Articles | Volume 17, issue 6
https://doi.org/10.5194/acp-17-4053-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Special issue:
https://doi.org/10.5194/acp-17-4053-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Technical note: Conversion of isoprene hydroxy hydroperoxides (ISOPOOHs) on metal environmental simulation chamber walls
Anne-Kathrin Bernhammer
Institute for Ion and Applied Physics, University of Innsbruck, 6020
Innsbruck, Austria
IONICON Analytik GmbH, 6020 Innsbruck, Austria
Martin Breitenlechner
Institute for Ion and Applied Physics, University of Innsbruck, 6020
Innsbruck, Austria
now at: John A. Paulson School of Engineering and Applied Sciences
and Department of Chemistry and Chemical Biology, Harvard University,
Cambridge, MA, USA
Frank N. Keutsch
John A. Paulson School of Engineering and Applied Sciences and
Department of Chemistry and Chemical Biology, Harvard University, Cambridge,
MA, USA
Institute for Ion and Applied Physics, University of Innsbruck, 6020
Innsbruck, Austria
IONICON Analytik GmbH, 6020 Innsbruck, Austria
Viewed
Total article views: 4,206 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 21 Oct 2016)
| HTML | XML | Total | Supplement | BibTeX | EndNote | |
|---|---|---|---|---|---|---|
| 2,654 | 1,379 | 173 | 4,206 | 560 | 183 | 246 |
- HTML: 2,654
- PDF: 1,379
- XML: 173
- Total: 4,206
- Supplement: 560
- BibTeX: 183
- EndNote: 246
Total article views: 3,669 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 24 Mar 2017)
| HTML | XML | Total | Supplement | BibTeX | EndNote | |
|---|---|---|---|---|---|---|
| 2,377 | 1,129 | 163 | 3,669 | 380 | 177 | 231 |
- HTML: 2,377
- PDF: 1,129
- XML: 163
- Total: 3,669
- Supplement: 380
- BibTeX: 177
- EndNote: 231
Total article views: 537 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 21 Oct 2016)
| HTML | XML | Total | Supplement | BibTeX | EndNote | |
|---|---|---|---|---|---|---|
| 277 | 250 | 10 | 537 | 180 | 6 | 15 |
- HTML: 277
- PDF: 250
- XML: 10
- Total: 537
- Supplement: 180
- BibTeX: 6
- EndNote: 15
Viewed (geographical distribution)
Total article views: 4,206 (including HTML, PDF, and XML)
Thereof 4,147 with geography defined
and 59 with unknown origin.
Total article views: 3,669 (including HTML, PDF, and XML)
Thereof 3,632 with geography defined
and 37 with unknown origin.
Total article views: 537 (including HTML, PDF, and XML)
Thereof 515 with geography defined
and 22 with unknown origin.
| Country | # | Views | % |
|---|
| Country | # | Views | % |
|---|
| Country | # | Views | % |
|---|
| Total: | 0 |
| HTML: | 0 |
| PDF: | 0 |
| XML: | 0 |
- 1
1
| Total: | 0 |
| HTML: | 0 |
| PDF: | 0 |
| XML: | 0 |
- 1
1
| Total: | 0 |
| HTML: | 0 |
| PDF: | 0 |
| XML: | 0 |
- 1
1
Cited
15 citations as recorded by crossref.
- Large contribution to secondary organic aerosol from isoprene cloud chemistry H. Lamkaddam et al. https://doi.org/10.1126/sciadv.abe2952
- Modelling the gas–particle partitioning and water uptake of isoprene-derived secondary organic aerosol at high and low relative humidity D. Amaladhasan et al. https://doi.org/10.5194/acp-22-215-2022
- A perspective on the reactions of organic peroxy radicals with HO2 N. Illmann https://doi.org/10.1039/D5EA00023H
- Exploring biogenic secondary organic aerosol using a PTRMS-CHARON in laboratory experiments: characterization and fingerprint analysis C. Ramírez-Romero et al. https://doi.org/10.5194/amt-19-3049-2026
- New particle formation from isoprene under upper-tropospheric conditions J. Shen et al. https://doi.org/10.1038/s41586-024-08196-0
- Measurement report: Source apportionment of volatile organic compounds at the remote high-altitude Maïdo observatory B. Verreyken et al. https://doi.org/10.5194/acp-21-12965-2021
- Advancing green analytical solutions: A review of proton transfer reaction mass spectrometry in atmospheric aerosol research Y. Li https://doi.org/10.1016/j.greeac.2024.100175
- Proton-Transfer-Reaction Mass Spectrometry: Applications in Atmospheric Sciences B. Yuan et al. https://doi.org/10.1021/acs.chemrev.7b00325
- The INNpinJeR: a new wall-free reactor for studying gas-phase reactions W. Scholz et al. https://doi.org/10.1039/D1EA00072A
- Synthesis and Characterization of Atmospherically Relevant Hydroxy Hydroperoxides P. Mettke et al. https://doi.org/10.3390/atmos13040507
- Rapid conversion of isoprene photooxidation products in terrestrial plants E. Canaval et al. https://doi.org/10.1038/s43247-020-00041-2
- Molecular understanding of new-particle formation from α-pinene between −50 and +25 °C M. Simon et al. https://doi.org/10.5194/acp-20-9183-2020
- Biomass burning emission disturbances of isoprene oxidation in a tropical forest F. Santos et al. https://doi.org/10.5194/acp-18-12715-2018
- Secondary Organic Aerosol (SOA) through Uptake of Isoprene Hydroxy Hydroperoxides (ISOPOOH) and its Oxidation Products P. Mettke et al. https://doi.org/10.1021/acsearthspacechem.2c00385
- Analysis of Volatile Organic Compound Product Distributions under Reduced NOx Conditions in the NSF NCAR Atmospheric Simulation Chamber: Implications for In Situ VOC Measurements E. Asher et al. https://doi.org/10.1021/acsearthspacechem.4c00407
15 citations as recorded by crossref.
- Large contribution to secondary organic aerosol from isoprene cloud chemistry H. Lamkaddam et al. https://doi.org/10.1126/sciadv.abe2952
- Modelling the gas–particle partitioning and water uptake of isoprene-derived secondary organic aerosol at high and low relative humidity D. Amaladhasan et al. https://doi.org/10.5194/acp-22-215-2022
- A perspective on the reactions of organic peroxy radicals with HO2 N. Illmann https://doi.org/10.1039/D5EA00023H
- Exploring biogenic secondary organic aerosol using a PTRMS-CHARON in laboratory experiments: characterization and fingerprint analysis C. Ramírez-Romero et al. https://doi.org/10.5194/amt-19-3049-2026
- New particle formation from isoprene under upper-tropospheric conditions J. Shen et al. https://doi.org/10.1038/s41586-024-08196-0
- Measurement report: Source apportionment of volatile organic compounds at the remote high-altitude Maïdo observatory B. Verreyken et al. https://doi.org/10.5194/acp-21-12965-2021
- Advancing green analytical solutions: A review of proton transfer reaction mass spectrometry in atmospheric aerosol research Y. Li https://doi.org/10.1016/j.greeac.2024.100175
- Proton-Transfer-Reaction Mass Spectrometry: Applications in Atmospheric Sciences B. Yuan et al. https://doi.org/10.1021/acs.chemrev.7b00325
- The INNpinJeR: a new wall-free reactor for studying gas-phase reactions W. Scholz et al. https://doi.org/10.1039/D1EA00072A
- Synthesis and Characterization of Atmospherically Relevant Hydroxy Hydroperoxides P. Mettke et al. https://doi.org/10.3390/atmos13040507
- Rapid conversion of isoprene photooxidation products in terrestrial plants E. Canaval et al. https://doi.org/10.1038/s43247-020-00041-2
- Molecular understanding of new-particle formation from α-pinene between −50 and +25 °C M. Simon et al. https://doi.org/10.5194/acp-20-9183-2020
- Biomass burning emission disturbances of isoprene oxidation in a tropical forest F. Santos et al. https://doi.org/10.5194/acp-18-12715-2018
- Secondary Organic Aerosol (SOA) through Uptake of Isoprene Hydroxy Hydroperoxides (ISOPOOH) and its Oxidation Products P. Mettke et al. https://doi.org/10.1021/acsearthspacechem.2c00385
- Analysis of Volatile Organic Compound Product Distributions under Reduced NOx Conditions in the NSF NCAR Atmospheric Simulation Chamber: Implications for In Situ VOC Measurements E. Asher et al. https://doi.org/10.1021/acsearthspacechem.4c00407
Saved (final revised paper)
Latest update: 04 Sep 2026
Short summary
Isoprene is the predominant non-methane compound emitted by the biosphere. In the atmosphere oxidation by OH under low NOx produces isoprene hydroxy hydroperoxides (ISOPOOHs). This work has found an effective conversion of ISOPOOHs to volatile carbonyls on metal environmental simulation chamber walls. Likely catalyzed decomposition reactions also occur for other hydroxyl hydroperoxides on metal surfaces.
Isoprene is the predominant non-methane compound emitted by the biosphere. In the atmosphere...
Special issue
Altmetrics
Final-revised paper
Preprint