
                                         (calculated since 06 Jun 2017)
                        
                        
                            
                                
                            
                    
                    
                    | HTML | XML | Total | Supplement | BibTeX | EndNote | |
|---|---|---|---|---|---|---|
| 2,797 | 1,344 | 106 | 4,247 | 384 | 124 | 175 | 
- HTML: 2,797
 - PDF: 1,344
 - XML: 106
 - Total: 4,247
 - Supplement: 384
 - BibTeX: 124
 - EndNote: 175
 
                        
                            Total article views: 842 (including HTML, PDF, and XML)
                        
                            
                                
                                
                            
                                
                                
                            
                        
                        
                            Cumulative views and downloads 
                                         (calculated since 13 Dec 2016)
                        
                        
                            
                                
                            
                    
        
                
            | HTML | XML | Total | Supplement | BibTeX | EndNote | |
|---|---|---|---|---|---|---|
| 502 | 301 | 39 | 842 | 224 | 21 | 54 | 
- HTML: 502
 - PDF: 301
 - XML: 39
 - Total: 842
 - Supplement: 224
 - BibTeX: 21
 - EndNote: 54
 
Viewed (geographical distribution)
                                Total article views: 5,089 (including HTML, PDF, and XML)
                                
                                Thereof 5,089 with geography defined
                                    and 0 with unknown origin. 
                            
        
                            
                                Total article views: 4,247 (including HTML, PDF, and XML)
                                
                                Thereof 4,247 with geography defined
                                    and 0 with unknown origin. 
                            
        
                            
                                Total article views: 842 (including HTML, PDF, and XML)
                                
                                Thereof 837 with geography defined
                                    and 5 with unknown origin. 
                            
                    | Country | # | Views | % | 
|---|
| Country | # | Views | % | 
|---|
| Country | # | Views | % | 
|---|
| Total: | 0 | 
| HTML: | 0 | 
| PDF: | 0 | 
| XML: | 0 | 
- 1
 
1
                            | Total: | 0 | 
| HTML: | 0 | 
| PDF: | 0 | 
| XML: | 0 | 
- 1
 
1
                            | Total: | 0 | 
| HTML: | 0 | 
| PDF: | 0 | 
| XML: | 0 | 
- 1
 
1
                            Cited
43 citations as recorded by crossref.
- Chemical composition of ultrafine aerosol particles in central Amazonia during the wet season H. Glicker et al. 10.5194/acp-19-13053-2019
 - Identification and quantification of IEPOX in ambient aerosols, using electron and chemical ionization sources GC/MS as their trimethylsilyl ethers, and using H-NMR L. Li et al. 10.1016/j.scitotenv.2023.162186
 - Multi-year statistical and modeling analysis of submicrometer aerosol number size distributions at a rain forest site in Amazonia L. Varanda Rizzo et al. 10.5194/acp-18-10255-2018
 - Additional Benefits of Federal Air-Quality Rules: Model Estimates of Controllable Biogenic Secondary Organic Aerosol A. Carlton et al. 10.1021/acs.est.8b01869
 - Organosulfates from Dark Aqueous Reactions of Isoprene-Derived Epoxydiols Under Cloud and Fog Conditions: Kinetics, Mechanism, and Effect of Reaction Environment on Regioselectivity of Sulfate Addition S. Petters et al. 10.1021/acsearthspacechem.0c00293
 - Evaluation of Biogenic Organic Aerosols in the Amazon Rainforest Using WRF‐Chem With MOSAIC J. Mao et al. 10.1029/2021JD034913
 - The effects of isoprene and NOx on secondary organic aerosols formed through reversible and irreversible uptake to aerosol water M. El-Sayed et al. 10.5194/acp-18-1171-2018
 - Regional Similarities and NOx‐Related Increases in Biogenic Secondary Organic Aerosol in Summertime Southeastern United States J. Liu et al. 10.1029/2018JD028491
 - Assessing the role of anthropogenic and biogenic sources on PM1 over southern West Africa using aircraft measurements J. Brito et al. 10.5194/acp-18-757-2018
 - Influences of nitrogen oxides and isoprene on ozone-temperature relationships in the Amazon rain forest D. Wei et al. 10.1016/j.atmosenv.2019.02.044
 - Secondary organic aerosol formation from ambient air in an oxidation flow reactor in central Amazonia B. Palm et al. 10.5194/acp-18-467-2018
 - Isoprene photo-oxidation products quantify the effect of pollution on hydroxyl radicals over Amazonia Y. Liu et al. 10.1126/sciadv.aar2547
 - Largely underestimated production of isoprene epoxydiols (IEPOX) through high-NO oxidation pathways in urban areas S. Wang et al. 10.1038/s41612-025-01151-4
 - Development of a hydrophilic interaction liquid chromatography (HILIC) method for the chemical characterization of water-soluble isoprene epoxydiol (IEPOX)-derived secondary organic aerosol T. Cui et al. 10.1039/C8EM00308D
 - Secondary Organic Aerosol Formation from Isoprene: Selected Research, Historic Account and State of the Art M. Claeys & W. Maenhaut 10.3390/atmos12060728
 - Effects of anthropogenic pollutants on biogenic secondary organic aerosol formation in the atmosphere of Mt. Hua, China C. Wu et al. 10.5194/acp-25-11975-2025
 - Strong influence of black carbon on aerosol optical properties in central Amazonia during the fire season R. Stern et al. 10.5194/acp-25-9451-2025
 - African volcanic emissions influencing atmospheric aerosols over the Amazon rain forest J. Saturno et al. 10.5194/acp-18-10391-2018
 - Amazonian biogenic volatile organic compounds under global change A. Yáñez‐Serrano et al. 10.1111/gcb.15185
 - Rapid growth of anthropogenic organic nanoparticles greatly alters cloud life cycle in the Amazon rainforest R. Zaveri et al. 10.1126/sciadv.abj0329
 - Tropical and Boreal Forest – Atmosphere Interactions: A Review P. Artaxo et al. 10.16993/tellusb.34
 - Organosulfates in aerosols downwind of an urban region in central Amazon M. Glasius et al. 10.1039/C8EM00413G
 - Urban pollution greatly enhances formation of natural aerosols over the Amazon rainforest M. Shrivastava et al. 10.1038/s41467-019-08909-4
 - Increasing Isoprene Epoxydiol-to-Inorganic Sulfate Aerosol Ratio Results in Extensive Conversion of Inorganic Sulfate to Organosulfur Forms: Implications for Aerosol Physicochemical Properties M. Riva et al. 10.1021/acs.est.9b01019
 - Urban influence on the concentration and composition of submicron particulate matter in central Amazonia S. de Sá et al. 10.5194/acp-18-12185-2018
 - Observations of sesquiterpenes and their oxidation products in central Amazonia during the wet and dry seasons L. Yee et al. 10.5194/acp-18-10433-2018
 - CCN activity and organic hygroscopicity of aerosols downwind of an urban region in central Amazonia: seasonal and diel variations and impact of anthropogenic emissions R. Thalman et al. 10.5194/acp-17-11779-2017
 - Contributions of biomass-burning, urban, and biogenic emissions to the concentrations and light-absorbing properties of particulate matter in central Amazonia during the dry season S. de Sá et al. 10.5194/acp-19-7973-2019
 - Natural and Anthropogenically Influenced Isoprene Oxidation in Southeastern United States and Central Amazon L. Yee et al. 10.1021/acs.est.0c00805
 - Anthropogenic influences on the physical state of submicron particulate matter over a tropical forest A. Bateman et al. 10.5194/acp-17-1759-2017
 - Ground-based observation of clusters and nucleation-mode particles in the Amazon D. Wimmer et al. 10.5194/acp-18-13245-2018
 - Mixing states of Amazon basin aerosol particles transported over long distances using transmission electron microscopy K. Adachi et al. 10.5194/acp-20-11923-2020
 - Near-canopy horizontal concentration heterogeneity of semivolatile oxygenated organic compounds and implications for 2-methyltetrols primary emissions J. Ye et al. 10.1039/D0EA00006J
 - Exploration of oxidative chemistry and secondary organic aerosol formation in the Amazon during the wet season: explicit modeling of the Manaus urban plume with GECKO-A C. Mouchel-Vallon et al. 10.5194/acp-20-5995-2020
 - The sources and diurnal variations of submicron aerosols in a coastal–rural environment near Houston, US J. Li et al. 10.5194/acp-25-13975-2025
 - Aircraft observations of the chemical composition and aging of aerosol in the Manaus urban plume during GoAmazon 2014/5 J. Shilling et al. 10.5194/acp-18-10773-2018
 - Aircraft-based observations of isoprene-epoxydiol-derived secondary organic aerosol (IEPOX-SOA) in the tropical upper troposphere over the Amazon region C. Schulz et al. 10.5194/acp-18-14979-2018
 - Elemental Mixing State of Aerosol Particles Collected in Central Amazonia during GoAmazon2014/15 M. Fraund et al. 10.3390/atmos8090173
 - Contributions of mobile, stationary and biogenic sources to air pollution in the Amazon rainforest: a numerical study with the WRF-Chem model S. Abou Rafee et al. 10.5194/acp-17-7977-2017
 - Observations of Manaus urban plume evolution and interaction with biogenic emissions in GoAmazon 2014/5 G. Cirino et al. 10.1016/j.atmosenv.2018.08.031
 - Joint Impacts of Acidity and Viscosity on the Formation of Secondary Organic Aerosol from Isoprene Epoxydiols (IEPOX) in Phase Separated Particles Y. Zhang et al. 10.1021/acsearthspacechem.9b00209
 - Evaluation of the new capture vaporizer for aerosol mass spectrometers (AMS) through field studies of inorganic species W. Hu et al. 10.1080/02786826.2017.1296104
 - Limited formation of isoprene epoxydiols‐derived secondary organic aerosol under NOx‐rich environments in Eastern China Y. Zhang et al. 10.1002/2016GL072368
 
41 citations as recorded by crossref.
- Chemical composition of ultrafine aerosol particles in central Amazonia during the wet season H. Glicker et al. 10.5194/acp-19-13053-2019
 - Identification and quantification of IEPOX in ambient aerosols, using electron and chemical ionization sources GC/MS as their trimethylsilyl ethers, and using H-NMR L. Li et al. 10.1016/j.scitotenv.2023.162186
 - Multi-year statistical and modeling analysis of submicrometer aerosol number size distributions at a rain forest site in Amazonia L. Varanda Rizzo et al. 10.5194/acp-18-10255-2018
 - Additional Benefits of Federal Air-Quality Rules: Model Estimates of Controllable Biogenic Secondary Organic Aerosol A. Carlton et al. 10.1021/acs.est.8b01869
 - Organosulfates from Dark Aqueous Reactions of Isoprene-Derived Epoxydiols Under Cloud and Fog Conditions: Kinetics, Mechanism, and Effect of Reaction Environment on Regioselectivity of Sulfate Addition S. Petters et al. 10.1021/acsearthspacechem.0c00293
 - Evaluation of Biogenic Organic Aerosols in the Amazon Rainforest Using WRF‐Chem With MOSAIC J. Mao et al. 10.1029/2021JD034913
 - The effects of isoprene and NOx on secondary organic aerosols formed through reversible and irreversible uptake to aerosol water M. El-Sayed et al. 10.5194/acp-18-1171-2018
 - Regional Similarities and NOx‐Related Increases in Biogenic Secondary Organic Aerosol in Summertime Southeastern United States J. Liu et al. 10.1029/2018JD028491
 - Assessing the role of anthropogenic and biogenic sources on PM1 over southern West Africa using aircraft measurements J. Brito et al. 10.5194/acp-18-757-2018
 - Influences of nitrogen oxides and isoprene on ozone-temperature relationships in the Amazon rain forest D. Wei et al. 10.1016/j.atmosenv.2019.02.044
 - Secondary organic aerosol formation from ambient air in an oxidation flow reactor in central Amazonia B. Palm et al. 10.5194/acp-18-467-2018
 - Isoprene photo-oxidation products quantify the effect of pollution on hydroxyl radicals over Amazonia Y. Liu et al. 10.1126/sciadv.aar2547
 - Largely underestimated production of isoprene epoxydiols (IEPOX) through high-NO oxidation pathways in urban areas S. Wang et al. 10.1038/s41612-025-01151-4
 - Development of a hydrophilic interaction liquid chromatography (HILIC) method for the chemical characterization of water-soluble isoprene epoxydiol (IEPOX)-derived secondary organic aerosol T. Cui et al. 10.1039/C8EM00308D
 - Secondary Organic Aerosol Formation from Isoprene: Selected Research, Historic Account and State of the Art M. Claeys & W. Maenhaut 10.3390/atmos12060728
 - Effects of anthropogenic pollutants on biogenic secondary organic aerosol formation in the atmosphere of Mt. Hua, China C. Wu et al. 10.5194/acp-25-11975-2025
 - Strong influence of black carbon on aerosol optical properties in central Amazonia during the fire season R. Stern et al. 10.5194/acp-25-9451-2025
 - African volcanic emissions influencing atmospheric aerosols over the Amazon rain forest J. Saturno et al. 10.5194/acp-18-10391-2018
 - Amazonian biogenic volatile organic compounds under global change A. Yáñez‐Serrano et al. 10.1111/gcb.15185
 - Rapid growth of anthropogenic organic nanoparticles greatly alters cloud life cycle in the Amazon rainforest R. Zaveri et al. 10.1126/sciadv.abj0329
 - Tropical and Boreal Forest – Atmosphere Interactions: A Review P. Artaxo et al. 10.16993/tellusb.34
 - Organosulfates in aerosols downwind of an urban region in central Amazon M. Glasius et al. 10.1039/C8EM00413G
 - Urban pollution greatly enhances formation of natural aerosols over the Amazon rainforest M. Shrivastava et al. 10.1038/s41467-019-08909-4
 - Increasing Isoprene Epoxydiol-to-Inorganic Sulfate Aerosol Ratio Results in Extensive Conversion of Inorganic Sulfate to Organosulfur Forms: Implications for Aerosol Physicochemical Properties M. Riva et al. 10.1021/acs.est.9b01019
 - Urban influence on the concentration and composition of submicron particulate matter in central Amazonia S. de Sá et al. 10.5194/acp-18-12185-2018
 - Observations of sesquiterpenes and their oxidation products in central Amazonia during the wet and dry seasons L. Yee et al. 10.5194/acp-18-10433-2018
 - CCN activity and organic hygroscopicity of aerosols downwind of an urban region in central Amazonia: seasonal and diel variations and impact of anthropogenic emissions R. Thalman et al. 10.5194/acp-17-11779-2017
 - Contributions of biomass-burning, urban, and biogenic emissions to the concentrations and light-absorbing properties of particulate matter in central Amazonia during the dry season S. de Sá et al. 10.5194/acp-19-7973-2019
 - Natural and Anthropogenically Influenced Isoprene Oxidation in Southeastern United States and Central Amazon L. Yee et al. 10.1021/acs.est.0c00805
 - Anthropogenic influences on the physical state of submicron particulate matter over a tropical forest A. Bateman et al. 10.5194/acp-17-1759-2017
 - Ground-based observation of clusters and nucleation-mode particles in the Amazon D. Wimmer et al. 10.5194/acp-18-13245-2018
 - Mixing states of Amazon basin aerosol particles transported over long distances using transmission electron microscopy K. Adachi et al. 10.5194/acp-20-11923-2020
 - Near-canopy horizontal concentration heterogeneity of semivolatile oxygenated organic compounds and implications for 2-methyltetrols primary emissions J. Ye et al. 10.1039/D0EA00006J
 - Exploration of oxidative chemistry and secondary organic aerosol formation in the Amazon during the wet season: explicit modeling of the Manaus urban plume with GECKO-A C. Mouchel-Vallon et al. 10.5194/acp-20-5995-2020
 - The sources and diurnal variations of submicron aerosols in a coastal–rural environment near Houston, US J. Li et al. 10.5194/acp-25-13975-2025
 - Aircraft observations of the chemical composition and aging of aerosol in the Manaus urban plume during GoAmazon 2014/5 J. Shilling et al. 10.5194/acp-18-10773-2018
 - Aircraft-based observations of isoprene-epoxydiol-derived secondary organic aerosol (IEPOX-SOA) in the tropical upper troposphere over the Amazon region C. Schulz et al. 10.5194/acp-18-14979-2018
 - Elemental Mixing State of Aerosol Particles Collected in Central Amazonia during GoAmazon2014/15 M. Fraund et al. 10.3390/atmos8090173
 - Contributions of mobile, stationary and biogenic sources to air pollution in the Amazon rainforest: a numerical study with the WRF-Chem model S. Abou Rafee et al. 10.5194/acp-17-7977-2017
 - Observations of Manaus urban plume evolution and interaction with biogenic emissions in GoAmazon 2014/5 G. Cirino et al. 10.1016/j.atmosenv.2018.08.031
 - Joint Impacts of Acidity and Viscosity on the Formation of Secondary Organic Aerosol from Isoprene Epoxydiols (IEPOX) in Phase Separated Particles Y. Zhang et al. 10.1021/acsearthspacechem.9b00209
 
2 citations as recorded by crossref.
- Evaluation of the new capture vaporizer for aerosol mass spectrometers (AMS) through field studies of inorganic species W. Hu et al. 10.1080/02786826.2017.1296104
 - Limited formation of isoprene epoxydiols‐derived secondary organic aerosol under NOx‐rich environments in Eastern China Y. Zhang et al. 10.1002/2016GL072368
 
Discussed (final revised paper)
Latest update: 04 Nov 2025
Altmetrics
                
                Final-revised paper
            
            
                    Preprint