Technical note: Conversion of isoprene hydroxy hydroperoxides (ISOPOOHs) on metal environmental simulation chamber walls

Bernhammer, Anne-Kathrin; Breitenlechner, Martin; Keutsch, Frank N.; Hansel, Armin

doi:https://doi.org/10.5194/acp-17-4053-2017

Articles | Volume 17, issue 6

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Articles | Volume 17, issue 6

https://doi.org/10.5194/acp-17-4053-2017

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https://doi.org/10.5194/acp-17-4053-2017

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Technical note

24 Mar 2017

Technical note |

| 24 Mar 2017

Technical note: Conversion of isoprene hydroxy hydroperoxides (ISOPOOHs) on metal environmental simulation chamber walls

Anne-Kathrin Bernhammer, Martin Breitenlechner, Frank N. Keutsch, and Armin Hansel

Anne-Kathrin Bernhammer

https://orcid.org/0000-0002-0614-3649

Institute for Ion and Applied Physics, University of Innsbruck, 6020 Innsbruck, Austria

IONICON Analytik GmbH, 6020 Innsbruck, Austria

Martin Breitenlechner

Institute for Ion and Applied Physics, University of Innsbruck, 6020 Innsbruck, Austria

now at: John A. Paulson School of Engineering and Applied Sciences and Department of Chemistry and Chemical Biology, Harvard University, Cambridge, MA, USA

Frank N. Keutsch

John A. Paulson School of Engineering and Applied Sciences and Department of Chemistry and Chemical Biology, Harvard University, Cambridge, MA, USA

Armin Hansel

CORRESPONDING AUTHOR

armin.hansel@uibk.ac.at

https://orcid.org/0000-0002-1062-2394

Institute for Ion and Applied Physics, University of Innsbruck, 6020 Innsbruck, Austria

IONICON Analytik GmbH, 6020 Innsbruck, Austria

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Views and downloads (calculated since 24 Mar 2017)

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Apr 2017	83	36	2	121
May 2017	47	27	3	77
Jun 2017	33	14	2	49
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Aug 2017	17	14	0	31
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Jan 2018	20	13	0	33
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Apr 2018	11	6	1	18
May 2018	13	12	1	26
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Oct 2020	9	9	2	20
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May 2021	13	9	1	23
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Apr 2022	9	9	0	18
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Oct 2023	43	4	1	48
Nov 2023	30	4	0	34
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Feb 2024	38	5	0	43
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Oct 2024	20	12	1	33
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Month	HTML	PDF	XML	Total
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Apr 2017	83	36	2	121
May 2017	47	27	3	77
Jun 2017	33	14	2	49
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Jan 2018	20	13	0	33
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Mar 2018	18	16	1	35
Apr 2018	11	6	1	18
May 2018	13	12	1	26
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Aug 2018	12	6	0	18
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Dec 2018	11	4	1	16
Jan 2019	4	5	0	9
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May 2020	9	6	0	15
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May 2021	13	9	1	23
Jun 2021	8	5	1	14
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Jan 2022	14	7	0	21
Feb 2022	13	8	1	22
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Apr 2022	9	9	0	18
May 2022	7	5	0	12
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Feb 2023	18	7	0	25
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May 2023	30	9	0	39
Jun 2023	40	6	3	49
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Aug 2023	40	8	3	51
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Oct 2023	43	4	1	48
Nov 2023	30	4	0	34
Dec 2023	40	7	2	49
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Feb 2024	38	5	0	43
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May 2024	14	8	3	25
Jun 2024	27	4	1	32
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Sep 2024	20	9	0	29
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Nov 2024	11	5	3	19
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Total article views: 481 (including HTML, PDF, and XML)

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Views and downloads (calculated since 21 Oct 2016)

Month	HTML	PDF	XML	Total
Mar 2017	199	57	6	262
Apr 2017	83	36	2	121
May 2017	47	27	3	77
Jun 2017	33	14	2	49
Jul 2017	24	10	0	34
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Apr 2023	12	9	0	21
May 2023	30	9	0	39
Jun 2023	40	6	3	49
Jul 2023	42	8	3	53
Aug 2023	40	8	3	51
Sep 2023	44	2	0	46
Oct 2023	43	4	1	48
Nov 2023	30	4	0	34
Dec 2023	40	7	2	49
Jan 2024	36	5	0	41
Feb 2024	38	5	0	43
Mar 2024	43	10	3	56
Apr 2024	37	12	2	51
May 2024	14	8	3	25
Jun 2024	27	4	1	32
Jul 2024	35	13	3	51
Aug 2024	22	10	2	34
Sep 2024	20	9	0	29
Oct 2024	20	12	1	33
Nov 2024	11	5	3	19
Dec 2024	17	7	1	25
Jan 2025	17	3	0	20
Feb 2025	31	11	1	43
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Cumulative views and downloads (calculated since 21 Oct 2016)

Month	HTML	PDF	XML	Total
Mar 2017	199	57	6	262
Apr 2017	83	36	2	121
May 2017	47	27	3	77
Jun 2017	33	14	2	49
Jul 2017	24	10	0	34
Aug 2017	17	14	0	31
Sep 2017	13	12	1	26
Oct 2017	17	7	1	25
Nov 2017	14	9	1	24
Dec 2017	10	6	0	16
Jan 2018	20	13	0	33
Feb 2018	11	12	0	23
Mar 2018	18	16	1	35
Apr 2018	11	6	1	18
May 2018	13	12	1	26
Jun 2018	8	11	2	21
Jul 2018	8	8	0	16
Aug 2018	12	6	0	18
Sep 2018	19	7	1	27
Oct 2018	19	4	2	25
Nov 2018	13	11	1	25
Dec 2018	11	4	1	16
Jan 2019	4	5	0	9
Feb 2019	14	6	0	20
Mar 2019	6	6	0	12
Apr 2019	10	11	0	21
May 2019	18	11	0	29
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Jul 2019	12	9	0	21
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Nov 2019	9	4	0	13
Dec 2019	5	5	0	10
Jan 2020	9	3	0	12
Feb 2020	12	6	1	19
Mar 2020	1	3	0	4
Apr 2020	5	6	0	11
May 2020	9	6	0	15
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May 2021	13	9	1	23
Jun 2021	8	5	1	14
Jul 2021	10	10	0	20
Aug 2021	4	6	1	11
Sep 2021	16	13	0	29
Oct 2021	10	34	1	45
Nov 2021	6	22	0	28
Dec 2021	7	2	0	9
Jan 2022	14	7	0	21
Feb 2022	13	8	1	22
Mar 2022	9	8	0	17
Apr 2022	9	9	0	18
May 2022	7	5	0	12
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Jan 2023	7	6	0	13
Feb 2023	18	7	0	25
Mar 2023	9	8	0	17
Apr 2023	12	9	0	21
May 2023	30	9	0	39
Jun 2023	40	6	3	49
Jul 2023	42	8	3	53
Aug 2023	40	8	3	51
Sep 2023	44	2	0	46
Oct 2023	43	4	1	48
Nov 2023	30	4	0	34
Dec 2023	40	7	2	49
Jan 2024	36	5	0	41
Feb 2024	38	5	0	43
Mar 2024	43	10	3	56
Apr 2024	37	12	2	51
May 2024	14	8	3	25
Jun 2024	27	4	1	32
Jul 2024	35	13	3	51
Aug 2024	22	10	2	34
Sep 2024	20	9	0	29
Oct 2024	20	12	1	33
Nov 2024	11	5	3	19
Dec 2024	17	7	1	25
Jan 2025	17	3	0	20
Feb 2025	31	11	1	43
Mar 2025	18	12	8	38

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China	2	721	22
Germany	3	278	8
Austria	4	119	3
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China	2	685	24
Germany	3	232	8
Austria	4	81	2
United Kingdom	5	71	2

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Germany	2	46	9
Austria	3	38	7
China	4	36	7
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Cited

Show all Final revised paper only Preprint only

12 citations as recorded by crossref.

Proton-Transfer-Reaction Mass Spectrometry: Applications in Atmospheric Sciences B. Yuan et al. 10.1021/acs.chemrev.7b00325
The INNpinJeR: a new wall-free reactor for studying gas-phase reactions W. Scholz et al. 10.1039/D1EA00072A
Large contribution to secondary organic aerosol from isoprene cloud chemistry H. Lamkaddam et al. 10.1126/sciadv.abe2952
Modelling the gas–particle partitioning and water uptake of isoprene-derived secondary organic aerosol at high and low relative humidity D. Amaladhasan et al. 10.5194/acp-22-215-2022
Synthesis and Characterization of Atmospherically Relevant Hydroxy Hydroperoxides P. Mettke et al. 10.3390/atmos13040507
New particle formation from isoprene under upper-tropospheric conditions J. Shen et al. 10.1038/s41586-024-08196-0
Rapid conversion of isoprene photooxidation products in terrestrial plants E. Canaval et al. 10.1038/s43247-020-00041-2
Molecular understanding of new-particle formation from α-pinene between −50 and +25 °C M. Simon et al. 10.5194/acp-20-9183-2020
Measurement report: Source apportionment of volatile organic compounds at the remote high-altitude Maïdo observatory B. Verreyken et al. 10.5194/acp-21-12965-2021
Biomass burning emission disturbances of isoprene oxidation in a tropical forest F. Santos et al. 10.5194/acp-18-12715-2018
Secondary Organic Aerosol (SOA) through Uptake of Isoprene Hydroxy Hydroperoxides (ISOPOOH) and its Oxidation Products P. Mettke et al. 10.1021/acsearthspacechem.2c00385
Advancing green analytical solutions: A review of proton transfer reaction mass spectrometry in atmospheric aerosol research Y. Li 10.1016/j.greeac.2024.100175

12 citations as recorded by crossref.

Proton-Transfer-Reaction Mass Spectrometry: Applications in Atmospheric Sciences B. Yuan et al. 10.1021/acs.chemrev.7b00325
The INNpinJeR: a new wall-free reactor for studying gas-phase reactions W. Scholz et al. 10.1039/D1EA00072A
Large contribution to secondary organic aerosol from isoprene cloud chemistry H. Lamkaddam et al. 10.1126/sciadv.abe2952
Modelling the gas–particle partitioning and water uptake of isoprene-derived secondary organic aerosol at high and low relative humidity D. Amaladhasan et al. 10.5194/acp-22-215-2022
Synthesis and Characterization of Atmospherically Relevant Hydroxy Hydroperoxides P. Mettke et al. 10.3390/atmos13040507
New particle formation from isoprene under upper-tropospheric conditions J. Shen et al. 10.1038/s41586-024-08196-0
Rapid conversion of isoprene photooxidation products in terrestrial plants E. Canaval et al. 10.1038/s43247-020-00041-2
Molecular understanding of new-particle formation from α-pinene between −50 and +25 °C M. Simon et al. 10.5194/acp-20-9183-2020
Measurement report: Source apportionment of volatile organic compounds at the remote high-altitude Maïdo observatory B. Verreyken et al. 10.5194/acp-21-12965-2021
Biomass burning emission disturbances of isoprene oxidation in a tropical forest F. Santos et al. 10.5194/acp-18-12715-2018
Secondary Organic Aerosol (SOA) through Uptake of Isoprene Hydroxy Hydroperoxides (ISOPOOH) and its Oxidation Products P. Mettke et al. 10.1021/acsearthspacechem.2c00385
Advancing green analytical solutions: A review of proton transfer reaction mass spectrometry in atmospheric aerosol research Y. Li 10.1016/j.greeac.2024.100175

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Short summary

Isoprene is the predominant non-methane compound emitted by the biosphere. In the atmosphere oxidation by OH under low NO_x produces isoprene hydroxy hydroperoxides (ISOPOOHs). This work has found an effective conversion of ISOPOOHs to volatile carbonyls on metal environmental simulation chamber walls. Likely catalyzed decomposition reactions also occur for other hydroxyl hydroperoxides on metal surfaces.

Isoprene is the predominant non-methane compound emitted by the biosphere. In the atmosphere...

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The CERN CLOUD experiment (ACP/AMT inter-journal SI)

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