Atmospheric Chemistry and Physics
Atmospheric Chemistry and Physics
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Articles | Volume 17, issue 6
Articles | Volume 17, issue 6
https://doi.org/10.5194/acp-17-4053-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
Special issue:
https://doi.org/10.5194/acp-17-4053-2017
© Author(s) 2017. This work is distributed under
the Creative Commons Attribution 3.0 License.
Articles | Volume 17, issue 6
Technical note
 | 
24 Mar 2017
Technical note |  | 24 Mar 2017

Technical note: Conversion of isoprene hydroxy hydroperoxides (ISOPOOHs) on metal environmental simulation chamber walls

Anne-Kathrin Bernhammer, Martin Breitenlechner, Frank N. Keutsch, and Armin Hansel

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Short summary
Isoprene is the predominant non-methane compound emitted by the biosphere. In the atmosphere oxidation by OH under low NOx produces isoprene hydroxy hydroperoxides (ISOPOOHs). This work has found an effective conversion of ISOPOOHs to volatile carbonyls on metal environmental simulation chamber walls. Likely catalyzed decomposition reactions also occur for other hydroxyl hydroperoxides on metal surfaces.
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