Articles | Volume 17, issue 10
https://doi.org/10.5194/acp-17-6373-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-17-6373-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
29 May 2017
Research article |
| 29 May 2017
Chemical and isotopic composition of secondary organic aerosol generated by α-pinene ozonolysis
Department of Chemistry, University of Copenhagen, 2100, Copenhagen Ø, Denmark
now at: Airlabs, 2200, Copenhagen N, Denmark
Ulrike Dusek
Institute for Marine and Atmospheric research Utrecht (IMAU), Utrecht University, 3584 CC, Utrecht, the Netherlands
Centre for Isotope Research, Energy and Sustainability Research Institute Groningen, 9747 AG Groningen, the Netherlands
Stephanie M. King
Department of Chemistry, University of Copenhagen, 2100, Copenhagen Ø, Denmark
now at: Haldor Topsøe A/S, 2800, Kgs. Lyngby, Denmark
Rupert Holzinger
Institute for Marine and Atmospheric research Utrecht (IMAU), Utrecht University, 3584 CC, Utrecht, the Netherlands
Thomas Rosenørn
Department of Chemistry, University of Copenhagen, 2100, Copenhagen Ø, Denmark
Infuser ApS, 2200, Copenhagen N, Denmark
Peter Sperlich
Max-Planck Institute for Biogeochemistry, 07745 Jena, Germany
now at: National Institute of Water and Atmospheric Research (NIWA), Wellington 6021, New Zealand
Maxime Julien
CEISAM, UMR CNRS6230, BP 92208, Nantes 44322 cedex 3, France
Gerald S. Remaud
CEISAM, UMR CNRS6230, BP 92208, Nantes 44322 cedex 3, France
Merete Bilde
Department of Chemistry, University of Copenhagen, 2100, Copenhagen Ø, Denmark
now at: Aarhus University, Department of Chemistry, 8000 Aarhus C, Denmark
Thomas Röckmann
Institute for Marine and Atmospheric research Utrecht (IMAU), Utrecht University, 3584 CC, Utrecht, the Netherlands
Matthew S. Johnson
Department of Chemistry, University of Copenhagen, 2100, Copenhagen Ø, Denmark
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Cited
18 citations as recorded by crossref.
- Evaluating the Impact of Increased Heavy Oil Consumption on Urban Pollution Levels through Isotope (δ13C, δ34S, 14C) Composition L. Bučinskas et al. 10.3390/atmos15080883
- On the formation of highly oxidized pollutants by autoxidation of terpenes under low-temperature-combustion conditions: the case of limonene and α-pinene R. Benoit et al. 10.5194/acp-23-5715-2023
- Gas-to-particle partitioning of atmospheric water-soluble organic aerosols: Indications from high-resolution observations of stable carbon isotope H. Yu et al. 10.1016/j.atmosenv.2024.120494
- Reaction Kinetics of Organic Aerosol Studied by Droplet Assisted Ionization: Enhanced Reactivity in Droplets Relative to Bulk Solution Y. Zhang et al. 10.1021/jasms.0c00057
- Stable isotope compositions, source apportionment and transformation processes of carbonaceous aerosols in PM10 in the urban city of Hyderabad, India P. Attri et al. 10.1016/j.uclim.2024.102101
- Organic aerosol formation and aging processes in Beijing constrained by size-resolved measurements of radiocarbon and stable isotopic 13C H. Ni et al. 10.1016/j.envint.2021.106890
- The Ozonolysis of Terpenoids, a Pandora's Box of by-Products J. Hanson 10.3184/174751917X15064232103029
- Sources and atmospheric processing of size segregated aerosol particles revealed by stable carbon isotope ratios and chemical speciation A. Masalaite et al. 10.1016/j.envpol.2018.04.073
- Seasonal observation and source apportionment of carbonaceous aerosol from forested rural site (Lithuania) A. Masalaite et al. 10.1016/j.atmosenv.2021.118934
- Seasonal changes of sources and volatility of carbonaceous aerosol at urban, coastal and forest sites in Eastern Europe (Lithuania) A. Masalaite et al. 10.1016/j.atmosenv.2020.117374
- High contributions of fossil sources to more volatile organic aerosol H. Ni et al. 10.5194/acp-19-10405-2019
- Seasonal changes in stable carbon isotopic composition in the bulk aerosol and gas phases at a suburban site in Prague P. Vodička et al. 10.1016/j.scitotenv.2021.149767
- Carbon isotope seasonal characteristics of fine carbonaceous aerosol in Jinzhong City, Shanxi Province, China H. Bai et al. 10.1016/j.atmosenv.2020.118164
- The Sources and Atmospheric Processes of Strong Light‐Absorbing Components in Water Soluble Brown Carbon: Insights From a Multi‐Proxy Study of PM2.5 in 10 Chinese Cities Y. Mo et al. 10.1029/2023JD039512
- Non‐Fossil Origin Explains the Large Seasonal Variation of Highly Processed Organic Aerosol in the Northeastern Tibetan Plateau (3,200 m a.s.l.) H. Ni et al. 10.1029/2023GL104710
- Photodegradation of Secondary Organic Aerosols by Long-Term Exposure to Solar Actinic Radiation V. Baboomian et al. 10.1021/acsearthspacechem.0c00088
- Dual-isotope ratios of carbonaceous aerosols for seasonal observation and their assessment as source indicators A. Mašalaitė et al. 10.1016/j.scitotenv.2024.175094
- Characteristics, sources and evolution of fine aerosol (PM 1 ) at urban, coastal and forest background sites in Lithuania A. Masalaite et al. 10.1016/j.atmosenv.2016.10.038
17 citations as recorded by crossref.
- Evaluating the Impact of Increased Heavy Oil Consumption on Urban Pollution Levels through Isotope (δ13C, δ34S, 14C) Composition L. Bučinskas et al. 10.3390/atmos15080883
- On the formation of highly oxidized pollutants by autoxidation of terpenes under low-temperature-combustion conditions: the case of limonene and α-pinene R. Benoit et al. 10.5194/acp-23-5715-2023
- Gas-to-particle partitioning of atmospheric water-soluble organic aerosols: Indications from high-resolution observations of stable carbon isotope H. Yu et al. 10.1016/j.atmosenv.2024.120494
- Reaction Kinetics of Organic Aerosol Studied by Droplet Assisted Ionization: Enhanced Reactivity in Droplets Relative to Bulk Solution Y. Zhang et al. 10.1021/jasms.0c00057
- Stable isotope compositions, source apportionment and transformation processes of carbonaceous aerosols in PM10 in the urban city of Hyderabad, India P. Attri et al. 10.1016/j.uclim.2024.102101
- Organic aerosol formation and aging processes in Beijing constrained by size-resolved measurements of radiocarbon and stable isotopic 13C H. Ni et al. 10.1016/j.envint.2021.106890
- The Ozonolysis of Terpenoids, a Pandora's Box of by-Products J. Hanson 10.3184/174751917X15064232103029
- Sources and atmospheric processing of size segregated aerosol particles revealed by stable carbon isotope ratios and chemical speciation A. Masalaite et al. 10.1016/j.envpol.2018.04.073
- Seasonal observation and source apportionment of carbonaceous aerosol from forested rural site (Lithuania) A. Masalaite et al. 10.1016/j.atmosenv.2021.118934
- Seasonal changes of sources and volatility of carbonaceous aerosol at urban, coastal and forest sites in Eastern Europe (Lithuania) A. Masalaite et al. 10.1016/j.atmosenv.2020.117374
- High contributions of fossil sources to more volatile organic aerosol H. Ni et al. 10.5194/acp-19-10405-2019
- Seasonal changes in stable carbon isotopic composition in the bulk aerosol and gas phases at a suburban site in Prague P. Vodička et al. 10.1016/j.scitotenv.2021.149767
- Carbon isotope seasonal characteristics of fine carbonaceous aerosol in Jinzhong City, Shanxi Province, China H. Bai et al. 10.1016/j.atmosenv.2020.118164
- The Sources and Atmospheric Processes of Strong Light‐Absorbing Components in Water Soluble Brown Carbon: Insights From a Multi‐Proxy Study of PM2.5 in 10 Chinese Cities Y. Mo et al. 10.1029/2023JD039512
- Non‐Fossil Origin Explains the Large Seasonal Variation of Highly Processed Organic Aerosol in the Northeastern Tibetan Plateau (3,200 m a.s.l.) H. Ni et al. 10.1029/2023GL104710
- Photodegradation of Secondary Organic Aerosols by Long-Term Exposure to Solar Actinic Radiation V. Baboomian et al. 10.1021/acsearthspacechem.0c00088
- Dual-isotope ratios of carbonaceous aerosols for seasonal observation and their assessment as source indicators A. Mašalaitė et al. 10.1016/j.scitotenv.2024.175094
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Latest update: 20 Nov 2024
Short summary
Isotope studies can constrain budgets of secondary organic aerosol (SOA) that is pivotal to air pollution and climate. SOA from α-pinene ozonolysis was found to be enriched in 13C relative to the precursor. The observed difference in 13C between the gas and particle phases may arise from isotope-dependent changes in branching ratios. Alternatively, some gas-phase products involve carbon atoms from highly enriched and depleted sites, giving a non-kinetic origin to the observed fractionations.
Isotope studies can constrain budgets of secondary organic aerosol (SOA) that is pivotal to air...
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