Articles | Volume 17, issue 11
https://doi.org/10.5194/acp-17-6583-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-17-6583-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
06 Jun 2017
Research article |
| 06 Jun 2017
Ozonolysis of α-phellandrene – Part 1: Gas- and particle-phase characterisation
Felix A. Mackenzie-Rae
CORRESPONDING AUTHOR
School of Molecular Sciences, The University of Western Australia, Crawley WA 6009, Australia
Tengyu Liu
State Key Laboratory of Organic Geochemistry and Guangdong Key Laboratory of Environmental Protection and Resources Utilization, Guangzhou Institute of
Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China
University of Chinese Academy of Sciences, Beijing 100049, China
now at: School of Energy and Environment, City University of Hong Kong, Hong Kong, China
State Key Laboratory of Organic Geochemistry and Guangdong Key Laboratory of Environmental Protection and Resources Utilization, Guangzhou Institute of
Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China
University of Chinese Academy of Sciences, Beijing 100049, China
Sandra M. Saunders
School of Molecular Sciences, The University of Western Australia, Crawley WA 6009, Australia
Zheng Fang
State Key Laboratory of Organic Geochemistry and Guangdong Key Laboratory of Environmental Protection and Resources Utilization, Guangzhou Institute of
Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China
University of Chinese Academy of Sciences, Beijing 100049, China
Yanli Zhang
State Key Laboratory of Organic Geochemistry and Guangdong Key Laboratory of Environmental Protection and Resources Utilization, Guangzhou Institute of
Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China
Center for Excellence in Regional Atmospheric Environment, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China
Xinming Wang
State Key Laboratory of Organic Geochemistry and Guangdong Key Laboratory of Environmental Protection and Resources Utilization, Guangzhou Institute of
Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China
Center for Excellence in Regional Atmospheric Environment, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China
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Cited
10 citations as recorded by crossref.
- Phytochemical composition, radical scavenging activities and molecular docking of essential oils from Bougainvillea formosa O. Odeja et al. https://doi.org/10.58985/jeopc.2026.v04i01.78
- Composition and volatility of secondary organic aerosol (SOA) formed from oxidation of real tree emissions compared to simplified volatile organic compound (VOC) systems A. Ylisirniö et al. https://doi.org/10.5194/acp-20-5629-2020
- Ozonolysis of α-phellandrene – Part 2: Compositional analysis of secondary organic aerosol highlights the role of stabilised Criegee intermediates F. Mackenzie-Rae et al. https://doi.org/10.5194/acp-18-4673-2018
- Kinetic and mechanistic study of the gas-phase reaction of ozone with γ-terpinene L. Fayad et al. https://doi.org/10.1016/j.atmosenv.2020.118073
- Formation of secondary organic aerosols from the reaction of γ-terpinene with ozone: yields and morphology L. Fayad et al. https://doi.org/10.1016/j.atmosenv.2021.118600
- Revisiting the global budget of atmospheric glyoxal: updates on terrestrial and marine precursor emissions, chemistry, and impacts on atmospheric oxidation capacity A. Zhang et al. https://doi.org/10.5194/acp-26-5123-2026
- Potential of Climate Change and Herbivory to Affect the Release and Atmospheric Reactions of BVOCs from Boreal and Subarctic Forests H. Yu et al. https://doi.org/10.3390/molecules26082283
- Characterization and Quantification of Particle-Bound Criegee Intermediates in Secondary Organic Aerosol S. Campbell et al. https://doi.org/10.1021/acs.est.2c04101
- A Narrative Review on the Bioactivity and Health Benefits of Alpha-Phellandrene S. Thangaleela et al. https://doi.org/10.3390/scipharm90040057
- Compilation of reaction kinetics parameters determined in the Key Development Project for Air Pollution Formation Mechanism and Control Technologies in China Y. Liu et al. https://doi.org/10.1016/j.jes.2022.06.021
10 citations as recorded by crossref.
- Phytochemical composition, radical scavenging activities and molecular docking of essential oils from Bougainvillea formosa O. Odeja et al. https://doi.org/10.58985/jeopc.2026.v04i01.78
- Composition and volatility of secondary organic aerosol (SOA) formed from oxidation of real tree emissions compared to simplified volatile organic compound (VOC) systems A. Ylisirniö et al. https://doi.org/10.5194/acp-20-5629-2020
- Ozonolysis of α-phellandrene – Part 2: Compositional analysis of secondary organic aerosol highlights the role of stabilised Criegee intermediates F. Mackenzie-Rae et al. https://doi.org/10.5194/acp-18-4673-2018
- Kinetic and mechanistic study of the gas-phase reaction of ozone with γ-terpinene L. Fayad et al. https://doi.org/10.1016/j.atmosenv.2020.118073
- Formation of secondary organic aerosols from the reaction of γ-terpinene with ozone: yields and morphology L. Fayad et al. https://doi.org/10.1016/j.atmosenv.2021.118600
- Revisiting the global budget of atmospheric glyoxal: updates on terrestrial and marine precursor emissions, chemistry, and impacts on atmospheric oxidation capacity A. Zhang et al. https://doi.org/10.5194/acp-26-5123-2026
- Potential of Climate Change and Herbivory to Affect the Release and Atmospheric Reactions of BVOCs from Boreal and Subarctic Forests H. Yu et al. https://doi.org/10.3390/molecules26082283
- Characterization and Quantification of Particle-Bound Criegee Intermediates in Secondary Organic Aerosol S. Campbell et al. https://doi.org/10.1021/acs.est.2c04101
- A Narrative Review on the Bioactivity and Health Benefits of Alpha-Phellandrene S. Thangaleela et al. https://doi.org/10.3390/scipharm90040057
- Compilation of reaction kinetics parameters determined in the Key Development Project for Air Pollution Formation Mechanism and Control Technologies in China Y. Liu et al. https://doi.org/10.1016/j.jes.2022.06.021
Saved (final revised paper)
Latest update: 23 Oct 2026
Short summary
The atmospheric decomposition of the biogenic α-phellandrene with ozone is characterised by conducting carefully controlled experiments in a smog chamber. Major gas-phase products are identified based on theoretical/mechanism insight, with yields quantified. Meanwhile, a significant amount of aerosol is formed and characterised, with Criegee intermediates found to be important for new particle formation. It is concluded that α-phellandrene contributes to aerosol formation/growth where emitted.
The atmospheric decomposition of the biogenic α-phellandrene with ozone is characterised by...
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